CN106747639A - A kind of foamed concrete thermal-insulating material - Google Patents

A kind of foamed concrete thermal-insulating material Download PDF

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Publication number
CN106747639A
CN106747639A CN201611209285.5A CN201611209285A CN106747639A CN 106747639 A CN106747639 A CN 106747639A CN 201611209285 A CN201611209285 A CN 201611209285A CN 106747639 A CN106747639 A CN 106747639A
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China
Prior art keywords
insulating material
foamed concrete
concrete thermal
fiber
present
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CN201611209285.5A
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Chinese (zh)
Inventor
王云伍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing Dacheng Anticorrosion Insulation Material Co Ltd
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Anqing Dacheng Anticorrosion Insulation Material Co Ltd
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Priority to CN201611209285.5A priority Critical patent/CN106747639A/en
Publication of CN106747639A publication Critical patent/CN106747639A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to building thermal insulation material field, more particularly to a kind of foamed concrete thermal-insulating material.A kind of foamed concrete thermal-insulating material, by percentage to the quality, is made up of following components:Cement 31~46%, slag powders 7~20%, gypsum 14~21%, feldspar powder 10~18%, river sand 9~14%, foam stabilizer 2~3.5%, foaming agent 1~3%, fiber 0.9~1.4%, coagulant 0.3~0.8%, water reducer 0.2~0.6%, waterproofing agent 0.1~0.4%.The beneficial effects of the present invention are:By the reasonably combined of each component, with good mechanical property, thermal and insulating performance and water resistance;Especially medium density, heat-insulating property is good, and thermal conductivity factor is low.

