CN106702449A - Steel belt electroplating process for Bundy tube - Google Patents

Steel belt electroplating process for Bundy tube Download PDF

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Publication number
CN106702449A
CN106702449A CN201710043488.XA CN201710043488A CN106702449A CN 106702449 A CN106702449 A CN 106702449A CN 201710043488 A CN201710043488 A CN 201710043488A CN 106702449 A CN106702449 A CN 106702449A
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CN
China
Prior art keywords
plating
copper
groove
steel band
plating groove
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Pending
Application number
CN201710043488.XA
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Chinese (zh)
Inventor
石磊
刘科高
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Shandong Jianzhu University
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Shandong Jianzhu University
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Priority to CN201710043488.XA priority Critical patent/CN106702449A/en
Publication of CN106702449A publication Critical patent/CN106702449A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/06Wires; Strips; Foils
    • C25D7/0614Strips or foils
    • C25D7/0621In horizontal cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/02Tanks; Installations therefor
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper
    • C25D3/40Electroplating: Baths therefor from solutions of copper from cyanide baths, e.g. with Cu+
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/36Pretreatment of metallic surfaces to be electroplated of iron or steel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

Provided is a steel belt electroplating process for a Bundy tube. According to the steel belt electroplating process for the Bundy tube, cyanide copper pre-plating is mainly adopted, and then sulfate acidic copper plating is carried out. An obtained Bundy tube copper coating is fine and uniform, so that manufacturing of the Bundy tube is facilitated; and through a designed S-type electroplating method, the production space is saved, investment cost is reduced, and accordingly profits are increased.

