CN106750648A - A kind of nitrile rubber washer oil seal material - Google Patents

A kind of nitrile rubber washer oil seal material Download PDF

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Publication number
CN106750648A
CN106750648A CN201611140631.9A CN201611140631A CN106750648A CN 106750648 A CN106750648 A CN 106750648A CN 201611140631 A CN201611140631 A CN 201611140631A CN 106750648 A CN106750648 A CN 106750648A
Authority
CN
China
Prior art keywords
parts
nitrile rubber
oil seal
seal material
colloidal silica
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611140631.9A
Other languages
Chinese (zh)
Inventor
王化勇
吴喜林
吕晓刚
张建华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhu Jituo Rubber Technologies Co Ltd
Original Assignee
Wuhu Jituo Rubber Technologies Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhu Jituo Rubber Technologies Co Ltd filed Critical Wuhu Jituo Rubber Technologies Co Ltd
Priority to CN201611140631.9A priority Critical patent/CN106750648A/en
Publication of CN106750648A publication Critical patent/CN106750648A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/10Materials in mouldable or extrudable form for sealing or packing joints or covers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/10Materials in mouldable or extrudable form for sealing or packing joints or covers
    • C09K2003/1034Materials or components characterised by specific properties
    • C09K2003/1078Fire-resistant, heat-resistant materials

Abstract

The invention discloses a kind of nitrile rubber washer oil seal material, the constituent of the oil sealing material is included:80 100 parts of nitrile rubber, 20 30 parts of N550 carbon blacks, 20 30 parts of fume colloidal silica, 35 parts of molybdenum bisuphide, 35 parts of polytetrafluoroethylene powder, 5 10 parts of ethers plasticizer, 0.5 part of sulphur, 1 4.5 parts of accelerator, 1 part of stearic acid, 13 parts of paraffin;Oil sealing self-lubricating property can be significantly improved by using molybdenum bisuphide, polytetrafluoroethylene powder, it is good low, sealing property to be worn away with bearing touch, again by using fume colloidal silica, improve sizing material heat resistance, at a relatively high elasticity is maintained, washer oil seal obtained in inventive formulation can for a long time be used under environment containing soap lye.

Description

A kind of nitrile rubber washer oil seal material
Technical field
The present invention relates to field of rubber technology, more particularly to a kind of nitrile rubber washer oil seal material.
Background technology
Nitrile rubber is that as obtained in butadiene and acrylonitrile through emulsion polymerization, nitrile rubber mainly uses low temperature emulsion Polymerization is produced, and oil resistivity is fabulous, and wearability is higher, and preferably, bonding force is strong for heat resistance, but the oil being made using nitrile rubber Envelope lower temperature resistance is poor, insulating properties are inferior, elasticity is slightly lower, therefore, solve the problems, such as that this class is particularly important.
The content of the invention
In view of the shortcomings of the prior art, oil sealing is improved the invention provides a kind of nitrile rubber washer oil seal material Elasticity and heat resistance.
In order to solve the above problems, the invention provides a kind of nitrile rubber washer oil seal material, the composition of the oil sealing material Composition is included:Nitrile rubber 80-100 parts, 20-30 parts of N550 carbon blacks, fume colloidal silica 20-30 parts, molybdenum bisuphide 3-5 Part, polytetrafluoroethylene powder 3-5 parts, 5-10 parts of ethers plasticizer, 0.5 part of sulphur, accelerator 1-4.5 parts, 1 part of stearic acid, paraffin 1-3 parts.
Further improvement is that:The constituent of the oil sealing material is included:90 parts of nitrile rubber, 25 parts of N550 carbon blacks, gas 25 parts of phase method white carbon, 4 parts of molybdenum bisuphide, 4 parts of polytetrafluoroethylene powder, 7 parts of ethers plasticizer, 0.5 part of sulphur, accelerator 3 Part, 1 part of stearic acid, 2 parts of paraffin.
Further improvement is that:The accelerator is 2- benzothiazolyl mercaptans or dibenzothiazyl disulfide.
The beneficial effects of the invention are as follows:The present invention can significantly improve oil sealing certainly using molybdenum bisuphide, polytetrafluoroethylene powder Greasy property, it is good with the low, sealing property of bearing touch abrasion, then by using fume colloidal silica, improve sizing material heat resistance Can, at a relatively high elasticity is maintained, washer oil seal obtained in inventive formulation can for a long time make under environment containing soap lye With.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention is further described below in conjunction with embodiment, the present embodiment It is only used for explaining the present invention, is not intended to limit the scope of the present invention..
Embodiment one
A kind of nitrile rubber washer oil seal material, the constituent of the oil sealing material is included:100 parts of nitrile rubber, N550 carbon blacks 30 parts, 30 parts of fume colloidal silica, 5 parts of molybdenum bisuphide, 5 parts of polytetrafluoroethylene powder, 10 parts of ethers plasticizer, 0.5 part of sulphur, 4.5 parts of accelerator, 1 part of stearic acid, 3 parts of paraffin, add up to 189 parts.The accelerator is 2- benzothiazolyl mercaptans or curing Bisbenzothiazole.
Embodiment two
A kind of nitrile rubber washer oil seal material, the constituent of the oil sealing material is included:80 parts of nitrile rubber, N550 carbon blacks 20 Part, 20 parts of fume colloidal silica, 3 parts of molybdenum bisuphide, 3 parts of polytetrafluoroethylene powder, 5 parts of ethers plasticizer, 0.5 part of sulphur, promotion 1 part of agent, 1 part of stearic acid, 1 part of paraffin, add up to 143.5 parts.The accelerator is 2- benzothiazolyl mercaptans or diphenyl disulfide And thiazole.
Embodiment three
A kind of nitrile rubber washer oil seal material, the constituent of the oil sealing material is included:90 parts of sound of chopping wood nitrile rubber, N550 carbon blacks 25 parts, 25 parts of fume colloidal silica, 4 parts of molybdenum bisuphide, 4 parts of polytetrafluoroethylene powder, 7 parts of ethers plasticizer, 0.5 part of sulphur, promote Enter 3 parts of agent, 1 part of stearic acid, 2 parts of paraffin, add up to 161.5 parts.The accelerator is 2- benzothiazolyl mercaptans or curing two Benzothiazole.
The present invention can significantly improve oil sealing self-lubricating property using molybdenum bisuphide, polytetrafluoroethylene powder, with bearing touch Wear away low, sealing property good, then by using fume colloidal silica, improve sizing material heat resistance, maintain at a relatively high Elasticity, washer oil seal obtained in inventive formulation can for a long time use under environment containing soap lye.

