CN106700288A - 一种抗老化船舶电缆材料 - Google Patents

一种抗老化船舶电缆材料 Download PDF

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CN106700288A
CN106700288A CN201611182041.2A CN201611182041A CN106700288A CN 106700288 A CN106700288 A CN 106700288A CN 201611182041 A CN201611182041 A CN 201611182041A CN 106700288 A CN106700288 A CN 106700288A
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唐亮
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Abstract

本发明公开了一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶15‑25份，丁基橡胶10‑20份，三元乙丙橡胶20‑30份，氟硅橡胶15‑25份，妥尔油0.1‑0.6份，氯化石蜡0.4‑0.8份，棕榈蜡0.2‑0.8份，硫化剂PDM1‑2份，硫化剂HTDM 0.5‑1.5份，促进剂CZ 1‑2份，防老剂AW 0.6‑1.4份，防老剂A 1‑2份，防老剂BLE 0.5‑1.5份，煅烧高岭土50‑80份，海泡石3‑10份，亚麻纤维10‑14份，椰子纤维15‑25份，羧甲基纤维素钠1‑2份。

Description

一种抗老化船舶电缆材料
技术领域
本发明涉及矿用电缆技术领域，尤其涉及一种抗老化船舶电缆材料。
背景技术
众所周知，海上环境复杂多变，船舶电缆在船舶内部铺设时，极易发生弯折，但海上气候变化复杂、日夜温差大，电缆弯折时极易损害，不耐撞击，且撞击损坏后的电缆无法使用，且海上环境恶劣对电缆耐老化性能要求较高。
发明内容
本发明提出了一种抗老化船舶电缆材料，抗老化、耐腐蚀及力学性能极为优异。
本发明提出的一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶15-25份，丁基橡胶10-20份，三元乙丙橡胶20-30份，氟硅橡胶15-25份，妥尔油0.1-0.6份，氯化石蜡0.4-0.8份，棕榈蜡0.2-0.8份，硫化剂PDM1-2份，硫化剂HTDM 0.5-1.5份，促进剂CZ 1-2份，防老剂AW 0.6-1.4份，防老剂A 1-2份，防老剂BLE 0.5-1.5份，煅烧高岭土50-80份，海泡石3-10份，亚麻纤维10-14份，椰子纤维15-25份，羧甲基纤维素钠1-2份。
优选地，氢化丁腈橡胶、丁基橡胶、三元乙丙橡胶、氟硅橡胶的重量比为20-23：14-16：22-24：16-20。
优选地，妥尔油、氯化石蜡、棕榈蜡的重量比为0.2-0.4：0.5-0.6：0.3-0.5。
优选地，硫化剂PDM、硫化剂HTDM、促进剂CZ的重量比为1.2-1.4：1-1.2：1.2-1.4。
优选地，防老剂AW、防老剂A、防老剂BLE的重量比为1-1.2：1.2-1.4：1-1.2。
优选地，煅烧高岭土、海泡石、亚麻纤维、椰子纤维、羧甲基纤维素钠的重量比为60-70：6-8：11-12：20-22：1.4-1.6。
优选地，所述的抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶20-23份，丁基橡胶14-16份，三元乙丙橡胶22-24份，氟硅橡胶16-20份，妥尔油0.2-0.4份，氯化石蜡0.5-0.6份，棕榈蜡0.3-0.5份，硫化剂PDM 1.2-1.4份，硫化剂HTDM 1-1.2份，促进剂CZ1.2-1.4份，防老剂AW 1-1.2份，防老剂A 1.2-1.4份，防老剂BLE 1-1.2份，煅烧高岭土60-70份，海泡石6-8份，亚麻纤维11-12份，椰子纤维20-22份，羧甲基纤维素钠1.4-1.6份。
本发明采用氢化丁腈橡胶、丁基橡胶、三元乙丙橡胶及氟硅橡胶作为主料，并采用硫化剂PDM、硫化剂HTDM、促进剂CZ作为硫化体系，保证制品的抗老化、耐腐蚀性能，耐撞击，且力学性能极为优异，妥尔油、氯化石蜡及棕榈蜡与上述组分协同作用，制品硬度与韧性均较高，通过添加适量的煅烧高岭土、海泡石、亚麻纤维及椰子纤维协同作为填充增强材料，可进一步增强制品抗老化与力学性能，适于在船舶环境，且比表面积大，对其周围的物料吸附力极强，与其他原料共同作用，制品不仅质量轻，且力学性能、耐腐蚀及抗老化性能进一步增强。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶25份，丁基橡胶10份，三元乙丙橡胶30份，氟硅橡胶15份，妥尔油0.6份，氯化石蜡0.4份，棕榈蜡0.8份，硫化剂PDM 1份，硫化剂HTDM 1.5份，促进剂CZ 1份，防老剂AW 1.4份，防老剂A 1份，防老剂BLE1.5份，煅烧高岭土50份，海泡石10份，亚麻纤维10份，椰子纤维25份，羧甲基纤维素钠1份。
