CN106738140A - Garden landscape anticorrosive wood prepared by a kind of utilization birchwood - Google Patents
Garden landscape anticorrosive wood prepared by a kind of utilization birchwood Download PDFInfo
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- CN106738140A CN106738140A CN201611099146.1A CN201611099146A CN106738140A CN 106738140 A CN106738140 A CN 106738140A CN 201611099146 A CN201611099146 A CN 201611099146A CN 106738140 A CN106738140 A CN 106738140A
- Authority
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- Prior art keywords
- preservative
- anticorrosive wood
- wood
- impregnation tank
- pressure impregnation
- Prior art date
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- Granted
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- 239000002023 wood Substances 0.000 title claims abstract description 33
- 239000003755 preservative agent Substances 0.000 claims abstract description 29
- 230000002335 preservative effect Effects 0.000 claims abstract description 29
- 238000005470 impregnation Methods 0.000 claims abstract description 19
- 235000018185 Betula X alpestris Nutrition 0.000 claims abstract description 15
- 235000018212 Betula X uliginosa Nutrition 0.000 claims abstract description 15
- 238000001035 drying Methods 0.000 claims abstract description 5
- 238000005554 pickling Methods 0.000 claims abstract description 4
- AQASRZOCERRGBL-UHFFFAOYSA-N Dauricine Natural products CN1CCC2=CC(OC)=C(OC)C=C2C1CC1=CC=C(O)C(OC2=CC=C(C=C2)CC2N(C)CCC=3C=C(C(=CC=32)OC)OC)=C1 AQASRZOCERRGBL-UHFFFAOYSA-N 0.000 claims description 15
- AQASRZOCERRGBL-ROJLCIKYSA-N dauricine Chemical compound CN1CCC2=CC(OC)=C(OC)C=C2[C@H]1CC1=CC=C(O)C(OC2=CC=C(C=C2)C[C@H]2N(C)CCC=3C=C(C(=CC=32)OC)OC)=C1 AQASRZOCERRGBL-ROJLCIKYSA-N 0.000 claims description 15
- 238000007598 dipping method Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 10
- 239000000523 sample Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 3
- 208000015181 infectious disease Diseases 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229930004069 diterpene Natural products 0.000 description 2
- 150000004141 diterpene derivatives Chemical class 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 2
- DGMVLYHSSDLCMR-UHFFFAOYSA-N plumisclerin A Natural products C1CCC23C4C(OC(C)=O)OC=C(C(=O)CCC(C)C)C4CC3C1(COC(C)=O)C2OC(C)=O DGMVLYHSSDLCMR-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011864 timber preservative Substances 0.000 description 2
- 241000228245 Aspergillus niger Species 0.000 description 1
- -1 Dauricine compound Chemical class 0.000 description 1
- 206010064571 Gene mutation Diseases 0.000 description 1
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 description 1
- 241000228153 Penicillium citrinum Species 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- OUFJROAVKKYZEN-UHFFFAOYSA-N [Cr].[Cu].[As] Chemical compound [Cr].[Cu].[As] OUFJROAVKKYZEN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- TYKINIHWJMYLLD-UHFFFAOYSA-N arsoric acid;copper;zinc Chemical compound [Cu].[Zn].O[As](O)(O)=O TYKINIHWJMYLLD-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 231100000704 bioconcentration Toxicity 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- AYWHENVLARCQQQ-UHFFFAOYSA-N copper;1h-pyrrole Chemical class [Cu].C=1C=CNC=1 AYWHENVLARCQQQ-UHFFFAOYSA-N 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- PWGQHOJABIQOOS-UHFFFAOYSA-N copper;dioxido(dioxo)chromium Chemical compound [Cu+2].[O-][Cr]([O-])(=O)=O PWGQHOJABIQOOS-UHFFFAOYSA-N 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- BPQWCZKMOKHAJF-UHFFFAOYSA-N scheele's green Chemical compound [Cu+2].O[As]([O-])[O-] BPQWCZKMOKHAJF-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/0207—Pretreatment of wood before impregnation
- B27K3/0214—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/04—Combined bleaching or impregnating and drying of wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses garden landscape anticorrosive wood prepared by a kind of utilization birchwood, by following steps, birch material dried process makes its moisture content≤13% to described anticorrosive wood；（3）, timber pickling preservative treatment：Dried timber is fitted into high-pressure impregnation tank, after covering, by high-pressure impregnation tank suction to 0.07MPa~0.08MPa, kept for 30~60 minutes, preservative, removal vacuum are then filled in high-pressure impregnation tank, slowly it is forced into 1.5~1.7MPa, and pressurize 2~4 hours, release, discharge preservative, then high-pressure impregnation tank is evacuated to 0.07MPa~0.08MPa again, kept for 35 minutes, release vacuum, take out timber；（4）, by the drying of wood after impregnation process to moisture content≤12%, obtain required birch anti-corrosion.
