CN106723532A - A kind of emgloves - Google Patents

A kind of emgloves Download PDF

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Publication number
CN106723532A
CN106723532A CN201611012253.6A CN201611012253A CN106723532A CN 106723532 A CN106723532 A CN 106723532A CN 201611012253 A CN201611012253 A CN 201611012253A CN 106723532 A CN106723532 A CN 106723532A
Authority
CN
China
Prior art keywords
palm
layer
surface layer
emgloves
hand surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611012253.6A
Other languages
Chinese (zh)
Inventor
缪建良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Changan Shuguang Glove Factory
Original Assignee
Wuxi Changan Shuguang Glove Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Changan Shuguang Glove Factory filed Critical Wuxi Changan Shuguang Glove Factory
Priority to CN201611012253.6A priority Critical patent/CN106723532A/en
Publication of CN106723532A publication Critical patent/CN106723532A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/0055Plastic or rubber gloves
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/30Antimicrobial, e.g. antibacterial
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Gloves (AREA)

Abstract

The invention discloses a kind of emgloves, including outer layer and internal layer, outer layer includes:Palm body and arm part, palm body are provided with thread gluing projection by palm of the hand surface layer and the back of the hand surface layer split, palm of the hand surface layer or the back of the hand surface layer;The internal layer is to be made up of the latex of the oxidation shitosan of 0.2 2wt%, the silk gum of 0.5 3wt%, the organosilicon polymer of 0 2wt%, the yittrium oxide of 0.2 1wt% and surplus.Emgloves of the invention, make NRL films reduce the aspect such as water-solubility protein spillings, ageing-resistant performance, reduction film surface viscosity and antibiotic property be improved significantly.

Description

A kind of emgloves
Technical field
The present invention relates to labour protection technical field, more particularly to a kind of emgloves.
Background technology
Gloves are widely used as the instrument of protection hand, and emgloves is due to excellent with waterproof, antifouling, heat-resisting etc. Point and by large-scale production and application.Emgloves elasticity is good, and can degrade, but emgloves of the prior art is One layer of rubber, cold winter when in use can be very inconvenient, and palmar hand and arm part are inseparable, and emgloves top Simply a simple elastic band, is easy to break after long-time use, inconvenient using a dishcloth when bowl is usually cleaned, The different types of thing of cleaning can not be applicable, there is a problem of having gloves on unstable when taking thing.
Natural emulsion is a kind of through biosynthesis, reproducible natural resources, extensively should because of excellent combination property For in the products such as medical catheter, medical gloves and sheath.But natural emulsion makes its oil resistant because containing unsaturated double-bond Property, resistance to ag(e)ing are poor, and micro- virgin water-solubility protein therein causes human allergy to react.Nonrubber materials in latex are in latex To latex film surface migration cause film surfaces stick in film forming procedure and easily gone bad by microorganism infection, thus limit as latex The application of material.
The content of the invention
It is an object of the invention to propose a kind of emgloves, make NRL films reduce water-solubility protein overflow, it is resistance to Ageing properties, reduce the aspect such as film surface viscosity and antibiotic property be improved significantly.
It is that, up to this purpose, the present invention uses following technical scheme:
A kind of emgloves, including outer layer and internal layer, outer layer include:Palm body and arm part, palm body is by the palm of the hand It is raised that surface layer and the back of the hand surface layer split, palm of the hand surface layer or the back of the hand surface layer are provided with thread gluing;The internal layer is by the oxygen of 0.2-2wt% Change the latex of shitosan, the silk gum of 0.5-3wt%, the organosilicon polymer of 0-2wt%, the yittrium oxide of 0.2-1wt% and surplus Composition.
Shitosan has the effect such as protein that catches, but insoluble in latex alkaline system, the present invention is filled using oxidation first Glycan, is applied to the modified of natural emulsion, and oxidation shitosan catches the protein in latex and the reaction that interacts occurs, Change the water solubility of protein and be locked in the glued membrane of solidification, reduce the spilling of aqueous soluble protein matter.The oxidation shell of addition 1.0% The water-solubility protein spill-out of the modified latex film of glycan can be reduced to 45.71 μ g/g.
There is silk gum many rubber such as antibacterial, anti-inflammatory, anti-oxidant, corrosion-resistant to need but the property that does not possess, by its with The oxidation common modified natural emulsion of shitosan, makes the protein binding in silk gum and oxidation chitosan composite and rubber, wherein changing Learning the effect such as crosslinking, hydrogen bond crosslinks makes protein structure that the change in different levels to occur, and causes allergen protein to be modified, and and glue Albumen in grain protective layer carries out, from combination, constituting soft condensed state structure, in the presence of rubber solidification, migrates and determines in rubber In the crack and space of glue microfacies, improve rubber membrane compactness barrier and it is reinforcing while, made glued membrane is resistance to molten The aspects such as agent, ageing-resistant, antibiotic property and reduction water-solubility protein spill-out are improved in varying degrees.
The organosilicon polymer that the present invention is used, has the advantages that good physiological inertia, anticoagulation and antithrombus formation, And surface can be low, can be enriched with product surface, anaphylactogen is isolated with human body skin, antianaphylactic effect is produced.Above-mentioned Organosilicon polymer is further introduced on the basis of modified technique, made latex film is increasing resistance to ag(e)ing, solvent resistance, reducing Film skin-friction coefficient and viscosity have improvement.
Emgloves of the invention makes NRL films reduce water-solubility protein spilling, ageing-resistant performance, reduce film table The aspect such as face viscosity and antibiotic property be improved significantly.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of emgloves, including outer layer and internal layer, outer layer include:Palm body and arm part, palm body is by the palm of the hand It is raised that surface layer and the back of the hand surface layer split, palm of the hand surface layer or the back of the hand surface layer are provided with thread gluing;The internal layer is by the oxidation of 0.2wt% The latex composition of shitosan, the silk gum of 0.5wt%, the yittrium oxide of 0.2wt% and surplus.
Embodiment 2
A kind of emgloves, including outer layer and internal layer, outer layer include:Palm body and arm part, palm body is by the palm of the hand It is raised that surface layer and the back of the hand surface layer split, palm of the hand surface layer or the back of the hand surface layer are provided with thread gluing;The internal layer is by the oxidation shell of 2wt% The latex composition of glycan, the silk gum of 3wt%, the organosilicon polymer of 2wt%, the yittrium oxide of 1wt% and surplus.
Embodiment 3
A kind of emgloves, including outer layer and internal layer, outer layer include:Palm body and arm part, palm body is by the palm of the hand It is raised that surface layer and the back of the hand surface layer split, palm of the hand surface layer or the back of the hand surface layer are provided with thread gluing;The internal layer is by the oxidation shell of 1wt% The latex composition of glycan, the silk gum of 2wt%, the organosilicon polymer of 1wt%, the yittrium oxide of 0.5wt% and surplus.

