CN106747913A - A kind of nursery organic fertilizer carrier containing long-acting amino acid and preparation method thereof - Google Patents
A kind of nursery organic fertilizer carrier containing long-acting amino acid and preparation method thereof Download PDFInfo
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- CN106747913A CN106747913A CN201611025809.5A CN201611025809A CN106747913A CN 106747913 A CN106747913 A CN 106747913A CN 201611025809 A CN201611025809 A CN 201611025809A CN 106747913 A CN106747913 A CN 106747913A
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- rice
- amino acid
- rice husk
- preparation
- organic fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of nursery organic fertilizer carrier containing long-acting amino acid and preparation method thereof, it is made up of the raw material of following weight portion:Rice husk, 3 ~ 4mol/L NaOH solutions, ZnCl2、CuCl2, maize flour, plant ash, rape cake, rotten milk, EM bacteria agent, rice straw, brown sugar residue, rape stalk, cellulase preparation, dried silkworm chrysalis meal and appropriate water.Organic matter milk rich in protein, maize flour and rape cake etc. are fermented; by the way of liquid state fermentation, it is more thorough that aspect is fermented, while the organic product after fermentation is dissolved in water; the rice husk granular absorption of charing is recycled, the amino acid to decomposing is a protection very well.
Description
Technical field
The invention belongs to the technology field of fertilizer organic fertilizer, and in particular to a kind of nursery containing long-acting amino acid
Organic fertilizer carrier and preparation method thereof.
Background technology
China is Rice Production big country, and the rice husk for having tens million of tons every year is produced, and rice husk has content of ashes very high, and
And most in ash content is silica, therefore using rice husk as fuel, a kind of simply fuel of low heat value.Activated carbon has
Acid-fast alkali-proof, pore structure are flourishing, the characteristics of specific surface area is big, adsorption capacity is high, so active carbon adsorption is considered as one
Plant highly effective, economic sorbing material.
Rice husk is already known as fuel and feed, as fuel contamination environment, as feed then crude protein
Content be only 3%, and crude fibre amount up to more than 45%, digestible protein, digestible energy and metabolizable energy are all negative value, it is difficult to quilt
Poultry is digested and assimilated, and the absorption of wherein a large amount of crude protein and the influence of silicon industry to other nutriments.Silicon is rich in rice husk, is water
Rice absorbs enrichment, the distribution on rice husk, it is considered that silicon is mainly with a kind of nothing in growth and development process from soil
The presence of machine bonding scheme, it is thus proposed that silicon may be connected with organic group, with laboratory facilities and instrument and equipment in recent years
Constantly improve and development, by laboratory facilities such as wave spectrums, it is found that silicon is predominantly located at rice husk external skins and near grain of rice endodermis,
And there is part to be combined with polysaccharide, and find that two distributed areas binding properties have certain difference, in addition, practicing heavy wall between distributed area again
Also with the presence of certain silicon in cell tissue.
Charcoal is bio-organic materials(Biomass)In anoxic or anoxybiotic environment, what is generated after high temperature pyrolysis consolidates
State product.The high-quality energy, soil conditioner are can not only be used for, can also be sealed as reducing agent, fertilizer slow release carrier and carbon dioxide
Agent etc. is deposited, carbon fixation and emission reduction, water source purifying, heavy metal adsorption and soil improvement etc. is widely used to, can be to a certain extent
The whole world such as climate change, environmental pollution and soil function degeneration hot issue deeply concerned provides solution.Charcoal is almost
Pure carbon, burying to after underground can have hundreds of to the more than one thousand years will not to disappear, and soil has been entered equal to carbon sequestration.Charcoal is rich in micro-
Hole, can not only supplement the content of organics of soil, can also effectively preserve moisture and nutriment, increase soil fertility.It is true
On, why fertile soil is mostly presented black, just because phosphorus content reason high.Britain environmental protection great master James draws
Fu Luoke claims, and charcoal is the unique hope for mitigating Disastrous climate change.Researcher also illustrates that charcoal can also improve agriculture
Industry productivity ratio, reduces the demand to the intensive fertilizer of carbon.The pore space structure of charcoal particle very easy aggregation nutriment and beneficial
Microorganism, so that soil becomes fertile, beneficial to plant growth, realizes allowing agricultural to have more continuation while volume increase.Still better
It is that it is locked in carbon in biota, rather than allows it to be discharged into air.
