CN105690518A - Log and raw bamboo protective agent and application method thereof - Google Patents

Log and raw bamboo protective agent and application method thereof Download PDF

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Publication number
CN105690518A
CN105690518A CN201610105100.XA CN201610105100A CN105690518A CN 105690518 A CN105690518 A CN 105690518A CN 201610105100 A CN201610105100 A CN 201610105100A CN 105690518 A CN105690518 A CN 105690518A
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China
Prior art keywords
log
protective agent
parts
agent
former bamboo
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CN201610105100.XA
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CN105690518B (en
Inventor
孙芳利
方群
鲍滨福
于红卫
杜春贵
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Zhejiang A&F University ZAFU
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Zhejiang A&F University ZAFU
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52Impregnating agents containing mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/08Impregnating by pressure, e.g. vacuum impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/002Cane, bamboo
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/20Removing fungi, molds or insects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment
    • B27K2240/70Hydrophobation treatment

Abstract

The invention discloses a log and raw bamboo protective agent. The log and raw bamboo protective agent comprises a main protective agent body and a hydrophobic agent and is characterized in that the main protective agent body is composed of, by weight, 1.0-10.0 parts of fungicide and insecticide, 10-30.0 parts of water-soluble monomers and/or polymer, 0.0-5.0 parts of coloring agents and 100.0 parts of water; and the hydrophobic agent is composed of, by weight, 90.0-98.0 parts of paraffin and 2.0-10.0 parts of auxiliaries. According to application of the protective agent, the bottom of a log or the bottom of raw bamboo is erected in a tank containing the main protective agent or transversely immersed into the tank containing the main protective agent, or vacuum pressure treatment is adopted; then the log or the raw bamboo is subjected to hydrophobic drying treatment, and the log or the raw bamboo is cooled and discharged. The treated log and the raw bamboo are low in moisture content, quite remarkable in fungus, insect and cracking resistant effect, good in medicine leachability resistance, long in validity period, capable of conducting drying and coloring treatment and good in energy-saving effect.