Description
Technical field
The present invention relates to a kind of preservative, garden landscape anticorrosive wood prepared by specifically a kind of utilization birchwood belongs to agriculture
Industry technical field.
Background technology
Anticorrosive wood, is to pass through after artificial addition chemical preservative common wood, makes it have anticorrosion, protection against the tide, prevents
The characteristics such as fungi, ant prevention, anti-mildew and waterproof.Can directly contact soil and wet environment, commonly using out of doors
Plate, engineering, landscape, anticorrosive wood flower stand etc., have a rest and appreciate wild beauty for people, are outdoor flooring, garden landscape, wooden autumn
Thousandth, the ideal material of recreational facilities, wooden footway etc..
Conventional timber preservative is divided into three major types at present：Oil-type preservation, mainly antiseptic oil, coal tar, carbolineum etc.；
Oil carries preservative, mainly including pentachlorophenol, copper naphthenate, copper 8-quinolinolate etc.；Water ballast preservative includes the water containing arsenic or chromium
Load type preservative, such as CCA (copper chromium arsenic), ACC (acid copper chromate), ACA (ammonical copper arsenite), ACZA (the molten arsenic acid zinc-copper of ammonia)
Deng such as ACQ of the waterborne preservative without arsenic or chromium (ammoniacal copper quaternary), CBA-A (copper borazol), CA-B (copper azoles) etc..These are passed
System timber preservative achieves preferable antiseptic effect, but pollution can be produced to environment, and is made by bioconcentration and food chain
With so that medicament is accumulated, remained in vivo, or even causes the chronic murder by poisoning such as carcinogenic, teratogenesis, gene mutation.
Plumisclerin A,a Diterpene with a New Skeleton from the Soft
CoralPlumigorgiaterminosclera Org.Lett.,2010,12(5),912–914。
It is found by the applicant that PlumisclerinA coordinates with Dauricine under certain proportion having for preparing birch anticorrosive wood
There is the effect of anti-corrosion synergy.
The content of the invention
For the problem that above-mentioned prior art is present, it is an object of the invention to provide garden prepared by a kind of utilization birchwood
Woods landscape anticorrosive wood, it is to prepare anticorrosive wood favorable anti-corrosion effect, low cost as material by the use of birch.
To achieve these goals, the technical solution adopted by the present invention is:Garden landscape prepared by a kind of utilization birchwood
Anticorrosive wood, by following steps, birch material dried process makes its moisture content≤13% to described anticorrosive wood；(3), timber pickling
Preservative treatment：Dried timber is fitted into high-pressure impregnation tank, after covering, by high-pressure impregnation tank suction extremely
0.07MPa~0.08MPa, is kept for 30~60 minutes, and preservative is then filled in high-pressure impregnation tank, and removal vacuum is slow to add
It is depressed into 1.5~1.7MPa, and pressurize 2~4 hours, preservative is discharged in release, is then evacuated to high-pressure impregnation tank again
0.07MPa~0.08MPa, is kept for 35 minutes, releases vacuum, takes out timber；(4), by the drying of wood after impregnation process to containing
Water rate≤12%, obtains required birch anticorrosive wood.
