CN106750857A - A kind of production technology of bubble film - Google Patents

A kind of production technology of bubble film Download PDF

Info

Publication number
CN106750857A
CN106750857A CN201611085062.2A CN201611085062A CN106750857A CN 106750857 A CN106750857 A CN 106750857A CN 201611085062 A CN201611085062 A CN 201611085062A CN 106750857 A CN106750857 A CN 106750857A
Authority
CN
China
Prior art keywords
parts
agent
raw material
bubble film
crosslinking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611085062.2A
Other languages
Chinese (zh)
Inventor
崔九峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
Original Assignee
TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd filed Critical TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
Priority to CN201611085062.2A priority Critical patent/CN106750857A/en
Publication of CN106750857A publication Critical patent/CN106750857A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/544—Silicon-containing compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2431/00—Presence of polyvinyl acetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention relates to a kind of production technology of bubble film.Comprise the following steps, (1) refrigeration auxiliary agent the step of, refrigerating temperature range be 5 DEG C 25 DEG C；(2) the step of raw material mixes, raw material includes EVA resin, coupling agent, foaming agent, crosslinking agent, crosslinking coagent, antioxidant, UV absorbers and the light stabilizer that VA contents are 28 33%, 90 110 parts of EVA resin, 0.1 0.4 parts of coupling agent, 0.8 1.5 parts of foaming agent, 0.5 1.0 parts of crosslinking agent, 0.3 0.8 parts of crosslinking coagent, 0.1 0.3 parts of antioxidant, 0.1 0.3 parts of UV absorbers, 0.2 0.4 parts of light stabilizer are counted by weight；(3) the step of feeding intake, mixed raw material is put into the hopper of extruder, and dosing operation is carried out under air-proof condition, and time control is within 5min；(4) using casting film-forming Process Production bubble film the step of, this step temperature control is at 60 90 DEG C；(5) the step of finished product is refrigerated, the bubble film to obtaining carries out stored refrigerated, and refrigerated condition is 18 30 DEG C of constant refrigeration, and cold preservation time is less than 6 months.