Claims (1)

1. a kind of emgloves, including outer layer and internal layer, outer layer include:Palm body and arm part, palm body is by palm of the hand face It is raised that layer and the back of the hand surface layer split, palm of the hand surface layer or the back of the hand surface layer are provided with thread gluing;The internal layer is by the oxidation of 0.2-2wt% The latex group of shitosan, the silk gum of 0.5-3wt%, the organosilicon polymer of 0-2wt%, the yittrium oxide of 0.2-1wt% and surplus Into.
CN201611012253.6A 2016-11-17 2016-11-17 A kind of emgloves Pending CN106723532A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611012253.6A CN106723532A (en) 2016-11-17 2016-11-17 A kind of emgloves

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611012253.6A CN106723532A (en) 2016-11-17 2016-11-17 A kind of emgloves

Publications (1)

Publication Number Publication Date
CN106723532A true CN106723532A (en) 2017-05-31

Family

ID=58968445

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611012253.6A Pending CN106723532A (en) 2016-11-17 2016-11-17 A kind of emgloves

Country Status (1)

Country Link
CN (1) CN106723532A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101704964A (en) * 2009-10-28 2010-05-12 田晓慧 Medical security level rubber product with sericin modified surface and preparation method thereof
CN101717530A (en) * 2009-11-09 2010-06-02 田晓慧 Natural rubber liquid slurry containing chitosan/sericin and preparation method thereof
CN103044725A (en) * 2013-01-10 2013-04-17 田晓慧 Nano silicasol modified natural rubber slurry and preparation method thereof
CN203602821U (en) * 2013-08-08 2014-05-21 张荣祝 Camouflage glove weaved by knitting threads
CN205378880U (en) * 2016-01-26 2016-07-13 安徽师范大学 Latex gloves

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101704964A (en) * 2009-10-28 2010-05-12 田晓慧 Medical security level rubber product with sericin modified surface and preparation method thereof
CN101717530A (en) * 2009-11-09 2010-06-02 田晓慧 Natural rubber liquid slurry containing chitosan/sericin and preparation method thereof
CN103044725A (en) * 2013-01-10 2013-04-17 田晓慧 Nano silicasol modified natural rubber slurry and preparation method thereof
CN203602821U (en) * 2013-08-08 2014-05-21 张荣祝 Camouflage glove weaved by knitting threads
CN205378880U (en) * 2016-01-26 2016-07-13 安徽师范大学 Latex gloves

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170531

WD01 Invention patent application deemed withdrawn after publication