The principle active component of described preservative is:PlumisclerinA and Dauricine, PlumisclerinA its
Structural formula is as follows：
The ratio between described PlumisclerinA and the parts by weight of Dauricine are 1:1-30:1, PlumisclerinA with
The weight of Dauricine accounts for the 0.3%~5% of preservative gross weight.
The present invention prepares anticorrosive wood by using birch as raw material, and low manufacture cost, preservative utilizes native compound
PlumisclerinA and Dauricine compound preservative, it is pollution-free, it is found by the applicant that PlumisclerinA matches somebody with somebody with Dauricine
5 find that the birch anticorrosive wood for preparing has good anti-mold effect under specific ratio, particularly in PlumisclerinA
It is 13-16 with the ratio between parts by weight of Dauricine:Between 1, its collaboration anti-mold effect is apparent, and small toxicity, is good for
Kang Huanbao.
Specific embodiment
Dauricine, No. CAS:524-17-4, Chengdu Zhi Biaohuachun Bioisystech Co., Ltd etc. are on sale.
The preparation method of compound PlumisclerinA involved in the present invention is referring to document：(Plumisclerin A,a
Diterpene with a New Skeleton from the Soft CoralPlumigorgiaterminosclera
Org.Lett.,2010,12(5),912–914)。
Effect test:
Examination material birch anticorrosive wood, birch material dried process makes its moisture content≤13%；(3), at timber pickling preservative
Reason：Dried timber is fitted into high-pressure impregnation tank, after covering, by high-pressure impregnation tank suction to 0.07MPa~
0.08MPa, is kept for 30~60 minutes, then fills preservative in high-pressure impregnation tank, removal vacuum, slowly it is forced into 1.5~
Preservative is discharged in 1.7MPa, and pressurize 2~4 hours, release, then by high-pressure impregnation tank be evacuated to again 0.07MPa~
0.08MPa, is kept for 35 minutes, releases vacuum, takes out timber；(4), by the drying of wood after impregnation process to moisture content≤
12%, obtain required birch anticorrosive wood.
Birch is all processed into the sample of 100mm × 60mm × 10mm (length × width x thickness) in this experiment.
Mould:Aspergillus niger (AspergillusnigerV.Tiegh), Penicillium citrinum (Penicilliumcitrintim
Thom), strain is provided by INST OF WOOD INDUDTRY CHINESE.
Experimental facilities
MJX-8503 Intelligent culture casees, BCL-1360-B type superclean benches etc..
Groined type is put during same group of sample is placed on into beaker, and weight bears down on one to prevent from floating, and is subsequently poured into liquid simultaneously
Its liquid level is set to be higher by sample material top 2cm.After taking-up, the raffinate of specimen surface is wiped.Blank control group sample is soaked with sterilized water,
Sample after treatment is placed in ventilation, and gas is dry 21 days.
Anti-mold effect is evaluated
With reference to national standard《Mould inhibitor prevents and treats the experimental technique of timber mould and Stain fungi》, the interior of detection process sample
Fungicidal properties.Sample is connect in 4 weeks after bacterium, and the killed value and specimen surface of every sample of 3 days observed and recordeds are gone mouldy
Degree, and reference sample killed value.
| The degree that specimen surface goes mouldy | The examination bacterium killed value of infection area |
| Specimen surface is without mycelia | 0 |
| Specimen surface infection area ＜ 1/4 | 1 |
| Specimen surface infects area 1/4~1/2 | 2 |
| Specimen surface infects area 1/2~3/4 | 3 |
| Specimen surface infection area ＞ 3/4 | 4 |
Medicament is to the preventing efficiency computing formula of mould:
In E=(1-Dt/D0) × 100% formula:E is preventing efficiency (%)；Dt is the average killed value of chemicals treatment sample；
D0 is the average killed value of untreated control sample,
By after indoor mould proof experiment in 4 weeks, the preventing and treating of anticorrosive wood sample prepared by various concentrations component preservative to mould
Effect is shown in Table.
The auxiliary formula of preservative is：Polyvinylpyrrolidone 2%, n-butanol 5%, excess water,
A is PlumisclerinA, and B is Dauricine.
