CN103965554A - Butyl blending emulsion chemical protective glove and preparation method thereof - Google Patents
Butyl blending emulsion chemical protective glove and preparation method thereof Download PDFInfo
- Publication number
- CN103965554A CN103965554A CN201410194274.9A CN201410194274A CN103965554A CN 103965554 A CN103965554 A CN 103965554A CN 201410194274 A CN201410194274 A CN 201410194274A CN 103965554 A CN103965554 A CN 103965554A
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- butyl
- polymer blended
- blending
- blending emulsion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Gloves (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Abstract
The invention discloses a butyl blending emulsion chemical protective glove and a preparation method thereof. The butyl blending emulsion chemical protective glove comprises a glove liner and a macromolecule blending emulsion material outer gumming layer, wherein the macromolecule blending emulsion material outer gumming layer comprises the components of a macromolecule blending alloy material main body, a vulcanizer, a promoter and a vulcanization activator according to the mass ratio of 100 to 0.5-5 to 0-2 to 1-3; the macromolecule blending alloy material main body comprises 60 to 100 percent of butyl rubber and 0 to 40 percent of other high polymer materials; the high polymer materials are PVC, PE, phenolic aldehyde or nitrile rubber. The butyl blending emulsion chemical protective glove overcomes defects in binding power and tear resistance, has excellent performances of chemical corrosion prevention, solvent resistance and oil resistance, has an excellent water resisting property and an electrical insulating property, and also has wear resisting, cut preventing and puncture resisting properties and the like; the preparation process is accomplished through mechanized linkage and flow production; the production is feasible, the technology is reasonable, the cost is reasonable, and the butyl blending emulsion chemical protective glove and the preparation method are applicable to industrialized scale production.
Description
Technical field
The present invention relates to a kind of butyl blending emulsion chemical defence gloves and preparation method thereof, is taking isoprene-isobutylene rubber as main body superpolymer intermingling material gloves and preparation method thereof, be a kind of can be used for the fields such as labour protection to the corrosion resistant protective gloves of chemical mediator.
Background technology
Along with day by day flourishing, corrosion-resistant, the oil resistant of industry, solvent-proof macromolecular material gloves demand are also increasing.No matter airtight performance of existing macromolecular material gloves, the performance that still tolerates corrosive medium corrosion is not ideal, its barrier propterty needs further to be improved, and cannot meet the labor protection needs of special dimension.Based on this, the present invention is proposed.
Summary of the invention
For the above-mentioned technical problem of prior art; the object of this invention is to provide a kind of butyl blending emulsion chemical defence gloves and preparation method thereof; taking isoprene-isobutylene rubber as main body superpolymer intermingling material gloves and preparation method thereof, be a kind of can be used for the fields such as labour protection to the corrosion resistant protective gloves of chemical mediator.
For achieving the above object, the present invention is achieved by the following technical solutions:
Butyl blending emulsion chemical defence gloves, comprise glove liner and outer rubber shoe latex layer, described glove liner is the glove liner of the fiber seamless knitted such as nylon, terylene, cotton or artificial silk, described outer rubber shoe latex layer is the outer rubber shoe latex layer of polymer blended material, and the outer rubber shoe latex layer of described polymer blended material is composed of the following components: polymer blended alloy material main body, vulcanizing agent, promotor and vulcanization activator; The mass parts ratio of described polymer blended alloy material main body, vulcanizing agent, promotor and vulcanization activator is: polymer blended alloy material main body: vulcanizing agent: promotor: vulcanization activator=100:0. 5-5:0-2:1-3; Described polymer blended alloy material main body comprises isoprene-isobutylene rubber and other macromolecular material of 0%-40% of 60%-100%; Other described macromolecular material is PVC, PE, phenolic aldehyde or paracril.
Described vulcanizing agent is sulphur, superoxide or metal oxide.
Described promotor is zinc diethyldithiocarbamate class.
Described vulcanization activator is zinc oxide and/or stearic acid.
