CN106723333A - A kind of electret superfine fibre cigarette filter tip material and preparation method thereof - Google Patents
A kind of electret superfine fibre cigarette filter tip material and preparation method thereof Download PDFInfo
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- CN106723333A CN106723333A CN201611097429.2A CN201611097429A CN106723333A CN 106723333 A CN106723333 A CN 106723333A CN 201611097429 A CN201611097429 A CN 201611097429A CN 106723333 A CN106723333 A CN 106723333A
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- Prior art keywords
- electret
- melt
- fibre
- superfine fibre
- filter tip
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0229—Filter rod forming processes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Filtering Materials (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Electrostatic Separation (AREA)
Abstract
The present invention relates to a kind of electret superfine fibre cigarette filter tip material and preparation method thereof, electret superfine fibre cigarette filter tip material of the invention is the melt-blown micro fibre of 15 μm of diameter;The superfine fibre is made up of the thermoplastic of 94 99 weight portions and the electret master batch of 16 weight portions;The melt-blown micro fibre have passed through electret treatment;The thermoplastic is any one in PP, PET, PA, PLA or PE.The present invention is improved conventional meltblown method, and the superfine fibre beam for preparing 15 μm of diameter is once changed over into cloth by traditional, and fibre fineness is uniform, and electret superfine fibre cigarette filter tip material of the invention is avoided that the problem of environmental pollution in acetate fiber production.The present invention carries out electret treatment to superfine fibre, and the fiber after treatment carries lasting electrostatic, and electric charge conservation rate can trap particulate dust, filtration resistance low advantage high with filter efficiency up to more than 2 years by electrostatic effect.
Description
Technical field
The present invention relates to cigarette cigarette filter tip material field and non-woven field, more particularly to a kind of electret superfine fibre is fragrant
Cigarette filter tip material and preparation method thereof.
Background technology
Include particulate, normally referred to as tar in cigarette smoke.Contain substantial amounts of chemical composition in tar, there are 4000 to arrive
5000 kinds, be all the unburnt product of tobacco.Cigaratte filter is in order to the tar in filter tobacco etc. is harmful
Material.Existing frequently-used cigarette filter tip material is acetate fiber cigaratte filter, and acetate fiber is obtained using wet spinning, production
Technological process is long, and the solvent used in spinning process is harmful to environment, there is three-waste pollution.Additionally, cellulose acetate fibre is in filter
The effect of the harmful carcinogen (such as polycyclic aromatic hydrocarbon and aldehyde material) in except cigarette main flume is not very good, removal
Only 40% or so of polycyclic aromatic hydrocarbon material.
Cigarette filter can filter smoke composition, to reduce the soakage of tar and nicotine.But cigarette cigarettes are filtered
After mouth, draw resistance is greatly increased, and noxious material is more.Such as carbon monoxide, BaP are all in smoking process, by cigarette
Careless contained organic substance imperfect combustion generation, resistance is bigger during smoking, and oxygen supply is more insufficient, burns more incomplete, has
The growing amount of noxious material is also more.Fiber is thinner, and strainability is better.Three kinds of major functions of cigarette cigaratte filter include direct
Intercept, inertia is compressed and precipitin, most common is directly to intercept cigaratte filter.Filtering is a process for complexity, also
It is after saying that tar droplet is separated from smog, to be just attached to above when they reach the surface of cigarette filter tip material.It is fine
Dimension is thinner, and the filter efficiency of cigarette cigaratte filter is higher, and the acetate fiber diameter used by convention filter is between 7~20 μm.
The content of the invention
In order to solve the problems, such as that cigarette filter material filter efficiency is not high in the prior art, the present invention provides a kind of electret and surpasses
Fine fibre cigarette filter tip material and preparation method thereof and preparation facilities.
A kind of electret superfine fibre cigarette filter tip material, is the melt-blown micro fibre of 1-5 μm of diameter.
Further, the melt-blown micro fibre is female by the thermoplastic of 94-99 weight portions and the electret of 1-6 weight portions
Grain is made.
Further, the melt-blown micro fibre have passed through electret treatment.
A kind of preparation method of electret superfine fibre cigarette filter tip material, specifically includes following steps:
Step S1, the electret master batch of the thermoplastic of 94-99 weight portions and 1-6 weight portions is uniformly mixed, mixed
Close material;
Step S2, device for melt blowing prepare melt-blown micro fibre using compound;
Step S3, cooling beaming device are cooled down and boundling to the melt-blown micro fibre that device for melt blowing sprays;
Step S4, collection device are processed and collected to melt-blown micro fibre, obtain electret superfine fibre cigaratte filter
Material.
