CN105503046A - High-performance heat-preservation thermal-insulation wall material - Google Patents

High-performance heat-preservation thermal-insulation wall material Download PDF

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Publication number
CN105503046A
CN105503046A CN201510584932.XA CN201510584932A CN105503046A CN 105503046 A CN105503046 A CN 105503046A CN 201510584932 A CN201510584932 A CN 201510584932A CN 105503046 A CN105503046 A CN 105503046A
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China
Prior art keywords
wall material
parts
performance heat
heat
water
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Pending
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CN201510584932.XA
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Chinese (zh)
Inventor
张津践
朱蓬莱
王建英
牛茂威
张小兵
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Zhejiang Nanxing Test For Construction Co Ltd
Hangzhou Laibaode New Material Technology Co Ltd
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Zhejiang Nanxing Test For Construction Co Ltd
Hangzhou Laibaode New Material Technology Co Ltd
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Application filed by Zhejiang Nanxing Test For Construction Co Ltd, Hangzhou Laibaode New Material Technology Co Ltd filed Critical Zhejiang Nanxing Test For Construction Co Ltd
Priority to CN201510584932.XA priority Critical patent/CN105503046A/en
Publication of CN105503046A publication Critical patent/CN105503046A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a preparation method of a high-performance heat-preservation thermal-insulation wall material. The high-performance heat-preservation thermal-insulation wall material comprises, by weight, 20-40 parts of cement, 10-30 parts of ceramsite, 20-40 parts of blast furnace slag and 30-50 parts of fly ash. The high-performance heat-preservation thermal-insulation wall material has a sand ratio of 39-42%, contains 0.2-0.5% of silicon oxide aerogel based on dry materials, contains a water reducer of which the use amount is determined according to fluidity and has a water-binder ratio of 0.45-0.50. The preparation method comprises dispersing prepared silicon oxide aerogel in water, uniformly mixing cement, ceramsite, blast furnace slag and fly ash according to the above ratio to obtain a uniform mixture, adding a water reducer into water, carrying out strong stirring, carrying out casting according to a certain volume ratio and carrying out maintenance to obtain the high-performance heat-preservation thermal-insulation wall material with excellent thermal insulation and high strength. The high-performance heat-preservation thermal-insulation wall material has light weight, thermal-insulation effects, high strength and good fireproof performances.