The preparation method of butyl blending emulsion chemical defence gloves, comprises the following steps:
(1) prepare polymer blended alloy material main body: the isoprene-isobutylene rubber of 60%-100% and other macromolecular material of 0%-40% are carried out to interface adjusting, blend, maturation balance more than 24 hours; Other described macromolecular material is PVC, PE, phenolic aldehyde or paracril;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts of the polymer blended alloy material main bodys making in described step (1), add vulcanizing agent 0.5-5 part, promotor 0-2 part and vulcanization activator 1-3 part, stir, maturation is more than 24 hours; Described vulcanizing agent is sulphur, superoxide or metal oxide; Described promotor is zinc diethyldithiocarbamate class; Described vulcanization activator is zinc oxide or stearic acid;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 100-130 DEG C of sulfuration, dry 60-120min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make the polymer blended chemical defence gloves of butyl.
Beneficial effect of the present invention is as follows:
Butyl blending emulsion chemical defence gloves of the present invention and preparation method thereof, taking isoprene-isobutylene rubber as main body superpolymer intermingling material gloves and preparation method thereof, be a kind of can be used for the fields such as labour protection to the corrosion resistant protective gloves of chemical mediator, solve the undesirable disadvantage of cohesive force and tear resistance etc. in the past, keep again isoprene-isobutylene rubber gas tightness, the advantage that isolated corrosive medium immerses and tolerance medium is denuded, there is anti-chemical product corrosion, resistance to solvent, oil resistant, there are good water tolerance and electric insulating quality, there is again wear-resistant anti-cutting, resistance toly the various excellent properties such as pierce through.Butyl blending emulsion chemical defence gloves of the present invention, comprise various fiber seamless knitted linings, blending emulsion material at liner surface dipping one deck taking butyl as main body, this macromolecular material contains isoprene-isobutylene rubber and other rubber and plastic macromolecular material, also have vulcanizing agent, promotor and other plural components, be dried and form through cooperation, phase interface adjusting, emulsion blending, balance, maturation reequilibrate, dipping, sulfuration, preparation process mechanize interlock, streamline operration complete; Produce feasible, technology is reliable, cost is reasonable, is suitable for commercial scale production.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited to this.
The preparation method of the butyl blending emulsion chemical defence gloves in the present invention, the peptizer using in step (3) is the conventional peptizer in this area; Peptizer in the present invention and other chemical substance all can adopt technique well known in the art synthetic, or adopt commercially available prod.
embodiment 1
The preparation method of butyl blending emulsion chemical defence gloves of the present invention, comprises the following steps:
(1) prepare blending emulsion colloid: the PVC of 90% isoprene-isobutylene rubber and 10% is carried out to interface adjusting, blend, maturation balance more than 24 hours;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts, the blending emulsion colloid making in step (1), adds 3 parts, 5 parts, sulphur, 2 parts of zinc diethyldithiocarbamate classes and zinc oxide, stirs, and maturation is more than 24 hours;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 130 DEG C of sulfurations, dry 120min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make butyl blending emulsion chemical defence gloves.
embodiment 2
The preparation method of butyl blending emulsion chemical defence gloves of the present invention, comprises the following steps:
(1) prepare blending emulsion colloid: the PE of 60% isoprene-isobutylene rubber and 40% is carried out to interface adjusting, blend, maturation balance more than 24 hours;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts, the blending emulsion colloid making in step (1), add 1 part of 0.5 part of metal oxide, 1 part of zinc diethyldithiocarbamate class and stearic acid, stir, maturation is more than 24 hours;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 100 DEG C of sulfurations, dry 60min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make butyl blending emulsion chemical defence gloves.
embodiment 3
The preparation method of butyl blending emulsion chemical defence gloves of the present invention, comprises the following steps:
(1) prepare blending emulsion colloid: the phenolic aldehyde of 75% isoprene-isobutylene rubber and 25% is carried out to interface adjusting, blend, maturation balance more than 24 hours;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts, the blending emulsion colloid making in step (1), adds 2 parts of peroxidase 12 .75 part and stearic acid, stir, maturation 24 hours;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 115 DEG C of sulfurations, dry 90min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make butyl blending emulsion chemical defence gloves.
embodiment 4
The preparation method of butyl blending emulsion chemical defence gloves of the present invention, comprises the following steps:
(1) prepare blending emulsion colloid: 80% isoprene-isobutylene rubber and 20%PE are carried out to interface adjusting, blend, maturation balance more than 24 hours;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts, the blending emulsion colloid making in step (1), add 1.6 parts of 4 parts, sulphur, 1.5 parts of zinc diethyldithiocarbamate classes and zinc oxide and stearic acid, stir, maturation is more than 24 hours;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 125 DEG C of sulfurations, dry 110min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make butyl blending emulsion chemical defence gloves.
embodiment 5
The preparation method of butyl blending emulsion chemical defence gloves of the present invention, comprises the following steps:
(1) prepare blending emulsion colloid: 95% isoprene-isobutylene rubber and 5% paracril are carried out to interface adjusting, blend, maturation balance more than 24 hours;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts, the blending emulsion colloid making in step (1), add 1.6 parts of 4 parts, sulphur, 1.5 parts of zinc diethyldithiocarbamate classes and zinc oxide and stearic acid, stir, maturation is more than 24 hours;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 125 DEG C of sulfurations, dry 110min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make butyl blending emulsion chemical defence gloves.
