CN106747011A - A kind of massif slope concrete special baffle plate - Google Patents

A kind of massif slope concrete special baffle plate Download PDF

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Publication number
CN106747011A
CN106747011A CN201611261460.5A CN201611261460A CN106747011A CN 106747011 A CN106747011 A CN 106747011A CN 201611261460 A CN201611261460 A CN 201611261460A CN 106747011 A CN106747011 A CN 106747011A
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CN
China
Prior art keywords
parts
baffle plate
steel fibre
modified
concrete special
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Pending
Application number
CN201611261460.5A
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Chinese (zh)
Inventor
薛念念
汤俊怀
李青松
王军
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Anhui city clean environment Technology Co., Ltd.
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Anhui Huapu Environmental Remediation Mstar Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Anhui Huapu Environmental Remediation Mstar Technology Ltd filed Critical Anhui Huapu Environmental Remediation Mstar Technology Ltd
Priority to CN201611261460.5A priority Critical patent/CN106747011A/en
Publication of CN106747011A publication Critical patent/CN106747011A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D17/00Excavations; Bordering of excavations; Making embankments
    • E02D17/20Securing of slopes or inclines

Abstract

The invention discloses a kind of massif slope concrete special baffle plate, its raw material includes by weight:100 parts of cement, 250 350 parts of stone, 100 200 parts of quartz sand, 10 35 parts of gangue, modified 30 50 parts of steel fibre, 20 50 parts of corn stalk powder, 5 12 parts of talcum powder, 10 35 parts of nano-calcium carbonate, 20 35 parts of flyash, 20 35 parts of silicon ash, 20 35 parts of iron ore, 25 parts of epoxy resin latex, 15 parts of acrylonitrile-butadiene rubber powder, 2 10 parts of water reducer, 25 parts of additive, 20 50 parts of water;The raw material of additive includes:Hydroxy alkyl sulfonic acid sodium, zinc stearate, Firebrake ZB, sodium gluconate, tributyl 2-acetylcitrate, benzoic acid, bicyclopentadiene epoxides, aluminum oxide.Massif slope concrete special baffle plate proposed by the present invention, it has excellent anti-cracking performance, and anti-permeability performance and good endurance.