Claims (3)

1. a kind of nitrile rubber washer oil seal material, it is characterised in that the constituent of the oil sealing material is included:Nitrile rubber 80-100 parts, 20-30 parts of N550 carbon blacks, fume colloidal silica 20-30 parts, molybdenum bisuphide 3-5 parts, polytetrafluoroethylene powder 3-5 Part, 5-10 parts of ethers plasticizer, 0.5 part of sulphur, accelerator 1-4.5 parts, 1 part, paraffin 1-3 parts of stearic acid.
2. a kind of nitrile rubber washer oil seal material as claimed in claim 1, it is characterised in that:The constituent of the oil sealing material Include:90 parts of nitrile rubber, 25 parts of N550 carbon blacks, 25 parts of fume colloidal silica, 4 parts of molybdenum bisuphide, polytetrafluoroethylene powder 4 Part, 7 parts of ethers plasticizer, 0.5 part of sulphur, 3 parts of accelerator, 1 part of stearic acid, 2 parts of paraffin.
3. a kind of nitrile rubber washer oil seal material as described in claim 1 and 2 is any, it is characterised in that:The accelerator It is 2- benzothiazolyl mercaptans or dibenzothiazyl disulfide.
CN201611140631.9A 2016-12-12 2016-12-12 A kind of nitrile rubber washer oil seal material Pending CN106750648A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611140631.9A CN106750648A (en) 2016-12-12 2016-12-12 A kind of nitrile rubber washer oil seal material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611140631.9A CN106750648A (en) 2016-12-12 2016-12-12 A kind of nitrile rubber washer oil seal material

Publications (1)

Publication Number Publication Date
CN106750648A true CN106750648A (en) 2017-05-31

Family

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Family Applications (1)

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CN201611140631.9A Pending CN106750648A (en) 2016-12-12 2016-12-12 A kind of nitrile rubber washer oil seal material

Country Status (1)

Country Link
CN (1) CN106750648A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662491A (en) * 2020-06-04 2020-09-15 江门市鑫辉密封科技有限公司 Formula and preparation method of nitrile rubber
CN115572421A (en) * 2022-09-30 2023-01-06 上海熹贾精密技术有限公司 Wear-resistant nitrile rubber material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396591A (en) * 2013-06-14 2013-11-20 中国船舶重工集团公司第七二五研究所 Oilfield ultrahigh-pressure acid-resistant rubber seal material and preparation method thereof
CN104045876A (en) * 2014-06-25 2014-09-17 青岛国强环保科技有限公司 Rubber for shaft sleeves
CN104151641A (en) * 2014-07-15 2014-11-19 宁国天运橡塑制品有限公司 Oil-resistant sealing ring
CN105646964A (en) * 2014-12-01 2016-06-08 中国科学院兰州化学物理研究所 Silt environment resistant long-life water-lubricated bearing composite material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396591A (en) * 2013-06-14 2013-11-20 中国船舶重工集团公司第七二五研究所 Oilfield ultrahigh-pressure acid-resistant rubber seal material and preparation method thereof
CN104045876A (en) * 2014-06-25 2014-09-17 青岛国强环保科技有限公司 Rubber for shaft sleeves
CN104151641A (en) * 2014-07-15 2014-11-19 宁国天运橡塑制品有限公司 Oil-resistant sealing ring
CN105646964A (en) * 2014-12-01 2016-06-08 中国科学院兰州化学物理研究所 Silt environment resistant long-life water-lubricated bearing composite material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国化工学会橡胶专业委员会: "《橡胶助剂手册》", 30 April 2000, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111662491A (en) * 2020-06-04 2020-09-15 江门市鑫辉密封科技有限公司 Formula and preparation method of nitrile rubber
CN115572421A (en) * 2022-09-30 2023-01-06 上海熹贾精密技术有限公司 Wear-resistant nitrile rubber material and preparation method thereof

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Application publication date: 20170531