实施例2
一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶15份，丁基橡胶20份，三元乙丙橡胶20份，氟硅橡胶25份，妥尔油0.1份，氯化石蜡0.8份，棕榈蜡0.2份，硫化剂PDM 2份，硫化剂HTDM 0.5份，促进剂CZ 2份，防老剂AW 0.6份，防老剂A 2份，防老剂BLE0.5份，煅烧高岭土80份，海泡石3份，亚麻纤维14份，椰子纤维15份，羧甲基纤维素钠2份。
实施例3
一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶23份，丁基橡胶14份，三元乙丙橡胶24份，氟硅橡胶16份，妥尔油0.4份，氯化石蜡0.5份，棕榈蜡0.5份，硫化剂PDM 1.2份，硫化剂HTDM 1.2份，促进剂CZ 1.2份，防老剂AW 1.2份，防老剂A 1.2份，防老剂BLE 1.2份，煅烧高岭土60份，海泡石8份，亚麻纤维11份，椰子纤维22份，羧甲基纤维素钠1.4份。
实施例4
一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶20份，丁基橡胶16份，三元乙丙橡胶22份，氟硅橡胶20份，妥尔油0.2份，氯化石蜡0.6份，棕榈蜡0.3份，硫化剂PDM 1.4份，硫化剂HTDM 1份，促进剂CZ 1.4份，防老剂AW 1份，防老剂A 1.4份，防老剂BLE1份，煅烧高岭土70份，海泡石6份，亚麻纤维12份，椰子纤维20份，羧甲基纤维素钠1.6份。
实施例5
一种抗老化船舶电缆材料，其原料按重量份包括：氢化丁腈橡胶22份，丁基橡胶15份，三元乙丙橡胶23份，氟硅橡胶18份，妥尔油0.32份，氯化石蜡0.55份，棕榈蜡0.4份，硫化剂PDM 1.3份，硫化剂HTDM 1.1份，促进剂CZ 1.3份，防老剂AW 1.15份，防老剂A 1.3份，防老剂BLE 1.1份，煅烧高岭土64份，海泡石7份，亚麻纤维11.5份，椰子纤维21份，羧甲基纤维素钠1.5份。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种抗老化船舶电缆材料，其特征在于，其原料按重量份包括：氢化丁腈橡胶15-25份，丁基橡胶10-20份，三元乙丙橡胶20-30份，氟硅橡胶15-25份，妥尔油0.1-0.6份，氯化石蜡0.4-0.8份，棕榈蜡0.2-0.8份，硫化剂PDM 1-2份，硫化剂HTDM 0.5-1.5份，促进剂CZ 1-2份，防老剂AW 0.6-1.4份，防老剂A 1-2份，防老剂BLE 0.5-1.5份，煅烧高岭土50-80份，海泡石3-10份，亚麻纤维10-14份，椰子纤维15-25份，羧甲基纤维素钠1-2份。
2.根据权利要求1所述的抗老化船舶电缆材料，其特征在于，氢化丁腈橡胶、丁基橡胶、三元乙丙橡胶、氟硅橡胶的重量比为20-23：14-16：22-24：16-20。
3.根据权利要求1所述的抗老化船舶电缆材料，其特征在于，妥尔油、氯化石蜡、棕榈蜡的重量比为0.2-0.4：0.5-0.6：0.3-0.5。
4.根据权利要求1所述的抗老化船舶电缆材料，其特征在于，硫化剂PDM、硫化剂HTDM、促进剂CZ的重量比为1.2-1.4：1-1.2：1.2-1.4。
5.根据权利要求1所述的抗老化船舶电缆材料，其特征在于，防老剂AW、防老剂A、防老剂BLE的重量比为1-1.2：1.2-1.4：1-1.2。
6.根据权利要求1所述的抗老化船舶电缆材料，其特征在于，煅烧高岭土、海泡石、亚麻纤维、椰子纤维、羧甲基纤维素钠的重量比为60-70：6-8：11-12：20-22：1.4-1.6。
7.根据权利要求1所述的抗老化船舶电缆材料，其特征在于，其原料按重量份包括：氢化丁腈橡胶20-23份，丁基橡胶14-16份，三元乙丙橡胶22-24份，氟硅橡胶16-20份，妥尔油0.2-0.4份，氯化石蜡0.5-0.6份，棕榈蜡0.3-0.5份，硫化剂PDM 1.2-1.4份，硫化剂HTDM 1-1.2份，促进剂CZ 1.2-1.4份，防老剂AW 1-1.2份，防老剂A 1.2-1.4份，防老剂BLE 1-1.2份，煅烧高岭土60-70份，海泡石6-8份，亚麻纤维11-12份，椰子纤维20-22份，羧甲基纤维素钠1.4-1.6份。
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880556A (zh) * 2017-12-25 2018-04-06 洛阳名力科技开发有限公司 一种抗老化的耐磨电缆材料
CN108129720A (zh) * 2017-12-25 2018-06-08 洛阳名力科技开发有限公司 电缆材料
CN108148432A (zh) * 2017-12-25 2018-06-12 洛阳名力科技开发有限公司 一种阻燃电缆材料
CN108276685A (zh) * 2017-12-29 2018-07-13 安徽天星电缆科技有限公司 一种高拉伸强度机器人手臂扭转电缆料

