CN106746919A - A kind of artificial stone and preparation method thereof - Google Patents
A kind of artificial stone and preparation method thereof Download PDFInfo
- Publication number
- CN106746919A CN106746919A CN201710022873.6A CN201710022873A CN106746919A CN 106746919 A CN106746919 A CN 106746919A CN 201710022873 A CN201710022873 A CN 201710022873A CN 106746919 A CN106746919 A CN 106746919A
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- China
- Prior art keywords
- polyester resin
- natural stone
- imitation natural
- artificial stone
- stone
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
Abstract
The invention provides a kind of artificial stone, belong to architectural constructional materials field, obtained by the raw material solidification including imitation natural stone nano pulp and imitation natural stone base-material, by the component and its percentage by weight that define imitation natural stone nano pulp, obtained a kind of floral designs it is clear, substantially, effect is true to nature, the more preferable artificial stone of stereoeffect, solve the problems, such as that artificial stone imitates that the imitative natural effects of natural lines are not good in the prior art, need to be improved the equipment for manufacturing artificial stone.
Description
Technical field
The present invention relates to architectural constructional materials field, more particularly to a kind of artificial stone and preparation method thereof.
Background technology
Artificial stone is a kind of now widely used stone material, and it is different from lithotome, with binding agent, thickness filler and is helped
Agent is made through certain technical process, the numerous characteristics with natural marble, granite, additionally, due to can manual adjustment,
So in a great variety, suppleness is good, not clear aobvious, associative perception is strong and bright and colourful to be connected treatment.Artificial stone is increasingly subject to people
Pay close attention to, particularly the artificial stone of imitation natural stone lines have the bigger market space.
Current artificial stone imitates natural lines and there is a problem of that imitative natural effects are not good, main in the prior art to be set using improvement
It is standby to realize, as CN1451558A disclose it is a kind of using a punching press if can assign natural-like stone Art Stone surface fine color
The equipment of color and grain pattern decoration, CN203019518U discloses a kind of equipment for producing natural-like stone crack Ceramic Tiles,
These equipment are complicated, and operation is whard to control, and commercially the case of successful Application is simultaneously few, and imitate natural lines effect and pay no attention to
Think.
The content of the invention
In view of this, it is an object of the invention to provide a kind of artificial stone, it is possible to increase the decorative pattern vivid effect of artificial stone,
Stereoeffect is more preferable.
In order to realize foregoing invention purpose, the present invention provides following technical scheme：
The invention provides a kind of artificial stone, solidified by the raw material including imitation natural stone nano pulp and imitation natural stone base-material
Obtain, the imitation natural stone nano pulp includes saturated polyester resin, aerosil, calcium carbonate, dispersant and toner；Institute
Stating imitation natural stone base-material includes unsaturated polyester resin, cobalt iso-octoate, curing agent and fleur.
Preferably, the mass ratio 0.02~0.03 of the imitation natural stone nano pulp and imitation natural stone base-material:100.
Preferably, the imitation natural stone nano pulp includes following components in percentage by weight：Saturated polyester resin 20~
30%, aerosil 10~15%, calcium carbonate 50~60%, dispersant 0.5~3%, the toner of surplus.
Preferably, the particle diameter of the aerosil is 2000~8000 mesh.
Preferably, the saturated polyester resin includes adjacent benzene-type saturated polyester resin, metaphenylene saturated polyester resin and right
The mixture of one or more in benzene-type saturated polyester resin.
Preferably, the equal molecular mass of the number of the saturated polyester resin is 18000~30000.
Preferably, the particle diameter of the calcium carbonate is 100~200nm.
Preferably, the dispersant includes polyacrylic dispersant, and the equal molecular mass of number of the dispersant is 50000
~80000.
Preferably, in the imitation natural stone base-material mass ratio of cobalt iso-octoate and unsaturated polyester resin for 0.04~
0.08:100。
Preferably, the curing agent and the mass ratio of unsaturated polyester resin are 1~3:100；
Preferably, the fleur and the mass ratio of unsaturated polyester resin are 1:2~3.
