CN106751187A - A kind of high leakproofness plastics - Google Patents
A kind of high leakproofness plastics Download PDFInfo
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- CN106751187A CN106751187A CN201611144188.2A CN201611144188A CN106751187A CN 106751187 A CN106751187 A CN 106751187A CN 201611144188 A CN201611144188 A CN 201611144188A CN 106751187 A CN106751187 A CN 106751187A
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- activated carbon
- carbon composite
- high leakproofness
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of high leakproofness plastics, its raw material includes by weight:30 50 parts of ABS resin, 25 55 parts of polyvinyl chloride, 15 25 parts of polymethyl methacrylate, 15 20 parts of Fypro, 39 parts of expanded perlite, 4 10 parts of flyash, 37 parts of nanometer silicon carbide, 37 parts of talcum powder, 37 parts of aluminium borate whisker, 48 parts of activated carbon composite, 12 parts of silane coupler, 24 parts of methyl pentachlorostearate, 25 parts of calcium zinc stabilizer, 0.4 0.8 parts of rare earth compound, 12 parts of molybdenum bisuphide, 1 1.5 parts of diaminomethyl cyclohexyl-methane, 24 parts of IPD, 1, 1 pair of 26 parts of (t-butyl peroxy) thiacyclohexane, 12 parts of antioxidant, 12 parts of lubricant, 13 parts of light stabilizer.
Description
Technical field
The present invention relates to plastics arts, more particularly to a kind of high leakproofness plastics.
Background technology
Plastics refer to the synthetic resin with HMW as key component, add suitable additives, such as plasticizer, stabilization
Agent, fire retardant, lubricant, colouring agent etc., the material of processed shaping.Plastics are the products in 20th century, since it be developed with
Come, the purposes of each side is increasingly extensive.Plastics are remarkable insulators, and coefficient of thermal expansion is small, and most plastics lower temperature resistances are good, no
Easy firing, but heat endurance is poor, it is easily aging, and water proofing property is poor, and sealing property can not meet demand.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of high leakproofness plastics, and heat endurance is high, prevents
Water, ageing-resistant performance are excellent, and sealing property is outstanding.
A kind of high leakproofness plastics proposed by the present invention, its raw material includes by weight:ABS resin 30-50 parts, polychlorostyrene second
Alkene 25-55 parts, polymethyl methacrylate 15-25 parts, Fypro 15-20 parts, expanded perlite 3-9 parts, flyash 4-
10 parts, nanometer silicon carbide 3-7 parts, talcum powder 3-7 parts, aluminium borate whisker 3-7 parts, activated carbon composite 4-8 parts, silane coupler 1-2 parts,
Methyl pentachlorostearate 2-4 parts, calcium zinc stabilizer 2-5 parts, rare earth compound 0.4-0.8 parts, molybdenum bisuphide 1-2 parts, two
1-1.5 parts of aminomethyl cyclohexyl-methane, IPD 2-4 parts, 1,1- double -2-6 parts of (t-butyl peroxy) thiacyclohexane, antioxygen
Agent 1-2 parts, lubricant 1-2 parts, light stabilizer 1-3 parts.
Preferably, ABS resin, polyvinyl chloride, polymethyl methacrylate, activated carbon composite, diaminomethyl cyclohexyl-methane, different
The weight ratio of isophoronediamine, 1,1- pair-(t-butyl peroxy) thiacyclohexane is 35-45:30-50:18-22:5-7:1.1-1.4:
2.5-3.5:3-5.
Preferably, Fypro, expanded perlite, flyash, nanometer silicon carbide, talcum powder, aluminium borate whisker, compound
Charcoal, the weight ratio of silane coupler are 16-18:5-7:6-8:4-6:4-6:4-6:5-7:1.2-1.8.
Preferably, its raw material includes by weight:ABS resin 35-45 parts, polyvinyl chloride 30-50 parts, polymethylacrylic acid
It is methyl esters 18-22 parts, Fypro 16-18 parts, expanded perlite 5-7 parts, flyash 6-8 parts, nanometer silicon carbide 4-6 parts, sliding
Stone flour 4-6 parts, aluminium borate whisker 4-6 parts, activated carbon composite 5-7 parts, silane coupler 1.2-1.8 parts, methyl pentachlorostearate 2.5-
3.5 parts, calcium zinc stabilizer 3-4 parts, rare earth compound 0.5-0.7 parts, molybdenum bisuphide 1.2-1.8 parts, diaminomethyl hexamethylene
Methylmethane 1.1-1.4 parts, IPD 2.5-3.5 parts, 1,1- double -3-5 parts of (t-butyl peroxy) thiacyclohexane, antioxidant
1.2-1.8 parts, lubricant 1.3-1.7 parts, light stabilizer 1.5-2.5 parts.
