CN102876242A - Epoxy resin adhesive for bonding fluororubber and metal - Google Patents
Epoxy resin adhesive for bonding fluororubber and metal Download PDFInfo
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- CN102876242A CN102876242A CN2012103527614A CN201210352761A CN102876242A CN 102876242 A CN102876242 A CN 102876242A CN 2012103527614 A CN2012103527614 A CN 2012103527614A CN 201210352761 A CN201210352761 A CN 201210352761A CN 102876242 A CN102876242 A CN 102876242A
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- epoxy
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- 230000001070 adhesive effect Effects 0.000 title abstract description 7
- 239000000853 adhesive Substances 0.000 title abstract description 6
- 239000003822 epoxy resin Substances 0.000 title abstract description 5
- 229920000647 polyepoxide Polymers 0.000 title abstract description 5
- 229920001973 fluoroelastomer Polymers 0.000 title abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 9
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 9
- 229920001194 natural rubber Polymers 0.000 claims abstract description 9
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- IJVRPNIWWODHHA-UHFFFAOYSA-N 2-cyanoprop-2-enoic acid Chemical compound OC(=O)C(=C)C#N IJVRPNIWWODHHA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 6
- 239000006229 carbon black Substances 0.000 claims abstract description 6
- 229920002681 hypalon Polymers 0.000 claims abstract description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 6
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 4
- 229920002449 FKM Polymers 0.000 claims description 18
- 239000004593 Epoxy Substances 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 238000004026 adhesive bonding Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- QZRMKGRPCTVXBS-UHFFFAOYSA-N 2,6,8-trimethylnonan-4-yl dihydrogen phosphate Chemical compound CC(C)CC(C)CC(CC(C)C)OP(O)(O)=O QZRMKGRPCTVXBS-UHFFFAOYSA-N 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 235000019241 carbon black Nutrition 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- -1 polyoxyethylene Polymers 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 3
- 229960001701 chloroform Drugs 0.000 claims description 3
- 239000003595 mist Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 229960001124 trientine Drugs 0.000 claims description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 229920001606 poly(lactic acid-co-glycolic acid) Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an epoxy resin adhesive for bonding fluororubber and metal. The adhesive comprises component A and component B. The component A comprises the following materials by weight: 30-40 parts of epoxy resin, 5-6 parts of rosin-modified resin, 2-3 parts of chlorosulfonated polyethylene, 5-10 parts of natural rubber powder, 2-4 parts of chlorinated paraffin, 2-4 parts of ferric oxide micropowder, 2-4 parts of magnesia, 3-6 parts of carbon black, 2-3 parts of a silane coupling agent, 1-2 parts of dodecyl phosphate, 1-2 parts of silica sol, 1-2 parts of alumina sol, 1-3 parts of acrylate, 1-2 parts of titanium dioxide, 3-6 parts of polymethyl methacrylate, 3-6 parts of alpha-cyanoacrylate, 2-4 parts of tricresyl phosphate, 5-10 parts of polyethylene glycol, 3-4 parts of poly(lactic acid-co-glycolic acid), and 40-60 parts of organic solvent. The component B comprises the following materials by weight: 15-20 parts of a curing agent, and 20-30 parts of dimethyl formamide.
Description
Technical field
The invention provides the epoxyn of a kind of viton and the gluing usefulness of metal, belong to the adhesive technology field.
Background technology
Because metallic surface is fine and close, polarity is large, intensity is high, metallic substance should adopt the tackiness agent such as resol, modified epoxy, urethane, acrylate aspect the selecting of tackiness agent, and thermosol, inorganic glue etc.
Bonding the bonding of unvulcanized viton and metal and the viton of sulfuration and bonding two kinds of metal of including for viton and metal.For the former, generally be rubber unvulcanizate rubber cement or the isocyanate adhesive that adopts organic silicon adhesive, contains tackifier; And for the latter, generally be the tackiness agent that adopts epoxy resin.
But, use the tackiness agent of epoxy resin to go viton and metal are carried out when bonding, its resistance toheat is bad, and technique is loaded down with trivial details, need to carry out sulfidizing to viton, causes its bonding strength to be vulnerable to impact.