Description

A kind of foamed concrete thermal-insulating material
Technical field
The present invention relates to building thermal insulation material field, more particularly to a kind of foamed concrete thermal-insulating material.
Background technology
Foam concrete is most widely applied early in American-European countries such as the U.S., Britain, Holland, and China is also increasingly Pay attention to Building Energy-saving Work, in recent years, the research and development of foam concrete are all paid much attention to both at home and abroad, foam concrete is with it Lightweight, thermal and insulating performance are good, sound-proof refractory is good, foam concrete also has that pumpability is good, waterproof ability is strong, in regulation room Humidity, can largely utilize industrial residue the advantages of, be widely used rapidly.
Foam concrete is mainly to be made up of calcareous material and siliceous material, but density reduction while thermal conductivity factor also with Reduction.And excessive density it is too low when, the integrality of foam concrete pore structure can be destroyed again.Foam concrete heat-preserving material It is Binder Materials that material mainly uses sulphate aluminium cement, ferrous aluminate cement, when this is primarily due to such cement setting hardening Between the development of short, early strength it is fast, it is good with gas production rate uniformity that it condenses hardening rate.But its price is higher, and this kind of , less than Portland cement product, during particularly for external wall, product service life can be big for the durability of cement products It is big to shorten.
And it is also common fault that current cellular concrete product is present that water absorption rate height is, too high water absorption rate can cause foam to mix Coefficient of softing, frost resistance, service life of solidifying soil product etc. are remarkably decreased, and greatly hinder being applied clinically and popularized for foam concrete.
At present, feasible solution is when to select effective efficiency additive by suitable cooperation, to above mentioned problem It is improved.
The content of the invention
It is an object of the invention to provide a kind of foamed concrete thermal-insulating material, with good mechanical property, insulation Performance and water resistance, cost-effective solution problems of the prior art.
Concrete technical scheme of the present invention is as follows:
A kind of foamed concrete thermal-insulating material, by percentage to the quality, is made up of following components:
Cement 31~46%, slag powders 7~20%, gypsum 14~21%, feldspar powder 10~18%, river sand 9~14%, surely Infusion 2~3.5%, foaming agent 1~3%, fiber 0.9~1.4%, coagulant 0.3~0.8%, water reducer 0.2~0.6% is prevented Aqua 0.1~0.4%.
Further, a kind of foamed concrete thermal-insulating material, by percentage to the quality, is made up of following components:
Cement 46%, slag powders 9.6%, gypsum 17.4%, feldspar powder 10%, river sand 10.2%, foam stabilizer 2%, foaming Agent 2%, fiber 1.4%, coagulant 0.5%, water reducer 0.5%, waterproofing agent 0.4%.
Further, a kind of foamed concrete thermal-insulating material, by percentage to the quality, is made up of following components:
Cement 31%, slag powders 16.1%, gypsum 16.7%, feldspar powder 15.4%, river sand 13.6%, foam stabilizer 2.2%, Foaming agent 3%, fiber 1.1%, coagulant 0.3%, water reducer 0.2%, waterproofing agent 0.4%.
Further, the slag powders are S95 grades of ground blast furnace slag powder.
Further, the diameter of the river sand is between 0.5~2mm.
Further, the diameter of the fiber is between 5~12mm.
Further, the fiber uses polypropylene fibre or short glass fiber.
Further, the coagulant uses sodium metaaluminate.
Further, the water reducer uses the aqueous water reducer of polycarboxylic-acid.
Further, the waterproofing agent uses odium stearate or aquation dicalcium silicate.
The present invention compared with prior art, has the advantages that:
(1) foamed concrete thermal-insulating material of the invention is reasonably combined by each component, with good mechanical property, Thermal and insulating performance and water resistance;Especially medium density, heat-insulating property is good, and thermal conductivity factor is low.
(2) all there is certain shrinkage in cement products, and slag powders can reduce the adiabatic temperature rise of concrete, reduce mixed The dry-shrinkage deformed and time deformation of soil is coagulated, volume stability is improved.Feldspar powder, river sand, fiber can improve product shear strength, Rupture strength and wearability.
(3) gypsum not only can shorten setting time, while early strength can also be improved.
(4) foam stabilizer can significantly improve the foam structure of foam concrete, its inner cell is become tiny, size equal First, spherical degree is high, connected ratio reduction between abscess.
(5) the foaming agent foaming that the present invention is used is fast, and foam volume is big, but it is more difficult to deposit bubble, less stable, but coordinates After above-mentioned foam stabilizer, ensure bubble it is many, foaming soon in the case of, deposit bubble rate and also significantly improve.
(6) it is raw material that Portland cement is selected in the present invention, when coagulant can effectively overcome it to condense hardening Between slow shortcoming.
(7) water reducer can significantly reduce the slurry ratio of mud in the case of foam concrete slurry workability identical is ensured. Aqueous polycarboxylate water-reducer is used to reduce and condense firm time with reduces cost, dispersion efficiency can also be far above dry powder-shaped system Agent, reduces mixing water amount, improves the consistency of cell wall.
(8) it is to reduce that foam concrete water absorption rate is most effective, easily method to add waterproofing agent, can significantly improve sample Water resistance and it has good adaptability with low density foam concrete system, will not only destroy bubble when being directly incorporated into Pore structure is acted on certain foam stabilizing on the contrary.
Specific embodiment
It is clearly and completely described below in conjunction with embodiment specific embodiment of the invention, it is clear that described Embodiment is a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
A kind of foamed concrete thermal-insulating material, by percentage to the quality, is made up of following components:
Cement 31~46%, slag powders 7~20%, gypsum 14~21%, feldspar powder 10~18%, river sand 9~14%, surely Infusion 2~3.5%, foaming agent 1~3%, fiber 0.9~1.4%, coagulant 0.3~0.8%, water reducer 0.2~0.6% is prevented Aqua 0.1~0.4%.
Heretofore described cement uses 42.5 grades or 52.5 grades of portland cements, it is preferred that use 42.5 grades of silicate Cement.
Heretofore described slag powders are S95 grades of ground blast furnace slag powder.
Heretofore described feldspar powder is preferred, using feldspar in powder.
Heretofore described gypsum is using granularity in 100~300 mesh land plasters.