Preferably, activated carbon composite is prepared using following technique:HPG, dichloromethane are stirred, is added dropwise to toluene
The pyridine solution of sulfonic acid chloride, is heated up after completion of dropping, and stirring is poured into absolute ethyl alcohol and precipitated, filtering, add hemp stalk charcoal, bamboo charcoal,
Turf, water stirring, are added dropwise CMS sodium water solution, continue to stir after completion of dropping, and filtering dry, pulverize and is combined
Charcoal.
Preferably, activated carbon composite is prepared using following technique:By HPG, dichloromethane stirring 4-8h, stirring temperature
It is 3-7 DEG C to spend, and the pyridine solution of paratoluensulfonyl chloride is added dropwise, and 35-45 DEG C is warming up to after completion of dropping, stirs 30-60min,
Enter precipitation in absolute ethyl alcohol, filtering adds hemp stalk charcoal, bamboo charcoal, turf, water stirring 40-60min, and whipping temp is 80-90 DEG C,
CMS sodium water solution is added dropwise, continues to stir 4-8h after completion of dropping, filtering dry, pulverize and obtain activated carbon composite.
Preferably, activated carbon composite is prepared using following technique:By weight by 25-35 parts of HPG, 80-120 parts
Dichloromethane stirs 4-8h, and whipping temp is 3-7 DEG C, and it is the pyrrole of the paratoluensulfonyl chloride of 20-25wt% that 4-10 parts of concentration is added dropwise
Pyridine solution, is warming up to 35-45 DEG C after completion of dropping, stir 30-60min, pours into 220-340 parts of absolute ethyl alcohol and precipitates, filtering,
14-18 parts of hemp stalk charcoal, 10-18 parts of bamboo charcoal, 6-18 parts of turf, 80-120 parts of water stirring 40-60min are added, whipping temp is 80-
90 DEG C, it is the CMS sodium water solution of 18-22g/L that 14-20 parts of concentration is added dropwise, and continues to stir 4-8h, mistake after completion of dropping
Filter, dry, pulverize and obtain activated carbon composite.
The present invention is obtained using conventional fabrication process.
The present invention uses 1, the 1- pairs-(tert-butyl group with polyvinyl chloride, ABS resin, polymethyl methacrylate as major ingredient
Peroxide) thiacyclohexane, diaminomethyl cyclohexyl-methane, IPD as cross-linking system, make the present invention it is not only heat-resist,
And it is ageing-resistant, then coordinate activated carbon composite to act on, disperse between can effectively promoting said components, it is crosslinked closely knit, waterproof and heat endurance
Can further enhance;In activated carbon composite of the invention, paratoluensulfonyl chloride is used to act on activated hydroxyl groups HPG, and
Nano particle is cross-linked to form with sodium carboxymethyl starch, not only sticky moderate, good fluidity, and also emulsibility is good, can effectively promote
Bamboo charcoal, hemp stalk charcoal, turf are mutually dispersed, strengthen absorption and decomposition to harmful substance in air, insulation, waterproof and ventilative
Excellent performance, and with flourishing specific surface area, it contains abundant organo-functional group, with methyl pentachlorostearate, silane idol
Connection agent coordinates, and can strengthen adhesion between organic matter of the invention and inorganic matter, and good dispersion each other, can form network knot
Structure, makes that sealing of the invention is fabulous, and water resistance is further enhanced, and tensile strength and impact strength are excellent;Polyamides
Amine fiber, flyash, talcum powder, expanded perlite, aluminium borate whisker, nanometer silicon carbide coordinate as filler, make of the invention
Extreme hardness, coordinates molybdenum bisuphide, calcium zinc stabilizer, rare earth compound, methyl pentachlorostearate effect, and rationally control
Match each other, on the premise of ensureing that hardness of the invention meets condition, toughness is fabulous, while shielding ultraviolet rays ability is strong,
Further acted synergistically with antioxidant, light stabilizer, effectively prevent the injury of ultraviolet, increased substantially of the invention anti-ageing
Change performance, security is high.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high leakproofness plastics proposed by the present invention, its raw material includes by weight:30 parts of ABS resin, polyvinyl chloride
55 parts, 15 parts of polymethyl methacrylate, 20 parts of Fypro, 3 parts of expanded perlite, 10 parts of flyash, nanometer silicon carbide 3
Part, 7 parts of talcum powder, 3 parts of aluminium borate whisker, 8 parts of activated carbon composite, 1 part of silane coupler, 4 parts of methyl pentachlorostearate, calcium zinc stabilization
2 parts of agent, 0.8 part of rare earth compound, 1 part of molybdenum bisuphide, 1.5 parts of diaminomethyl cyclohexyl-methane, IPD 2
Part, 1,1- double -6 parts of (t-butyl peroxy) thiacyclohexane, 1 part of antioxidant, 2 parts of lubricant, 1 part of light stabilizer.