Description

A kind of production technology of bubble film
Technical field
The present invention relates to a kind of production technology of bubble film.
Background technology
In fields such as building decorations, doubling glass has obtained more and more widely should with its good characteristic such as attractive in appearance, firm With doubling glass includes the glass film layers and the glass positioned at both sides positioned at center.Existing glass film is generally monochrome, It is typically also that opaque monochrome is adjusted, it is necessary to when representing combination colour effect to produce the doubling glass for being formed, typically by multicolour Doubling glass is applied in combination.However as the lifting and transformation of people's estheticism, the doubling glass of monotone can not expire The aesthetic requirement of sufficient people, the technology that people are badly in need of to represent on a piece of doubling glass similar bubble effect occurs, existing Have in technology and there is not yet above-mentioned production technology.
The content of the invention
The present invention provides a kind of production technology of bubble film to solve technical problem present in known technology, makes glue Piece possesses bubble effect.
The present invention is adopted the technical scheme that to solve technical problem present in known technology：A kind of bubble film Production technology is comprised the following steps, (1) refrigeration auxiliary agent the step of, auxiliary agent is helped including coupling agent, foaming agent, crosslinking agent and crosslinking Agent, refrigerating temperature range is -5 DEG C -25 DEG C；(2) the step of raw material mixes, raw material is mixed in mixer, raw material bag Include EVA resin, coupling agent, foaming agent, crosslinking agent, crosslinking coagent, antioxidant, UV absorbers that VA contents are 28-33% And light stabilizer, 90-110 parts of EVA resin, coupling agent 0.1-0.4 parts, foaming agent 0.8-1.5 parts, crosslinking agent are counted by weight 0.5-1.0 parts, crosslinking coagent 0.3-0.8 parts, antioxidant 0.1-0.3 parts, UV absorbers 0.1-0.3 parts, light stabilizer 0.2-0.4 parts；(3) the step of feeding intake, mixed raw material is put into the hopper of extruder, and dosing operation is in air-proof condition Under carry out, time control is within 5min；(4) using casting film-forming Process Production bubble film the step of, this step temperature control System is at 60-90 DEG C；(5) the step of finished product is refrigerated, the bubble film to obtaining carry out it is stored refrigerated, refrigerated condition be 18-30 DEG C Constant refrigeration, cold preservation time be less than 6 months.
Advantages and positive effects of the present invention are：The invention provides a kind of production technology of bubble film, by that will pass The glass film production technology of system is combined with foam process, has obtained the film product with bubble effect, improves doubling The alternative of glass production, whole production procedure is concise, easily operated.
Preferably：The step of raw material mixes in step (2) is carried out under air-proof condition, and incorporation time is 5-10min.
Preferably：The coupling agent is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxysilane, ammonia third Ethyl triethoxy silicane alkane, aminoethylaminopropyl trimethoxy silane, aminoethylaminopropyl triethoxysilane, aminoethylaminopropyl Methyl dimethoxysilane, vinyltrimethoxy silane, VTES, methacryloxy trimethoxy One or more in silane.
Specific embodiment
For the content of the invention of the invention, feature and effect can be further appreciated that, following examples detailed description is hereby lifted as follows：
Embodiment 1
(1) auxiliary agent is refrigerated, auxiliary agent includes coupling agent, foaming agent, crosslinking agent and crosslinking coagent, and refrigerating temperature range is -3 ℃；
(2) raw material is mixed in mixer, raw material includes EVA resin, coupling agent, the foaming that VA contents are 30% Agent, crosslinking agent, crosslinking coagent, antioxidant, UV absorbers and light stabilizer；
95 parts of EVA resin, 0.15 part of coupling agent, 0.9 part of foaming agent, 0.6 part of crosslinking agent, crosslinking coagent are counted by weight 0.4 part, 0.1 part of antioxidant, 0.1 part of UV absorbers, 0.2 part of light stabilizer；
(3) mixed raw material is put into the hopper of extruder, dosing operation is carried out under air-proof condition, when feeding intake Between be 2min；
(4) using casting film-forming Process Production bubble film the step of, this step temperature control is at 65 DEG C；
(5) the bubble film for obtaining is carried out stored refrigerated, refrigerated condition is 18 DEG C of constant refrigeration, and cold preservation time is 2 Individual month.
Wherein, the step of raw material mixes in step (2) is carried out under air-proof condition, and incorporation time is 5min；Coupling agent is selected It is taken as aminopropyl trimethoxysilane.
Embodiment 2
(1) auxiliary agent is refrigerated, auxiliary agent includes coupling agent, foaming agent, crosslinking agent and crosslinking coagent, and refrigerating temperature range is 5 DEG C；
(2) raw material is mixed in mixer, raw material includes EVA resin, coupling agent, the foaming that VA contents are 30% Agent, crosslinking agent, crosslinking coagent, antioxidant, UV absorbers and light stabilizer；
100 parts of EVA resin, 0.2 part of coupling agent, 1.2 parts of foaming agent, 0.7 part of crosslinking agent, crosslinking coagent are counted by weight 0.5 part, 0.2 part of antioxidant, 0.2 part of UV absorbers, 0.3 part of light stabilizer；
(4) mixed raw material is put into the hopper of extruder, dosing operation is carried out under air-proof condition, when feeding intake Between be 3min；
(4) using casting film-forming Process Production bubble film the step of, this step temperature control is at 75 DEG C；
(5) the bubble film for obtaining is carried out stored refrigerated, refrigerated condition is 18 DEG C of constant refrigeration, and cold preservation time is 3 Individual month.
Wherein, the step of raw material mixes in step (2) is carried out under air-proof condition, and incorporation time is 7min；Coupling agent is selected It is taken as aminoethylaminopropyl triethoxysilane.
Embodiment 3
(1) auxiliary agent is refrigerated, auxiliary agent includes coupling agent, foaming agent, crosslinking agent and crosslinking coagent, and refrigerating temperature range is 15 ℃；
(2) raw material is mixed in mixer, raw material includes EVA resin, coupling agent, the foaming that VA contents are 32% Agent, crosslinking agent, crosslinking coagent, antioxidant, UV absorbers and light stabilizer；
108 parts of EVA resin is counted by weight, and 0.35 part of coupling agent, 1.4 parts of foaming agent, 0.9 part of crosslinking agent, crosslinking are helped 0.8 part of agent, 0.3 part of antioxidant, 0.3 part of UV absorbers, 0.4 part of light stabilizer；
(5) mixed raw material is put into the hopper of extruder, dosing operation is carried out under air-proof condition, when feeding intake Between be 4min；
(4) using casting film-forming Process Production bubble film the step of, this step temperature control is at 85 DEG C；
(5) the bubble film for obtaining is carried out stored refrigerated, refrigerated condition is 18 DEG C of constant refrigeration, and cold preservation time is 4 Individual month.
Wherein, the step of raw material mixes in step (2) is carried out under air-proof condition, and incorporation time is 8min；Coupling agent is selected It is taken as VTES.