The content of the invention
The present invention is in order to optimize the mode that organic fertilizer is used in field, it is to avoid present in actually used:It is single organic
The problem that fertile usage amount is big, inorganic nutrients are not enough etc., using desiliconization rice hull carbon for main body is prepared for a kind of organic fertilizer carrier, specifically
It is realized by the following method:
A kind of nursery organic fertilizer carrier containing long-acting amino acid, it is characterised in that be made up of the raw material of following weight portion:Rice husk
30 ~ 40,3 ~ 4mol/L NaOH solutions 80 ~ 120, ZnCl2 5~10、CuCl20.5 ~ 1.0, maize flour 10 ~ 20, plant ash 3 ~ 6,
Rape cake 40 ~ 60, rotten milk 25 ~ 30, EM bacteria agent 2 ~ 3, rice straw 40 ~ 50, brown sugar residue 10 ~ 16, rape stalk 20 ~ 30,
Cellulase preparation 0.5 ~ 1.0, dried silkworm chrysalis meal 6 ~ 10 and appropriate water.
A kind of preparation method of the nursery organic fertilizer carrier containing long-acting amino acid, it is characterised in that including following
Step:
(1)Rice husk is dried into rear grinding particulate, is subsequently adding in 3 ~ 4mol/L NaOH solutions, oil bath heating to 80 ~ 90 DEG C of bars
Under part, insulation is slowly stirred 6 ~ 8h, pulls rice husk particle out, is dried after hot bath washing by soaking to neutrality, and desiliconization rice husk is obtained
Grain;
(2)Mixing ZnCl2、CuCl2And add the water of 10 ~ 15 times of its gross weights to be diluted to mixed solution, add(1)Described rice
Shell particle 20 ~ 25h of impregnating active, after the completion of be put into 1.0 ~ 1.5h of closed charing in 500 ~ 600 DEG C of retorts, wash and dry;
(3)Slag is broken into after rape straw and rice straw are mixed, by weight 1:2 ~ 4 ratio is soaked, while plus
Enter cellulase preparation to be digested, after the completion of worry too much and stalk slag and grind to form pulvis;
(4)Mixing plant ash, brown sugar residue and other following residual components being not directed to, are milled to after being homogenized and are transferred to fermentation tank and add
Enter(3)Gained enzymolysis liquid, high-temperature sterilization is inoculated with EM bacteria agent, and 10 ~ 15L/min of blowing air, 150 ~ 200r/min of speed of agitator is carried out
50 ~ 70h of liquid state fermentation;
(5)It is right(4)Tunning carry out filtering to obtain zymotic fluid, add(2)Charing particle first adsorb 20 ~ 30min, finally plus
Enter(3)Gained pulvis, mixing.
The example that biomass carbon is applied into organic fertilizer is very common, and the present invention is of course not merely by biomass carbon
Simply added, our company is, by years of researches, biomass carbon not only to be applied to the production of fertilizer, while
Also apply to the fields such as cement, mortar and silica gel.Here by constantly exploration discovery, biomass carbon also has as adsorbent
There is the possibility of further investigation.
Invention with rice husk as stock, due to silicon in rice husk with SiO2Form is present, and is mentioned according to background technology,
The overwhelming majority is present in the SiO of rice husk2Outer surface and endodermis, first with NaOH solution immersion dissolving SiO2As silicate and
Hydrogen, so that departing from rice husk, leaves larger pore structure on rice husk, virtually increases the specific surface area of rice husk.