Description

A kind of massif slope concrete special baffle plate
Technical field
The present invention relates to technical field of concrete, more particularly to a kind of massif slope concrete special baffle plate.
Background technology
Concrete as one of maximum construction material of current consumption, from invention in 1824 so far, be the mankind progress and Expanding economy is made that tremendous contribution, has turned into the conventional reinforcement material in massif slope at present, but existing concrete its Anti-cracking performance and anti-permeability performance are still less desirable, and the concrete baffle plate being made of it is applied to meeting during the place such as massif slope Cracking, poor durability defect, limits the application of concrete baffle plate.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of massif slope concrete special baffle plate, its With excellent anti-cracking performance, and anti-permeability performance and good endurance.
A kind of massif slope concrete special baffle plate proposed by the present invention, its raw material includes by weight:100 parts of cement, Stone 250-350 parts, quartz sand 100-200 parts, gangue 10-35 parts, modified 30-50 parts of steel fibre, corn stalk powder 20-50 Part, talcum powder 5-12 parts, nano-calcium carbonate 10-35 parts, flyash 20-35 parts, silicon ash 20-35 parts, iron ore 20-35 parts, ring 2-5 parts, acrylonitrile-butadiene rubber powder 1-5 parts, water reducer 2-10 parts, additive 2-5 parts, water 20-50 parts of oxygen tree fat liquor;
Wherein, its raw material of the additive includes by weight:2-5 parts of hydroxy alkyl sulfonic acid sodium, zinc stearate 1-3 parts, Firebrake ZB 1-5 parts, sodium gluconate 3-7 parts, tributyl 2-acetylcitrate 0.8-1.5 parts, benzoic acid 0.7-1.5 parts, two rings 1-2 parts, aluminum oxide 2-5 parts of pentadiene epoxides.
Preferably, its raw material includes by weight:100 parts of cement, stone 280-320 parts, quartz sand 135-175 parts, coal Spoil 19-26 parts, modified 39-47 parts of steel fibre, corn stalk powder 31-38 parts, talcum powder 8.5-10 parts, nano-calcium carbonate 19- 25 parts, flyash 27-31 parts, silicon ash 28-32 parts, iron ore 27-31 parts, epoxy resin latex 3.8-4.3 parts, acrylonitrile-butadiene rubber powder 3.2-4.3 parts, water reducer 5-8.6 parts, additive 3.8-4.7 parts, water 30-38 parts.
Preferably, its raw material includes by weight:100 parts of cement, 300 parts of stone, 160 parts of quartz sand, 25 parts of gangue, Modified 42 parts of steel fibre, 35 parts of corn stalk powder, 9 parts of talcum powder, 21 parts of nano-calcium carbonate, 30 parts of flyash, 30 parts of silicon ash, iron 28 parts of ore in sand form, 4 parts of epoxy resin latex, 4 parts of acrylonitrile-butadiene rubber powder, 6 parts of water reducer, 4.3 parts of additive, 35 parts of water.
Preferably, its raw material of the additive includes by weight:3.8 parts of hydroxy alkyl sulfonic acid sodium, 2 parts of zinc stearate, 3 parts of Firebrake ZB, 5 parts of sodium gluconate, 1.2 parts of tributyl 2-acetylcitrate, 1.2 parts of benzoic acid, bicyclopentadiene epoxidation 1.6 parts of thing, 3.2 parts of aluminum oxide.
Preferably, the modified steel fibre is prepared according to following technique:Silane coupler KH-560 is added into ethanol In, the pH value of regulation system is 4-5, stirs 20-35min, is subsequently adding trbasic zinc phosphate and phosphoric acid, is added after being warming up to 60-70 DEG C Steel fibre, is incubated 30-50min, then through washing, being dried to obtain the modified steel fibre.
Preferably, the modified steel fibre is prepared according to following technique:By weight by 2-3 parts of silane coupler KH-560 is added in 100 parts of ethanol, and the pH value of regulation system is 4-5, stirs 25-30min, be subsequently adding 2-10 part trbasic zinc phosphate with 1-5 parts of phosphoric acid, adds 20-35 parts of steel fibre after being warming up to 63-68 DEG C, 35-45min is incubated, then through washing, being dried to obtain institute State modified steel fibre.
Preferably, the content of silica is 45-55wt% in the iron ore, and the content of aluminum oxide is 5-10wt%, The content of iron oxide is 5-10wt%;The apparent density 3200-3500kg/m of iron ore3, loose bulk density is 1800- 2000kg/m3, voidage is 32-35%.
Preferably, the water reducer is that poly carboxylic acid series water reducer, melamine water reducing agent are 2-10 by weight:1-5's Mixture.