Summary of the invention
For above commentary to prior art, technical problem to be solved by this invention is: a kind of tackiness agent to unvulcanized viton and metal sticking is provided, and allows it have preferably adhesiveproperties.The technical scheme that adopts is:
The epoxyn of a kind of viton and the gluing usefulness of metal, comprise A component and B component, described A component includes 30～40 parts of Resins, epoxy by weight, 5～6 parts of modified rosin resins, 2～3 parts of chlorosulfonated polyethylenes, 5～10 parts in natural rubber powder, 2～4 parts of clorafins, 2～4 parts of ferric oxide micro mists, 2～4 parts in magnesium oxide, 3～6 parts of carbon blacks, 2～3 parts of silane coupling agents, 1～2 part of 1-isobutyl-3,5-dimethylhexylphosphoric acid, 1～2 part of silicon sol, 1～2 part of aluminium colloidal sol, 1～3 part of acrylate, 1～2 part of titanium dioxide, 3～6 parts of polymethylmethacrylates, 3～6 parts of α-cyanoacrylates, 2～4 parts of tritolyl phosphates, 5～10 parts of polyoxyethylene glycol, 3～4 parts of polylactic-co-glycolic acids, 40～60 parts of organic solvents; Described B component includes 15～20 parts in solidifying agent, 20～30 parts of dimethyl formamides.
Above-mentioned Resins, epoxy is preferably from E-40 Resins, epoxy, E-42 Resins, epoxy, E-44 Resins, epoxy.
Above-mentioned solidifying agent is a kind of in quadrol, diethylenetriamine, triethylene tetramine, tetraethylene pentamine preferably.
The particle diameter of natural rubber powder is preferably from 20～200 μ m.
Above-mentioned organic solvent is a kind of in trichloromethane, methylene dichloride, teos acid, acetone preferably.
The preparation method is:
S1: Resins, epoxy, modified rosin resin, chlorosulfonated polyethylene, natural rubber powder, clorafin, ferric oxide micro mist, magnesium oxide, carbon black, silane coupling agent, 1-isobutyl-3,5-dimethylhexylphosphoric acid, silicon sol, aluminium colloidal sol, acrylate, titanium dioxide, polymethylmethacrylate, α-cyanoacrylate, tritolyl phosphate, polyoxyethylene glycol, polylactic-co-glycolic acid are joined in the organic solvent, stir, as the A component;
S2: solidifying agent is dissolved in dimethyl formamide, stirs, as the B component;
S3: A component and B component are merged, stir, get tackiness agent.
Using method is: tackiness agent is put between viton and the metal, place 3h and be cured under 150～170 ℃ of conditions.
Technique effect
The epoxyn of viton provided by the invention and the gluing usefulness of metal does not need vulcanizable fluororubber in use, and bonding strength is high.
Embodiment
Prepare each component by the weight ratio shown in the table 1.
The weight proportion of table 1 embodiment 1～embodiment 3
Above-mentioned Resins, epoxy adopts E-40 Resins, epoxy.
Above-mentioned solidifying agent adopts triethylene tetramine.
The particle diameter of natural rubber powder is 20～200 μ m.
Above-mentioned organic solvent adopts trichloromethane.
The preparation method is:
S1: Resins, epoxy, modified rosin resin, chlorosulfonated polyethylene, natural rubber powder, clorafin, ferric oxide micro mist, magnesium oxide, carbon black, silane coupling agent, 1-isobutyl-3,5-dimethylhexylphosphoric acid, silicon sol, aluminium colloidal sol, acrylate, titanium dioxide, polymethylmethacrylate, α-cyanoacrylate, tritolyl phosphate, polyoxyethylene glycol, polylactic-co-glycolic acid are joined in the organic solvent, stir, as the A component;
S2: solidifying agent is dissolved in dimethyl formamide, stirs, as the B component;
S3: A component and B component are merged, stir, get tackiness agent.
Performance test
First that the steel test specimen of specified dimension is rustless to the surface with sand papering, re-use the acetone cleaning and degreasing, tackiness agent in above-described embodiment and solidifying agent are put on the steel test specimen by a certain percentage, again the viton plate is superimposed on the steel test specimen, under 160 ℃ of conditions, place 3h and be cured.Test at tension testing machine according to GB/T13936-92 " vulcanized rubber and metal sticking tensile shear strength measuring method ".To soak 72h in test specimen 0.5% sodium hydroxide solution again, after the taking-up, repeat above-mentioned test subject.Test-results is as shown in table 2.