Description

Bundy tube steel band electroplating technology
Technical field
Bundy tube steel band electroplating technology, is specifically related to the technical field of continuous steel strip electroplating.
Background technology
What Bundy tube was mainly manufactured by steel band copper facing, it is commonly utilized in automobile oil pipe, floor heating pipe, air-conditioner pipe etc. Aspect.Cyanide electroplating can obtain the good coating of fine and close, smooth, adhesion, so continuous copper-plating of steel strip uses cyanide electroplating Technique, although the clearly superseded cyanidation technology of country, but the technique of replacement is not found till now, and because it is widely used in essence The fields such as close electronic instrument, precision instrument, Aero-Space, can only delay to eliminate.Cyanide electroplating is most widely used, earliest plating Copper method, but cyanide electroplating can cause that the adhesion of coating is bad because phosphorus content is higher, the easy sealing-off of coating surface, in system Local corrosion phenomenon is easily caused after into Bundy tube.Not only causing the Bundy tube after the waste of resource, and corrosion can cause gas The seepage of body, liquid etc., during conveying flammable explosive gas liquid or toxic gas, can cause huge to the safety of staff Harm, and environment is polluted, do not meet the principle of the environmentally friendly production in the world today.By substantial amounts of experiment table Bright, phosphorus content is few in acidiccopper plating, can combine coating even closer, is difficult sealing-off, can effectively economize on resources, and protects The safety of shield personnel, while meeting current green production principle.
According to documents, it is necessary to multiple copper plating grooves, auxiliary tank and other auxiliary set in original continuous copper-plating of steel strip Standby, continuous copper-plating of steel strip production line is up to 80 meters, and floor space is big, every meter of about 20,000 yuan of steel strip production line, one-time investment Too big, comprehensive production efficiency is low, it is necessary to the attended operation of extensive work personnel, causes the waste of financial resource and material resource.Steel originally Band copperizing continuously typically can only once electroplate one or two steel bands, and in present invention, steel band is in preceding treatment groove and coating bath All it is S-type trend, greatly reduces floor space, saves production line cost about 1/2nd, and because containing in acidiccopper plating Phosphorus amount is few, can combine coating even closer, and the Bundy tube of making is difficult sealing-off, can effectively economize on resources, and protects people The safety of member.
Documents:Utility model:One kind prevents copper facing steel strip surface oxidation unit, 2013202792627;A kind of steel band Copper facing coating bath leakage-resistant device, 2013202762886;A kind of steel band copper facing electroplating bath level automatic alarm, 2013202762585;A kind of highly automated warning device of steel band copper facing liquid level, 2013202762566;A kind of steel band plates copper coating The device of homogenization, 2013201687888;A kind of EGR of continuous copper-plating of steel strip liquid, 2011201517430;A kind of steel Electroplating bath with copperizing continuously, 2011201517426;A kind of the automatic of continuous copper-plating of steel strip puts hydrogen production device, 201120151752X;A kind of atomizing cleaning device for continuous copper-plating of steel strip, 2011201517587;A kind of continuous copper-plating of steel strip is online Process the device of sodium carbonate, 2011201517341;A kind of recycling device of cleaning water of conductive roll in steel strip continuous copper plating, 2011201517553;Invention Announce:New steel belt copperizing continuously technology groove, 2014101949610;A kind of continuous copper-plating of steel strip Technique, 2014101949644;A kind of continuous copper-plating of steel strip method, 201410194963X;A kind of continuous copper-plating of steel strip I, 2014101949663;A kind of electroplating technology of continuous copper-plating of steel strip, 2014101949625;A kind of continuous copper-plating of steel strip method, 2014101949659;Invention is authorized:A kind of technique of continuous copper-plating of steel strip, 2014101949678;Continuous copper-plating of steel strip, 2011102908756;A kind of method of continuous copper-plating of steel strip online recycling, 2011102908737.
The content of the invention
A kind of Bundy tube steel band electro-plating method, mainly including steel band, conductive rollers, copper plating groove, air exhauster, high-pressure nozzle, Dividing plate, inductor, room groove, can open it is transparent plating groove lid, controller, blast pipe, treatment trough, wire, copper pre-plating groove;Including preceding Processing procedure and electro-coppering process, pre-treatment mainly include ultrasonic oil removal, electrolytic degreasing, washing, activation, washing;Electroplated Journey mainly includes copper facing, recovery, washing;It is mainly characterized by:Pretreatment tank is built with cyanide electroplating liquid;Copper plating groove is built with sulphur Hydrochlorate copper plating bath;The size of copper plating groove cell body:1800mm long, 1200mm wide, 500mm high;Copper plating groove is each side There is a room groove;Dividing plate is provided with the groove of room, high-pressure nozzle is provided with above and below each dividing plate both sides, shower nozzle can be in 45° angle cleans steel band up and down;Conductive rollers are provided with outside coating bath, conductive and correction steel band is can be used to;It is provided with above coating bath Transparent plating groove lid can be opened.In continuous copper-plating of steel strip production process, steel band first carries out cyanide electroplating by copper pre-plating groove and locates in advance Reason, steel band is returned in coating bath into the correction effect after copper plating groove out by conductive rollers, carries out sulfate plating.Cross herein High-pressure nozzle in journey Vacancy groove can be cleaned to steel band, to enter the copper facing of next round.In continuous copper-plating of steel strip groove, Transparent plating groove lid can be opened, it is necessary to be opened with controller when changing anode, transparent plating groove lid can be opened and packed up to coating bath both sides, it is real Existing bidirectional operation.Can open transparent plating groove lid can by wire by signal transmission to inductor, signal is passed through wire by inductor Air exhauster is passed to, by blast pipe be transported in treatment trough toxic gas by air exhauster, made without toxic gas in coating bath, to protect Demonstrate,prove the safety of staff.
In present invention, steel band is S-type trend, saves production line cost about 1/2nd, and because of sulfate plating Phosphorus content is few in copper, can combine coating even closer, and the Bundy tube of making is difficult sealing-off, can effectively economize on resources, The safety of protection personnel, but tack of the coating of cyanide electroplating on steel band is good, so first pass through cyanide electroplating liquid carrying out Copper pre-plating, while meeting current green production principle.
Specification width figure
Fig. 1 is a kind of schematic diagram of Bundy tube novel electroplating method.
Fig. 2 is a kind of front view of Bundy tube steel band electro-plating method.
1 is steel band in figure, and 2 is conductive rollers, and 3 is coating bath, and 4 is air exhauster, and 5 is high-pressure nozzle, and 6 is dividing plate, and 7 is sensing Device, 8 is room groove, and 9 is that can open transparent plating groove lid, and 10 is controller, and 11 is blast pipe, and 12 is treatment trough, and 13 is wire, 14 It is copper pre-plating groove.
Embodiment 1
The embodiment is used to illustrate a kind of steel band electro-plating method for being applied to Bundy tube of present invention offer.
(One)Pre-treatment groove
(1)Hot water washing groove:300mm steel bands wide are totally immersed in 70~80 DEG C of hot water, 20~30s is cleaned, cell body Size:1800mm long, 1200mm wide, 500mm high.
(2)Ultrasonic oil removal groove, ultrasonic oil removal cleaning agent, concentration is 5%, and temperature is 40 ~ 50 °C, ultrasonic frequency It is 25 kHz, the size of cell body:1800mm long, 1200mm wide, 500mm high;
(3)Electrolytic degreasing groove:By step(2)Steel band after treatment is immersed in electrolytic degreasing liquid, and alkali liquid temperature is 60~80 DEG C, Current density is 8~10A/dm2, first negative electrode oil removing 1min, then anode oil removing 15s(After oil removing with concentration be 600ppm with Under low chlorine ion water or pure water, cleaned).
(Two)Copper electroplating groove(2)
(5)Copperizing continuously groove:The design of coating bath, it is main to use pp sheet materials(Thickness 15mm)Made with lucite, periphery shaped steel Reinforce, each parameter is 6000mm long, 1800mm wide, 500mm high.
A kind of Bundy tube steel band electro-plating method, mainly including steel band, conductive rollers, copper plating groove, air exhauster, high-pressure nozzle, Dividing plate, inductor, room groove, can open it is transparent plating groove lid, controller, blast pipe, treatment trough, wire, copper pre-plating groove;Including preceding Processing procedure and electro-coppering process, pre-treatment mainly include ultrasonic oil removal, electrolytic degreasing, washing, activation, washing;Electroplated Journey mainly includes copper facing, recovery, washing;It is mainly characterized by:Pretreatment tank is built with cyanide electroplating liquid;Copper plating groove is built with sulphur Hydrochlorate copper plating bath;The size of copper plating groove cell body:6000mm long, 1800mm wide, 500mm high;Copper plating groove is each side There is a room groove;Dividing plate is provided with the groove of room, high-pressure nozzle is provided with above and below each dividing plate both sides, shower nozzle can be in 45° angle cleans steel band up and down;Conductive rollers are provided with outside coating bath, conductive and correction steel band is can be used to;It is provided with above coating bath Transparent plating groove lid can be opened;Transparent plating groove lid can be opened to be connected with controller and inductor respectively by wire;Inductor with take out Blower fan is connected by wire;Air exhauster is connected with blast pipe;Blast pipe is connected with treatment trough.In continuous copper-plating of steel strip production process In, steel band first carries out cyanide electroplating pretreatment by copper pre-plating groove, and steel band enters after copper plating groove out by the correction of conductive rollers Effect is returned in coating bath, and the high-pressure nozzle in the groove of room can be cleaned to steel band in the process, to enter next round Copper facing.In continuous copper-plating of steel strip groove, transparent plating groove lid can be opened, it is necessary to be opened with controller when changing anode, can opened Bright plating groove lid is packed up to coating bath both sides, realizes bidirectional operation.Can open it is transparent plating groove lid can by wire by signal transmission to sense Answer device, inductor that signal is passed into air exhauster by wire, toxic gas is transported to treatment trough by air exhauster by blast pipe It is interior, make in coating bath without toxic gas, to ensure the safety of staff.