The diameter of heretofore described river sand is between 0.5~2mm.
Heretofore described foam stabilizer uses polyvinyl alcohol or polyacrylamide, it is preferred that use polyvinyl alcohol.
Heretofore described foaming agent uses aquation dicalcium silicate or cetyl benzenesulfonic acid sodium, it is preferred that use 16 Sodium alkyl benzene sulfonate.
The diameter of heretofore described fiber is between 5~12mm.
Heretofore described fiber uses polypropylene fibre or short glass fiber, it is preferred that use short glass fiber.
Heretofore described coagulant uses sodium metaaluminate.
Heretofore described water reducer uses the aqueous water reducer of polycarboxylic-acid.
Heretofore described waterproofing agent uses odium stearate or aquation dicalcium silicate, it is preferred that use aquation dicalcium silicate.
Embodiment 1
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 35.5%, slag powders 20%, gypsum 14%, feldspar powder 12.2%, river sand 11.8%, foam stabilizer 2.7%, hair Infusion 1.3%, fiber 1.2%, coagulant 0.6%, water reducer 0.3%, waterproofing agent 0.1%.
Described in the present embodiment, cement uses 42.5 grades or 52.5 grades of portland cements, and the present embodiment is with 42.5 grades of silicic acid Illustrated as a example by salt cement.
Described in the present embodiment, slag powders are S95 grades of ground blast furnace slag powder.
Described in the present embodiment, feldspar powder is preferred, using feldspar in powder.
Described in the present embodiment, gypsum is using granularity in 100~300 mesh land plasters.
Described in the present embodiment, the diameter of river sand is between 0.5~2mm.
Described in the present embodiment, foam stabilizer uses polyvinyl alcohol or polyacrylamide, and the present embodiment is by taking polyvinyl alcohol as an example Illustrate.
Described in the present embodiment, foaming agent uses aquation dicalcium silicate or cetyl benzenesulfonic acid sodium, and the present embodiment is with ten Illustrated as a example by six sodium alkyl benzene sulfonates.
Described in the present embodiment, the diameter of fiber is between 5~12mm.
Described in the present embodiment, fiber uses polypropylene fibre or short glass fiber, and the present embodiment is fine with staple glass Illustrated as a example by dimension.
Described in the present embodiment, coagulant uses sodium metaaluminate.
Described in the present embodiment, water reducer uses the aqueous water reducer of polycarboxylic-acid.
Described in the present embodiment, waterproofing agent uses odium stearate or aquation dicalcium silicate, and the present embodiment is with aquation silicic acid two Illustrated as a example by calcium.
The preparation method of the foamed concrete thermal-insulating material described in the present embodiment, comprises the following steps:
According to mass percent, cement, slag powders, gypsum, feldspar powder, river sand, coagulant and waterproofing agent are mixed, and stir Mix uniform, obtain mixed powder;The aqueous water reducer of polycarboxylic-acid is soluble in water, and the consumption of water is about the 0.38 of the mixed powder ~0.45 times;Foam stabilizer is subsequently adding, 2-5min is mixed with the speed of 15~25r/min;Add foaming agent and cement mortar 1-3min is mixed under the speed of 250-300r/min;Stand 1~2 minute;Mould, 80 DEG C of drying, normal temperature is added to conserve, Obtain foamed concrete thermal-insulating material.
Embodiment 2
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 36.8%, slag powders 14.3%, gypsum 19.8%, feldspar powder 13.6%, river sand 9%, foam stabilizer 2.4%, Foaming agent 2.2%, fiber 1%, coagulant 0.3%, water reducer 0.4%, waterproofing agent 0.2%.
Embodiment 3
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 46%, slag powders 9.6%, gypsum 17.4%, feldspar powder 10%, river sand 10.2%, foam stabilizer 2%, foaming Agent 2%, fiber 1.4%, coagulant 0.5%, water reducer 0.5%, waterproofing agent 0.4%.
Embodiment 4
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 45.3%, slag powders 7%, gypsum 15.5%, feldspar powder 11.6%, river sand 14%, foam stabilizer 3.2%, hair Infusion 1%, fiber 1.3%, coagulant 0.7%, water reducer 0.4%, waterproofing agent 0.2%.
Embodiment 5
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 32.9%, slag powders 12.2%, gypsum 20.6%, feldspar powder 17.3%, river sand 9.7%, foam stabilizer 2.8%, foaming agent 2.5%, fiber 0.9%, coagulant 0.4%, water reducer 0.6%, waterproofing agent 0.4%.
Embodiment 6
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 26.1%, slag powders 18.9%, gypsum 21%, feldspar powder 14.9%, river sand 12%, foam stabilizer 3.5%, hair Infusion 1.5%, fiber 1.2%, coagulant 0.4%, water reducer 0.2%, waterproofing agent 0.3%.
Embodiment 7
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 37%, slag powders 8.5%, gypsum 18.1%, feldspar powder 18%, river sand 11.5%, foam stabilizer 3%, foaming Agent 1.8%, fiber 0.9%, coagulant 0.8%, water reducer 0.3%, waterproofing agent 0.1%.
Embodiment 8
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 31%, slag powders 16.1%, gypsum 16.7%, feldspar powder 15.4%, river sand 13.6%, foam stabilizer 2.2%, Foaming agent 3%, fiber 1.1%, coagulant 0.3%, water reducer 0.2%, waterproofing agent 0.4%.
Embodiment 9
The present embodiment is improved on the basis of embodiment 1, and the content described in embodiment 1 is also the present embodiment institute Have, no longer specifically repeat herein.
Described in the present embodiment, a kind of foamed concrete thermal-insulating material by percentage to the quality, is made up of following components:
Cement 44.3%, slag powders 7.4%, gypsum 14.7%, feldspar powder 12.8%, river sand 13.1%, foam stabilizer 2.5%, foaming agent 2.8%, fiber 1.3%, coagulant 0.5%, water reducer 0.3%, waterproofing agent 0.3%.
Performance evaluation is carried out to foamed concrete thermal-insulating material obtained in above-described embodiment 1~9, result such as following table is obtained:
As seen from the above table, in embodiment 3, when fiber and feldspar powder addition are larger, the rupture strength of material is substantially carried Height, and the rational proportion for passing through different component, other performances are also showed well;In embodiment 8, when foaming agent addition is larger When, there is obvious influence on density, and when waterproofing agent addition is larger, water absorption rate also can be reduced substantially, illustrate this hair Component in bright can be effectively combined to material, adapt to and regulation.
Finally it should be noted that:Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations;To the greatest extent Pipe has been described in detail with reference to foregoing embodiments to the present invention, it will be understood by those within the art that:Its according to The technical scheme described in foregoing embodiments can so be modified, or which part or all technical characteristic are entered Row equivalent;And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology The scope of scheme.

