CN106751415A - A kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions and preparation method thereof - Google Patents
A kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions and preparation method thereof Download PDFInfo
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- CN106751415A CN106751415A CN201611197104.1A CN201611197104A CN106751415A CN 106751415 A CN106751415 A CN 106751415A CN 201611197104 A CN201611197104 A CN 201611197104A CN 106751415 A CN106751415 A CN 106751415A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2357/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08J2357/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2409/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2409/06—Copolymers with styrene
- C08J2409/08—Latex
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/54—Aqueous solutions or dispersions
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses a kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions and preparation method thereof, by following component by weight:Petropols:30~50 parts;Organic pigment:3~10 parts;Styrene butadiene rubber sbr emulsion:5~10 parts;EVA emulsions:10~15 parts;Styrene block copolymer(SBS) emulsion:4~9 parts;Modified milk agent:1~6 part;Water:20~40 parts.Preparation method is comprised the following steps:Prepare material, emulsion and water be prepared by mixing into seed soap lye, and be heated to liquid Petropols, shear the complex emulsions for obtaining primary colors by colloid mill, then with organic pigment dispersed with stirring, final production goes out the cold mixing cold-application high-viscosity chromatic complex emulsions of shades of colour.Material rigidity-toughness balanced, adhesiveness in the present invention are strong, good stability, water resistant are anti-skidding, good endurance, with good pavement performance.
Description
Technical field
It is made present invention relates particularly to a kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions and preparation method thereof
Standby cold mixing cold-application high-viscosity chromatic complex emulsions have cold mixing cold-application without heating, strongly adherent, low temperature resistant, high temperature resistance, color and luster
Persistently the features such as, the colored road surface that can be widely applied to various road surfaces is mated formation.
Background technology
Colorful Asphalt Pavement can trace back to the 1950's, be begun one's study from countries such as America and Europes, and this road surface not only may be used
Preferably coordinate with the art of architecture around road, and may also operate as the effect of beautifying city and induction traffic, and
The characteristic and style in a country or a city can also be embodied, the image and function in whole city is lifted.All the time, road
Road road surface only has the cement pavement of grey and the bituminous paving of black, and black absorbs heat to form huge thermal source, and this is urban heat island
The one of the main reasons that effect is formed.The birth of colored road surface alleviates this problem well.Colorful Asphalt Pavement in recent years
It is more and more in highway, the first-class place of road or square to build the times flavour of traffic as a kind of new paving technology
Use.The security warning of traffic engineering such as parking lot, Accident Area, cycle track etc. is widely used in American-European, Japan
And beautification.Each environmental area that colorful surface layer is widely used to life is developed so far, decoration, U.S. of sports equipment is common in
Change, business block, gardens cell, Tourism Concept luminous point etc..As can be seen here, colored road surface material possesses wide market using preceding
Scape.
The research of China's colored road surface starts from early 1980s, starts late, Chang An University Hao Pei texts in 1999
Etc. developing the serial color asphalt that performance can be comparable with high-quality asphalt, and on the bicycle lane of Chengdu provicial commander street
Making Experiment Road, using effect is good;Tongji University Lv Wei people etc. use two kinds of resins and the chromatic cementing agent of mineral oil first
Carry out the research of test method and performance, Wang Liquan of Shenyang Urban-Construction Asphalt Concrete Factory in 2003 etc. is also adopted by Petropols
The research of color asphalt has been carried out with mineral oil.At present, colored road surface material on the market is generally color resin particle
(MMA), heat mix color asphalt, colour-wash etc..These colored road surface generally existing poor adhesions, easily peeling, color and luster are inadequate
Bright-coloured, production mix and high temperature construction, high cost are expensive, easily the defect such as pollution, it is impossible to meet large-area construction and length
Effect keeps, therefore, it is difficult to be used widely.
The content of the invention
Goal of the invention:The present invention provides a kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions and its preparation side
Method, production cost is small, pollution less, it is waterproof antiwear, practical, it is bright-colored persistently.