Description

A kind of high-performance heat-preserving heat-insulating wall material
Technical field
The present invention relates to building thermal insulation material and field of engineering technology, be specifically related to a kind of high-performance heat-preserving heat-insulating wall material and preparation method thereof.
Background technology
Materials for wall is maximum, the indispensable material of construction of building field consumption, and its development has close relationship with the energy, environment.For many years, construction wall generally adopts single-material, as hollow concrete block wall, vacation concrete wall etc.
Because single-material thermal conductivity is comparatively large, can not meet heat insulating requirement, therefore, need often to adopt material and thermal insulation material (as rock wool, mineral wool, polystyrene board etc.) in city according to building energy conservation form combined wall.Combined wall has played the strong point of bi-material well, and body of wall both can not have been made blocked up, again can load-bearing, and heat insulation effect is good again.
Exterior wall internal insulation now Insulation is major way mainly with rock wool or mineral wool and plasterboard compound, glass wool and plasterboard compound, polystyrene foamed plastics and plasterboard compound, aerated plaster plate and body of wall smear adiabatic mortar greatly.But the current performance such as insulating wall material intensity, weather resistance is still far below traditional bearing wall.
The advantages such as the method described in this patent utilizes silica aerogel thermal conductivity low, and fire resistance is good, can utilize slag and flyash, resource utilization degree is high, environment-friendly high-efficiency simultaneously.
Summary of the invention
The object of the invention is to build concrete heat-insulating heat-shielding net on both macro and micro two yardstick, thus develop a kind of high-performance heat-preserving heat-insulating wall material of exploitation and preparation technology thereof, the heat insulation haydite primarily of porous wherein in macro-scale realizes, and heat insulation on micro-scale realizes primarily of micron-sized silica aerogel powder.
Object of the present invention is achieved through the following technical solutions (this part is revised according to the mode of claim.)
Bottom solid material to add water mixing by following composition and quality proportioning: cement 20 ~ 40 parts, haydite 10 ~ 30 parts, blast-furnace slag 20 ~ 40 parts, 30 ~ 50 parts, flyash, sand coarse aggregate ratio 39% ~ 42%, silica aerogel be dry material 0.2% ~ 0.5%, water reducer volume determines according to degree of mobilization, water-cement ratio is 0.45 ~ 0.5, after abundant stirring, through building, maintenance, final acquisition has good thermal insulation property, high intensity and high performance heat-preserving heat-insulating wall material.
Foregoing method, preferred scheme is that concrete steps are as follows:
With tetraethoxysilance or positive methyl-monosilane or water glass for carbon source, adopt sol-gel method, prepare silica aerogel;
Take the water of certain mass by design proportioning, by heavily taking silica aerogel powder, utilizing dispersion agent it fully to be incorporated in water and also fully stirring obtained slip, adding water reducer, carry out secondary stirring 3 ~ 5min;
Cement, haydite, blast-furnace slag, flyash are put into stirrer dry mixing 3mim ~ 5mim and carried out premix;
The slip that [0011] is obtained slowly adds in [0012], stirs, and process is built, maintenance, final obtained high-performance insulating wall material.
Foregoing method, the preferred label of cement is the Portland cement of P.O42.5R, the high-strength fly-ash haydite of pottery material preferable particle size 5mm ~ 15mm.
Water reducer used is conventional high efficiency water reducing agent, and water-reducing rate is not less than 20%.
For ensureing the necessary performance such as intensity, weather resistance, fire prevention of insulating wall material, the present invention adopts concrete as heat-preserving heat-insulating wall material.
In order to improve concrete heat insulating effect, utilize the porousness of haydite on the one hand, realize heat obstruct to a certain extent, but because haydite yardstick is larger, be generally more than 5mm, heat obstruct can only be carried out on a macroscopic scale, micron-sized silica aerogel is utilized to realize the obstruct of heat on microcosmic on the other hand, silica aerogel has round shape multi-branched nanoporous three network structures of high-permeability, it is the solid-state material that current thermal conductivity is minimum, the sol-gel method adopted by the present invention obtains in a large number, this material be used in the present invention constructing concrete micro-scale heat intercept network, thus significantly improve concrete heat insulating effect.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the scope of protection of present invention is not limited to the scope that embodiment represents:
Example 1: take tetraethoxy as carbon source, adopts sol-gel method to prepare solid netted silica aerogel, by obtained silica aerogel, through grinding powdering; Take and account for powder quality 0.2% quality oxide silica aerogel powder, add dispersion agent and water fully stirs into distributed slurry, then add powder quality 0.8% high efficiency water reducing agent.By the high-strength fly-ash haydite adding 35 parts of cement in stirrer successively, massfraction 15% particle diameter is 5mm ~ 10mm, 20 parts of blast-furnace slags, 30 parts of flyash, sand coarse aggregate ratio is set as 39%, stir 3min mixing, add the shaping cast of the even mixing of slip of mixing, after form removal, namely maintenance obtains high-performance heat insulating wall material.
Embodiment 2: take tetraethoxy as carbon source, adopts sol-gel method to prepare solid netted silica aerogel, by obtained aerogel grinding powdering; Take powder quality 0.31% silica aerogel powder, add appropriate dispersion agent and stir into distributed slurry, then add powder quality 0.9% high efficiency water reducing agent.In stirrer, add 30 parts of cement, the high-strength fly-ash haydite of 20 parts, 20 parts of blast-furnace slags, 30 parts of flyash successively, setting sand coarse aggregate ratio is 42%, and high-speed stirring 3mim mixes.The slip adding mixing enters abundant stirring, casting, namely obtains high-performance heat insulating wall material after form removal.

Claims (5)

1. a high-performance heat-preserving heat-insulating wall material, comprise bottom solid material and silica aerogel, it is characterized in that, bottom solid material is cement 20 ~ 40 parts, haydite 10 ~ 30 parts, blast-furnace slag 20 ~ 40 parts, 30 ~ 50 parts, flyash, sand coarse aggregate ratio 39% ~ 42% by following composition and weight proportion, silica aerogel be dry material 0.2% ~ 0.5%, water reducer volume determines according to mix degree of mobilization, water-cement ratio is 0.45 ~ 0.5, after fully stirring through building, maintenance obtains finished product.
2. high-performance heat-preserving heat-insulating wall material according to claim 1, is characterized in that, described silica aerogel is with tetraethoxysilance or just methyl-monosilane or water glass, for carbon source, are adopting sol-gel method to obtain.
3. high-performance heat-preserving heat-insulating wall material according to claim 1, is characterized in that, described silica aerogel is dry powder.
4. high-performance heat-preserving heat-insulating wall material according to claim 1, is characterized in that, the preferred label of described cement is the Portland cement of P.O42.5R, and the high-strength ceramic granule of pottery material preferable particle size 5 ~ 15mm, piles up apparent density 800kg/m 3~ 900kg/m 3, cylindrical compress strength is 7.3MPa.
5. the high-performance heat-preserving heat-insulating wall material according to any one of claim 1-4, comprise the steps: (1) by silica aerogel powder by dispersant in water, add water reducer; (2) cement, haydite, blast-furnace slag, flyash are mixed, dry mixing 3 ~ 5mim, mixes; (3) under whipped state, the mixed solution in (1) is injected respective volume mould molding; Eventually pass maintenance and obtain high-performance insulating wall material.
CN201510584932.XA 2015-09-09 2015-09-09 High-performance heat-preservation thermal-insulation wall material Pending CN105503046A (en)

