CN106726783A - A kind of camellia makeup remover and preparation method thereof - Google Patents
A kind of camellia makeup remover and preparation method thereof Download PDFInfo
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- CN106726783A CN106726783A CN201710025960.7A CN201710025960A CN106726783A CN 106726783 A CN106726783 A CN 106726783A CN 201710025960 A CN201710025960 A CN 201710025960A CN 106726783 A CN106726783 A CN 106726783A
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- Prior art keywords
- camellia
- makeup remover
- solution
- preparation
- oil
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B5/00—Preserving by using additives, e.g. anti-oxidants
- C11B5/0021—Preserving by using additives, e.g. anti-oxidants containing oxygen
- C11B5/0035—Phenols; Their halogenated and aminated derivates, their salts, their esters with carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
Abstract
The invention belongs to cosmetic field, a kind of camellia makeup remover and preparation method thereof is disclosed.Methods described is：(1) mixing camellia oil, ethanol and alkali catalyst carries out back flow reaction, and stratification, except sub-cloud solution, obtains upper solution；(2) it is gradual to be warming up to reaction temperature during sucrose and base catalyst to add the upper solution of step (1), and react under reduced pressure, salt water washing is then used, stratification, except sub-cloud solution, obtains upper solution；(3) upper solution of step (2) is vacuum dried, adds antioxidant, obtain final product camellia makeup remover.Camellia of the invention makeup removing oil viscosity is small, good to color make-up dissolving and dispersive property, non-stimulated and be readily cleaned.
Description
Technical field
The invention belongs to cosmetic field, and in particular to a kind of camellia makeup remover and preparation method thereof.
Background technology
Today's society, cosmetic has turned into universal phenomenon.After but face is made up, such as clean out not in time, remain in skin
Cosmetics easily induce epifolliculitis in skin pore, cause the disease of skin such as redness, blackhead, acne, and facial color scar is caused in the course of time
It is calm.
Cosmetics especially color make-up, containing substantial amounts of grease, oiliness film is formed in face, it is difficult to directly removing.Makeup remover
It is then, using the similar principle for mixing, by dissolving grease, and to be emulsified agent dispersion and be easy to remove facial oil.But at present
Makeup remover is generally mineral oil, synthesis grease, and long-term use causes pachylosis, pore increase.Application number 201610329542.2, Shen
Please numbers 201610321948.6 patent application disclose makeup remover based on vegetable oil, but vegetable oil viscosity is larger, oil
Soapy feeling is strong, is unfavorable for facial uniform application and cleans up.
Camellia seed oil contains abundant unrighted acid and vitamins and other nutritious components, has preferably maintenance to make to skin
With.The patent application of application number 201410648953.9 discloses a kind of camellia oil makeup remover, but is directly equally deposited with camellia oil
In the shortcoming of greasy and difficult cleaning.
The content of the invention
In order to overcome the shortcoming and deficiency of prior art, primary and foremost purpose of the invention is to provide a kind of camellia oil makeup remover
Preparation method.The present invention is esterified by the ethyl esterified of camellia oil with sucrose, prepared camellia oil makeup remover non-greasy, it is easy to
Makeup removing and cleaning.
Another object of the present invention is to provide the camellia makeup remover obtained by above-mentioned preparation method.
The purpose of the present invention is achieved through the following technical solutions：
A kind of preparation method of camellia makeup remover, comprises the following steps：
(1) mixing camellia oil, ethanol and alkali catalyst carries out back flow reaction, and stratification, except sub-cloud solution, is obtained
To upper solution；
(2) it is gradual to be warming up to reaction temperature during sucrose and base catalyst to add the upper solution of step (1), and
React under reduced pressure, then use salt water washing, stratification, except sub-cloud solution；
(3) upper solution of step (2) is vacuum dried, adds antioxidant, obtain final product camellia makeup remover.
Camellia oil described in step (1) is the product oil after tea seed squeezes crude oil or refining；
Ethanol described in step (1) is (0.5~2) with the volume ratio of camellia oil：1；The back flow reaction condition is in 70
~90 DEG C of 1~3h of reaction.