By experimental result it can be seen that single PlumisclerinA and Dauricine prepare anticorrosive wood and have as preservative
There is certain anti-mold effect, but effect is not notable, and substantial amounts of experiment shows only PlumisclerinA and Dauricine 13-
16:Anticorrosive wood prepared by 1 ratio preservative is good for the prevention effect of mould, and other ratio groups are not notable, it is seen that
PlumisclerinA is with Dauricine in 13-16:The birch anticorrosive wood prepared as preservative when 1 cooperates with antiseptic effect substantially,
With significant progressive.
Claims (3)
1. the garden landscape anticorrosive wood that prepared by a kind of utilization birchwood, described anticorrosive wood is by following steps, the birch drying of wood
Treatment, makes its moisture content≤13%；The treatment of timber pickling preservative：Dried timber is fitted into high-pressure impregnation tank, is covered
Afterwards, by high-pressure impregnation tank suction to 0.07MPa~0.08MPa, kept for 30~60 minutes, then noted in high-pressure impregnation tank
Full preservative, removal vacuum is slowly forced into 1.5~1.7MPa, and pressurize 2~4 hours, and preservative is discharged in release, then will
High-pressure impregnation tank is evacuated to 0.07MPa~0.08MPa again, is kept for 35 minutes, releases vacuum, takes out timber；At dipping
The drying of wood after reason obtains required birch anticorrosive wood to moisture content≤12%.
2. the garden landscape anticorrosive wood that prepared by a kind of utilization birchwood according to claim 1, it is characterised in that it is described
The principle active component of preservative be:PlumisclerinA and Dauricine, its structural formula of PlumisclerinA are as follows：
。
3. the garden landscape anticorrosive wood that prepared by a kind of utilization birchwood according to claim 1, it is characterised in that described
The ratio between parts by weight of PlumisclerinA and Dauricine are 1:1-30:1, PlumisclerinA with the weight of Dauricine
Account for the 0.3%~5% of preservative gross weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611099146.1A CN106738140B (en) | 2016-12-04 | 2016-12-04 | A kind of garden landscape anticorrosive wood prepared using birchwood |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611099146.1A CN106738140B (en) | 2016-12-04 | 2016-12-04 | A kind of garden landscape anticorrosive wood prepared using birchwood |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106738140A true CN106738140A (en) | 2017-05-31 |
| CN106738140B CN106738140B (en) | 2018-05-15 |
Family
ID=58884112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611099146.1A Expired - Fee Related CN106738140B (en) | 2016-12-04 | 2016-12-04 | A kind of garden landscape anticorrosive wood prepared using birchwood |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106738140B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107471365A (en) * | 2017-09-29 | 2017-12-15 | 徐州得铸生物科技有限公司 | A kind of municipal gardens anticorrosive wood |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029264A (en) * | 2014-06-25 | 2014-09-10 | 江苏东珠景观股份有限公司 | High-durability preservative-treated timber for landscape planting |
| CN104210001A (en) * | 2014-07-24 | 2014-12-17 | 株洲市长缨有害生物防治有限责任公司 | Insect and mould inhibitor and application thereof |
| CN104858964A (en) * | 2014-12-25 | 2015-08-26 | 王玉燕 | Anticorrosive wood production method |
-
2016
- 2016-12-04 CN CN201611099146.1A patent/CN106738140B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029264A (en) * | 2014-06-25 | 2014-09-10 | 江苏东珠景观股份有限公司 | High-durability preservative-treated timber for landscape planting |
| CN104210001A (en) * | 2014-07-24 | 2014-12-17 | 株洲市长缨有害生物防治有限责任公司 | Insect and mould inhibitor and application thereof |
| CN104858964A (en) * | 2014-12-25 | 2015-08-26 | 王玉燕 | Anticorrosive wood production method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107471365A (en) * | 2017-09-29 | 2017-12-15 | 徐州得铸生物科技有限公司 | A kind of municipal gardens anticorrosive wood |
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| Publication number | Publication date |
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| CN106738140B (en) | 2018-05-15 |
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