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CN105503046A true CN105503046A (en) 2016-04-20

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110606707A (en) * 2019-10-16 2019-12-24 周铸 Preparation method of light energy-saving anti-seismic partition plate
CN111645188A (en) * 2020-07-09 2020-09-11 上海市建筑科学研究院有限公司 Preparation method of recycled aggregate pervious concrete based on cement paste coated aggregate
CN112441808A (en) * 2020-11-17 2021-03-05 国佳新材湖北环保凝胶产业园有限公司 Aerogel building block and preparation method thereof
CN114656811A (en) * 2022-04-12 2022-06-24 武汉理工大学 Fireproof heat-preservation heat-insulation inorganic coating material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102040361A (en) * 2010-08-27 2011-05-04 李宁 Modified self-insulating composite external wall material
WO2011083174A1 (en) * 2010-01-11 2011-07-14 Parexlanko Insulating silica xerogel plaster
CN102659351A (en) * 2012-04-10 2012-09-12 太原理工大学 Thermal-insulation loading recycled concrete
EP2514731A1 (en) * 2011-04-20 2012-10-24 Knauf Insulation Wood wool lightweight construction element
CN102795826A (en) * 2012-08-20 2012-11-28 宁波荣山新型材料有限公司 Aerogel/inorganic lightweight aggregate composite thermal insulation material and preparation method thereof
CN103553502A (en) * 2013-11-07 2014-02-05 北京建筑材料科学研究总院有限公司 Lightweight inorganic insulation board containing silica aerogel and preparation method thereof
CN104763063A (en) * 2015-02-15 2015-07-08 深圳市华科德新材料有限公司 Nano porous silica aerogel heat insulation and preserving plate

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011083174A1 (en) * 2010-01-11 2011-07-14 Parexlanko Insulating silica xerogel plaster
CN102040361A (en) * 2010-08-27 2011-05-04 李宁 Modified self-insulating composite external wall material
EP2514731A1 (en) * 2011-04-20 2012-10-24 Knauf Insulation Wood wool lightweight construction element
CN102659351A (en) * 2012-04-10 2012-09-12 太原理工大学 Thermal-insulation loading recycled concrete
CN102795826A (en) * 2012-08-20 2012-11-28 宁波荣山新型材料有限公司 Aerogel/inorganic lightweight aggregate composite thermal insulation material and preparation method thereof
CN103553502A (en) * 2013-11-07 2014-02-05 北京建筑材料科学研究总院有限公司 Lightweight inorganic insulation board containing silica aerogel and preparation method thereof
CN104763063A (en) * 2015-02-15 2015-07-08 深圳市华科德新材料有限公司 Nano porous silica aerogel heat insulation and preserving plate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110606707A (en) * 2019-10-16 2019-12-24 周铸 Preparation method of light energy-saving anti-seismic partition plate
CN111645188A (en) * 2020-07-09 2020-09-11 上海市建筑科学研究院有限公司 Preparation method of recycled aggregate pervious concrete based on cement paste coated aggregate
CN111645188B (en) * 2020-07-09 2021-12-24 上海市建筑科学研究院有限公司 Preparation method of recycled aggregate pervious concrete based on cement paste coated aggregate
CN112441808A (en) * 2020-11-17 2021-03-05 国佳新材湖北环保凝胶产业园有限公司 Aerogel building block and preparation method thereof
CN114656811A (en) * 2022-04-12 2022-06-24 武汉理工大学 Fireproof heat-preservation heat-insulation inorganic coating material and preparation method thereof
CN114656811B (en) * 2022-04-12 2023-03-14 武汉理工大学 Fireproof heat-preservation heat-insulation inorganic coating material and preparation method thereof

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Application publication date: 20160420