Step (1) described alkali catalyst is NaOH, potassium hydroxide or caustic alcohol；The consumption of the alkali catalyst
With amount ratio (1~10) g of camellia oil：1L.
Sucrose described in step (2) is 1kg with the upper solution solid-to-liquid ratio obtained by step (1)：(5~20) L, described is anti-
Temperature is answered for 110~140 DEG C, the heating-up time is 30~90min, the pressure for reacting under reduced pressure is 0.01~
0.1MPa, the 3~8h of time for reacting under reduced pressure.
Step (2) described base catalyst is natrium carbonicum calcinatum or Anhydrous potassium carbonate；The base catalyst consumption and step
Suddenly the amount ratio of (1) gained upper solution is (10~50) g：1L.
Step (2) described salt solution is the sodium-chloride water solution of 10~50g/L, and the consumption of the salt solution is step (1) gained
0.5~3 times of upper solution volume.
Step (3) the vacuum drying temperature is 80~120 DEG C, and pressure is 0.001~0.01MPa, and drying time is 3
~5h.
Antioxidant described in step (3) is butylated hydroxy anisole (BHA), dibutyl hydroxy toluene (BHT), the tert-butyl group
One or more of hydroquinones (TBHQ), propylgallate (PG), vitamin E (VE), described antioxidant and step
(2) gained upper solution amount ratio is (0.5~10) g：1L.
A kind of camellia makeup remover, is prepared by the above method.
The viscosity of the camellia makeup remover is 9~33mPa.s, is the 1/10~1/3 of vegetable oil, color make-up is dissolved and is disperseed
Performance is good, it is easy to clean.
Principle：The present invention makes camellia oil that structure change, the molecule of macromolecular glyceride occur under alkali catalyst effect
Chain dissociates, and is converted into the tea oil fatty-acid ethyl ester of small molecule, then formed in the presence of base catalyst (sodium carbonate, potassium carbonate)
Tea oil sucrose ester with emulsifying capacity, so as to obtain existing preferable remove functional oil, and the makeup removing oil product of non-greasy.
The present invention has the following advantages and effect relative to prior art：
(1) instant invention overcomes directly vegetable oil is used as makeup remover at present the drawbacks of, using structure of modification technology, plant is made
The macromolecule of thing oil is converted into low molecule, improves molecular activity, enhances the affinity interaction power to skin surface grease；
(2) makeup remover of the invention is the multi-functional makeup removers being integrated such as nutrition, anti-inflammatory, cleaning, without emulsifying agent,
And worked using the emulsifiability of itself；
(3) preparation process is simple of the present invention, is easy to industrialized production.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
Embodiment 1
The tea seed for taking 10L squeezes crude oil in retort, adds the ethanol and 50g potassium hydroxide of 10L, and 80 DEG C of backflows are anti-
Answer 2h, stratification to discard lower floor, obtain product 1 (18L)；To 1.8kg sucrose and 900g Anhydrous potassium carbonates is added in product 1, rise
Temperature reacts 5h to 130 DEG C (heating-up time is 60min) under 0.1MPa；The sodium-chloride water solution 18L drip washing of 10g/L is added, it is quiet
Layering is put, product 2 (15L) is obtained；Product 2 is dried into 3h under 100 DEG C, 0.001MPa, and adds 150gVE, stirred, i.e.,
Obtain camellia makeup remover.
Embodiment 2
The tea seed for taking 10L squeezes crude oil in retort, adds the ethanol and 10g caustic alcohols of 15L, 70 DEG C of back flow reactions
1h, stratification discards lower floor, obtains product 1 (20L)；To 4kg sucrose and 1kg natrium carbonicum calcinatums is added in product 1, it is warming up to
110 DEG C (heating-up time is 30min), 8h is reacted under 0.01MPa；The sodium-chloride water solution 10L drip washing of 50g/L is added, is stood
Layering, obtains product 2 (18L)；Product 2 is dried into 5h under 120 DEG C, 0.01MPa, and adds 9gBHT, stirred, obtain final product mountain
Tea makeup remover.