Technical scheme:A kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions, described colored road surface cold mixing
Cold-application high-viscosity chromatic complex emulsions by following component by weight:Petropols:30~50 parts;Organic pigment:3~
10 parts;Styrene butadiene rubber sbr emulsion:5~10 parts;EVA emulsions:10~15 parts;Styrene block copolymer(SBS) emulsion:4~9
Part;Modified milk agent:1~6 part;Water:20~40 parts.
As optimization:The EVA emulsions are ethane-acetic acid ethyenyl(Vinyl acetate)Ester copolymer.The EVA emulsions exist
The VAM of high content is introduced in strand, so as to reduce crystallinity, pliability, impact resistance is improve, is filled out
Material intermiscibility and heat sealing performance.
As optimization:The modified milk agent splits fast curdled milk agent slowly for cation.
A kind of colored road surface described in basis preparation method of cold mixing cold-application high-viscosity chromatic complex emulsions, including following step
Suddenly:
Step one:Prepare material:Llowing group of materials is ready:Petropols, organic pigment, styrene butadiene rubber sbr emulsion, EVA
Emulsion, styrene block copolymer(SBS) emulsion, modified milk agent, water;
Step 2:50 DEG C are heated water to, then by styrene butadiene rubber sbr emulsion, EVA emulsions, styrene block copolymer(SBS)
Emulsion, modified milk agent mix in sequentially adding water in proportion, are again heated to 50 DEG C, and side heating change stirs, and is prepared into kind
Sub- soap lye;
Step 3:Petropols liquid is heated to 130 DEG C, is shown as liquid;
Step 4:Sheared by colloid mill, the seed soap lye obtained by step 2 is mixed with the Petropols liquid obtained by step 3
Shearing is closed, the complex emulsions of primary colors are obtained;
Step 5:Primary colors complex emulsions obtained by step 4 and organic pigment dispersed with stirring, final production are gone out into shades of colour
Cold mixing cold-application high-viscosity chromatic complex emulsions.
Beneficial effect:Colored road surface in present invention cold mixing cold-application high-viscosity chromatic complex emulsions in construction and mix all
Need not heat, cold mixing cold-application, energy-conserving and environment-protective will not cause harm to environment, and with excellent heat-resisting, anti-freezing property, not
At same temperature and external environment condition effect, the surface aging that the oxidation of ultraviolet is caused is effective against, its high-temperature stable
Property, water resistant skid resistance is high, can make the colored road surface of different colours with material of the present invention, it is bright in colour persistently, it is colour-fast.
Small, instant effect is invested in present invention production and application;Show as low volatile, energy saving and favorable environment;Improve
Workman's operating environment, reduces construction period, is truly realized ready access upon use.
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.
Specific embodiment one:
According to a kind of described colored road surface preparation method of cold mixing cold-application high-viscosity chromatic complex emulsions, a kind of purplish red is prepared
Cold mixing cold-laid pavement high-viscosity chromatic complex emulsions, mainly include the following steps that:
Step one:Prepare material:Llowing group of materials is ready:Petropols:30 parts;Organic pigment:3 parts;Styrene butadiene rubber sbr
Emulsion:5 parts;EVA emulsions:10 parts;Styrene block copolymer(SBS) emulsion:4 parts;Modified milk agent:1 part;Water:20 parts;
The EVA emulsions are ethane-acetic acid ethyenyl(Vinyl acetate)Ester copolymer.The EVA emulsions are introduced in strand
The VAM of high content, so as to reduce crystallinity, improves pliability, impact resistance, filler intermiscibility and Re Mi
Sealing property;
The modified milk agent splits fast curdled milk agent slowly for cation;
Step 2:50 DEG C are heated water to, then by styrene butadiene rubber sbr emulsion, EVA emulsions, styrene block copolymer(SBS)
Emulsion, modified milk agent mix in sequentially adding water in proportion, are again heated to 50 DEG C, and side heating change stirs, and is prepared into kind
Sub- soap lye;
Step 3:Petropols liquid is heated to 130 DEG C, is shown as liquid;
Step 4:Sheared by colloid mill, the seed soap lye obtained by step 2 is mixed with the Petropols liquid obtained by step 3
Shearing is closed, the complex emulsions of primary colors are obtained;
Step 5:Primary colors complex emulsions obtained by step 4 and purplish red mill base dispersed with stirring, final production are gone out into various face
The cold mixing cold-application high-viscosity chromatic complex emulsions of color.
