CN103965554B - Butyl blending emulsion chemical defence glove and preparation method thereof - Google Patents
Butyl blending emulsion chemical defence glove and preparation method thereof Download PDFInfo
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- CN103965554B CN103965554B CN201410194274.9A CN201410194274A CN103965554B CN 103965554 B CN103965554 B CN 103965554B CN 201410194274 A CN201410194274 A CN 201410194274A CN 103965554 B CN103965554 B CN 103965554B
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- glove
- polymer blended
- butyl
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Gloves (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Abstract
The present invention relates to a kind of butyl blending emulsion chemical defence glove and preparation method thereof, including the outer rubber shoe latex layer of glove liner and blending emulsion material, the outer rubber shoe latex layer of polymeric industry is composed of the following components: polymer blended alloy material main body, vulcanizing agent, accelerator and vulcanizing activator, mass parts ratio is: polymer blended alloy material main body: vulcanizing agent: accelerator: vulcanizing activator=100:0.5-5:0-2:1-3；Polymer blended alloy material main body includes butyl rubber and other macromolecular material of 0%-40% of 60%-100%；Other macromolecular material is PVC, PE, phenolic aldehyde or nitrile rubber.The invention solves the disadvantage of cohesive force and tear resistance, there is chemically corrosion, solvent resistant, oil resistant, have good resistance to water and electric insulating quality, there is again wear-resistant anti-cutting, the various excellent properties such as being folded without breaking, preparation process mechanization linkage, line production complete；Produce feasible, technically reliable, cost reasonable, be suitable for industrial-scale production.
Description
Technical field
The present invention relates to a kind of butyl blending emulsion chemical defence glove and preparation method thereof, be with butyl rubber for main body high polymer intermingling material glove and preparation method thereof, be a kind of can be used for the fields such as labor protection to the corrosion resistant protective gloves of chemical mediator.
Background technology
Day by day flourishing along with industry, corrosion-resistant, oil resistant, solvent-proof macromolecular material glove demand are also increasing.Existing macromolecular material glove no matter airtight performance, or the performance of tolerance corrosive medium corrosion is not ideal, and its barrier propterty needs to be improved further, it is impossible to meet the labor protection needs of special dimension.Based on this, it is proposed to the present invention.
Summary of the invention
Above-mentioned technical problem for prior art; it is an object of the invention to provide a kind of butyl blending emulsion chemical defence glove and preparation method thereof; with butyl rubber for main body high polymer intermingling material glove and preparation method thereof, be a kind of can be used for the fields such as labor protection to the corrosion resistant protective gloves of chemical mediator.
For reaching above-mentioned purpose, the present invention is achieved by the following technical solutions:
Butyl blending emulsion chemical defence glove, including glove liner and outer rubber shoe latex layer, described glove liner is the glove liner of the fiber seamless knitted such as nylon, terylene, cotton or artificial silk, described outer rubber shoe latex layer is the outer rubber shoe latex layer of polymeric industry, and the outer rubber shoe latex layer of described polymeric industry is composed of the following components: polymer blended alloy material main body, vulcanizing agent, accelerator and vulcanizing activator；The mass parts ratio of described polymer blended alloy material main body, vulcanizing agent, accelerator and vulcanizing activator is: polymer blended alloy material main body: vulcanizing agent: accelerator: vulcanizing activator=100:0.5-5:0-2:1-3；Described polymer blended alloy material main body includes butyl rubber and other macromolecular material of 0%-40% of 60%-100%；Other described macromolecular material is PVC, PE, phenolic aldehyde or nitrile rubber.
Described vulcanizing agent is sulfur, peroxide or metal-oxide.
Described accelerator is (DDC)2Zn class.
Described vulcanizing activator is zinc oxide and/or stearic acid.
The preparation method of butyl blending emulsion chemical defence glove, comprises the following steps:
(1) polymer blended alloy material main body is prepared: the butyl rubber of 60%-100% and other macromolecular material of 0%-40% are carried out interface adjustment, blended, maturation balance more than 24 hours；Other described macromolecular material is PVC, PE, phenolic aldehyde or nitrile rubber；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, the polymer blended alloy material main body 100 parts prepared in described step (1), add vulcanizing agent 0.5-5 part, accelerator 0-2 part and vulcanizing activator 1-3 part, stir, maturation more than 24 hours；Described vulcanizing agent is sulfur, peroxide or metal-oxide；Described accelerator is (DDC)2Zn class；Described vulcanizing activator is zinc oxide or stearic acid；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 100-130 DEG C, dry 60-120min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare the polymer blended chemical defence glove of butyl.