Embodiment 2
A kind of high leakproofness plastics proposed by the present invention, its raw material includes by weight:50 parts of ABS resin, polyvinyl chloride
25 parts, 25 parts of polymethyl methacrylate, 15 parts of Fypro, 9 parts of expanded perlite, 4 parts of flyash, nanometer silicon carbide 7
Part, 3 parts of talcum powder, 7 parts of aluminium borate whisker, 4 parts of activated carbon composite, 2 parts of silane coupler, 2 parts of methyl pentachlorostearate, calcium zinc stabilization
5 parts of agent, 0.4 part of rare earth compound, 2 parts of molybdenum bisuphide, 1 part of diaminomethyl cyclohexyl-methane, 4 parts of IPD,
1,1- double -2 parts of (t-butyl peroxy) thiacyclohexane, 2 parts of antioxidant, 1 part of lubricant, 3 parts of light stabilizer.
Activated carbon composite is prepared using following technique:HPG, dichloromethane are stirred, paratoluensulfonyl chloride is added dropwise
Pyridine solution, is heated up after completion of dropping, and stirring is poured into absolute ethyl alcohol and precipitated, and filtering adds hemp stalk charcoal, bamboo charcoal, turf, water
Stirring, is added dropwise CMS sodium water solution, continues to stir after completion of dropping, and filtering dry, pulverize and obtain activated carbon composite.
Embodiment 3
A kind of high leakproofness plastics proposed by the present invention, its raw material includes by weight:35 parts of ABS resin, polyvinyl chloride
50 parts, 18 parts of polymethyl methacrylate, 18 parts of Fypro, 5 parts of expanded perlite, 8 parts of flyash, nanometer silicon carbide 4
Part, 6 parts of talcum powder, 4 parts of aluminium borate whisker, 7 parts of activated carbon composite, 1.2 parts of silane coupler, 3.5 parts of methyl pentachlorostearate, calcium zinc
3 parts of stabilizer, 0.7 part of rare earth compound, 1.2 parts of molybdenum bisuphide, 1.4 parts of diaminomethyl cyclohexyl-methane, isophorone
2.5 parts of diamines, 1,1- double -5 parts of (t-butyl peroxy) thiacyclohexane, 1.2 parts of antioxidant, 1.7 parts of lubricant, light stabilizer 1.5
Part.
Activated carbon composite is prepared using following technique:By HPG, dichloromethane stirring 6h, whipping temp is 5 DEG C, drop
Plus the pyridine solution of paratoluensulfonyl chloride, 40 DEG C are warming up to after completion of dropping, 45min is stirred, pour into absolute ethyl alcohol and precipitate, mistake
Filter, adds hemp stalk charcoal, bamboo charcoal, turf, water stirring 50min, and whipping temp is 85 DEG C, and CMS sodium water solution, drop is added dropwise
To add continue after finishing and stir 6h, filtering dry, pulverize and obtain activated carbon composite.
Embodiment 4
A kind of high leakproofness plastics proposed by the present invention, its raw material includes by weight:45 parts of ABS resin, polyvinyl chloride
30 parts, 22 parts of polymethyl methacrylate, 16 parts of Fypro, 7 parts of expanded perlite, 6 parts of flyash, nanometer silicon carbide 6
Part, 4 parts of talcum powder, 6 parts of aluminium borate whisker, 5 parts of activated carbon composite, 1.8 parts of silane coupler, 2.5 parts of methyl pentachlorostearate, calcium zinc
4 parts of stabilizer, 0.5 part of rare earth compound, 1.8 parts of molybdenum bisuphide, 1.1 parts of diaminomethyl cyclohexyl-methane, isophorone
3.5 parts of diamines, 1,1- double -3 parts of (t-butyl peroxy) thiacyclohexane, 1.8 parts of antioxidant, 1.3 parts of lubricant, light stabilizer 2.5
Part.