Further, the cooling beaming device of the step S3 includes packaged air conditioner and curtain net reception device;The step S3
Specially:Packaged air conditioner is cooled down to melt-blown micro fibre, and the melt-blown micro fibre after cooling falls along device for melt blowing successively
In the curtain net reception device of the breadth direction transmission of middle meltblown beam, curtain net reception device is surpassed to melt-blown micro fibre boundling
Fine fibre beam.
Further, the cooling beaming device of the step S3 includes packaged air conditioner and the first beaming device;The step S3
Specially:The packaged air conditioner is cooled down to the melt-blown micro fibre of the ejection of device for melt blowing, and first beaming device is to cold
But the melt-blown micro fibre after carries out boundling;And first beaming device is not less than in device for melt blowing along the width in breadth direction
Meltblown beam along breadth direction width.
Further, the melt-blown micro fibre is processed by electret after cooling down beaming device cooling and boundling, also and filled
Putting carries out electret treatment.
Further, the electret voltage of the electret processing unit is 5-20kV, electret interval 20-60mm, electret time
5-10s。
Further, the thermoplastic of the step S1 is any one in PP, PET, PA, PLA or PE.
The beneficial effects of the invention are as follows:Fiber is thinner, and the filter efficiency of cigarette cigaratte filter is higher, used by convention filter
Acetate fiber diameter between 7~20 μm, conventional meltblown cannot be obtained fibre bundle, and fabric nonwoven cloth can only be obtained, this
Invention is improved conventional meltblown method, and the cooling of meltblown fibers is accelerated by increasing cold side blowing, makes fiber completely cold
But collected in the case of, it is to avoid the bonding between meltblown fibers, disorientation, melt-blown fibre occur at relatively high temperatures prevented also from fiber
Dimension remains certain degree of orientation, and fiber strength is improved.Meanwhile, by curtain net by tradition prepare non-woven fabrics perpendicular to web width
Direction movement is changed to be moved along web width direction, and diameter can be directly obtained can reach 1~5 μm of superfine fibre beam, and carefully
Degree even variation is small, thus filter effect is high, is avoided that the problem of environmental pollution in acetate fiber production.The present invention is to melt-blown super
Fine fibre carries out electret treatment, is processed by distinctive electret, melt-blown micro fibre can be made to polarize and take electric charge, so as to not
In the case of increasing material respiratory resistance, the Electrostatic Absorption performance of material is improved, while electric charge conservation rate was up to more than 2 years, can
It is particulate dust, filtration resistance low advantage high with filter efficiency by electrostatic effect paved set.
Brief description of the drawings
Fig. 1 is preparation facilities structural representation when cooling down beaming device using the first implementation method;
Fig. 2 is preparation facilities structural representation when cooling down beaming device using second implementation method.
In accompanying drawing, the list of parts that each label is represented is as follows:
1st, device for melt blowing;2nd, packaged air conditioner;3rd, curtain net reception device;4th, the first beaming device;5th, collection device;6th, it is melt-blown super
Fine fibre;7th, electret processing unit;8th, fiber channel;9th, oil tanker;10th, the second beaming device
Specific embodiment
Principle of the invention and feature are described below in conjunction with accompanying drawing, example is served only for explaining the present invention, and
It is non-for limiting the scope of the present invention.
A kind of electret superfine fibre cigarette filter tip material, is the melt-blown micro fibre of 1-5 μm of diameter.
The melt-blown micro fibre is made up of the thermoplastic of 94-99 weight portions and the electret master batch of 1-6 weight portions.
The melt-blown micro fibre have passed through electret treatment.
A kind of preparation method of electret superfine fibre cigarette filter tip material, specifically includes following steps:
Step S1, the electret master batch of the thermoplastic of 94-99 weight portions and 1-6 weight portions is uniformly mixed, mixed
Close material;
Step S2, device for melt blowing 1 prepare melt-blown micro fibre 6 using compound;
Step S3, cooling beaming device are cooled down and boundling to the melt-blown micro fibre 6 that device for melt blowing 1 sprays;
Step S4, collection device 5 are processed and collected to melt-blown micro fibre 6, obtain the filter of electret superfine fibre cigarette
Mouth material.