Specific embodiment two:
According to a kind of described colored road surface preparation method of cold mixing cold-application high-viscosity chromatic complex emulsions, a kind of grass green is prepared
Cold mixing cold-laid pavement high-viscosity chromatic complex emulsions, mainly include the following steps that:
Step one:Prepare material:Llowing group of materials is ready:Petropols:50 parts;Organic pigment:10 parts;Butadiene-styrene rubber
SBR emulsion:10 parts;EVA emulsions:15 parts;Styrene block copolymer(SBS) emulsion:9 parts;Modified milk agent:6 parts;Water:40
Part;
The EVA emulsions are ethane-acetic acid ethyenyl(Vinyl acetate)Ester copolymer.The EVA emulsions are introduced in strand
The VAM of high content, so as to reduce crystallinity, improves pliability, impact resistance, filler intermiscibility and Re Mi
Sealing property;
The modified milk agent splits fast curdled milk agent slowly for cation;
Step one:Prepare material:Llowing group of materials is ready:Petropols, organic pigment, styrene butadiene rubber sbr emulsion, EVA
Emulsion, styrene block copolymer(SBS) emulsion, modified milk agent, water;
Step 2:50 DEG C are heated water to, then by styrene butadiene rubber sbr emulsion, EVA emulsions, styrene block copolymer(SBS)
Emulsion, modified milk agent mix in sequentially adding water in proportion, are again heated to 50 DEG C, and side heating change stirs, and is prepared into kind
Sub- soap lye;
Step 3:Petropols liquid is heated to 130 DEG C, is shown as liquid;
Step 4:Sheared by colloid mill, the seed soap lye obtained by step 2 is mixed with the Petropols liquid obtained by step 3
Shearing is closed, the complex emulsions of primary colors are obtained;
Step 5:Primary colors complex emulsions obtained by step 4 and grass green mill base dispersed with stirring, final production are gone out into various face
The cold mixing cold-application high-viscosity chromatic complex emulsions of color.
Specific embodiment three:
According to a kind of described colored road surface preparation method of cold mixing cold-application high-viscosity chromatic complex emulsions, a kind of glassy yellow is prepared
Cold mixing cold-laid pavement high-viscosity chromatic complex emulsions, mainly include the following steps that:
Step one:Prepare material:Llowing group of materials is ready:Petropols:40 parts;Organic pigment:7 parts;Styrene butadiene rubber sbr
Emulsion:8 parts;EVA emulsions:13 parts;Styrene block copolymer(SBS) emulsion:7 parts;Modified milk agent:4 parts;Water:30 parts;
The EVA emulsions are ethane-acetic acid ethyenyl(Vinyl acetate)Ester copolymer.The EVA emulsions are introduced in strand
The VAM of high content, so as to reduce crystallinity, improves pliability, impact resistance, filler intermiscibility and Re Mi
Sealing property;
The modified milk agent splits fast curdled milk agent slowly for cation;
Step one:Prepare material:Llowing group of materials is ready:Petropols, organic pigment, styrene butadiene rubber sbr emulsion, EVA
Emulsion, styrene block copolymer(SBS) emulsion, modified milk agent, water;
Step 2:50 DEG C are heated water to, then by styrene butadiene rubber sbr emulsion, EVA emulsions, styrene block copolymer(SBS)
Emulsion, modified milk agent mix in sequentially adding water in proportion, are again heated to 50 DEG C, and side heating change stirs, and is prepared into kind
Sub- soap lye;
Step 3:Petropols liquid is heated to 130 DEG C, is shown as liquid;
Step 4:Sheared by colloid mill, the seed soap lye obtained by step 2 is mixed with the Petropols liquid obtained by step 3
Shearing is closed, the complex emulsions of primary colors are obtained;
Step 5:Primary colors complex emulsions obtained by step 4 and organic pigment dispersed with stirring, final production are gone out into glassy yellow color
The cold mixing cold-application high-viscosity chromatic complex emulsions of slurry.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under enlightenment of the invention
The product of form, however, make any change in its shape or structure, it is every with skill identical or similar to the present application
Art scheme, is within the scope of the present invention.