Claims (3)

1. a kind of production technology of bubble film, it is characterized in that：Comprise the following steps,
(1) the step of refrigerating auxiliary agent, auxiliary agent includes coupling agent, foaming agent, crosslinking agent and crosslinking coagent, and refrigerating temperature range is -5 ℃-25℃；
(2) the step of raw material mixes, raw material is mixed in mixer, raw material includes that VA contents are the EVA trees of 28-33% Fat, coupling agent, foaming agent, crosslinking agent, crosslinking coagent, antioxidant, UV absorbers and light stabilizer, count by weight EVA resin 90-110 parts, coupling agent 0.1-0.4 parts, foaming agent 0.8-1.5 parts, crosslinking agent 0.5-1.0 parts, crosslinking coagent 0.3- 0.8 part, antioxidant 0.1-0.3 parts, UV absorbers 0.1-0.3 parts, light stabilizer 0.2-0.4 parts；
(3) the step of feeding intake, mixed raw material is put into the hopper of extruder, and dosing operation enters under air-proof condition OK, time control is within 5min；
(4) using casting film-forming Process Production bubble film the step of, this step temperature control is at 60-90 DEG C；
(5) the step of finished product is refrigerated, the bubble film to obtaining carries out stored refrigerated, and refrigerated condition is cold for 18-30 DEG C of constant temperature Hide, cold preservation time is less than 6 months.
2. the production technology of bubble film as claimed in claim 1, it is characterised in that：The step of raw material mixes in step (2) Carried out under air-proof condition, incorporation time is 5-10min.
3. the production technology of bubble film as claimed in claim 1, it is characterised in that：The coupling agent is chosen for aminopropyl three Methoxy silane, aminopropyltriethoxy dimethoxysilane, aminopropyl triethoxysilane, aminoethylaminopropyl trimethoxy silicon Alkane, aminoethylaminopropyl triethoxysilane, aminoethylaminopropyl methyl dimethoxysilane, vinyltrimethoxy silane, One or more in VTES, methacryloxy trimethoxy silane.
CN201611085062.2A 2016-12-01 2016-12-01 A kind of production technology of bubble film Pending CN106750857A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611085062.2A CN106750857A (en) 2016-12-01 2016-12-01 A kind of production technology of bubble film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611085062.2A CN106750857A (en) 2016-12-01 2016-12-01 A kind of production technology of bubble film

Publications (1)

Publication Number Publication Date
CN106750857A true CN106750857A (en) 2017-05-31

Family

ID=58914784

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611085062.2A Pending CN106750857A (en) 2016-12-01 2016-12-01 A kind of production technology of bubble film

Country Status (1)