Embodiment 3
The tea seed for taking 10L squeezes crude oil in retort, adds the ethanol and 100g NaOH of 20L, 90 DEG C of backflows
Reaction 3h, stratification discards lower floor, obtains product 1 (24L)；To addition 1.2kg sucrose and 240g Anhydrous potassium carbonates in product 1,
It is warming up under 140 DEG C (heating-up time 90min), 0.05MPa and reacts 3h；The sodium-chloride water solution 72L drip washing of 20g/L is added,
Stratification, obtains product 2 (20L)；Product 2 is dried into 5h under 80 DEG C, 0.005MPa, and adds 20gBHA, stirred, i.e.,
Obtain camellia makeup remover.
Embodiment 4
The commercially available camellia seed oil of 10L is taken in retort, the ethanol and 20g potassium hydroxide of 5L, 80 DEG C of back flow reactions is added
2h, stratification discards lower floor, obtains product 1 (12L)；To 2.4kg sucrose and 240g Anhydrous potassium carbonates is added in product 1, heat up
To 130 DEG C (heating-up time is 70min), 6h is reacted under 0.05MPa；The sodium-chloride water solution 24L drip washing of 30g/L is added, it is quiet
Layering is put, product 2 (10L) is obtained；Product 2 is dried into 3h under 90 DEG C, 0.001MPa, and adds 20gTBHQ, stirred, i.e.,
Obtain camellia makeup remover.
Embodiment 5
The commercially available camellia seed oil of 10L is taken in retort, the ethanol and 80g NaOH of 8L, 90 DEG C of back flow reactions is added
2.5h, stratification discards lower floor, obtains product 1 (15L)；To 1kg sucrose and 750g natrium carbonicum calcinatums is added in product 1, heat up
To 140 DEG C (heating-up time is 90min), 8h is reacted under 0.1MPa；The sodium-chloride water solution 30L drip washing of 30g/L is added, is stood
Layering, obtains product 2 (12L)；Product 2 is dried into 3h under 80 DEG C, 0.001MPa, and adds 60gPG, stirred, obtain final product mountain
Tea makeup remover.
Embodiment 6
The commercially available camellia seed oil of 10L is taken in retort, the ethanol and 15g caustic alcohols of 15L, 70 DEG C of back flow reactions is added
1.5h, stratification discards lower floor, obtains product 1 (22L)；To 1.1kg sucrose and 660g Anhydrous potassium carbonates is added in product 1, rise
Temperature reacts 5h to 110 DEG C (heating-up time is 50min) under 0.1MPa；The sodium-chloride water solution 44L drip washing of 10g/L is added, it is quiet
Layering is put, product 2 (20L) is obtained；Product 2 is dried into 4h under 110 DEG C, 0.005MPa, and adds 160gVE, stirred, i.e.,
Obtain camellia makeup remover.
The performance test of embodiment 7
The measure of the viscosity of camellia makeup remover and makeup removing effect obtained in embodiment 1~6：
Experimental technique：
(1) viscosimetric analysis：Using NDJ-1 rotary viscosimeters, product viscosity is determined according to instrument operation instruction；
(2) makeup removing effect is determined：The people of volunteer 60 is randomly divided into 6 groups, and camellia obtained in embodiment 1~6 is removed ornaments and formal dress respectively
The greasy feeling (≤25 points) of oil, dispersed (≤25 points), (≤25 points) evaluations of washable property (≤25 points) and comfortableness, calculate total
Point.
Experimental result：
The viscosity and makeup removing effect of the camellia makeup remover of the gained of embodiment 1~6 are shown in Table 1.Result shows that the present invention is obtained oil
Viscosity be only the 1/10~1/3 of camellia oil, makeup removing effect is better than commercially available white oil makeup remover, and quality is preferable.