Present invention also offers the preparation method of above-mentioned artificial stone, comprise the following steps：
(1) imitation natural stone nano pulp is slowly dropped in imitation natural stone base-material, obtains mixed material；
(2) mixed material that the step (1) is obtained is solidified in a mold and obtains artificial stone.
Preferably, the temperature of solidification is 10~30 DEG C in the step (2), and the time of the solidification is 6~7 days.
The invention provides a kind of artificial stone, solidified by the raw material including imitation natural stone nano pulp and imitation natural stone base-material
Obtain, imitation natural stone nano pulp forms elongated soft decorative pattern, random is scattered in imitation natural stone base-material, defines
The component of imitation natural stone nano pulp, obtained a kind of floral designs it is clear, substantially, effect is true to nature, the more preferable people of stereoeffect
Stone is made, artificial stone in the prior art is solved and is imitated that the imitative natural effects of natural lines are not good, needs to enter the equipment for manufacturing artificial stone
The improved problem of row.
Brief description of the drawings
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
Fig. 1 is the surface texture photo of artificial stone prepared by the embodiment of the present invention 1；
Fig. 2 is the surface texture photo of artificial stone prepared by the embodiment of the present invention 2.
Specific embodiment
The invention provides a kind of artificial stone, solidified by the raw material including imitation natural stone nano pulp and imitation natural stone base-material
Obtain, the imitation natural stone nano pulp includes saturated polyester resin, aerosil, calcium carbonate, dispersant and toner；Institute
Stating imitation natural stone base-material includes unsaturated polyester resin, cobalt iso-octoate, curing agent and fleur.
In the present invention, the mass ratio of the imitation natural stone nano pulp and imitation natural stone base-material be preferably 0.02~
0.03:100, more preferably 0.025~0.028:100.
In the present invention, the imitation natural stone nano pulp preferably includes following components in percentage by weight：Saturated polyester
Resin 20~30%, aerosil 10~15%, calcium carbonate 50~60%, dispersant 0.5~3%, the toner of surplus；
In the imitation natural stone nano pulp, the weight percentage of the saturated polyester resin is more preferably 24~26%, the gas
The weight percentage of aerosil is more preferably 12~13%, and the weight percentage of the calcium carbonate is more preferably 55~
58%, the weight percentage of the dispersant is more preferably 1~2%.
In the present invention, the particle diameter of the aerosil is preferably 2000~8000 mesh, more preferably 3000~
6000 mesh, most preferably 4000~5000 mesh.
In the present invention, the saturated polyester resin preferably includes adjacent benzene-type saturated polyester resin, metaphenylene saturated polyester
The mixture of one or more in resin and p-phenyl's saturated polyester resin；When the saturated polyester resin is mixture,
The mixture of preferably adjacent benzene-type saturated polyester resin and metaphenylene saturated polyester resin；The present invention mixes to saturated polyester resin
The mass ratio of each saturated polyester resin is not limited in thing, and those skilled in the art can according to actual needs select any mass ratio
Saturated polyester resin mixture, adjacent benzene-type saturated polyester resin and metaphenylene saturated polyester resin in embodiments of the present invention
Mass ratio be preferably 1:2~8, more preferably 1:6~7.
In the present invention, the equal molecular mass of the number of the saturated polyester resin is preferably 18000~30000, more preferably
20000~28000, most preferably 25000~26000.
In the present invention, the particle diameter of the calcium carbonate is preferably 100~200nm, more preferably 110~170nm, most preferably
It is 120~140nm.
In the present invention, the dispersant preferably includes polyacrylic dispersant, more preferably including Sodium Polyacrylate,
The mixture of one or more in polyacrylic acid and ammonium polyacrylate；It is preferably above-mentioned when the dispersant is mixture
Two kinds in component, more preferably the mixture of Sodium Polyacrylate and polyacrylic acid, Sodium Polyacrylate and ammonium polyacrylate is mixed
Compound；The present invention is not limited the mass ratio of each polyacrylic dispersant in the polyacrylic dispersant, this area
Technical staff can according to actual needs select the mixture of the polyacrylic dispersant of any mass ratio.