The final product rice hull carbon of invention is used to adsorb organic matter, and the final product after organic matter fermentation is often
Organic acid product is in the majority, and invention from this viewpoint, the oxidation of metal ion is carried out using the rice husk of desiliconization again, adds metal
Ion-oxygen agent carries out the activation to desiliconization rice husk, and that show that optimum chemical reagent selects by test of many times is ZnCl2
And CuCl2Mixed solution.The rice husk of desiliconization treatment, rice husk loses the effective SiO of surfaces externally and internally2Natural defence, exposed inner has
Machine macro-radical, in Cu2+And Zn2+Oxidation under turn into slough part OH-, make entirety with positive charge, and after fermenting
Organic matter in organic acid it is on the high side, organic acid can ionize out H+, therefore negative electrical charge is presented, even if also will not be to electricity after charing
The distribution of lotus produces large effect, there is mutual attraction absorption after so forming charge difference.
Beneficial effects of the present invention:Organic matter milk rich in protein, maize flour and rape cake etc. are fermented, is adopted
With the mode of liquid state fermentation, it is more thorough that aspect is fermented, while the organic product after fermentation is dissolved in water, recycles charcoal
The rice husk granular absorption of change, the amino acid to decomposing is a protection very well, and the activity time of organic fermentate is maintained for a long time,
Organic fertilizer rich in amino acid is all helpful to the growth of seedling and later resistance.
Specific embodiment
Embodiment 1:
A kind of nursery organic fertilizer carrier containing long-acting amino acid, it is characterised in that by following weight portion(Kg)Raw material be made:
Rice husk 35,3 ~ 4mol/L NaOH solutions 100, ZnCl2 8、CuCl20.6th, maize flour 15, plant ash 5, rape cake 55, rotten ox
Milk 26, EM bacteria agent 2, rice straw 42, brown sugar residue 12, rape stalk 25, cellulase preparation 0.8, dried silkworm chrysalis meal 8 and appropriate
Water.
A kind of preparation method of the nursery organic fertilizer carrier containing long-acting amino acid, it is characterised in that including following
Step:
(1)Rice husk is dried into rear grinding particulate, is subsequently adding in 3 ~ 4mol/L NaOH solutions, oil bath heating to 80 ~ 90 DEG C of bars
Under part, insulation is slowly stirred 6 ~ 8h, pulls rice husk particle out, is dried after hot bath washing by soaking to neutrality, and desiliconization rice husk is obtained
Grain;
(2)Mixing ZnCl2、CuCl2And add the water of 10 ~ 15 times of its gross weights to be diluted to mixed solution, add(1)Described rice
Shell particle 20 ~ 25h of impregnating active, after the completion of be put into 1.0 ~ 1.5h of closed charing in 500 ~ 600 DEG C of retorts, wash and dry;
(3)Slag is broken into after rape straw and rice straw are mixed, by weight 1:2 ~ 4 ratio is soaked, while plus
Enter cellulase preparation to be digested, after the completion of worry too much and stalk slag and grind to form pulvis;
(4)Mixing plant ash, brown sugar residue and other following residual components being not directed to, are milled to after being homogenized and are transferred to fermentation tank and add
Enter(3)Gained enzymolysis liquid, high-temperature sterilization is inoculated with EM bacteria agent, and 10 ~ 15L/min of blowing air, 150 ~ 200r/min of speed of agitator is carried out
50 ~ 70h of liquid state fermentation;
(5)It is right(4)Tunning carry out filtering to obtain zymotic fluid, add(2)Charing particle first adsorb 20 ~ 30min, finally plus
Enter(3)Gained pulvis, mixing.
The inorganic nutritive element of pepper planting is added to molten condition, by 1:1 ratio adds organic fertilizer of the present invention
Carrier, granulation, for the planting experiment of capsicum, relatively in the past without the way of carrier, more preferably, resistance increases the growing way of capsicum
By force, soil water-retaining, fertilizer-preserving ability are more preferable.