Activated carbon composite is prepared using following technique:By weight by 25 parts of HPGs, 120 parts of dichloromethane stirrings
4h, whipping temp is 7 DEG C, and it is the pyridine solution of the paratoluensulfonyl chloride of 25wt% that 4 parts of concentration are added dropwise, and is warming up to after completion of dropping
35 DEG C, stir 60min, pour into 220 parts of absolute ethyl alcohols and precipitate, filtering, add 18 parts of hemp stalk charcoals, 10 parts of bamboo charcoals, 18 parts of turfs,
80 parts of water stir 60min, and whipping temp is 80 DEG C, and it is the CMS sodium water solution of 18g/L that 20 parts of concentration are added dropwise, and is dripped
Continue to stir 8h after finishing, filtering dry, pulverize and obtain activated carbon composite.
Embodiment 5
A kind of high leakproofness plastics proposed by the present invention, its raw material includes by weight:40 parts of ABS resin, polyvinyl chloride
40 parts, 20 parts of polymethyl methacrylate, 17 parts of Fypro, 6 parts of expanded perlite, 7 parts of flyash, nanometer silicon carbide 5
Part, 5 parts of talcum powder, 5 parts of aluminium borate whisker, 6 parts of activated carbon composite, 1.5 parts of silane coupler, 3 parts of methyl pentachlorostearate, calcium zinc is steady
Determine 3.5 parts of agent, 0.6 part of rare earth compound, 1.5 parts of molybdenum bisuphide, 1.3 parts of diaminomethyl cyclohexyl-methane, isophorone
3 parts of diamines, 1,1- double -4 parts of (t-butyl peroxy) thiacyclohexane, 1.5 parts of antioxidant, 1.5 parts of lubricant, 2 parts of light stabilizer.
Activated carbon composite is prepared using following technique:By weight by 35 parts of HPGs, 80 parts of dichloromethane stirring 8h,
Whipping temp is 3 DEG C, and it is the pyridine solution of the paratoluensulfonyl chloride of 20wt% that 10 parts of concentration are added dropwise, and 45 are warming up to after completion of dropping
DEG C, 30min is stirred, to pour into 340 parts of absolute ethyl alcohols and precipitate, filtering adds 14 parts of hemp stalk charcoals, 18 parts of bamboo charcoals, 6 parts of turfs, 120
Part water stirring 40min, whipping temp is 90 DEG C, and it is the CMS sodium water solution of 22g/L, completion of dropping that 14 parts of concentration are added dropwise
Continue to stir 4h afterwards, filtering dry, pulverize and obtain activated carbon composite.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of high leakproofness plastics, it is characterised in that its raw material includes by weight:ABS resin 30-50 parts, polyvinyl chloride
25-55 parts, polymethyl methacrylate 15-25 parts, Fypro 15-20 parts, expanded perlite 3-9 parts, flyash 4-10
Part, nanometer silicon carbide 3-7 parts, talcum powder 3-7 parts, aluminium borate whisker 3-7 parts, activated carbon composite 4-8 parts, silane coupler 1-2 parts, five
2-4 parts of chlorine methyl stearate, calcium zinc stabilizer 2-5 parts, rare earth compound 0.4-0.8 parts, molybdenum bisuphide 1-2 parts, diamino
1-1.5 parts of methyl cyclohexane methylmethane, IPD 2-4 parts, 1,1- double -2-6 parts of (t-butyl peroxy) thiacyclohexane is anti-oxidant
Agent 1-2 parts, lubricant 1-2 parts, light stabilizer 1-3 parts.
2. high leakproofness plastics according to claim 1, it is characterised in that ABS resin, polyvinyl chloride, polymethylacrylic acid
The weight ratio of methyl esters, activated carbon composite, diaminomethyl cyclohexyl-methane, IPD, 1,1- pair-(t-butyl peroxy) thiacyclohexane
It is 35-45:30-50:18-22:5-7:1.1-1.4:2.5-3.5:3-5.
3. high leakproofness plastics according to claim 1 or claim 2, it is characterised in that Fypro, expanded perlite, fine coal
Ash, nanometer silicon carbide, talcum powder, aluminium borate whisker, activated carbon composite, the weight ratio of silane coupler are 16-18:5-7:6-8:4-6:
4-6:4-6:5-7:1.2-1.8.
