CN106732215A - A kind of enhancing colloidal sol for moistening fragrant pearl for cigarette and preparation method thereof - Google Patents
A kind of enhancing colloidal sol for moistening fragrant pearl for cigarette and preparation method thereof Download PDFInfo
- Publication number
- CN106732215A CN106732215A CN201710022651.4A CN201710022651A CN106732215A CN 106732215 A CN106732215 A CN 106732215A CN 201710022651 A CN201710022651 A CN 201710022651A CN 106732215 A CN106732215 A CN 106732215A
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- China
- Prior art keywords
- colloidal sol
- parts
- enhancing
- cigarette
- fragrant pearl
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- 230000002708 enhancing effect Effects 0.000 title claims abstract description 26
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000243 solution Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000011259 mixed solution Substances 0.000 claims abstract description 6
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 6
- 238000002604 ultrasonography Methods 0.000 claims abstract description 6
- 239000000706 filtrate Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 238000001914 filtration Methods 0.000 claims abstract description 3
- 108010010803 Gelatin Proteins 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 239000008273 gelatin Substances 0.000 claims description 7
- 229920000159 gelatin Polymers 0.000 claims description 7
- 235000019322 gelatine Nutrition 0.000 claims description 7
- 235000011852 gelatine desserts Nutrition 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 235000010413 sodium alginate Nutrition 0.000 claims description 6
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 239000000661 sodium alginate Substances 0.000 claims description 5
- 229940005550 sodium alginate Drugs 0.000 claims description 5
- 241000206575 Chondrus crispus Species 0.000 claims description 4
- 241000208125 Nicotiana Species 0.000 claims description 4
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 4
- 229920003064 carboxyethyl cellulose Polymers 0.000 claims description 4
- 238000007493 shaping process Methods 0.000 claims description 4
- 229920001817 Agar Polymers 0.000 claims description 3
- 229920003091 Methocel™ Polymers 0.000 claims description 3
- 239000008272 agar Substances 0.000 claims description 3
- 235000010419 agar Nutrition 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 239000001814 pectin Substances 0.000 claims description 3
- 235000010987 pectin Nutrition 0.000 claims description 3
- 229920001277 pectin Polymers 0.000 claims description 3
- 239000006187 pill Substances 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 230000007547 defect Effects 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 abstract description 2
- 239000002304 perfume Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 carboxyethyl Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0034—Additives, e.g. in view of promoting stabilisation or peptisation
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B3/00—Preparing tobacco in the factory
- A24B3/12—Steaming, curing, or flavouring tobacco
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Fats And Perfumes (AREA)
Abstract
The present invention provides a kind of enhancing colloidal sol for moistening fragrant pearl for cigarette and preparation method thereof, and the enhancing colloidal sol is made up of the raw material of following component and weight portion：56 1020 parts of 40 70 parts of colloidal sol, 35 parts of plasticizer, 38 parts of NMF, 10 30 parts of reinforcing agent and water, colloidal sol is soluble in water, and water-bath is stirred to dissolving；Add plasticizer, NMF and reinforcing agent, at the uniform velocity stir, after stirring 2h 5h, mixed solution is put into ultrasonic pond carries out ultrasound, mix each component to be more uniformly distributed, and using nanometer sieve aperture filtration treatment is carried out to resulting solution afterwards, filtrate is finally stood into 10 24h in 45 70 DEG C of environment, you can obtain moistening for cigarette the enhancing colloidal sol of fragrant pearl.Comprising plasticizer, NMF, reinforcing agent etc., it is too low to greatly improve the fragrant pearl hardness of tradition profit, easily makes moist for the sol formulation that the present invention is provided, and the defect such as be difficult to crumb.
Description
Technical field
The present invention relates to the fragrant pearl preparation field of cigarette profit, it is more particularly to a kind of for cigarette moisten fragrant pearl enhancing colloidal sol and
Its preparation method.