In the present invention, the equal molecular mass of number of the polyacrylic dispersant is preferably 50000~80000, more excellent
Elect 55000~75000, most preferably 60000~70000 as.
In the present invention, the imitation natural stone base-material is filled out including unsaturated polyester resin, cobalt iso-octoate, curing agent and powdery
Fill thing.
In the present invention, the unsaturated polyester resin preferably includes m-phthalate unsaturated polyester resin, p-phenyl's insatiable hunger
With the mixture of one or more in polyester resin, metaphenylene unsaturated polyester resin；The present invention is to the unsaturated polyester (UP) tree
The mass ratio of each unsaturated polyester resin is not limited in lipoprotein mixture, and those skilled in the art can select to appoint according to actual needs
The mixed thing of the unsaturated polyester resin of meaning mass ratio.
In the present invention, the equal molecular mass of the number of the unsaturated polyester resin is preferably 2000~3000, more preferably
2200~2800, most preferably 2500~2600；The viscosity of the unsaturated polyester resin is preferably 800~1500Pa.S, more
Preferably 900~1200Pa.S.
In the present invention, the cobalt iso-octoate is preferably 0.04~0.08 with the mass ratio of unsaturated polyester resin:100,
More preferably 0.05~0.07:100, most preferably 0.06~0.065:100.
In the present invention, the cobalt iso-octoate is preferably added as a solution, and the quality of the cobalt iso-octoate solution is dense
Degree is preferably 3~6%, more preferably 4~5.5%, most preferably 4.5~5%.
In the present invention, the curing agent is preferably peroxide, more preferably including methyl ethyl ketone peroxide, peroxidating hexamethylene
The mixture of one or more in ketone and dibenzoyl peroxide, most preferably methyl ethyl ketone peroxide, cyclohexanone peroxide and mistake
Two kinds of mixture in oxidation dibenzoyl, when the curing agent is two kinds in said components, preferably peroxidating first and second
Two kinds of mixture in the mixture of ketone and dibenzoyl peroxide, cyclohexanone peroxide and dibenzoyl peroxide.The present invention
Mass ratio to each curing agent in the curing agent mixture is not limited, and those skilled in the art can select according to actual needs
The mixture of the curing agent of any mass ratio, in embodiments of the present invention methyl ethyl ketone peroxide and dibenzoyl peroxide, peroxide
The mass ratio for changing cyclohexanone and dibenzoyl peroxide preferably independently is selected from 1:1~5:1, more preferably 2:1~5:1, most preferably
It is 3:1.
In the present invention, the curing agent is preferably 1~3 with the mass ratio of unsaturated polyester resin:100, more preferably
1.2~2.5:100, most preferably 1.5~2:100.
In the present invention, the fleur preferably includes aluminium hydrate powder and Paris white, the fleur
Particle diameter be preferably 80~600 mesh, more preferably 100~400 mesh, the mixture of most preferably 100 and 400 mesh.In the present invention
In, the fleur is preferably 1 with the mass ratio of unsaturated polyester resin:2~3, more preferably 1:2.4~2.6；This hair
Mass ratio in bright to aluminium hydrate powder and Paris white in the fleur is not limited, and those skilled in the art can root
According to the aluminium hydrate powder and the mixture of Paris white that select any mass ratio is actually needed, hydroxide in embodiments of the present invention
The mass ratio of aluminium powder and Paris white is preferably 1~7:1, more preferably 2~4:1.
Present invention also offers the preparation method of artificial stone described in above-mentioned technical proposal, comprise the following steps：
(1) imitation natural stone nano pulp is slowly dropped in imitation natural stone base-material, obtains mixed material；
(2) mixed material that the step (1) is obtained is solidified in a mold and obtains artificial stone.
The present invention mixes imitation natural stone nano pulp and imitation natural stone base-material, obtains mixed material.The present invention is to described
The mode of mixing does not have any special restriction, using hybrid mode well known to those skilled in the art；Of the invention real
Apply in example is preferably carried out by the way of stirring, and the rotating speed of the stirring is preferably 20~100rpm, more preferably 40~
70rpm, most preferably 50~60rpm, the time of the stirring are preferably 3~30min, more preferably 5~20min, most preferably
It is 10~15min.
