CN106750588A - A kind of new waterproof elastomeric material - Google Patents
A kind of new waterproof elastomeric material Download PDFInfo
- Publication number
- CN106750588A CN106750588A CN201611100326.7A CN201611100326A CN106750588A CN 106750588 A CN106750588 A CN 106750588A CN 201611100326 A CN201611100326 A CN 201611100326A CN 106750588 A CN106750588 A CN 106750588A
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- CN
- China
- Prior art keywords
- parts
- elastomeric material
- new waterproof
- waterproof elastomeric
- age resistor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of new waterproof elastomeric material, including:Natural rubber, Nano silica sol, paraffin, diethylene glycol (DEG), atlapulgite, barium titanate, magnesium hydroxide, vaseline, polyacrylonitrile, nano silicon, naphthenic oil, co-crosslinker and age resistor, described new waterproof elastomeric material is calculated according to mass percent, including following weight portion:0.1 0.5 parts of 26 parts of natural rubber, 14 parts of Nano silica sol, 25 parts of paraffin, 0.5 2.0 parts of diethylene glycol (DEG), 1 10 parts of atlapulgite, 35 parts of barium titanate, 14 parts of magnesium hydroxide, 37 parts of vaseline, 26 parts of polyacrylonitrile, 14 parts of nano silicon, 14 parts of naphthenic oil, 0.5 3.0 parts of co-crosslinker and age resistor.Through the above way, the new waterproof elastomeric material that the present invention is provided, is conducive to being applied to various environment, compared with other rubber products, with stronger combination property, with good ductility, easy to use, performance is significantly improved, additionally it is possible to reduce pollution of the rubber to environment.
Description
Technical field
The present invention relates to a kind of elastomeric material, more particularly to new waterproof elastomeric material.
Background technology
The rubber industry of China served indispensable supporting effect to national economy, especially by the development of more than 50 years
It is the raising and new diseases with China's Mechanization Level, and rubber industry is constantly interpenetrated with association area,
Opened up range of application and the field of rubber, product be widely used in coal, metallurgy, cement, harbour, mine, oil, automobile,
The fields such as weaving, light industry, engineering machinery, building, ocean, agricultural, Aeronautics and Astronautics.In recent years, rubber industry adheres to scientific development
See, the kind of product, specification, quality have obtained lasting, quick, coordination, the development of health, have substantially met the need of domestic market
Ask, improve the competitiveness in the international market of product.
The content of the invention
Be conducive to being applied to various environment the present invention solves the technical problem of how to provide one kind, with other rubber
Product is compared, and with stronger combination property, easy to use with good ductility, performance is significantly improved, additionally it is possible to reduced
Material prescription of the rubber to the pollution of environment.
In order to solve the above technical problems, one aspect of the present invention is:A kind of new waterproof rubber material is provided
Material, including:Natural rubber, Nano silica sol, paraffin, diethylene glycol (DEG), atlapulgite, barium titanate, magnesium hydroxide, vaseline, poly- third
Alkene nitrile, nano silicon, naphthenic oil, co-crosslinker and age resistor, described new waterproof elastomeric material is according to quality percentage
Than calculating, including following weight portion:Natural rubber 2-6 parts, Nano silica sol 1-4 parts, paraffin 2-5 parts, diethylene glycol (DEG) 0.5-2.0
Part, atlapulgite 1-10 parts, barium titanate 3-5 parts, magnesium hydroxide 1-4 parts, vaseline 3-7 parts, polyacrylonitrile 2-6 parts, nanometer two
Silica 1-4 parts, naphthenic oil 1-4 parts, co-crosslinker 0.5-3.0 parts and age resistor 0.1-0.5 parts.
In a preferred embodiment, described new waterproof elastomeric material is calculated according to mass percent, including following
Weight portion:5 parts of natural rubber, 3 parts of Nano silica sol, 4 parts of paraffin, 1.0 parts of diethylene glycol (DEG), 8 parts of atlapulgite, 4 parts of barium titanate, hydrogen
3 parts of magnesia, 5 parts of vaseline, 5 parts of polyacrylonitrile, 3 parts of nano silicon, 3 parts of naphthenic oil, 2.0 parts of co-crosslinker and anti-old
0.4 part of agent.
In a preferred embodiment, the accelerator is 2 benzothiazolyl mercaptans.
In a preferred embodiment, the accelerator is dibenzothiazyl disulfide.
In a preferred embodiment, the age resistor is thermo oxidative aging agent, antiozonant, harmful metal ion suppression
One kind in agent.
In a preferred embodiment, the age resistor is thermo oxidative aging agent, antiozonant, harmful metal ion suppression
It is various in agent
The beneficial effects of the invention are as follows:Be conducive to being applied to various environment, compared with other rubber products, with stronger synthesis
Performance, easy to use with good ductility, performance is significantly improved, additionally it is possible to reduce pollution of the rubber to environment.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
A kind of new waterproof elastomeric material, described new waterproof rubber are provided in one particular embodiment of the present invention
Material includes:Natural rubber, Nano silica sol, paraffin, diethylene glycol (DEG), atlapulgite, barium titanate, magnesium hydroxide, vaseline, poly- third
Alkene nitrile, nano silicon, naphthenic oil, co-crosslinker and age resistor, described new waterproof elastomeric material is according to quality percentage
Than calculating, including following weight portion:Natural rubber 2-6 parts, Nano silica sol 1-4 parts, paraffin 2-5 parts, diethylene glycol (DEG) 0.5-2.0
Part, atlapulgite 1-10 parts, barium titanate 3-5 parts, magnesium hydroxide 1-4 parts, vaseline 3-7 parts, polyacrylonitrile 2-6 parts, nanometer two
Silica 1-4 parts, naphthenic oil 1-4 parts, co-crosslinker 0.5-3.0 parts and age resistor 0.1-0.5 parts.