Background technology
The fragrant pearl of cigarette profit as a kind of effective product for improving cigarette taste, reducing tar and reducing harm, the flavouring that renders palatable, at home
It is widely used in outer various cigarettes.But because the various differences for making raw material, preparation technology and molding mode, can make
It is variant into product quality and stability between the fragrant pearl of different profits.The profit perfume pearl that the fragrant pearl preparing raw material of traditional profit makes is present
Hardness is too low, and by being differed greatly after storage, the phenomenon such as be difficult to crumb the hardness between each pearl.Additionally, the profit after shaping is fragrant
Bead surface out-of-flatness or easy bonding are also a problem that can not be ignored.
The content of the invention
For above-mentioned the deficiencies in the prior art, the present invention provides a kind of enhancing colloidal sol and its preparation for moistening fragrant pearl for cigarette
Method, adds this enhancing colloidal sol to prepare the fragrant pearl of profit, and it is too low to greatly improve the fragrant pearl hardness of tradition profit, easily makes moist, and is difficult to crumb
Etc. defect.
A kind of enhancing colloidal sol for moistening fragrant pearl for cigarette, it is characterised in that be made up of the raw material of following component and weight portion：
The colloidal sol includes one or more in gelatin, sodium alginate, agar, carragheen and pectin；
The plasticizer includes one or more in polyethylene glycol, silicone oil；
The NMF includes one or more in G ＆ W soluble starch；
The reinforcing agent includes one or more in carboxylic propyl methocel, methylcellulose, carboxyethyl cellulose.
The further enhancing colloidal sol, is made up of the raw material of following component and weight portion：Gelatin 30-50 parts, alginic acid
Sodium 10-20 parts, polyethylene glycol 3-5 parts, water soluble starch 3-7 parts, carboxyethyl cellulose 13-27 parts, water 69-1020 parts.
A kind of preparation method of the enhancing colloidal sol for moistening fragrant pearl for cigarette, comprises the following steps that：
(1) it is colloidal sol is soluble in water, it is placed in 60-90 DEG C of water-bath and stirs to dissolving；Add plasticizer, NMF and increasing
Strong agent, maintains constant temperature, at the uniform velocity stirs 2h-5h；
(2) step (1) gained mixed solution is put into ultrasonic pond carries out ultrasonic 1h-3h, mixes each component more equal
It is even,
(3) solution obtained by ultrasound will be passed through using the nanometer sieve aperture of 20-120 mesh to carrying out filtration treatment, finally will filter
Liquid stands 10-24h in 45-70 DEG C of environment, obtains final product cigarette enhancing colloidal sol.
It is a kind of to strengthen the application that colloidal sol moistens fragrant pearl in cigarette, when using, above-mentioned colloidal sol and tobacco aromaticss are put into pill dripping machine
In, by glue case temperature control at 50-80 DEG C, the temperature can guarantee that the intensity and interfacial tension of the enhancing colloidal sol are maintained and more manage
The state thought.After after pearl shaping, use quality fraction is 0.5% CaCl2Solution is washed, and has both obtained property molten better than tradition
Profit perfume pearl prepared by glue.
Beneficial effects of the present invention：Enhancing colloidal sol prepared by the present invention, can moisten the capsule material material of fragrant pearl as cigarette, use
In the perfume pearl of the profit comprising tobacco aromaticss is prepared, by adding different natural perfume material essence extracts, can be provided not for the fragrant pearl of profit
Same taste.
Enhancing colloidal sol prepared by the present invention, it is too low to greatly improve the fragrant pearl hardness of tradition profit, easily makes moist, and is difficult to crumb
Defect.
Specific embodiment
With reference to specific embodiment, the present invention is described further.
Embodiment 1
40 parts of gelatin and the mixing of 12 parts of sodium alginate is taken, 4 parts of polyethylene glycol, 5 parts of water soluble starch, carboxylic are then added
20 parts of ethyl cellulose, 850 parts of water.Above-mentioned mixed solution is put into 60 DEG C of water-bath, 3h is stirred；After the completion of to be mixed,
Use ultrasonic pond ultrasound 2h；The solution after ultrasonically treated is filtered using the nanometer sieve aperture of 90 mesh, then by filtrate 50
DEG C environment in stand 12h, obtain final product corresponding enhancing colloidal sol.