The present invention be a kind of can be used for the fields such as labour protection to the corrosion resistant protective gloves of chemical mediator; solve cohesive force and the undesirable disadvantage of tear resistance in the past; keep again isoprene-isobutylene rubber gas tightness, isolated corrosive medium to immerse and tolerated the advantage of dielectric corrosion; there is anti-chemical product corrosion; resistance to solvent, oil resistant, there are good water tolerance and electric insulating quality; there is again wear-resistant anti-cutting, resistance toly the various excellent properties such as pierce through.Butyl blending emulsion chemical defence gloves of the present invention, comprise various fiber seamless knitted linings, blending emulsion material at liner surface dipping one deck taking butyl as main body, this macromolecular material contains isoprene-isobutylene rubber and other rubber and plastic macromolecular material, also have vulcanizing agent, promotor and other plural components, be dried and form through cooperation, phase interface adjusting, emulsion blending, balance, maturation reequilibrate, dipping, sulfuration, preparation process mechanize interlock, streamline operration complete; Produce feasible, technology is reliable, cost is reasonable, is suitable for commercial scale production.
Above-described embodiment is only for the inventive concept of the present invention of explaining, but not restriction to rights protection of the present invention, allly utilizes this design to carry out the change of unsubstantiality to the present invention, all should fall into protection scope of the present invention.
Claims (5)
1. butyl blending emulsion chemical defence gloves, it is characterized in that: comprise glove liner and outer rubber shoe latex layer, described glove liner is the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted, described outer rubber shoe latex layer is the outer rubber shoe latex layer of polymer blended material, and the outer rubber shoe latex layer of described polymer blended material is composed of the following components: polymer blended alloy material main body, vulcanizing agent, promotor and vulcanization activator; The mass parts ratio of described polymer blended alloy material main body, vulcanizing agent, promotor and vulcanization activator is: polymer blended alloy material main body: vulcanizing agent: promotor: vulcanization activator=100:0. 5-5:0-2:1-3; Described polymer blended alloy material main body comprises isoprene-isobutylene rubber and other macromolecular material of 0%-40% of 60%-100%; Other described macromolecular material is PVC, PE, phenolic aldehyde or paracril.
2. butyl blending emulsion chemical defence gloves as claimed in claim 1, is characterized in that: described vulcanizing agent is sulphur, superoxide or metal oxide.
3. butyl blending emulsion chemical defence gloves as claimed in claim 1, is characterized in that: described promotor is zinc diethyldithiocarbamate class.
4. butyl blending emulsion chemical defence gloves as claimed in claim 1, is characterized in that: described vulcanization activator is zinc oxide and/or stearic acid.