Description

The former bamboo protective agent of log and using method thereof
Technical field
The present invention relates to a kind of wood bamboo chemical classes be fungi-proofing, the protective agent of insect protected and anticracking and using method thereof。
Background technology
China's bamboo resource is very abundant。Bamboo growth is fast, and the cycle is short, and bamboo wood in form and properties closest to timber, be widely used in the aspects such as papermaking, building, furniture and wood-based plate, be the important substitution material of timber。The growth cycle of timber is relatively long, and water and soil self-restraint effect is big, ecological protection effect is notable, and felling is controlled by strict, and the utilization of timber resources is by certain restriction。
Do not carry out the bamboo stem of division processing and the organizational structure of the tree bar former bamboo of maintenance and log and morphological characteristic after felling, there is mechanical strength and the aesthetic of former bamboo log, be widely used in furniture and building。But due to wood bamboo wood in acellular wall material such as starch, reducing sugar, protein, fat equal size all higher, it is easily used to when warm moist that generation is rotten, goes mouldy and the phenomenon such as damage by worms, seriously limit the application of the former bamboo of log, shorten its service life。Additionally, due to the water suction hygroscopicity of former bamboo, the anisotropy of log timberstructure and material, in use also can often there is cracking and metaboly in former bamboo log, especially ftractures, be further exacerbated by wooden bamboo wood rotten, damage by worms and go mouldy。Therefore, research wood bamboo wood resistance to rotten, go mouldy, the protective treatment technology such as Anti-moth-eating and cracking efficiently utilizing of wood bamboo wood is significant。
CN102687729A is disclosed the mode pressurizeed by evacuation and impregnates in bamboo wood a kind of former bamboo protective agent based on ammoniacal copper quaternary, N-2-benzimidazole ylcarbamic acid methyl ester to its method carrying out insect protected, anticorrosion, anti-mildew process, is not directed to anticracking。CN102189578A discloses one and is soaked 60-90 days in pond by log, then makes sheet material, conventionally dry technique, has certain crack resistence effect, but is not directed to antibacterial worm and processes。The technical problem to be solved in the present invention is to provide the wooden bamboo wood chemical protector of a kind of energy anticorrosion, mildew-resistant, insect protected, anticracking simultaneously, and provides a kind of simple wooden bamboo wood protective agent use technology。
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of energy is fungi-proofing, the former bamboo protective agent of log of insect protected and anticracking and using method thereof。
Solution the problems referred to above adopt the following technical scheme that
The former bamboo of this log is fungi-proofing, the protective agent of insect protected and anticracking is made up of two parts, i.e. protection host and water-repelling agent。
Protection host is formulated by following raw materials according and weight portion thereof:
Water-repelling agent is formulated by following raw materials according and weight portion thereof:
90.0~98.0 parts of paraffin
Auxiliary agent 2.0~10.0 parts
Described antifungal and insecticide are boric acid, Borax, four hydration eight sodium borate, DDAC, copper sulfate, copper chloride, zinc chloride, zinc sulfate, the molten ammoniacal copper quaternary of ammonia (ACQ), copper azoles (CuAz), copper chromium arsenic (CCA) and by each 1-2 kind in the nano wood antiseptics of the country being located in Zhejiang A & F University wooden comprehensive utilization of resources Engineering Technical Research Centre production and sales。
Described water-soluble monomer and/or polymer are the 1-3 kind in Polyethylene Glycol, chitosan, acrylic acid, itaconic acid, acrylamide, N, N'-methylene-bisacrylamide, NIPA, hydroxyethyl methylacrylate, chitosan quaternary ammonium salt, Polyethylene Glycol, polyvinyl alcohol, polyvinylpyrrolidone, copolyvidone。
Described coloring agent can be any sort dyestuff in acid stain or basic stain or reactive dye when needed。
Described paraffin is the mineral wax of fusing point 50-90 DEG C, vegetable wax or modified paraffin。
Described auxiliary agent is any one in Colophonium, methyl-silicone oil, vegetable oil and animal oil。
The former bamboo of this log is fungi-proofing, the using method of the protective agent of insect protected and anticracking carries out as follows:
(1) protective treatment of the former bamboo of log: the bottom of log or former bamboo is stood in the groove filling protection host, or former for log bamboo is laterally immersed in the groove filling protection host, 3-30 days, process then 1-3h according to vacuum pressed, concrete treatment temperature and time drug loading as required and determine;
(2) hydrophobic dried: the log after protection host processes or former bamboo are immersed in melted water-repelling agent immediately again, progressively heat up, intensification 2-5 DEG C per hour, it is incubated 0.5-1.0 hour, to 80 DEG C, then it is warming up to 100-110 DEG C with 1-2 DEG C per hour, is incubated 0.5-1.0 hour, until it reaches required water content requirement is only;
(3) cooling discharge: step (2) starts progressively to lower the temperature after completing, can Temperature fall or more than be progressively cooled to the fusing point of water-repelling agent with 2-5 DEG C per hour, namely 60-90 DEG C, take out, erasing surface paraffin or oil stain, stack。
The invention has the beneficial effects as follows: one, antifungal selected by this protective agent and insecticide are aqueous solvent, penetrating power is strong, the nontoxic or low toxicity to human body and environment, can effectively protect the former bamboo of log exempt from rotten and damage by worms。Two, selected water-soluble polymer or monomer are polymerized in the process of step (2), it is possible to antifungal and insecticide are bonded in log or former bamboo, it is prevented that it runs off。Owing to temperature-rise period is relatively slow, can effectively prevent the loss of monomer caused because heat of polymerization is excessive。Three, the present invention is through the process of several steps, not only gives log or former bamboo is fungi-proofing, insect protected and anti-crack function, and complete log or the drying process of former bamboo, save time and the energy。Four, the present invention protects and can contain coloring agent in host, changes log or former bamboo color when not changing process technique。The interpolation of coloring agent can select according to actual needs。