The performance test data of table 2 embodiment 1～embodiment 3 and reference examples
Can find out, tackiness agent provided by the invention is carrying out viton and metal when bonding, and its bonding strength is good, and tensile shear strength can reach more than the 6.7MPa, is carrying out after corrodibility destroys, and its bonding strength also has no obvious reduction.
Claims (5)
1. the epoxyn of a viton and the gluing usefulness of metal, comprise A component and B component, described A component includes 30～40 parts of Resins, epoxy by weight, 5～6 parts of modified rosin resins, 2～3 parts of chlorosulfonated polyethylenes, 5～10 parts in natural rubber powder, 2～4 parts of clorafins, 2～4 parts of ferric oxide micro mists, 2～4 parts in magnesium oxide, 3～6 parts of carbon blacks, 2～3 parts of silane coupling agents, 1～2 part of 1-isobutyl-3,5-dimethylhexylphosphoric acid, 1～2 part of silicon sol, 1～2 part of aluminium colloidal sol, 1～3 part of acrylate, 1～2 part of titanium dioxide, 3～6 parts of polymethylmethacrylates, 3～6 parts of α-cyanoacrylates, 2～4 parts of tritolyl phosphates, 5～10 parts of polyoxyethylene glycol, 3～4 parts of polylactic-co-glycolic acids, 40～60 parts of organic solvents; Described B component includes 15～20 parts in solidifying agent, 20～30 parts of dimethyl formamides; Its preparation method is:
S1: Resins, epoxy, modified rosin resin, chlorosulfonated polyethylene, natural rubber powder, clorafin, ferric oxide micro mist, magnesium oxide, carbon black, silane coupling agent, 1-isobutyl-3,5-dimethylhexylphosphoric acid, silicon sol, aluminium colloidal sol, acrylate, titanium dioxide, polymethylmethacrylate, α-cyanoacrylate, tritolyl phosphate, polyoxyethylene glycol, polylactic-co-glycolic acid are joined in the organic solvent, stir, as the A component;
S2: solidifying agent is dissolved in dimethyl formamide, stirs, as the B component;
S3: A component and B component are merged, stir, get tackiness agent.
2. the epoxyn of viton according to claim 1 and the gluing usefulness of metal, it is characterized in that: described Resins, epoxy is E-40 Resins, epoxy, E-42 Resins, epoxy, E-44 Resins, epoxy.
3. the epoxyn of viton according to claim 1 and the gluing usefulness of metal is characterized in that: described solidifying agent is a kind of in quadrol, diethylenetriamine, triethylene tetramine, the tetraethylene pentamine.
4. the epoxyn of viton according to claim 1 and the gluing usefulness of metal, it is characterized in that: the particle diameter of described natural rubber powder is 20～200 μ m.
5. the epoxyn of viton according to claim 1 and the gluing usefulness of metal is characterized in that: described organic solvent is a kind of in trichloromethane, methylene dichloride, teos acid, the acetone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210352761 CN102876242B (en) | 2012-09-20 | 2012-09-20 | Epoxy resin adhesive for bonding fluororubber and metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210352761 CN102876242B (en) | 2012-09-20 | 2012-09-20 | Epoxy resin adhesive for bonding fluororubber and metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102876242A true CN102876242A (en) | 2013-01-16 |
| CN102876242B CN102876242B (en) | 2013-11-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210352761 Expired - Fee Related CN102876242B (en) | 2012-09-20 | 2012-09-20 | Epoxy resin adhesive for bonding fluororubber and metal |
Country Status (1)
| Country | Link |
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| CN (1) | CN102876242B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305134A (en) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | High temperature resisting magnesium phosphate adhesive with high strength and preparation method thereof |