5. the preparation method of butyl blending emulsion chemical defence gloves, is characterized in that comprising the following steps:
(1) prepare polymer blended alloy material main body: the isoprene-isobutylene rubber of 60%-100% and other macromolecular material of 0%-40% are carried out to interface adjusting, blend, maturation balance more than 24 hours; Other described macromolecular material is PVC, PE, phenolic aldehyde or paracril;
(2) configure polymer blended outer glue-line emulsion: by mass parts, 100 parts of the polymer blended alloy material main bodys making in described step (1), add vulcanizing agent 0.5-5 part, promotor 0-2 part and vulcanization activator 1-3 part, stir, maturation is more than 24 hours; Described vulcanizing agent is sulphur, superoxide or metal oxide; Described promotor is zinc diethyldithiocarbamate; Described vulcanization activator is zinc oxide or stearic acid;
(3) dipping: the glove liner of nylon, terylene, cotton or rayon fiber seamless knitted is immersed in peptizer, then immerse the polymer blended outer glue-line emulsion having configured in step (2), after 100-130 DEG C of sulfuration, dry 60-120min makes finished product, then carry out finished product dry, after parching at 80 DEG C, make the polymer blended chemical defence gloves of butyl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410194274.9A CN103965554B (en) | 2014-05-09 | 2014-05-09 | Butyl blending emulsion chemical defence glove and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410194274.9A CN103965554B (en) | 2014-05-09 | 2014-05-09 | Butyl blending emulsion chemical defence glove and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103965554A true CN103965554A (en) | 2014-08-06 |
| CN103965554B CN103965554B (en) | 2016-07-06 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410194274.9A Active CN103965554B (en) | 2014-05-09 | 2014-05-09 | Butyl blending emulsion chemical defence glove and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104480720A (en) * | 2014-12-12 | 2015-04-01 | 天津大学 | Surface rubber coating modification method of plane-woven carbon fibres |
| CN105442312A (en) * | 2015-12-01 | 2016-03-30 | 南通强生安全防护科技有限公司 | Antibacterial cloth as well as preparation method and application thereof |
| CN108676262A (en) * | 2018-04-25 | 2018-10-19 | 国家电网公司 | Electro-insulating rubber composite material and preparation method, insulated rubber gloves and preparation method |
| CN109247639A (en) * | 2018-09-23 | 2019-01-22 | 南通嘉得利安全用品有限公司 | Wear-resistant protective gloves |
| CN110801065A (en) * | 2019-10-18 | 2020-02-18 | 广州双一乳胶制品有限公司 | Composite chemical corrosion resistant airtight protective gloves and preparation process thereof |
| CN111763392A (en) * | 2020-07-21 | 2020-10-13 | 江西中红普林医疗制品有限公司 | Disposable nitrile rubber modified PVC (polyvinyl chloride) glove and preparation method thereof |
| CN112048917A (en) * | 2020-09-03 | 2020-12-08 | 山东星宇手套有限公司 | Preparation method of double-layer butyl chemical-resistant gloves with linings |
| CN116480292A (en) * | 2023-04-04 | 2023-07-25 | 青岛青橡橡胶有限公司 | Acidizing fracturing hose and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104480720A (en) * | 2014-12-12 | 2015-04-01 | 天津大学 | Surface rubber coating modification method of plane-woven carbon fibres |
| CN105442312A (en) * | 2015-12-01 | 2016-03-30 | 南通强生安全防护科技有限公司 | Antibacterial cloth as well as preparation method and application thereof |
| CN108676262A (en) * | 2018-04-25 | 2018-10-19 | 国家电网公司 | Electro-insulating rubber composite material and preparation method, insulated rubber gloves and preparation method |
| CN108676262B (en) * | 2018-04-25 | 2021-05-07 | 国家电网公司 | Insulating rubber composite material and preparation method thereof, insulating rubber gloves and preparation method thereof |
| CN109247639A (en) * | 2018-09-23 | 2019-01-22 | 南通嘉得利安全用品有限公司 | Wear-resistant protective gloves |
| CN110801065A (en) * | 2019-10-18 | 2020-02-18 | 广州双一乳胶制品有限公司 | Composite chemical corrosion resistant airtight protective gloves and preparation process thereof |
| CN110801065B (en) * | 2019-10-18 | 2021-08-31 | 广州双一乳胶制品有限公司 | Composite chemical corrosion resistant airtight protective gloves and preparation process thereof |
| CN111763392A (en) * | 2020-07-21 | 2020-10-13 | 江西中红普林医疗制品有限公司 | Disposable nitrile rubber modified PVC (polyvinyl chloride) glove and preparation method thereof |
| CN111763392B (en) * | 2020-07-21 | 2022-03-22 | 江西中红普林医疗制品有限公司 | Disposable nitrile rubber modified PVC (polyvinyl chloride) glove and preparation method thereof |
| CN112048917A (en) * | 2020-09-03 | 2020-12-08 | 山东星宇手套有限公司 | Preparation method of double-layer butyl chemical-resistant gloves with linings |
| CN116480292A (en) * | 2023-04-04 | 2023-07-25 | 青岛青橡橡胶有限公司 | Acidizing fracturing hose and preparation method thereof |
| CN116480292B (en) * | 2023-04-04 | 2024-03-15 | 青岛青橡橡胶有限公司 | Acidizing fracturing hose and preparation method thereof |
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| Publication number | Publication date |
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| CN103965554B (en) | 2016-07-06 |
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