Detailed description of the invention
The present invention is described in further detail below in conjunction with embodiment:
The present invention is listed in table 1 (proportioning of water-repelling agent is simply clear, not another row embodiment) by protecting each raw material of host and weight value thereof by eight embodiments below:
Embodiment 4 (in synopsis 1 raw material of embodiment 4 correspondence and weight value):
First being dissolved in 100.0 parts of water respectively by 2.5 parts of boric acid and 2.5 parts of Boraxs, stirring, so as to be completely dissolved, be subsequently adding 30.0 parts of Polyethylene Glycol, stir, add 1.5 parts of acid staiies, be again stirring for being completely dissolved, obtain protection host。By 2 meters long fresh former bamboos (or log) without getting through ring, directly it is soaked in the protection host according to the preparation of embodiment 4 method 10 days。Taking out is placed in the water-repelling agent solution melted, 80 DEG C progressively it are warming up to according to per hour 5 DEG C, often raise 5 DEG C and be incubated 30 minutes, then according to per hour 2 DEG C be warming up to 105 DEG C, often raise 2 DEG C and be incubated 60 minutes, namely complete antibacterial, the insect protected to former bamboo (log) and anticracking process work。
All the other embodiment 1,2,3 and 5-8, the raw material of corresponding embodiment and weight value in equal synopsis, the method identical with embodiment 4 prepares antibacterial, worm and the former bamboo protective agent of anticracking log, all can reach described technique effect, wherein with embodiment 2,4 and 6 preferred。
The cracking phenomena in log former bamboo use procedure out of doors can be substantially reduced with the former bamboo of protective agent processing logs of the present invention, after process, the resistance of the bacterium such as aspergillus niger, Trichoderma spp., Aspergillus citrimum, stain fungus be reached more than 85%;The corrosion resistant ability of whiterot fungi, brown rot fungus can be reached strong corrosion resistant grade;The moth resistances such as Coptotermes formosanus Shtrari. is better。
Nano wood antiseptics in antifungal and insecticide is that the method announced for patent CN200810062170.7 " nano wood antiseptics and manufacture method thereof " formerly authorized by the applicant produces。
It is 9.2cm that embodiment 4,6 and 8 processes diameter, the former bamboo of Phyllostachys pubescens Mazei ex H.de Lebaie of long 200cm and diameter are 12.4cm, the Pinus massoniana Lamb log of long 200cm, former bamboo after process and log and untreated former bamboo and log are 25 DEG C in temperature, relative humidity be 65% climatic chamber in regulate moisture content 14 days, reach constant moisture content, weigh, obtain W1。Then A and B two crowdes it is classified as, A criticizes the opening being placed in outdoor overhead 20cm place and is exposed to the sun, B criticizes and is placed in the place that external genitalia, Zhejiang A & F University's biological test building undercurrent wets and has Coptotermes formosanus Shtrari., all tests 9 months for two batches, from January 15,6 days to 2016 April in 2015。Record A criticizes the cracking situation of former bamboo and B criticizes the going mouldy of former bamboo, damages by worms and rotten situation, and result is table 2 and 3 such as。The cracking of sample accounts for former bamboo gross area percentage ratio (being called for short flaw area ratio) with the area in crack and calculates, moth erosion situation accounts for gross area percentage ratio (being called for short moth erosion area ratio) calculating with surface channel quantity and surface moth erosion area, mould variable area is referred to " antifungus agent preventing and treating timber mycete and the test method of Stain fungi " (GB/T18261-2000) and calculates the area that goes mouldy and account for the percentage ratio (abbreviation go mouldy area ratio) of the gross area, rotten degree calculates weight-loss ratio with reference to " timber preservative is to rot fungi toxicity test room test method " (LY/T1283-2011)。
Embodiment 4,6 and 8 being processed the rate of body weight gain of material, increase-volume rate, dimensional stability, mildew-resistant, anticorrosion and termite-proof performance test, result is as follows。
Embodiment 4,6 and 8 processes the rate of body weight gain respectively 35.6 ± 2.1%, 31.4 ± 2.0% and 37.4 ± 1.2% of former bamboo wood, increase-volume rate respectively 4.3 ± 1.2%, 3.8 ± 1.0% and 4.6 ± 0.7%。Table 2 processes former bamboo for embodiment 4,6 and 8 and untreated former bamboo wood ftractures, damages by worms, goes mouldy and rotten situation。Untreated former bamboo is exposed to the sun 7 obvious cracks of middle appearance out of doors, and Coptotermes formosanus Shtrari. moth erosion is serious, and weight-loss ratio, up to 57.6%, goes mouldy completely。And the weightlessness that embodiment 4,6 and 8 processes the cracking significantly reducing former bamboo, goes mouldy, damages by worms and cause due to rot fungi and Coptotermes formosanus Shtrari.。
Also similar effect (table 3) can be reached by same method processing logs。Embodiment 4,6 and 8 processes the rate of body weight gain respectively 44.2 ± 2.8%, 39.4 ± 3.4% and 40.5 ± 1.9% of Pinus massoniana Lamb log, increase-volume rate respectively 7.4 ± 2.1%, 6.8 ± 1.4% and 5.9 ± 0.8%。Untreated Pinus massoniana Lamb is exposed to the sun 9 obvious cracks of middle appearance out of doors, and subjects to Coptotermes formosanus Shtrari. and stain fungus infects, bacterium worm the weight-loss ratio caused is up to 87.2%。And the weightlessness that embodiment 4,6 and 8 processes the cracking significantly reducing log, goes mouldy, damages by worms and cause due to rot fungi and Coptotermes formosanus Shtrari.。
Table 2 embodiment 4,6 and 8 processes former bamboo and untreated former bamboo wood ftractures, damages by worms, goes mouldy and rotten situation
Table 3 embodiment 4,6 and 8 processes Pinus massoniana Lamb log and untreated log ftractures, damages by worms, goes mouldy and rotten situation