| CN103805075A (en) * | 2014-02-25 | 2014-05-21 | 孟红琳 | Preparation method for composite adhesive for all-steel truck radical tire |
| CN104312506A (en) * | 2014-09-30 | 2015-01-28 | 苏州长盛机电有限公司 | Fluorosilicone-metal adhesive and preparation method thereof |
| CN104531028A (en) * | 2015-01-24 | 2015-04-22 | 李�杰 | Preparation method of modified epoxy resin adhesive for adhesion of silicon rubber and metal |
| CN106349954A (en) * | 2016-08-29 | 2017-01-25 | 郑丽芬 | Double-component tile-seam filling agent |
| CN106496670A (en) * | 2016-12-05 | 2017-03-15 | 苏州英得福机电科技有限公司 | A kind of natural rubber material |
| CN106750588A (en) * | 2016-12-05 | 2017-05-31 | 苏州英得福机电科技有限公司 | A kind of new waterproof elastomeric material |
| CN106750587A (en) * | 2016-12-05 | 2017-05-31 | 苏州英得福机电科技有限公司 | A kind of yielding rubber |
| CN108385848A (en) * | 2018-01-31 | 2018-08-10 | 安徽金丰新型建材有限公司 | A kind of sandwich board surface processing method of polyurethane core material |
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| JP2004076911A (en) * | 2002-08-22 | 2004-03-11 | Nok Corp | Rubber metal laminate gasket |
| CN101307216A (en) * | 2007-05-17 | 2008-11-19 | 西北工业大学 | Epoxy resin adhesive adhesive for adhering fluororubber with metal and method for preparing same |
| CN101983127A (en) * | 2008-04-04 | 2011-03-02 | Nok株式会社 | Fluororubber/metal layered gasket material |
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2012
- 2012-09-20 CN CN 201210352761 patent/CN102876242B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004076911A (en) * | 2002-08-22 | 2004-03-11 | Nok Corp | Rubber metal laminate gasket |
| CN101307216A (en) * | 2007-05-17 | 2008-11-19 | 西北工业大学 | Epoxy resin adhesive adhesive for adhering fluororubber with metal and method for preparing same |
| CN101983127A (en) * | 2008-04-04 | 2011-03-02 | Nok株式会社 | Fluororubber/metal layered gasket material |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305134B (en) * | 2013-06-24 | 2014-07-02 | 苏州新区佳合塑胶有限公司 | High temperature resisting magnesium phosphate adhesive with high strength and preparation method thereof |
| CN103305134A (en) * | 2013-06-24 | 2013-09-18 | 苏州新区佳合塑胶有限公司 | High temperature resisting magnesium phosphate adhesive with high strength and preparation method thereof |
| CN103805075B (en) * | 2014-02-25 | 2015-03-18 | 东莞市好东家汽车服务有限公司 | Preparation method for composite adhesive for all-steel truck radical tire |
| CN103805075A (en) * | 2014-02-25 | 2014-05-21 | 孟红琳 | Preparation method for composite adhesive for all-steel truck radical tire |
| CN104312506B (en) * | 2014-09-30 | 2016-06-01 | 苏州长盛机电有限公司 | A kind of trifluoropropyl siloxane-metal adhesive and its preparation method |
| CN104312506A (en) * | 2014-09-30 | 2015-01-28 | 苏州长盛机电有限公司 | Fluorosilicone-metal adhesive and preparation method thereof |
| CN104531028A (en) * | 2015-01-24 | 2015-04-22 | 李�杰 | Preparation method of modified epoxy resin adhesive for adhesion of silicon rubber and metal |
| CN104531028B (en) * | 2015-01-24 | 2016-08-31 | 郑州幼儿师范高等专科学校 | A kind of preparation method for silicone rubber Yu the modified epoxide resin adhesive of metal viscose glue |
| CN106349954A (en) * | 2016-08-29 | 2017-01-25 | 郑丽芬 | Double-component tile-seam filling agent |
| CN106496670A (en) * | 2016-12-05 | 2017-03-15 | 苏州英得福机电科技有限公司 | A kind of natural rubber material |
| CN106750588A (en) * | 2016-12-05 | 2017-05-31 | 苏州英得福机电科技有限公司 | A kind of new waterproof elastomeric material |
| CN106750587A (en) * | 2016-12-05 | 2017-05-31 | 苏州英得福机电科技有限公司 | A kind of yielding rubber |
| CN108385848A (en) * | 2018-01-31 | 2018-08-10 | 安徽金丰新型建材有限公司 | A kind of sandwich board surface processing method of polyurethane core material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102876242B (en) | 2013-11-06 |
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