Beneficial effects of the present invention is as follows:
Butyl blending emulsion chemical defence glove of the present invention and preparation method thereof, with butyl rubber for main body high polymer intermingling material glove and preparation method thereof, be a kind of can be used for the fields such as labor protection to the corrosion resistant protective gloves of chemical mediator, solve the undesirable disadvantages such as conventional cohesive force and tear resistance, maintain again butyl rubber air impermeability, the advantage that isolation corrosive medium immerses and tolerance medium is denuded, there is chemically corrosion, solvent resistant, oil resistant, there are good resistance to water and electric insulating quality, there is again wear-resistant anti-cutting, the various excellent properties such as being folded without breaking.The butyl blending emulsion chemical defence glove of the present invention, including various fiber seamless knitted linings, one layer of blending emulsion material based on butyl is impregnated in liner surface, this macromolecular material contains butyl rubber and other rubber and plastic macromolecular material, also have vulcanizing agent, accelerator and other compounding ingredients, drying form through cooperation, boundary adjustment, emulsion blending, balance, maturation reequilibrate, dipping, sulfuration, preparation process mechanization linkage, line production complete；Produce feasible, technically reliable, cost reasonable, be suitable for industrial-scale production.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to this.
The preparation method of the butyl blending emulsion chemical defence glove in the present invention, the coagulator used in step (3) is coagulator commonly used in the art；Coagulator in the present invention and other chemical substance all can adopt technique well known in the art to synthesize, or adopt commercially available prod.
Embodiment 1
The preparation method of butyl blending emulsion chemical defence glove of the present invention, comprises the following steps:
(1) blending emulsion colloid is prepared: butyl rubber and the PVC of 10% by 90% carry out interface adjustment, blended, maturation balance more than 24 hours；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, 100 parts of the blending emulsion colloid prepared in step (1), add 5 parts of sulfur, (DDC)2Zn class 2 parts and zinc oxide 3 parts, stir, maturation more than 24 hours；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 130 DEG C, dry 120min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare butyl blending emulsion chemical defence glove.
Embodiment 2
The preparation method of butyl blending emulsion chemical defence glove of the present invention, comprises the following steps:
(1) blending emulsion colloid is prepared: butyl rubber and the PE of 40% by 60% carry out interface adjustment, blended, maturation balance more than 24 hours；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, 100 parts of the blending emulsion colloid prepared in step (1), add metal-oxide 0.5 part, (DDC)2Zn class 1 part and stearic acid 1 part, stir, maturation more than 24 hours；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 100 DEG C, dry 60min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare butyl blending emulsion chemical defence glove.
Embodiment 3
The preparation method of butyl blending emulsion chemical defence glove of the present invention, comprises the following steps:
(1) blending emulsion colloid is prepared: butyl rubber and the phenolic aldehyde of 25% by 75% carry out interface adjustment, blended, maturation balance more than 24 hours；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, 100 parts of the blending emulsion colloid prepared in step (1), add peroxidase 12 .75 part and stearic acid 2 parts, stir, maturation 24 hours；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 115 DEG C, dry 90min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare butyl blending emulsion chemical defence glove.
Embodiment 4
The preparation method of butyl blending emulsion chemical defence glove of the present invention, comprises the following steps:
(1) blending emulsion colloid is prepared: butyl rubber and 20%PE by 80% carry out interface adjustment, blended, maturation balance more than 24 hours；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, 100 parts of the blending emulsion colloid prepared in step (1), add 4 parts of sulfur, (DDC)2Zn class 1.5 parts and zinc oxide and stearic acid 1.6 parts, stir, maturation more than 24 hours；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 125 DEG C, dry 110min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare butyl blending emulsion chemical defence glove.
Embodiment 5
The preparation method of butyl blending emulsion chemical defence glove of the present invention, comprises the following steps:
(1) blending emulsion colloid is prepared: butyl rubber and 5% nitrile rubber by 95% carry out interface adjustment, blended, maturation balance more than 24 hours；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, 100 parts of the blending emulsion colloid prepared in step (1), add 4 parts of sulfur, (DDC)2Zn class 1.5 parts and zinc oxide and stearic acid 1.6 parts, stir, maturation more than 24 hours；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 125 DEG C, dry 110min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare butyl blending emulsion chemical defence glove.
The present invention be a kind of can be used for the fields such as labor protection to the corrosion resistant protective gloves of chemical mediator; solve conventional cohesive force and the undesirable disadvantage of tear resistance; the advantage maintaining again butyl rubber air impermeability, isolation corrosive medium immersion and tolerance dielectric corrosion; there is chemically corrosion; solvent resistant, oil resistant, there are good resistance to water and electric insulating quality; there is again wear-resistant anti-cutting, the various excellent properties such as being folded without breaking.The butyl blending emulsion chemical defence glove of the present invention, including various fiber seamless knitted linings, one layer of blending emulsion material based on butyl is impregnated in liner surface, this macromolecular material contains butyl rubber and other rubber and plastic macromolecular material, also have vulcanizing agent, accelerator and other compounding ingredients, drying form through cooperation, boundary adjustment, emulsion blending, balance, maturation reequilibrate, dipping, sulfuration, preparation process mechanization linkage, line production complete；Produce feasible, technically reliable, cost reasonable, be suitable for industrial-scale production.