The viscosity of camellia makeup remover obtained in the embodiment 1~6 of table 1 and makeup removing effect score
Above-described embodiment is the present invention preferably implementation method, but embodiments of the present invention are not by above-described embodiment
Limitation, it is other it is any without departing from Spirit Essence of the invention and the change, modification, replacement made under principle, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of preparation method of camellia makeup remover, it is characterised in that comprise the following steps：
(1) mixing camellia oil, ethanol and alkali catalyst carries out back flow reaction, and stratification, except sub-cloud solution, is obtained
Layer solution；
(2) it is gradual to be warming up to reaction temperature during sucrose and base catalyst to add the upper solution of step (1), and subtracting
Pressure reaction, then uses salt water washing, and stratification, except sub-cloud solution, obtains upper solution；
(3) upper solution of step (2) is vacuum dried, adds antioxidant, obtain final product camellia makeup remover.
2. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Reaction temperature described in step (2)
It it is 110~140 DEG C, the heating-up time is 30~90min；The pressure for reacting under reduced pressure is 0.01~0.1MPa,
3~the 8h of time of the lower reaction of decompression.
3. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Sucrose described in step (2) and step
Suddenly the upper solution solid-to-liquid ratio obtained by (1) is 1kg：(5~20) L.
4. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Strong base catalyst described in step (1)
Agent is NaOH, potassium hydroxide or caustic alcohol；Base catalyst described in step (2) is natrium carbonicum calcinatum or Carbon Dioxide
Potassium.
5. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Ethanol and mountain described in step (1)
The volume ratio of tea oil is (0.5~2)：1；The back flow reaction condition is to react 1~3h in 70~90 DEG C.
6. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Strong base catalyst described in step (1)
The consumption of agent and amount ratio (1~10) g of camellia oil：1L；
Base catalyst consumption described in step (2) is (10~50) g with the amount ratio of step (1) gained upper solution：1L；
The consumption of salt solution described in step (2) is 0.5~3 times of step (1) gained upper solution volume；
Antioxidant and step (2) gained upper solution amount ratio described in step (3) are (0.5~10) g：1L.
7. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Camellia oil is described in step (1)
Tea seed squeezes the product oil after crude oil or refining；
Salt solution described in step (2) is the sodium-chloride water solution of 10~50g/L；Antioxidant described in step (3) is butyl
One or more of BHA, dibutyl hydroxy toluene, TBHQ, propylgallate, vitamin E.
8. the preparation method of camellia makeup remover according to claim 1, it is characterised in that：Step (3) is described vacuum drying
Temperature is 80~120 DEG C, and pressure is 0.001~0.01MPa, and drying time is 3~5h.
9. a kind of camellia makeup remover obtained according to claim 1~8 any one methods described.
10. camellia makeup remover according to claim 9, it is characterised in that：The viscosity of the camellia makeup remover be 9~
33mPa.s。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710025960.7A CN106726783B (en) | 2017-01-13 | 2017-01-13 | Camellia cleansing oil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710025960.7A CN106726783B (en) | 2017-01-13 | 2017-01-13 | Camellia cleansing oil and preparation method thereof |
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| CN106726783B CN106726783B (en) | 2020-05-22 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107184483A (en) * | 2017-06-29 | 2017-09-22 | 湖南大三湘油茶生态产业有限公司 | High penetration camellia massage essential oil promoting blood circulation and removing obstruction in channels and preparation method thereof |
| CN107550771A (en) * | 2017-06-29 | 2018-01-09 | 湖南大三湘油茶生态产业有限公司 | Salubrious camellia makeup remover of quality and preparation method thereof |
| CN110484353A (en) * | 2019-08-23 | 2019-11-22 | 福建师范大学 | A kind of preparation method of water solubility camellia oil |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107184483A (en) * | 2017-06-29 | 2017-09-22 | 湖南大三湘油茶生态产业有限公司 | High penetration camellia massage essential oil promoting blood circulation and removing obstruction in channels and preparation method thereof |
| CN107550771A (en) * | 2017-06-29 | 2018-01-09 | 湖南大三湘油茶生态产业有限公司 | Salubrious camellia makeup remover of quality and preparation method thereof |
| CN110484353A (en) * | 2019-08-23 | 2019-11-22 | 福建师范大学 | A kind of preparation method of water solubility camellia oil |
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