Embodiment 2
35 parts of gelatin and the mixing of 15 parts of sodium alginate is taken, 3 parts of polyethylene glycol, 6 parts of water soluble starch, carboxylic are then added
25 parts of ethyl cellulose, 1000 parts of water.Above-mentioned mixed solution is put into 62 DEG C of water-bath, 2.5h is stirred；Completion to be mixed
Afterwards, ultrasonic pond ultrasound 1h is used；The solution after ultrasonically treated is filtered using the nanometer sieve aperture of 60 mesh, then filtrate exists
14h is stood in 55 DEG C of environment, corresponding enhancing colloidal sol is obtained final product.
Embodiment 3
45 parts of gelatin, 18 parts of sodium alginates and 5 parts of carragheens are taken, 3 parts of glycerine, 18 parts of methylcellulose and 400 are added
Part water, after stirring 2h in 75 DEG C of water-bath, is then sonicated 3h, stands；Using the nanometer sieve aperture of 70 mesh to resulting solution
Filtered, resulting solution stands 20h at 65 DEG C, you can obtain strengthening colloidal sol.
Embodiment 4
600 parts of 50 parts of agar, 5 parts of silicone oil, 6 parts of glycerine, 25 parts of carboxylic propyl methocel and water are taken, is mixed,
4h is stirred in 80 DEG C of water-bath, 1.5h is then sonicated, stood；Resulting solution was carried out using the nanometer sieve aperture of 50 mesh
Filter, resulting solution stands 15h at 55 DEG C, you can obtain strengthening colloidal sol.
Embodiment 5
45 parts of carragheens and 15 parts of pectin mixing are taken, 5 parts of polyethylene glycol are then added, 7 parts of water soluble starch, carboxyethyl is fine
25 parts of dimension element, be put into above-mentioned mixed solution in 85 DEG C of water-bath by 1000 parts of water, stirs 2h；After the completion of to be mixed, using super
Sound pond ultrasound 3h；The solution after ultrasonically treated is filtered using the nanometer sieve aperture of 100 mesh, then the ring by filtrate at 70 DEG C
18h is stood in border, corresponding colloidal sol is obtained final product.
When using, above-mentioned enhancing colloidal sol and tobacco aromaticss are put into pill dripping machine, by glue case temperature control at 50-80 DEG C,
After after pearl shaping, use quality fraction is 0.5% CaCl2Solution is washed, you can to obtain moistening fragrant pearl.
Using fragrant pearl fragility is moistened obtained in the enhancing colloidal sol in above-described embodiment preferably, hardness is higher, bright according to 2007
Glue Capsules standard and version in 2010《Chinese Pharmacopoeia》Method is measured, raw as a result of the reinforcing agent of cellulose family
The hardness and feel of the fragrant pearl of finished product profit of product are substantially improved, and the profit perfume pearl prepared using different formulations is entered using hardness tester
Row hardness and brittleness are analyzed, and the profit perfume pearl hardness of the formula improves 21.11%, and brittleness reduces 57.89%.
The detailed description of specific embodiments of the present invention is the foregoing is only, the present invention is not limited with this, it is all at this
Any modification, equivalent and improvement for being made in the mentality of designing of invention etc., should be included in protection scope of the present invention it
It is interior.
Claims (4)
1. a kind of enhancing colloidal sol for moistening fragrant pearl for cigarette, it is characterised in that be made up of the raw material of following component and weight portion：
The colloidal sol includes one or more in gelatin, sodium alginate, agar, carragheen and pectin；
The plasticizer includes one or more in polyethylene glycol, silicone oil；
The NMF includes one or more in G ＆ W soluble starch；
The reinforcing agent includes one or more in carboxylic propyl methocel, methylcellulose, carboxyethyl cellulose.
2. the enhancing colloidal sol for moistening fragrant pearl for cigarette according to claim 1, it is characterised in that by following component and weight
The raw material composition of part：Gelatin 30-50 parts, sodium alginate 10-20 parts, polyethylene glycol 3-5 parts, water soluble starch 3-7 parts, carboxyethyl
Cellulose 13-27 parts, water 69-1020 parts.