When cooling down the first implementation method of beaming device, the cooling beaming device of the step S3 includes the He of packaged air conditioner 2
Curtain net reception device 3;The step S3 is specially:Packaged air conditioner 3 is cooled down to melt-blown micro fibre 6, melt-blown super after cooling
Fine fibre 6 falls along in the curtain net reception device 3 of breadth direction transmission of meltblown beam in device for melt blowing 1 successively, to melt-blown
The boundling of superfine fibre 6 obtains superfine fibre beam.
After the melt-blown micro fibre 6 is through the boundling of curtain net reception device 3, electret treatment is carried out by electret processing unit 7,
Further boundling is carried out by the second beaming device 10 again, afterwards into collection device 5.
When cooling down second implementation method of beaming device, the cooling beaming device of the step S3 includes the He of packaged air conditioner 2
First beaming device 4;The step S3 is specially:The packaged air conditioner is carried out to the melt-blown micro fibre 6 of the ejection of device for melt blowing 1
Cooling, the melt-blown micro fibre 6 after first beaming device, 4 pairs of coolings carries out boundling;And first beaming device 4 is along width
The width of cross direction not less than meltblown beam in device for melt blowing 1 along breadth direction width.
After the melt-blown micro fibre 6 is through the boundling of the first beaming device 4, electret treatment is carried out by electret processing unit 7,
Enter collection device 5 afterwards.
The electret voltage of the electret processing unit is 5-20kV, electret interval 20-60mm, electret time 5-10s.
The thermoplastic of the step S1 is any one in PP, PET, PA, PLA or PE.
The collection device 5 is cutting machine, and after oil tanker 9 oils to melt-blown micro fibre 6, guide wire apparatus are by melt-blown ultra-fine fibre
Dimension imports cutting machine, and melt-blown micro fibre 6 is cut into uniform segment by cutting machine, used as electret superfine fibre cigaratte filter material
Material.
It is as depicted in figs. 1 and 2 a kind of preparation facilities of electret superfine fibre cigarette filter tip material, including device for melt blowing 1,
Cooling beaming device, electret processing unit and collection device;
The device for melt blowing 1 is got one's things ready for preparing melt-blown micro fibre 6, and melt-blown micro fibre 6 being delivered into cooling collection
Put;
The cooling beaming device is arranged on the lower section of device for melt blowing 1, for the melt-blown micro fibre sprayed to device for melt blowing 1
6 are cooled down and boundling, obtain superfine fibre beam;
Electret processing unit is used for the treatment of superfine fibre Shu Jinhang electrets;
The collection device is used for superfine fibre Shu Jinhang treatment and collects, and obtains electret superfine fibre cigaratte filter material
Material.
It is as shown in Figure 1 the first implementation method of cooling beaming device, the cooling beaming device includes the He of packaged air conditioner 2
Curtain net reception device 3;
The packaged air conditioner 2 is arranged on the lower section of meltblown beam in device for melt blowing 1, melt-blown for what is sprayed to device for melt blowing 1
Superfine fibre 6 is cooled down, and the curtain net reception device 3 is arranged on the lower section of packaged air conditioner 2, for the melt-blown ultra-fine fibre after to cooling
Dimension 6 carries out boundling;The curtain net reception device 3 is processed along the breadth direction of meltblown beam in device for melt blowing 1 by away from electret
One end of device 7, is driven near one end of electret processing unit 7.
Aspirator is provided with the curtain net reception device 3, for melt-blown micro fibre 6 to be drawn into curtain net reception device
On 3 upper surface.
When cooling down the first implementation method of beaming device, also set up between the electret processing unit and collection device 5
There is the second beaming device 10, for the further boundlings of superfine fibre Shu Jinhang.
Second implementation method of cooling beaming device is illustrated in figure 2, the cooling beaming device includes the He of packaged air conditioner 2
First beaming device 4;The packaged air conditioner 2 is arranged on meltblown beam lower section in device for melt blowing 1, for the ejection to device for melt blowing 1
Melt-blown micro fibre 6 cooled down, first beaming device 4 is arranged on the lower section of packaged air conditioner 2, for melt-blown after to cooling
Superfine fibre 6 carries out boundling and obtains superfine fibre beam;The superfine fibre beam is transported to electret treatment dress by fiber channel 8
7 are put, superfine fibre is cut off and collected by after electret treatment into collection device.The fiber channel 8 act as support
Fibre bundle is held and guides, can be using forms such as supporting plates.First beaming device 4 is not less than melt-blown dress along the width in breadth direction
The width of meltblown beam in 1 along breadth direction is put, therefore all superfine fibres that device for melt blowing sprays can enter beaming device 4
Carry out boundling.