Massif slope concrete special baffle plate of the present invention, its raw material adds gangue, flyash, silicon ash and iron ore Sand, and the content in system is have adjusted, realized in system and be sufficient filling with, the space between each component particle is reduced, The overall porosity of concrete is reduced, pore structure is improved, hence it is evident that the impermeability of concrete is improve, while hydroxide can be reduced The enrichment of calcium content, improves interface binding power, improves the intensity of concrete;Modified steel fibre, corn stalk powder add body In system, in random distribution and mutual overlap joint in concrete, the extension of concrete microcrack is prevented, improve the anti-of concrete Cracking behavior, each fiber random distribution state can be cut off capillary porosity duct, and the dehydration area and capillary dehydration for reducing matrix are received Contracting tension force, hinders the migration of moisture, improves pore structure, so as to improve the intensity of concrete, splitting resistance and impermeability;It is preferred that square In the preparation process of the modified steel fibre of formula, steel fibre is processed using silane coupler KH-560, made silane coupler KH-560 there occurs the effect of chemisorbed or chemical bonding with steel fibre, improve the surface texture of steel fibre, add body In system, the interaction with epoxy resin, acrylonitrile-butadiene rubber powder in system is improve, improve the phase of modified steel fibre and system Capacitive, while steel fibre is processed using trbasic zinc phosphate and phosphoric acid, so as to form hydroxyapatite on the surface of steel fibre With the hydrated product such as brushite, make the uniform a large amount of corynebacterium zinc systems phosphoric acid film in surface of steel fibre so that surface become it is thick Rough, both sides effect plays positive-effect to the cohesion of steel fibre and basal body interface, increases modified steel fibre from coagulation Withdrawal force and shear strength in soil, it is therefore prevented that the extraction destruction of modified steel fibre;Hydroxy alkyl sulfonic acid sodium, zinc stearate, boron Sour zinc, sodium gluconate, tributyl 2-acetylcitrate, benzoic acid, bicyclopentadiene epoxides, aluminum oxide add system In, with synergy, independent spherical microbubble is generated in concrete, space is become more tortuous, further carry The high anti-permeability performance and anti-cracking performance of concrete;In epoxy resin latex, acrylonitrile-butadiene rubber powder addition system, the shape in system Into network, on the one hand, the skeleton with system is mutually penetrated, the intensity of concrete is improve, on the other hand, fill or enclose portion Point space, while the transition region between improving slurry, improves the rupture strength of concrete, bend-press ratio, prolongs to a certain extent The performance such as property, wear-resisting.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of massif slope concrete special baffle plate proposed by the present invention, its raw material includes by weight:100 parts of cement, 350 parts of stone, 100 parts of quartz sand, 35 parts of gangue, modified 30 parts of steel fibre, 50 parts of corn stalk powder, talcum powder 5 part, nanometer 35 parts of calcium carbonate, 20 parts of flyash, 35 parts of silicon ash, 20 parts of iron ore, 5 parts of epoxy resin latex, 1 part of acrylonitrile-butadiene rubber powder, diminishing 10 parts of agent, 2 parts of additive, 20 parts of water;
Wherein, its raw material of the additive includes by weight:2 parts of hydroxy alkyl sulfonic acid sodium, 3 parts of zinc stearate, boric acid 1 part of zinc, 7 parts of sodium gluconate, 0.8 part of tributyl 2-acetylcitrate, 1.5 parts of benzoic acid, bicyclopentadiene epoxides 1 Part, 5 parts of aluminum oxide.
Embodiment 2
A kind of massif slope concrete special baffle plate proposed by the present invention, its raw material includes by weight:100 parts of cement, 250 parts of stone, 200 parts of quartz sand, 10 parts of gangue, modified 50 parts of steel fibre, 20 parts of corn stalk powder, 12 parts of talcum powder, receive 10 parts of calcium carbonate of rice, 35 parts of flyash, 20 parts of silicon ash, 35 parts of iron ore, 2 parts of epoxy resin latex, 5 parts of acrylonitrile-butadiene rubber powder, subtract 2 parts of aqua, 5 parts of additive, 50 parts of water;
Wherein, its raw material of the additive includes by weight:5 parts of hydroxy alkyl sulfonic acid sodium, 1 part of zinc stearate, boric acid 5 parts of zinc, 3 parts of sodium gluconate, 1.5 parts of tributyl 2-acetylcitrate, 0.7 part of benzoic acid, bicyclopentadiene epoxides 2 Part, 2 parts of aluminum oxide;
The modified steel fibre is prepared according to following technique:By in silane coupler KH-560 addition ethanol, adjust The pH value of system is 4, stirs 35min, is subsequently adding trbasic zinc phosphate and phosphoric acid, and steel fibre is added after being warming up to 60 DEG C, is incubated 50min, then through washing, being dried to obtain the modified steel fibre.
Embodiment 3