4. high leakproofness plastics according to claim any one of 1-3, it is characterised in that its raw material includes by weight:ABS
Resin 35-45 parts, polyvinyl chloride 30-50 parts, polymethyl methacrylate 18-22 parts, Fypro 16-18 parts, expansion is precious
5-7 parts of pearl rock, flyash 6-8 parts, nanometer silicon carbide 4-6 parts, talcum powder 4-6 parts, aluminium borate whisker 4-6 parts, activated carbon composite 5-7
Part, silane coupler 1.2-1.8 parts, methyl pentachlorostearate 2.5-3.5 parts, calcium zinc stabilizer 3-4 parts, rare earth compound
0.5-0.7 parts, molybdenum bisuphide 1.2-1.8 parts, 1.1-1.4 parts of diaminomethyl cyclohexyl-methane, IPD 2.5-3.5
Part, 1,1- double -3-5 parts of (t-butyl peroxy) thiacyclohexane, antioxidant 1.2-1.8 parts, lubricant 1.3-1.7 parts, light stabilizer
1.5-2.5 parts.
5. high leakproofness plastics according to claim any one of 1-4, it is characterised in that activated carbon composite uses following technique system
It is standby:HPG, dichloromethane are stirred, the pyridine solution of paratoluensulfonyl chloride is added dropwise, heated up after completion of dropping, stirred
Mix, pour into absolute ethyl alcohol and precipitate, filtering adds hemp stalk charcoal, bamboo charcoal, turf, water stirring, sodium carboxymethyl starch is added dropwise water-soluble
Liquid, continues to stir after completion of dropping, and filtering dry, pulverize and obtain activated carbon composite.
6. high leakproofness plastics according to claim any one of 1-5, it is characterised in that activated carbon composite uses following technique system
It is standby:By HPG, dichloromethane stirring 4-8h, whipping temp is 3-7 DEG C, and the pyridine that paratoluensulfonyl chloride is added dropwise is molten
Liquid, is warming up to 35-45 DEG C after completion of dropping, stir 30-60min, pours into absolute ethyl alcohol and precipitates, and filtering adds hemp stalk charcoal, bamboo
Charcoal, turf, water stirring 40-60min, whipping temp is 80-90 DEG C, and CMS sodium water solution is added dropwise, and completion of dropping is follow-up
Continuous stirring 4-8h, filtering dry, pulverize and obtain activated carbon composite.
7. high leakproofness plastics according to claim any one of 1-6, it is characterised in that activated carbon composite uses following technique system
It is standby:By weight by 25-35 parts of HPG, 80-120 parts of dichloromethane stirring 4-8h, whipping temp is 3-7 DEG C, drop
Plus 4-10 parts of concentration is the pyridine solution of the paratoluensulfonyl chloride of 20-25wt%, 35-45 DEG C, stirring are warming up to after completion of dropping
30-60min, pours into 220-340 parts of absolute ethyl alcohol and precipitates, and filtering adds 14-18 parts of hemp stalk charcoal, 10-18 parts of bamboo charcoal, 6-18
Part turf, 80-120 parts of water stirring 40-60min, whipping temp is 80-90 DEG C, and it is the carboxylic of 18-22g/L that 14-20 parts of concentration is added dropwise
Methyl starch sodium water solution, continues to stir 4-8h after completion of dropping, and filtering dry, pulverize and obtain activated carbon composite.
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Publication number | Priority date | Publication date | Assignee | Title |
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CN108587413A (en) * | 2018-05-30 | 2018-09-28 | 安徽润晟建设有限公司 | A kind of exterior wall waterborne epoxy coatings |
CN109666246A (en) * | 2018-12-18 | 2019-04-23 | 广东石油化工学院 | A kind of modified enhancing modified resin |
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CN103951758A (en) * | 2014-04-11 | 2014-07-30 | 昆山京昆油田化学科技开发公司 | Preparation method for amphoteric hydroxypropyl guar gum derivative |
CN105199264A (en) * | 2015-09-29 | 2015-12-30 | 安徽蓝德集团股份有限公司 | High-stability corrosion-resistant power cable |
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CN1908108A (en) * | 2005-08-05 | 2007-02-07 | 比亚迪股份有限公司 | Encapsulating material and method for making same |
CN101575448A (en) * | 2008-05-08 | 2009-11-11 | 三星电子株式会社 | Novel thermoplastic elastomer-resin alloy composition and preparation method thereof |
CN103951758A (en) * | 2014-04-11 | 2014-07-30 | 昆山京昆油田化学科技开发公司 | Preparation method for amphoteric hydroxypropyl guar gum derivative |
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CN108587413A (en) * | 2018-05-30 | 2018-09-28 | 安徽润晟建设有限公司 | A kind of exterior wall waterborne epoxy coatings |
CN109666246A (en) * | 2018-12-18 | 2019-04-23 | 广东石油化工学院 | A kind of modified enhancing modified resin |
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Application publication date: 20170531 |