Above-described embodiment is only for illustrating the inventive concept of the present invention, but not the restriction to rights protection of the present invention, all changes utilizing this design that the present invention carries out unsubstantiality, protection scope of the present invention all should be fallen into.
Claims (2)
1. the preparation method of butyl blending emulsion chemical defence glove, it is characterised in that comprise the following steps:
(1) polymer blended alloy material main body is prepared: the butyl rubber of 60%-100% and other macromolecular material of 0%-40% are carried out interface adjustment, blended, maturation balance more than 24 hours；Other described macromolecular material is PVC, PE, phenolic aldehyde or nitrile rubber；
(2) polymer blended outer layer glue-line emulsion is configured: by mass parts, the polymer blended alloy material main body 100 parts prepared in described step (1), add vulcanizing agent 0.5-5 part, accelerator 0-2 part and vulcanizing activator 1-3 part, stir, maturation more than 24 hours；Described vulcanizing agent is sulfur, peroxide or metal-oxide；Described accelerator is (DDC)2Zn；Described vulcanizing activator is zinc oxide or stearic acid；
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in coagulator, it is then immersed in the polymer blended outer layer glue-line emulsion configured in step (2), after vulcanizing at 100-130 DEG C, dry 60-120min prepares finished product, then carry out finished product to dry, after parching at 80 DEG C, prepare the polymer blended chemical defence glove of butyl.
2. the preparation method of butyl blending emulsion chemical defence glove as claimed in claim 1, it is characterized in that: obtained glove include glove liner and outer rubber shoe latex layer, described glove liner is the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted, described outer rubber shoe latex layer is the outer rubber shoe latex layer of polymeric industry, and the outer rubber shoe latex layer of described polymeric industry is composed of the following components: polymer blended alloy material main body, vulcanizing agent, accelerator and vulcanizing activator；The mass parts ratio of described polymer blended alloy material main body, vulcanizing agent, accelerator and vulcanizing activator is: polymer blended alloy material main body: vulcanizing agent: accelerator: vulcanizing activator=100:0.5-5:0-2:1-3；Described polymer blended alloy material main body includes butyl rubber and other macromolecular material of 0%-40% of 60%-100%；Other described macromolecular material is PVC, PE, phenolic aldehyde or nitrile rubber.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410194274.9A CN103965554B (en) | 2014-05-09 | 2014-05-09 | Butyl blending emulsion chemical defence glove and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410194274.9A CN103965554B (en) | 2014-05-09 | 2014-05-09 | Butyl blending emulsion chemical defence glove and preparation method thereof |
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| CN103965554A CN103965554A (en) | 2014-08-06 |
| CN103965554B true CN103965554B (en) | 2016-07-06 |
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| CN104480720B (en) * | 2014-12-12 | 2016-10-05 | 天津大学 | A kind of method of the rubber surface coating modification of plane knitting carbon fiber |
| CN105442312A (en) * | 2015-12-01 | 2016-03-30 | 南通强生安全防护科技有限公司 | Antibacterial cloth as well as preparation method and application thereof |
| CN108676262B (en) * | 2018-04-25 | 2021-05-07 | 国家电网公司 | Insulating rubber composite material and preparation method thereof, insulating rubber gloves and preparation method thereof |
| CN109247639A (en) * | 2018-09-23 | 2019-01-22 | 南通嘉得利安全用品有限公司 | Wear-resistant protective gloves |
| CN110801065B (en) * | 2019-10-18 | 2021-08-31 | 广州双一乳胶制品有限公司 | Composite chemical corrosion resistant airtight protective gloves and preparation process thereof |
| CN111763392B (en) * | 2020-07-21 | 2022-03-22 | 江西中红普林医疗制品有限公司 | Disposable nitrile rubber modified PVC (polyvinyl chloride) glove and preparation method thereof |
| CN112048917B (en) * | 2020-09-03 | 2023-06-13 | 山东星宇手套有限公司 | Preparation method of lined double-layer butyl chemical-resistant glove |
| CN116480292B (en) * | 2023-04-04 | 2024-03-15 | 青岛青橡橡胶有限公司 | Acidizing fracturing hose and preparation method thereof |
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| CN1811234A (en) * | 2006-03-02 | 2006-08-02 | 南京大学 | Long-acting preserving and sealing protection method |
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