A kind of massif slope concrete special baffle plate proposed by the present invention, its raw material includes by weight:100 parts of cement, 320 parts of stone, 135 parts of quartz sand, 26 parts of gangue, modified 39 parts of steel fibre, 38 parts of corn stalk powder, 8.5 parts of talcum powder, receive 25 parts of calcium carbonate of rice, 27 parts of flyash, 32 parts of silicon ash, 27 parts of iron ore, 4.3 parts of epoxy resin latex, acrylonitrile-butadiene rubber powder 3.2 Part, 8.6 parts of water reducer, 3.8 parts of additive, 30 parts of water;
Wherein, its raw material of the additive includes by weight:4.3 parts of hydroxy alkyl sulfonic acid sodium, 1.6 parts of zinc stearate, 4.3 parts of Firebrake ZB, 4.2 parts of sodium gluconate, 1.3 parts of tributyl 2-acetylcitrate, 0.9 part of benzoic acid, bicyclopentadiene ring 1.7 parts of oxide, 3 parts of aluminum oxide;
The modified steel fibre is prepared according to following technique:By in silane coupler KH-560 addition ethanol, adjust The pH value of system is 5, stirs 20min, is subsequently adding trbasic zinc phosphate and phosphoric acid, and steel fibre is added after being warming up to 70 DEG C, is incubated 30min, then through washing, being dried to obtain the modified steel fibre;
The content of silica is 45wt% in the iron ore, and the content of aluminum oxide is 10wt%, the content of iron oxide It is 5wt%;The apparent density 3500kg/m of iron ore3, loose bulk density is 1800kg/m3, voidage is 35%;
The water reducer is that poly carboxylic acid series water reducer, melamine water reducing agent are 2 by weight:5 mixture.
Embodiment 4
A kind of massif slope concrete special baffle plate proposed by the present invention, its raw material includes by weight:100 parts of cement, 280 parts of stone, 175 parts of quartz sand, 19 parts of gangue, modified 47 parts of steel fibre, 31 parts of corn stalk powder, 10 parts of talcum powder, receive 19 parts of calcium carbonate of rice, 31 parts of flyash, 28 parts of silicon ash, 31 parts of iron ore, 3.8 parts of epoxy resin latex, acrylonitrile-butadiene rubber powder 4.3 Part, 5 parts of water reducer, 4.7 parts of additive, 38 parts of water;
Wherein, its raw material of the additive includes by weight:2.6 parts of hydroxy alkyl sulfonic acid sodium, 2.7 parts of zinc stearate, 2.1 parts of Firebrake ZB, 6.5 parts of sodium gluconate, 0.9 part of tributyl 2-acetylcitrate, 1.3 parts of benzoic acid, bicyclopentadiene ring 1.3 parts of oxide, 4.2 parts of aluminum oxide;
The modified steel fibre is prepared according to following technique:3 parts of silane coupler KH-560 are added by weight In 100 parts of ethanol, the pH value of regulation system is 4, stirs 30min, is subsequently adding 2 parts of trbasic zinc phosphates and 5 parts of phosphoric acid, is warming up to 63 DEG C 35 parts of steel fibres are added afterwards, 35min are incubated, then through washing, being dried to obtain the modified steel fibre;
The content of silica is 55wt% in the iron ore, and the content of aluminum oxide is 5wt%, and the content of iron oxide is 10wt%;The apparent density 3200kg/m of iron ore3, loose bulk density is 2000kg/m3, voidage is 32%;
The water reducer is that poly carboxylic acid series water reducer, melamine water reducing agent are 10 by weight:1 mixture.
Embodiment 5
A kind of massif slope concrete special baffle plate proposed by the present invention, its raw material includes by weight:100 parts of cement, 300 parts of stone, 160 parts of quartz sand, 25 parts of gangue, modified 42 parts of steel fibre, 35 parts of corn stalk powder, talcum powder 9 part, nanometer 21 parts of calcium carbonate, 30 parts of flyash, 30 parts of silicon ash, 28 parts of iron ore, 4 parts of epoxy resin latex, 4 parts of acrylonitrile-butadiene rubber powder, diminishing 6 parts of agent, 4.3 parts of additive, 35 parts of water;
Wherein, its raw material of the additive includes by weight:3.8 parts of hydroxy alkyl sulfonic acid sodium, 2 parts of zinc stearate, boron 3 parts of sour zinc, 5 parts of sodium gluconate, 1.2 parts of tributyl 2-acetylcitrate, 1.2 parts of benzoic acid, bicyclopentadiene epoxides 1.6 parts, 3.2 parts of aluminum oxide;
The modified steel fibre is prepared according to following technique:2 parts of silane coupler KH-560 are added by weight In 100 parts of ethanol, the pH value of regulation system is 5, stirs 25min, is subsequently adding 10 parts of trbasic zinc phosphates and 1 part of phosphoric acid, is warming up to 68 20 parts of steel fibres are added after DEG C, 45min is incubated, then through washing, being dried to obtain the modified steel fibre;
The content of silica is 50wt% in the iron ore, and the content of aluminum oxide is 8wt%, and the content of iron oxide is 7wt%;The apparent density 3300kg/m of iron ore3, loose bulk density is 1900kg/m3, voidage is 33%;
The water reducer is that poly carboxylic acid series water reducer, melamine water reducing agent are 7 by weight:4 mixture.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (8)