Claims (7)

1. the former bamboo protective agent of log, is divided into protection host and water-repelling agent two parts, it is characterized in that being formed by following raw materials according and weight portion mixture thereof:
(1) protection host:
Antifungal and insecticide 1.0~10.0 parts, water-soluble monomer and/or 10~30.0 parts of polymer, coloring agent 0.0~5.0 part, 100.0 parts of water;
(2) water-repelling agent:
90.0~98.0 parts of paraffin, auxiliary agent 2.0~10.0 parts。
2. the former bamboo protective agent of log as claimed in claim 1, is characterized in that described antifungal and insecticide are boric acid, Borax, four hydration eight sodium borate, DDAC, copper sulfate, copper chloride, zinc chloride, zinc sulfate, the molten ammoniacal copper quaternary of ammonia (ACQ), copper azoles (CuAz), copper chromium arsenic (CCA) and by each 1-2 kind in the nano wood antiseptics of the country being located in Zhejiang A & F University wooden comprehensive utilization of resources Engineering Technical Research Centre production and sales。
3. the former bamboo protective agent of log as claimed in claim 1, it is characterized in that described water-soluble monomer and/or polymer are the 1-3 kind in Polyethylene Glycol, chitosan, acrylic acid, itaconic acid, acrylamide, N, N'-methylene-bisacrylamide, NIPA, hydroxyethyl methylacrylate, chitosan quaternary ammonium salt, Polyethylene Glycol, polyvinyl alcohol, polyvinylpyrrolidone, copolyvidone。
4. the former bamboo protective agent of log as claimed in claim 1, is characterized in that described coloring agent when needed can for any sort dyestuff in acid stain or basic stain or reactive dye。
5. the former bamboo protective agent of log as claimed in claim 1, is characterized in that described paraffin is the mineral wax of fusing point 50-90 DEG C, vegetable wax or modified paraffin。
6. the former bamboo protective agent of log as claimed in claim 1, is characterized in that described auxiliary agent is any one in Colophonium, methyl-silicone oil, vegetable oil and animal oil。
7. the using method of application log former bamboo protective agent described in claim 1, is characterized in that carrying out as follows:
(1) protective treatment of the former bamboo of log: the bottom of log or former bamboo is stood in the groove filling protection host, or former for log bamboo is laterally immersed in the groove filling protection host, 3-30 days, process then 1-3h according to vacuum pressed, concrete treatment temperature and time drug loading as required and determine;
(2) hydrophobic dried: the log after protection host processes or former bamboo are immersed in melted water-repelling agent immediately again, progressively heat up, intensification 2-5 DEG C per hour, it is incubated 0.5-1.0 hour, to 80 DEG C, then it is warming up to 100-110 DEG C with 1-2 DEG C per hour, is incubated 0.5-1.0 hour, until it reaches required water content requirement is only;
(3) cooling discharge: step (2) starts progressively to lower the temperature after completing, can Temperature fall or more than be progressively cooled to the fusing point of water-repelling agent with 2-5 DEG C per hour, namely 60-90 DEG C, take out, erasing surface paraffin or oil stain, stack。
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106349798A (en) * 2016-08-31 2017-01-25 广东慧信环保有限公司 Novel hydrophobic agent and method for preparing same
CN106363726A (en) * 2016-08-23 2017-02-01 北京林业大学 Method of wood preservative treatment by means of biomass pyrolysis oil
CN106752947A (en) * 2016-11-30 2017-05-31 湖州练市双龙木业有限公司 A kind of mould proof protective agent for wood products and preparation method thereof
CN106863515A (en) * 2017-01-13 2017-06-20 亚振家具股份有限公司 A kind of environment-friendly type compounding timber protective agent and preparation method thereof
CN107053411A (en) * 2017-03-16 2017-08-18 浙江省林产品质量检测站 A kind of colouring method of bamboo material
CN108312273A (en) * 2018-02-11 2018-07-24 广西荔浦安吉利木业有限公司 A kind of timber protective agent and preparation method thereof
CN108422516A (en) * 2018-02-01 2018-08-21 霍山泓浩竹艺有限公司 A kind of production method inhibiting bamboo product water-swellable
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CN108908594A (en) * 2018-08-02 2018-11-30 安徽信达家居有限公司 A kind of processing method extending mould-proof-type bamboo wood effective time
CN108927869A (en) * 2018-08-06 2018-12-04 安徽三和工艺品有限公司 A method of improving the thin poplar piece toughness of fast-growing
CN109968480A (en) * 2017-12-28 2019-07-05 东莞市广信知识产权服务有限公司 A kind of mould proof protective agent of waterproofing wood
CN110355844A (en) * 2019-07-24 2019-10-22 浙江农林大学 A kind of protection of wood bamboo material water-base epoxy compound system and its application
CN112476682A (en) * 2020-12-03 2021-03-12 中国林业科学研究院木材工业研究所 Microemulsion type wood and bamboo preservative and preparation method thereof
CN112497374A (en) * 2020-11-28 2021-03-16 无锡市森泰木制品有限公司 Preparation method of environment-friendly antibacterial solid wood floor
CN113070965A (en) * 2021-04-26 2021-07-06 安徽凹凸家具有限公司 Furniture anti-cracking processing technology
CN114953060A (en) * 2022-07-05 2022-08-30 广西亿松木业有限公司 Preparation method of mildew-proof plywood