The beaming device 10 of first beaming device 4 and second can use horn mouth buncher.Second collection is got one's things ready
Putting 10, guide wire apparatus and cutting machine etc. can be fixed using modes such as supports.
Embodiment 1
A kind of preparation method of electret superfine fibre cigarette filter tip material, comprises the following steps:
Step S1, take the weight portion of polypropylene granules 96, the weight portion of electret master batch 4 be well mixed, obtain compound;
Step S2, four regional temperatures of setting electret superfine fibre cigarette filter tip material preparation facilities are respectively 260 DEG C,
260 DEG C, 270 DEG C, 270 DEG C, compound obtained by step S1 is fed the feed bin of screw extruder, through screw rod melt extruder shape
Into melt;
Step S3, melt are sprayed after measuring pump by spinneret, and drawing-off obtains melt-blown under 220 DEG C, 0.4MPa hot blasts
Superfine fibre, boundling is carried out after melt-blown micro fibre cooling using curtain net collection device or beaming device;
Step S4, electret treatment is carried out by the way of high-voltage corona discharge to the melt-blown micro fibre that step S3 is obtained,
The electret voltage is 10kV, electret interval 30mm, electret time 10s;
Step S5, electret is processed after melt-blown micro fibre carry out boundling successively, gluing and is cut off shaping, is stayed
Superfine fiber cigarette filter tip material.
The superfine fibre average diameter of the electret superfine fibre cigarette filter tip material made by the present embodiment can reach 2 μm,
Filter efficiency reaches 95%.
Embodiment 2
Step S1, take the weight portion of polypropylene granules 95,5 parts of electret master batch and be well mixed, obtain compound;
Step S2, four regional temperatures of setting electret superfine fibre cigarette filter tip material preparation facilities are respectively 260 DEG C,
260 DEG C, 270 DEG C, 270 DEG C, compound obtained by step S1 is fed the feed bin of screw extruder, through screw rod melt extruder shape
Into melt;
Step S3, melt are sprayed after measuring pump by spinneret, and drawing-off obtains melt-blown under 220 DEG C, 0.4MPa hot blasts
Superfine fibre, boundling is carried out after melt-blown micro fibre cooling using curtain net collection device or beaming device;
Step S4, electret treatment is carried out by the way of high-voltage corona discharge to the superfine fibre that step S3 is obtained, it is described
Electret voltage is 20kV, electret interval 20mm, electret time 10s;
Step S5, the superfine fibre after the treatment of melt-blown electret is carried out into boundling successively, gluing and is cut off shaping, is stayed
Superfine fiber cigarette filter tip material.
The superfine fibre average diameter of the electret superfine fibre cigarette filter tip material made by the present embodiment is 2 μm, filtering
Efficiency can reach 98%.
Embodiment 3
Step S1, take the weight portion of PET pellets 96, the weight portion of electret master batch 4 be well mixed, obtain compound;
Step S2, the compound is put into boiling type pre-crystallizer, pre-crystallized 2 hours at 120 DEG C, be then placed in
In filling drier, dried 8 hours at 180 DEG C;
Step S3, four regional temperatures of setting electret superfine fibre cigarette filter tip material preparation facilities are respectively 270 DEG C,
270 DEG C, 280 DEG C, 285 DEG C, the compound after step S2 treatment is fed the feed bin of screw extruder, through screw rod melt extruder
Form melt;
Step S4, melt are sprayed after measuring pump by spinneret, and drawing-off obtains melt-blown under 220 DEG C, 0.4MPa hot blasts
Superfine fibre, boundling is carried out after melt-blown micro fibre cooling using curtain net collection device or beaming device;
Step S5, electret treatment is carried out by the way of high-voltage corona discharge to the superfine fibre that step S4 is obtained, it is described
Electret voltage is 10kV, electret interval 30mm, electret time 10s;
Step S6, electret is processed after melt-blown micro fibre carry out boundling successively, gluing and is cut off shaping, is stayed
Superfine fiber cigarette filter tip material.
The superfine fibre average diameter of the electret superfine fibre cigarette filter tip material made by the present embodiment is 2.5 μm, mistake
Filter efficiency can reach 92%.