After obtaining mixed material, of the invention solidify the mixed material in a mold obtains artificial stone.In the present invention,
The temperature of the solidification is preferably 10~30 DEG C, more preferably 15~25 DEG C, most preferably 18~20 DEG C, the time of the solidification
Preferably 6~7 days.
After the completion of mixed material solidifies in a mold, the mixed material after preferred pair solidification of the present invention carries out conventional cutting
Cut, polish, polishing and obtain artificial stone.
The invention provides a kind of artificial stone, solidified by the raw material including imitation natural stone nano pulp and imitation natural stone base-material
Obtain, imitation natural stone nano pulp forms elongated soft decorative pattern, random is scattered in imitation natural stone base-material, by limit
Determined the component and its percentage by weight of imitation natural stone nano pulp, obtained a kind of floral designs it is clear, substantially, effect forces
Very, the more preferable artificial stone of stereoeffect, solves artificial stone in the prior art and imitates that the imitative natural effects of natural lines are not good, it is right to need
Manufacture the problem that the equipment of artificial stone is improved.
Artificial stone provided the present invention with reference to embodiment and preparation method thereof is described in detail, but can not
They are interpreted as limiting the scope of the present invention.
Embodiment 1
Weigh the adjacent benzene-type saturated polyester resin 300g that several equal molecular masses are 18000, the aerosil of 2000 mesh
30g, particle diameter is the calcium carbonate 100g of 100nm, and polyacrylic acid 0.6g, titanium dioxide 80g stirs 30min, obtains under the rotating speed of 40rpm
To imitation natural stone nano pulp.
Weigh the metaphenylene unsaturated polyester resin 500g that several equal molecular masses are 2000, cobalt iso-octoate 0.002g, peroxide
Change MEK 6.00g, the aluminium hydrate powder 3000g of 100 mesh, the aluminium hydrate powder 2000g of 400 mesh is stirred under the rotating speed of 40rpm
30min is mixed, imitation natural stone base-material is obtained.
Imitation natural stone nano pulp and imitation natural stone base-material are mixed, 30min is stirred under the rotating speed of 20rpm, then will
Compound is transferred in mould, is solidified 2 days in 30 DEG C, then obtains artificial stone by cutting, polishing, polishing.
Knowable to being taken pictures to the surface texture of artificial stone obtained in the present embodiment, the obtained artificial shell stone patterns figure of the present invention
Case is clear, obvious, effect is true to nature, stereoeffect is good.
Embodiment 2
Weigh p-phenyl's saturated polyester resin 400g that several equal molecular masses are 30000, the aerosil of 8000 mesh
50g, particle diameter is the calcium carbonate 160g, Sodium Polyacrylate 0.8g, iron oxide red 2.00g of 200nm, and iron oxide yellow powder 48.00 turns 60rpm's
The lower stirring 20min of speed, obtains imitation natural stone nano pulp.
Weigh the m-phthalate unsaturated polyester resin 4000g that several equal molecular masses are 3000, cobalt iso-octoate 0.06g, peroxide
Change ring ethyl ketone 8g, Paris white 3000g, the 90 mesh Paris white 2000g of 600 mesh, 30min is stirred under the rotating speed of 80rpm, obtain
To imitation natural stone base-material.
Imitation natural stone nano pulp and imitation natural stone base-material are mixed, 3min is stirred under the rotating speed of 100rpm, then will
Compound is transferred in mould, is solidified 2 days in 30 DEG C, then obtains artificial stone by cutting, polishing, polishing.
Knowable to being taken pictures to the surface texture of artificial stone obtained in the present embodiment, the obtained artificial shell stone patterns figure of the present invention
Case is clear, obvious, effect is true to nature, stereoeffect is good.
Embodiment 3
The 400g that several equal molecular masses are 20000, the aerosil 70g of 3000 mesh are weighed, particle diameter is the carbon of 110nm
Sour calcium 200g, ammonium polyacrylate 2g, lemon yellow 2.00g, medium chrome yellow 3.00g stir 20min, are imitated under the rotating speed of 50rpm
Natural stone nano pulp.