Claims (2)
1. a kind of nursery organic fertilizer carrier containing long-acting amino acid, it is characterised in that be made up of the raw material of following weight portion:Rice
Shell 30 ~ 40,3 ~ 4mol/L NaOH solutions 80 ~ 120, ZnCl2 5~10、CuCl20.5 ~ 1.0, maize flour 10 ~ 20, plant ash 3 ~
6th, rape cake 40 ~ 60, rotten milk 25 ~ 30, EM bacteria agent 2 ~ 3, rice straw 40 ~ 50, brown sugar residue 10 ~ 16, rape stalk 20 ~
30th, cellulase preparation 0.5 ~ 1.0, dried silkworm chrysalis meal 6 ~ 10 and appropriate water.
2. a kind of preparation method of the nursery organic fertilizer carrier containing long-acting amino acid according to claim 1, its feature exists
In, including following steps:
(1)Rice husk is dried into rear grinding particulate, is subsequently adding in 3 ~ 4mol/L NaOH solutions, oil bath heating to 80 ~ 90 DEG C of bars
Under part, insulation is slowly stirred 6 ~ 8h, pulls rice husk particle out, is dried after hot bath washing by soaking to neutrality, and desiliconization rice husk is obtained
Grain;
(2)Mixing ZnCl2、CuCl2And add the water of 10 ~ 15 times of its gross weights to be diluted to mixed solution, add(1)Described rice
Shell particle 20 ~ 25h of impregnating active, after the completion of be put into 1.0 ~ 1.5h of closed charing in 500 ~ 600 DEG C of retorts, wash and dry;
(3)Slag is broken into after rape straw and rice straw are mixed, by weight 1:2 ~ 4 ratio is soaked, while plus
Enter cellulase preparation to be digested, after the completion of worry too much and stalk slag and grind to form pulvis;
(4)Mixing plant ash, brown sugar residue and other following residual components being not directed to, are milled to after being homogenized and are transferred to fermentation tank and add
Enter(3)Gained enzymolysis liquid, high-temperature sterilization is inoculated with EM bacteria agent, and 10 ~ 15L/min of blowing air, 150 ~ 200r/min of speed of agitator is carried out
50 ~ 70h of liquid state fermentation;
(5)It is right(4)Tunning carry out filtering to obtain zymotic fluid, add(2)Charing particle first adsorb 20 ~ 30min, finally plus
Enter(3)Gained pulvis, mixing.
Priority Applications (1)
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CN201611025809.5A CN106747913A (en) | 2016-11-22 | 2016-11-22 | A kind of nursery organic fertilizer carrier containing long-acting amino acid and preparation method thereof |
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CN201611025809.5A CN106747913A (en) | 2016-11-22 | 2016-11-22 | A kind of nursery organic fertilizer carrier containing long-acting amino acid and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108314524A (en) * | 2018-03-13 | 2018-07-24 | 时科生物科技(上海)有限公司 | A kind of liquid fertilizer prepared as raw material using charcoal |
CN113501738A (en) * | 2021-08-06 | 2021-10-15 | 歙县霜蕊菊花研究所 | Multifunctional camellia chrysanthemum biogas slurry medicinal fertilizer and preparation process thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102126884A (en) * | 2010-01-12 | 2011-07-20 | 崔士明 | Novel long-acting compound fertilizer |
CN104829308A (en) * | 2015-04-11 | 2015-08-12 | 铜陵家宴生态农业发展有限公司 | Multifunctional coating farmland fertilizer and preparation method thereof |
-
2016
- 2016-11-22 CN CN201611025809.5A patent/CN106747913A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102126884A (en) * | 2010-01-12 | 2011-07-20 | 崔士明 | Novel long-acting compound fertilizer |
CN104829308A (en) * | 2015-04-11 | 2015-08-12 | 铜陵家宴生态农业发展有限公司 | Multifunctional coating farmland fertilizer and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108314524A (en) * | 2018-03-13 | 2018-07-24 | 时科生物科技(上海)有限公司 | A kind of liquid fertilizer prepared as raw material using charcoal |
CN113501738A (en) * | 2021-08-06 | 2021-10-15 | 歙县霜蕊菊花研究所 | Multifunctional camellia chrysanthemum biogas slurry medicinal fertilizer and preparation process thereof |
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Application publication date: 20170531 |
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