Claims (10)

1. a kind of foamed concrete thermal-insulating material, it is characterised in that by percentage to the quality, be made up of following components:
Cement 31~46%, slag powders 7~20%, gypsum 14~21%, feldspar powder 10~18%, river sand 9~14%, foam stabilizer 2~3.5%, foaming agent 1~3%, fiber 0.9~1.4%, coagulant 0.3~0.8%, water reducer 0.2~0.6%, waterproofing agent 0.1~0.4%.
2. foamed concrete thermal-insulating material as claimed in claim 1, it is characterised in that by percentage to the quality, by following groups It is grouped into:
Cement 46%, slag powders 9.6%, gypsum 17.4%, feldspar powder 10%, river sand 10.2%, foam stabilizer 2%, foaming agent 2%, fiber 1.4%, coagulant 0.5%, water reducer 0.5%, waterproofing agent 0.4%.
3. foamed concrete thermal-insulating material as claimed in claim 2, it is characterised in that by percentage to the quality, by following groups It is grouped into:
Cement 31%, slag powders 16.1%, gypsum 16.7%, feldspar powder 15.4%, river sand 13.6%, foam stabilizer 2.2%, foaming Agent 3%, fiber 1.1%, coagulant 0.3%, water reducer 0.2%, waterproofing agent 0.4%.
4. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the slag powders are S95 Level ground blast furnace slag powder.
5. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the diameter of the river sand exists Between 0.5~2mm.
6. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the diameter of the fiber exists Between 5~12mm.
7. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the fiber uses poly- third Alkene fiber or short glass fiber.
8. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the foam stabilizer is using inclined Sodium aluminate.
9. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the water reducer is using poly- The aqueous water reducer of carboxylic serials.
10. the foamed concrete thermal-insulating material as described in claim any one of 1-3, it is characterised in that the waterproofing agent is used Odium stearate or aquation dicalcium silicate.
CN201611209285.5A 2016-12-23 2016-12-23 A kind of foamed concrete thermal-insulating material Withdrawn CN106747639A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108484056A (en) * 2018-05-31 2018-09-04 诺弗斯绝热材料有限公司 A kind of freeze proof thermal insulation concrete material
CN109320284A (en) * 2018-11-30 2019-02-12 张竹昌 A kind of porous heat-insulating brick

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260065A (en) * 2011-05-25 2011-11-30 南京工业大学 Foam concrete and preparation method thereof
CN102887663A (en) * 2012-10-15 2013-01-23 同济大学 Compound foaming agent for foam concrete and preparation method thereof
CN104108912A (en) * 2014-06-19 2014-10-22 广东省建筑科学研究院 Lightweight high-performance foam concrete and preparation method thereof
CN104478362A (en) * 2014-12-24 2015-04-01 徐立新 Self-insulation foam concrete building block as well as manufacturing technology and mounting method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102260065A (en) * 2011-05-25 2011-11-30 南京工业大学 Foam concrete and preparation method thereof
CN102887663A (en) * 2012-10-15 2013-01-23 同济大学 Compound foaming agent for foam concrete and preparation method thereof
CN104108912A (en) * 2014-06-19 2014-10-22 广东省建筑科学研究院 Lightweight high-performance foam concrete and preparation method thereof
CN104478362A (en) * 2014-12-24 2015-04-01 徐立新 Self-insulation foam concrete building block as well as manufacturing technology and mounting method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108484056A (en) * 2018-05-31 2018-09-04 诺弗斯绝热材料有限公司 A kind of freeze proof thermal insulation concrete material
CN109320284A (en) * 2018-11-30 2019-02-12 张竹昌 A kind of porous heat-insulating brick

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Application publication date: 20170531