3. the preparation method of the enhancing colloidal sol for moistening fragrant pearl for cigarette according to claim 1 and 2, it is characterised in that specific
Step is as follows：
(1) it is colloidal sol is soluble in water, it is placed in 60-90 DEG C of water-bath and stirs to dissolving；Add plasticizer, NMF and enhancing
Agent, maintains constant temperature, at the uniform velocity stirs 2h-5h；
(2) step (1) gained mixed solution is put into ultrasonic pond carries out ultrasonic 1h-3h, mixes each component and is more uniformly distributed,
(3) solution obtained by ultrasound will be passed through using the nanometer sieve aperture of 20-120 mesh to carrying out filtration treatment, finally filtrate exists
10-24h is stood in 45-70 DEG C of environment, cigarette enhancing colloidal sol is obtained final product.
4. enhancing colloidal sol according to claim 1 and 2 moistens the application of fragrant pearl in cigarette, it is characterised in that：When using, will be upper
State enhancing colloidal sol and tobacco aromaticss are put into pill dripping machine, by glue case temperature control at 50-80 DEG C, after after pearl shaping, use matter
Amount fraction is 0.5% CaCl2Solution is washed, you can to obtain moistening fragrant pearl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710022651.4A CN106732215A (en) | 2017-01-12 | 2017-01-12 | A kind of enhancing colloidal sol for moistening fragrant pearl for cigarette and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710022651.4A CN106732215A (en) | 2017-01-12 | 2017-01-12 | A kind of enhancing colloidal sol for moistening fragrant pearl for cigarette and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106732215A true CN106732215A (en) | 2017-05-31 |
Family
ID=58948050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710022651.4A Pending CN106732215A (en) | 2017-01-12 | 2017-01-12 | A kind of enhancing colloidal sol for moistening fragrant pearl for cigarette and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106732215A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108402519A (en) * | 2018-03-08 | 2018-08-17 | 湖北中烟工业有限责任公司 | A kind of cigarette quickly defoamed quick-fried pearl and preparation method |
| CN109021307A (en) * | 2018-07-05 | 2018-12-18 | 湖北中烟工业有限责任公司 | A kind of sodium alginate-modified cigarette quick-fried pearl composite membrane and preparation method thereof |
| CN109161211A (en) * | 2018-09-17 | 2019-01-08 | 佛山市森昂生物科技有限公司 | A kind of preparation method of the quick-fried pearl lapping of cigarette |
| CN110835428A (en) * | 2019-12-13 | 2020-02-25 | 宋军 | Bead blasting coating material for cigarettes and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1947709A (en) * | 2005-10-14 | 2007-04-18 | 上海众伟生化有限公司 | Vegetative hard capsule casing material and its prodn. method |
-
2017
- 2017-01-12 CN CN201710022651.4A patent/CN106732215A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1947709A (en) * | 2005-10-14 | 2007-04-18 | 上海众伟生化有限公司 | Vegetative hard capsule casing material and its prodn. method |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108402519A (en) * | 2018-03-08 | 2018-08-17 | 湖北中烟工业有限责任公司 | A kind of cigarette quickly defoamed quick-fried pearl and preparation method |
| CN109021307A (en) * | 2018-07-05 | 2018-12-18 | 湖北中烟工业有限责任公司 | A kind of sodium alginate-modified cigarette quick-fried pearl composite membrane and preparation method thereof |
| CN109161211A (en) * | 2018-09-17 | 2019-01-08 | 佛山市森昂生物科技有限公司 | A kind of preparation method of the quick-fried pearl lapping of cigarette |
| CN109161211B (en) * | 2018-09-17 | 2020-12-22 | 叶思思 | Preparation method of bead blasting packaging material for cigarettes |
| CN110835428A (en) * | 2019-12-13 | 2020-02-25 | 宋军 | Bead blasting coating material for cigarettes and preparation method thereof |
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Application publication date: 20170531 |
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