In embodiment:Described new waterproof elastomeric material is calculated according to mass percent, including following weight portion:Naturally
5 parts of rubber, 3 parts of Nano silica sol, 4 parts of paraffin, 1.0 parts of diethylene glycol (DEG), 8 parts of atlapulgite, 4 parts of barium titanate, 3 parts of magnesium hydroxide,
0.4 part of 5 parts of vaseline, 5 parts of polyacrylonitrile, 3 parts of nano silicon, 3 parts of naphthenic oil, 2.0 parts of co-crosslinker and age resistor.
The accelerator is 2 benzothiazolyl mercaptans.The accelerator is dibenzothiazyl disulfide.The age resistor is
One kind in thermo oxidative aging agent, antiozonant, harmful metal ion inhibitor.The age resistor is thermo oxidative aging agent, resists
It is various in ozonidate, harmful metal ion inhibitor.
Therefore, the present invention has advantages below:Be conducive to being applied to various environment, compared with other rubber products, have
Stronger combination property, easy to use with good ductility, performance is significantly improved, additionally it is possible to reduce rubber to environment
Pollution.
Embodiments of the invention are the foregoing is only, the scope of the claims of the invention is not thereby limited, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (6)
1. a kind of new waterproof elastomeric material, it is characterised in that including:Natural rubber, Nano silica sol, paraffin, diethylene glycol (DEG), work
Property carclazyte, barium titanate, magnesium hydroxide, vaseline, polyacrylonitrile, nano silicon, naphthenic oil, co-crosslinker and age resistor,
Described new waterproof elastomeric material is calculated according to mass percent, including following weight portion:Natural rubber 2-6 parts, nano-silicon
Colloidal sol 1-4 parts, paraffin 2-5 parts, diethylene glycol (DEG) 0.5-2.0 parts, atlapulgite 1-10 parts, barium titanate 3-5 parts, magnesium hydroxide 1-4 parts,
Vaseline 3-7 parts, polyacrylonitrile 2-6 parts, nano silicon 1-4 parts, naphthenic oil 1-4 parts, co-crosslinker 0.5-3.0 parts and anti-
Old agent 0.1-0.5 parts.
2. new waterproof elastomeric material according to claim 1, it is characterised in that described new waterproof elastomeric material is pressed
Calculated according to mass percent, including following weight portion:5 parts of natural rubber, 3 parts of Nano silica sol, 4 parts of paraffin, diethylene glycol (DEG) 1.0
Part, 8 parts of atlapulgite, 4 parts of barium titanate, 3 parts of magnesium hydroxide, 5 parts of vaseline, 5 parts of polyacrylonitrile, 3 parts of nano silicon, ring
0.4 part of 3 parts of alkane oil, 2.0 parts of co-crosslinker and age resistor.
3. new waterproof elastomeric material according to claim 1, it is characterised in that the accelerator is 2 mercapto benzos
Thiazole.
4. new waterproof elastomeric material according to claim 1, it is characterised in that the accelerator be diphenyl disulfide simultaneously
Thiazole.
5. new waterproof elastomeric material according to claim 1, it is characterised in that the age resistor is thermo oxidative aging
One kind in agent, antiozonant, harmful metal ion inhibitor.
6. new waterproof elastomeric material according to claim 1, it is characterised in that the age resistor is thermo oxidative aging
It is various in agent, antiozonant, harmful metal ion inhibitor.
Priority Applications (1)
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CN201611100326.7A CN106750588A (en) | 2016-12-05 | 2016-12-05 | A kind of new waterproof elastomeric material |
Applications Claiming Priority (1)
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CN201611100326.7A CN106750588A (en) | 2016-12-05 | 2016-12-05 | A kind of new waterproof elastomeric material |
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CN106750588A true CN106750588A (en) | 2017-05-31 |
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CN201611100326.7A Pending CN106750588A (en) | 2016-12-05 | 2016-12-05 | A kind of new waterproof elastomeric material |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102775618A (en) * | 2012-07-27 | 2012-11-14 | 华南理工大学 | Wet smelting method for preparing natural rubber/nanometer silicon dioxide rubber compound |
CN102816350A (en) * | 2012-07-30 | 2012-12-12 | 华南理工大学 | Wet mixing method for preparing natural rubber/carbon black-nano silica rubber compound |
CN102876242A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | Epoxy resin adhesive for bonding fluororubber and metal |
CN105254935A (en) * | 2015-08-27 | 2016-01-20 | 苏州国泰科技发展有限公司 | Environment-friendly rubber compound for automobile tyre |
-
2016
- 2016-12-05 CN CN201611100326.7A patent/CN106750588A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102775618A (en) * | 2012-07-27 | 2012-11-14 | 华南理工大学 | Wet smelting method for preparing natural rubber/nanometer silicon dioxide rubber compound |
CN102816350A (en) * | 2012-07-30 | 2012-12-12 | 华南理工大学 | Wet mixing method for preparing natural rubber/carbon black-nano silica rubber compound |
CN102876242A (en) * | 2012-09-20 | 2013-01-16 | 吴江市天源塑胶有限公司 | Epoxy resin adhesive for bonding fluororubber and metal |
CN105254935A (en) * | 2015-08-27 | 2016-01-20 | 苏州国泰科技发展有限公司 | Environment-friendly rubber compound for automobile tyre |
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Application publication date: 20170531 |
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