Weigh the metaphenylene unsaturated polyester resin 4000g that several equal molecular masses are 2200, cobalt iso-octoate 0.1g, peroxidating
MEK 6g, dibenzoyl peroxide 2g, the aluminium hydrate powder 1000g, 400 mesh aluminium hydrate powder 3000g, 100 mesh carbon of 150 mesh
Sour calcium powder 1000g stirs 10min under the rotating speed of 30rpm, obtains imitation natural stone base-material.
Imitation natural stone nano pulp and imitation natural stone base-material are mixed, 15min is stirred under the rotating speed of 60rpm, then will
Compound is transferred in mould, is solidified 2 days in 35 DEG C, then obtains artificial stone by cutting, polishing, polishing.
Embodiment 4
Weigh p-phenyl's saturated polyester resin 500g that several equal molecular masses are 25000, the aerosil of 4000 mesh
90g, particle diameter is the calcium carbonate 200g, polyacrylic acid 2g, Sodium Polyacrylate 3g, titanium dioxide 20g, ultramarine blue 2g, iron oxide yellow powder of 170nm
6g stirs 10min under the rotating speed of 35rpm, obtains imitation natural stone nano pulp.
Weigh the metaphenylene unsaturated polyester resin 4000g that several equal molecular masses are 2600, cobalt iso-octoate 0.6g, peroxidating
MEK 6.00g, benzoyl peroxide 2.00g, the aluminium hydrate powder 2000g of 200 mesh, the Paris white 1000g of 300 mesh, 90
Purpose Paris white 2000g, 30min is stirred under the rotating speed of 40rpm, obtains imitation natural stone base-material.
Imitation natural stone nano pulp and imitation natural stone base-material are mixed, 10min is stirred under the rotating speed of 50rpm, then will
Compound is transferred in mould, is solidified 2 days in 35 DEG C, then obtains artificial stone by cutting, polishing, polishing.
Embodiment 5
Weigh p-phenyl's saturated polyester resin 400g that several equal molecular masses are 28000, the aerosil of 5000 mesh
160g, particle diameter is the calcium carbonate 20g, ammonium polyacrylate 1g, Sodium Polyacrylate 2g, titanium dioxide 12g, dark green 0.1g, lemon of 120nm
Lemon Huang 2g stirs 25min under the rotating speed of 20rpm, obtains imitation natural stone nano pulp.
Weigh the metaphenylene unsaturated polyester resin 4000g that several equal molecular masses are 2800, cobalt iso-octoate 0.6g, peroxidating
MEK 7g, dibenzoyl peroxide 3g, the aluminium hydrate powder 1000g of 100 mesh, the aluminium hydrate powder 2000g of 325 mesh, 400 mesh
Paris white 3000g stir 20min under the rotating speed of 10rpm, obtain imitation natural stone base-material.
Imitation natural stone nano pulp and imitation natural stone base-material are mixed, 20min is stirred under the rotating speed of 70rpm, then will
Compound is transferred in mould, is solidified 2 days in 25 DEG C, then obtains artificial stone by cutting, polishing, polishing.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (9)
1. a kind of artificial stone, it is characterised in that solidified by the raw material including imitation natural stone nano pulp and imitation natural stone base-material
Arrive, the imitation natural stone nano pulp includes saturated polyester resin, aerosil, calcium carbonate, dispersant and toner；It is described
Imitation natural stone base-material includes unsaturated polyester resin, cobalt iso-octoate, curing agent and fleur.
2. artificial stone according to claim 1, it is characterised in that the imitation natural stone nano pulp and imitation natural stone base-material
Mass ratio be 0.02~0.03:100.
3. artificial stone according to claim 1, it is characterised in that the imitation natural stone nano pulp includes following weight hundred
Divide the component of ratio：Saturated polyester resin 20~30%, aerosil 10~15%, calcium carbonate 50~60%, dispersant 0.5
~3%, the toner of surplus.
4. the artificial stone according to claim 1 or 3, it is characterised in that the particle diameter of the aerosil is 2000~
8000 mesh.