Country Link
CN (1) CN106750857A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402246A (en) * 2008-11-18 2009-04-08 广州市鹿山化工材料有限公司 Process for producing doubling glass cement film, product and uses thereof
CN201511733U (en) * 2009-10-15 2010-06-23 牛永立 Composite glass
CN201669942U (en) * 2010-05-17 2010-12-15 马义贵 Glass composite board
CN102618180A (en) * 2012-03-23 2012-08-01 天津三瑞塑胶制品有限公司 Luminous glass film
CN103205212A (en) * 2013-04-27 2013-07-17 汕头市安德利环保科技有限公司 EVA (Ethylene vinyl-acetate) film and manufacturing method thereof
CN103788883A (en) * 2014-01-23 2014-05-14 天津三瑞塑胶制品有限公司 Production method of luminous flow-line EVA laminated glass film
CN105985738A (en) * 2015-02-11 2016-10-05 温州瑞阳光伏材料有限公司 Laminated glass functional glue film and preparation technology thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101402246A (en) * 2008-11-18 2009-04-08 广州市鹿山化工材料有限公司 Process for producing doubling glass cement film, product and uses thereof
CN201511733U (en) * 2009-10-15 2010-06-23 牛永立 Composite glass
CN201669942U (en) * 2010-05-17 2010-12-15 马义贵 Glass composite board
CN102618180A (en) * 2012-03-23 2012-08-01 天津三瑞塑胶制品有限公司 Luminous glass film
CN103205212A (en) * 2013-04-27 2013-07-17 汕头市安德利环保科技有限公司 EVA (Ethylene vinyl-acetate) film and manufacturing method thereof
CN103788883A (en) * 2014-01-23 2014-05-14 天津三瑞塑胶制品有限公司 Production method of luminous flow-line EVA laminated glass film
CN105985738A (en) * 2015-02-11 2016-10-05 温州瑞阳光伏材料有限公司 Laminated glass functional glue film and preparation technology thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赵西安 编著: "《建筑幕墙工程手册》", 31 December 2002, 中国建筑工业出版社 *

Similar Documents

Publication Publication Date Title
CN106584879A (en) Production technology of mirror surface black decoration film
CN106634652A (en) Production process for dimming film
CN103788883A (en) Production method of luminous flow-line EVA laminated glass film
CN107400466A (en) A kind of production technology of ultralow medium-temperature reinforced description film
CN106431002A (en) Preparation method of highly transparent liquid silica gel protective glass container
CN106750857A (en) A kind of production technology of bubble film
CN101935411B (en) Quick wax spray rubber composition and preparation method thereof
CN107602997A (en) A kind of production technology of EVA colored solars film
CN110845990A (en) Ceramic tile crack beautifying agent and preparation method thereof
CN102166806B (en) Production technology of anti-yellowing resin imitation diamond with high light transmittance and high weatherability
CN106633345A (en) Production process of jade sand color film
CN104310862B (en) Artificial quartz stone plate for ground pavement and preparation method thereof
CN105153702A (en) Rubber material for pressing fastener sealing cover and method for preparing sealing cover
CN107760007A (en) A kind of mobile phone shell radiating plastics and preparation method thereof
CN106916562A (en) A kind of mould proof sealing neutral silicone resin and preparation method thereof
CN108841075B (en) Flame-retardant polypropylene material and preparation method thereof
CN109679558A (en) The naked film of footwear material hot melt adhesive, sandwich insole and production method using it
CN107814986A (en) Double durometer rubber moulding materials and preparation method thereof
CN100395848C (en) Technology for producing synthesized insulator without needing two-section sulfuration
CN105504285A (en) Preparation method for organic and inorganic compound adhesive
CN106634651A (en) Production process for microlite ceramic tile composite adhesive film
CN107400467A (en) A kind of production technology of EVA bathrooms safety door special adhesive
CN107522935A (en) A kind of production technology of EVA ultraviolet isolatings film
CN107603502A (en) A kind of production technology of EVA glass diffusion film
CN109822806A (en) A kind of production technology of electrochromic intelligent film

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170531

RJ01 Rejection of invention patent application after publication