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101298150A (en) * 2008-06-03 2008-11-05 浙江林学院 Wood preservative complex containing chitose metal complex
CN101323121A (en) * 2008-06-27 2008-12-17 浙江林学院 Modified chitosan metal composite wood preservative and method for producing the same
CN101992489A (en) * 2009-08-27 2011-03-30 焦永彬 Preparation process of environment-friendly antiseptic wood
CN102267150A (en) * 2011-06-30 2011-12-07 北京展辰化工有限公司 Water-based wood protective agent and preparation method thereof
CN102490229A (en) * 2011-11-25 2012-06-13 广东省林业科学研究院 Wood preservation and water repellent agent and preparation method thereof
CN103171007A (en) * 2011-12-26 2013-06-26 福建省漳平木村林产有限公司 Production method of crack-resistant and corrosion-resistant wood and impregnating liquid

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101298150A (en) * 2008-06-03 2008-11-05 浙江林学院 Wood preservative complex containing chitose metal complex
CN101323121A (en) * 2008-06-27 2008-12-17 浙江林学院 Modified chitosan metal composite wood preservative and method for producing the same
CN101992489A (en) * 2009-08-27 2011-03-30 焦永彬 Preparation process of environment-friendly antiseptic wood
CN102267150A (en) * 2011-06-30 2011-12-07 北京展辰化工有限公司 Water-based wood protective agent and preparation method thereof
CN102490229A (en) * 2011-11-25 2012-06-13 广东省林业科学研究院 Wood preservation and water repellent agent and preparation method thereof
CN103171007A (en) * 2011-12-26 2013-06-26 福建省漳平木村林产有限公司 Production method of crack-resistant and corrosion-resistant wood and impregnating liquid

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《化工百科全书》编辑委员会: "《化工百科全书 第12卷 木材和林产化学品-前列腺素》", 30 November 1996, 北京:化学工业出版社 *
余丽萍: "醇类化合物对硼基木材防腐剂抗流失性的影响", 《北京林业大学学报》 *
曲荣君等: "《材料化学实验》", 31 March 2008 *

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