5. the artificial stone according to claim 1 or 3, it is characterised in that the saturated polyester resin includes adjacent benzene-type saturation
The mixture of one or more in polyester resin, metaphenylene saturated polyester resin and p-phenyl's saturated polyester resin；
The equal molecular mass of number of the saturated polyester resin is 18000~30000.
6. the artificial stone according to claim 1 or 3, it is characterised in that the particle diameter of the calcium carbonate is 100~200nm.
7. the artificial stone according to claim 1 or 3, it is characterised in that the dispersant includes polyacrylic dispersant,
The equal molecular mass of number of the polyacrylic dispersant is 50000~80000.
8. artificial stone according to claim 1 and 2, it is characterised in that in the imitation natural stone base-material cobalt iso-octoate with not
The mass ratio of saturated polyester resin is 0.04~0.08:100；
Curing agent and the mass ratio of unsaturated polyester resin are 1~3 in the imitation natural stone base-material:100；
Fleur and the mass ratio of unsaturated polyester resin are 1 in the imitation natural stone base-material:2~3.
9. the preparation method of artificial stone described in claim 1~8 any one, comprises the following steps：
(1) imitation natural stone nano pulp is slowly dropped in imitation natural stone base-material, stirring at low speed obtains mixed material；
(2) mixed material that the step (1) is obtained is solidified in a mold and obtains artificial stone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710022873.6A CN106746919A (en) | 2017-01-12 | 2017-01-12 | A kind of artificial stone and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710022873.6A CN106746919A (en) | 2017-01-12 | 2017-01-12 | A kind of artificial stone and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106746919A true CN106746919A (en) | 2017-05-31 |
Family
ID=58947405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201710022873.6A Pending CN106746919A (en) | 2017-01-12 | 2017-01-12 | A kind of artificial stone and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111978792A (en) * | 2020-09-08 | 2020-11-24 | 广东意新家居有限责任公司 | Method for preparing color paste of monochromatic protoplasm of artificial stone and artificial stone |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001146452A (en) * | 1999-09-08 | 2001-05-29 | Nippon Shokubai Co Ltd | Artificial stone plate |
| CN102329100A (en) * | 2010-07-12 | 2012-01-25 | 周军 | Artificial quartz stone checkered plate and process thereof |
| CN103878865A (en) * | 2014-03-14 | 2014-06-25 | 上虞市康超装饰材料有限公司 | Method for manufacturing abnormal-shaped artificial stone with grains and manufactured abnormal-shaped artificial stone |
| CN105482413A (en) * | 2015-12-28 | 2016-04-13 | 山东源根化学技术研发有限公司 | Heat-resistant anti-aging high-strength artificial transparent stone and preparation method thereof |
| CN105776953A (en) * | 2016-03-14 | 2016-07-20 | 广东中旗新材料科技有限公司 | Dotted pattern man-made quartzite sheet material and production process thereof |
-
2017
- 2017-01-12 CN CN201710022873.6A patent/CN106746919A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001146452A (en) * | 1999-09-08 | 2001-05-29 | Nippon Shokubai Co Ltd | Artificial stone plate |
| CN102329100A (en) * | 2010-07-12 | 2012-01-25 | 周军 | Artificial quartz stone checkered plate and process thereof |
| CN103878865A (en) * | 2014-03-14 | 2014-06-25 | 上虞市康超装饰材料有限公司 | Method for manufacturing abnormal-shaped artificial stone with grains and manufactured abnormal-shaped artificial stone |
| CN105482413A (en) * | 2015-12-28 | 2016-04-13 | 山东源根化学技术研发有限公司 | Heat-resistant anti-aging high-strength artificial transparent stone and preparation method thereof |
| CN105776953A (en) * | 2016-03-14 | 2016-07-20 | 广东中旗新材料科技有限公司 | Dotted pattern man-made quartzite sheet material and production process thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111978792A (en) * | 2020-09-08 | 2020-11-24 | 广东意新家居有限责任公司 | Method for preparing color paste of monochromatic protoplasm of artificial stone and artificial stone |
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Application publication date: 20170531 |