1. a kind of massif slope concrete special baffle plate, it is characterised in that its raw material includes by weight:100 parts of cement, stone 250-350 parts, quartz sand 100-200 parts, gangue 10-35 parts, modified 30-50 parts of steel fibre, corn stalk powder 20-50 parts, Talcum powder 5-12 parts, nano-calcium carbonate 10-35 parts, flyash 20-35 parts, silicon ash 20-35 parts, iron ore 20-35 parts, asphalt mixtures modified by epoxy resin Fat liquor 2-5 parts, acrylonitrile-butadiene rubber powder 1-5 parts, water reducer 2-10 parts, additive 2-5 parts, water 20-50 parts;
Wherein, its raw material of the additive includes by weight:2-5 parts of hydroxy alkyl sulfonic acid sodium, zinc stearate 1-3 parts, boric acid Zinc 1-5 parts, sodium gluconate 3-7 parts, tributyl 2-acetylcitrate 0.8-1.5 parts, benzoic acid 0.7-1.5 parts, two rings penta 2 1-2 parts, aluminum oxide 2-5 parts of alkene epoxides.
2. massif slope concrete special baffle plate according to claim 1, it is characterised in that its raw material includes by weight: 100 parts of cement, stone 280-320 parts, quartz sand 135-175 parts, gangue 19-26 parts, modified 39-47 parts of steel fibre, corn Powder of straw 31-38 parts, talcum powder 8.5-10 parts, nano-calcium carbonate 19-25 parts, flyash 27-31 parts, silicon ash 28-32 parts, iron ore Sand 27-31 parts, epoxy resin latex 3.8-4.3 parts, acrylonitrile-butadiene rubber powder 3.2-4.3 parts, water reducer 5-8.6 parts, additive 3.8- 4.7 parts, water 30-38 parts.
3. massif slope concrete special baffle plate according to claim 1 or claim 2, it is characterised in that its raw material is wrapped by weight Include:100 parts of cement, 300 parts of stone, 160 parts of quartz sand, 25 parts of gangue, modified 42 parts of steel fibre, 35 parts of corn stalk powder, 9 parts of talcum powder, 21 parts of nano-calcium carbonate, 30 parts of flyash, 30 parts of silicon ash, 28 parts of iron ore, 4 parts of epoxy resin latex, butyronitrile 4 parts of rubber powder, 6 parts of water reducer, 4.3 parts of additive, 35 parts of water.
4. the massif slope concrete special baffle plate according to any one of claim 1-3, it is characterised in that the additive Its raw material includes by weight:3.8 parts of hydroxy alkyl sulfonic acid sodium, 2 parts of zinc stearate, 3 parts of Firebrake ZB, 5 parts of sodium gluconate, second 1.2 parts of acyl ATBC, 1.2 parts of benzoic acid, 1.6 parts of bicyclopentadiene epoxides, 3.2 parts of aluminum oxide.
5. the massif slope concrete special baffle plate according to any one of claim 1-4, it is characterised in that the modified steel Fiber is prepared according to following technique:By in silane coupler KH-560 addition ethanol, the pH value of regulation system is 4-5, is stirred 20-35min is mixed, trbasic zinc phosphate and phosphoric acid is subsequently adding, steel fibre is added after being warming up to 60-70 DEG C, be incubated 30-50min, Ran Houjing Wash, be dried to obtain the modified steel fibre.
6. the massif slope concrete special baffle plate according to any one of claim 1-5, it is characterised in that the modified steel Fiber is prepared according to following technique:By weight by 2-3 parts of silane coupler KH-560 100 parts of ethanol of addition, adjust The pH value of system is 4-5, stirs 25-30min, 2-10 parts of trbasic zinc phosphate and 1-5 parts of phosphoric acid is subsequently adding, after being warming up to 63-68 DEG C 20-35 parts of steel fibre is added, 35-45min is incubated, then through washing, being dried to obtain the modified steel fibre.
7. the massif slope concrete special baffle plate according to any one of claim 1-6, it is characterised in that the iron ore The content of middle silica is 45-55wt%, and the content of aluminum oxide is 5-10wt%, and the content of iron oxide is 5-10wt%;Iron The apparent density 3200-3500kg/m of ore in sand form3, loose bulk density is 1800-2000kg/m3, voidage is 32-35%.
8. the massif slope concrete special baffle plate according to any one of claim 1-7, it is characterised in that the water reducer For poly carboxylic acid series water reducer, melamine water reducing agent are 2-10 by weight:The mixture of 1-5.
CN201611261460.5A 2016-12-30 2016-12-30 A kind of massif slope concrete special baffle plate Pending CN106747011A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107698205A (en) * 2017-10-25 2018-02-16 桐城市永锦建筑工程有限公司 A kind of casting concrete

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003423A (en) * 2007-01-05 2007-07-25 华南理工大学 Method for producing enhanced cement mortar, and concrete from surface modified steel fiber and reinforcing steel bar
CN105236895A (en) * 2015-10-27 2016-01-13 黑龙江科技大学 High-performance gold tailing sand concrete

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101003423A (en) * 2007-01-05 2007-07-25 华南理工大学 Method for producing enhanced cement mortar, and concrete from surface modified steel fiber and reinforcing steel bar
CN105236895A (en) * 2015-10-27 2016-01-13 黑龙江科技大学 High-performance gold tailing sand concrete

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107698205A (en) * 2017-10-25 2018-02-16 桐城市永锦建筑工程有限公司 A kind of casting concrete

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Application publication date: 20170531