Claims (4)
1. a kind of colored road surface cold mixing cold-application high-viscosity chromatic complex emulsions, it is characterised in that:Described colored road surface cold mixing
Cold-application high-viscosity chromatic complex emulsions by following component by weight:Petropols:30~50 parts;Organic pigment:3~
10 parts;Styrene butadiene rubber sbr emulsion:5~10 parts;EVA emulsions:10~15 parts;Styrene block copolymer(SBS) emulsion:4~9
Part;Modified milk agent:1~6 part;Water:20~40 parts.
2. colored road surface according to claim 1 cold mixing cold-application high-viscosity chromatic complex emulsions, it is characterised in that:It is described
EVA emulsions are ethane-acetic acid ethyenyl(Vinyl acetate)Ester copolymer.
3. colored road surface according to claim 1 cold mixing cold-application high-viscosity chromatic complex emulsions, it is characterised in that:It is described to change
Property emulsifying agent splits fast curdled milk agent slowly for cation.
4. a kind of colored road surface according to claim 1 preparation method of cold mixing cold-application high-viscosity chromatic complex emulsions, its
It is characterised by, comprises the following steps:
Step one:Prepare material:Llowing group of materials is ready:Petropols, organic pigment, styrene butadiene rubber sbr emulsion, EVA
Emulsion, styrene block copolymer(SBS) emulsion, modified milk agent, water;
Step 2:50 DEG C are heated water to, then by styrene butadiene rubber sbr emulsion, EVA emulsions, styrene block copolymer(SBS)
Emulsion, modified milk agent mix in sequentially adding water in proportion, are again heated to 50 DEG C, and side heating change stirs, and is prepared into kind
Sub- soap lye;
Step 3:Petropols liquid is heated to 130 DEG C, is shown as liquid;
Step 4:Sheared by colloid mill, the seed soap lye obtained by step 2 is mixed with the Petropols liquid obtained by step 3
Shearing is closed, the complex emulsions of primary colors are obtained;
Step 5:Primary colors complex emulsions obtained by step 4 and organic pigment dispersed with stirring, final production are gone out into shades of colour
Cold mixing cold-application high-viscosity chromatic complex emulsions.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1760280A (en) * | 2005-03-25 | 2006-04-19 | 杨毅男 | Coloured modified emulsified asphalt |
CN101205346A (en) * | 2007-12-11 | 2008-06-25 | 左美俊 | Chromatic cementing agent emulsion and method for preparing same |
CN102952405A (en) * | 2011-08-19 | 2013-03-06 | 深圳市天之泰道路材料有限公司 | Colored asphalt and preparation method thereof |
CN103214859A (en) * | 2013-04-17 | 2013-07-24 | 黄云涌 | modified emulsified asphalt preparation method |
CN105542494A (en) * | 2015-12-30 | 2016-05-04 | 上海浦东路桥沥青材料有限公司 | Colored emulsified asphalt |
-
2016
- 2016-12-22 CN CN201611197104.1A patent/CN106751415A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1760280A (en) * | 2005-03-25 | 2006-04-19 | 杨毅男 | Coloured modified emulsified asphalt |
CN101205346A (en) * | 2007-12-11 | 2008-06-25 | 左美俊 | Chromatic cementing agent emulsion and method for preparing same |
CN102952405A (en) * | 2011-08-19 | 2013-03-06 | 深圳市天之泰道路材料有限公司 | Colored asphalt and preparation method thereof |
CN103214859A (en) * | 2013-04-17 | 2013-07-24 | 黄云涌 | modified emulsified asphalt preparation method |
CN105542494A (en) * | 2015-12-30 | 2016-05-04 | 上海浦东路桥沥青材料有限公司 | Colored emulsified asphalt |
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