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104693627A (zh) * 2015-03-11 2015-06-10 安徽弘博电缆集团有限公司 一种高强度耐腐蚀柔韧船舶电缆材料
CN105185451A (zh) * 2015-09-22 2015-12-23 晋源电气集团股份有限公司 一种船用抗老化耐腐蚀电缆
CN105175839A (zh) * 2015-09-16 2015-12-23 安徽华润仪表线缆有限公司 一种船舶用改性氢化丁腈橡胶电缆材料

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104693627A (zh) * 2015-03-11 2015-06-10 安徽弘博电缆集团有限公司 一种高强度耐腐蚀柔韧船舶电缆材料
CN105175839A (zh) * 2015-09-16 2015-12-23 安徽华润仪表线缆有限公司 一种船舶用改性氢化丁腈橡胶电缆材料
CN105185451A (zh) * 2015-09-22 2015-12-23 晋源电气集团股份有限公司 一种船用抗老化耐腐蚀电缆

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107880556A (zh) * 2017-12-25 2018-04-06 洛阳名力科技开发有限公司 一种抗老化的耐磨电缆材料
CN108129720A (zh) * 2017-12-25 2018-06-08 洛阳名力科技开发有限公司 电缆材料
CN108148432A (zh) * 2017-12-25 2018-06-12 洛阳名力科技开发有限公司 一种阻燃电缆材料
CN108276685A (zh) * 2017-12-29 2018-07-13 安徽天星电缆科技有限公司 一种高拉伸强度机器人手臂扭转电缆料

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Application publication date: 20170524