Embodiment 4
Step S1, take the weight portion of PET pellets 95, the weight portion of electret master batch 5 be well mixed, obtain compound;
Step S2, the compound is put into boiling type pre-crystallizer, pre-crystallized 2 hours at 120 DEG C, be then placed in
In filling drier, dried 8 hours at 180 DEG C;
Step S3, four regional temperatures of setting electret superfine fibre cigarette filter tip material preparation facilities are respectively 270 DEG C,
270 DEG C, 280 DEG C, 285 DEG C, the compound after step S2 treatment is fed the feed bin of screw extruder, through screw rod melt extruder
Form melt;
Step S4, melt are sprayed after measuring pump by spinneret, and drawing-off obtains melt-blown under 220 DEG C, 0.4MPa hot blasts
Superfine fibre, boundling is carried out after melt-blown micro fibre cooling using curtain net collection device or beaming device;
Step S5, electret treatment is carried out by the way of high-voltage corona discharge to the superfine fibre that step S4 is obtained, it is described
Electret voltage is 20kV, electret interval 20mm, electret time 10s;
Step S6, electret is processed after melt-blown micro fibre carry out boundling successively, gluing and is cut off shaping, is stayed
Superfine fiber cigarette filter tip material.
The superfine fibre average diameter of the electret superfine fibre cigarette filter tip material made by the present embodiment is 2.5 μm, mistake
Filter efficiency can reach 94%.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all it is of the invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (9)
1. a kind of electret superfine fibre cigarette filter tip material, it is characterised in that be 1-5 μm of melt-blown micro fibre of diameter.
2. electret superfine fibre cigarette filter tip material according to claim 1, it is characterised in that the melt-blown micro fibre
It is made up of the thermoplastic of 94-99 weight portions and the electret master batch of 1-6 weight portions.
3. electret superfine fibre cigarette filter tip material according to claim 1, it is characterised in that the melt-blown micro fibre
Have passed through electret treatment.
4. a kind of preparation method of electret superfine fibre cigarette filter tip material, it is characterised in that specifically include following steps:
Step S1, the electret master batch of the thermoplastic of 94-99 weight portions and 1-6 weight portions is uniformly mixed, obtain compound;
Step S2, device for melt blowing (1) prepare melt-blown micro fibre (6) using compound;
Step S3, cooling beaming device are cooled down and boundling to the melt-blown micro fibre (6) that device for melt blowing (1) sprays;
Step S6, collection device (5) are processed and collected to melt-blown micro fibre (6), obtain the filter of electret superfine fibre cigarette
Mouth material.
5. the preparation method of electret superfine fibre cigarette filter tip material according to claim 4, it is characterised in that the step
The cooling beaming device of rapid S3 includes packaged air conditioner (2) and curtain net reception device (3);The step S3 is specially:Packaged air conditioner (3) is right
Melt-blown micro fibre (6) is cooled down, and the melt-blown micro fibre (6) after cooling falls along melt-blown in device for melt blowing (1) successively
On curtain net reception device (3) of the breadth direction transmission of die head, curtain net reception device (3) is obtained to melt-blown micro fibre (6) boundling
To superfine fibre beam.
6. the preparation method of electret superfine fibre cigarette filter tip material according to claim 4, it is characterised in that the step
The cooling beaming device of rapid S3 includes packaged air conditioner (2) and the first beaming device (4);The step S3 is specially:The packaged air conditioner
Melt-blown micro fibre (6) to the ejection of device for melt blowing (1) is cooled down, first beaming device (4) to cooling after it is molten
Spraying super-fine-fiber (6) carries out boundling;And first beaming device (4) is not less than device for melt blowing (1) along the width in breadth direction
Middle meltblown beam along breadth direction width.
7. the preparation method of the electret superfine fibre cigarette filter tip material according to claim 4-6, it is characterised in that described
Melt-blown micro fibre (6) also carries out electret treatment after cooling down beaming device cooling and boundling by electret processing unit (4).
8. the preparation method of the electret superfine fibre cigarette filter tip material according to claims 7, it is characterised in that described
The electret voltage of electret processing unit (4) is 5-20kV, electret interval 20-60mm, electret time 5-10s.
9. the preparation method of electret superfine fibre cigarette filter tip material according to claim 4, it is characterised in that the step
The thermoplastic of rapid S1 is any one in PP, PET, PA, PLA or PE.
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CN110477450A (en) * | 2019-08-28 | 2019-11-22 | 深圳市智叶科技有限公司 | A kind of electronic cigarette filter tip and preparation method thereof |
CN112281250A (en) * | 2020-08-17 | 2021-01-29 | 金发科技股份有限公司 | Antibacterial melt-blown polyamide composite material and preparation method and application thereof |
CN112281250B (en) * | 2020-08-17 | 2022-01-25 | 金发科技股份有限公司 | Antibacterial melt-blown polyamide composite material and preparation method and application thereof |
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