Claims (1)

1. Bundy tube steel band electroplating technology, mainly including steel band, conductive rollers, copper plating groove, air exhauster, high-pressure nozzle, dividing plate, sense Answer device, room groove, transparent plating groove lid, controller, blast pipe, treatment trough, wire, copper pre-plating groove can be opened;Including pre-treatment Journey and electro-coppering process, pre-treatment mainly include ultrasonic oil removal, electrolytic degreasing, washing, activation, washing;Electroplating process is main Including copper pre-plating, copper facing, recovery, washing;It is mainly characterized by:Pretreatment tank is built with cyanide electroplating liquid;Copper plating groove built with Acidiccopper plating liquid;The size of copper plating groove cell body:1800mm long, 1200mm wide, 500mm high;The left and right sides of copper plating groove Respectively there is a room groove;Dividing plate is provided with the groove of room, high-pressure nozzle is provided with above and below each dividing plate both sides, shower nozzle can Steel band is cleaned up and down in 45° angle;Conductive rollers are provided with outside coating bath, conductive and correction steel band is can be used to;Set in the top of coating bath Having can open transparent plating groove lid.
CN201710043488.XA 2017-01-21 2017-01-21 Steel belt electroplating process for Bundy tube Pending CN106702449A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710043488.XA CN106702449A (en) 2017-01-21 2017-01-21 Steel belt electroplating process for Bundy tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710043488.XA CN106702449A (en) 2017-01-21 2017-01-21 Steel belt electroplating process for Bundy tube

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Publication Number Publication Date
CN106702449A true CN106702449A (en) 2017-05-24

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140661A (en) * 2010-01-29 2011-08-03 富葵精密组件(深圳)有限公司 Electroplating device
CN201933171U (en) * 2010-12-21 2011-08-17 苏州市甘泉自动化环保设备厂 Chemical tank in electroplating workshop
CN102417960A (en) * 2011-12-07 2012-04-18 南通弘扬金属制品有限公司 Copper clad steel wire and production method thereof
CN103952737A (en) * 2014-05-11 2014-07-30 山东建筑大学 Steel band continuous copper plating VI

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102140661A (en) * 2010-01-29 2011-08-03 富葵精密组件(深圳)有限公司 Electroplating device
CN201933171U (en) * 2010-12-21 2011-08-17 苏州市甘泉自动化环保设备厂 Chemical tank in electroplating workshop
CN102417960A (en) * 2011-12-07 2012-04-18 南通弘扬金属制品有限公司 Copper clad steel wire and production method thereof
CN103952737A (en) * 2014-05-11 2014-07-30 山东建筑大学 Steel band continuous copper plating VI

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