CN106700281A - Superconductor thermal ethylene propylene diene methylene rubber - Google Patents
Superconductor thermal ethylene propylene diene methylene rubber Download PDFInfo
- Publication number
- CN106700281A CN106700281A CN201611072729.5A CN201611072729A CN106700281A CN 106700281 A CN106700281 A CN 106700281A CN 201611072729 A CN201611072729 A CN 201611072729A CN 106700281 A CN106700281 A CN 106700281A
- Authority
- CN
- China
- Prior art keywords
- parts
- ethylene propylene
- propylene diene
- rubber
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 16
- 239000005060 rubber Substances 0.000 title claims abstract description 16
- 239000002887 superconductor Substances 0.000 title abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008117 stearic acid Substances 0.000 claims abstract description 8
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract description 6
- 229920002943 EPDM rubber Polymers 0.000 claims description 17
- 239000000654 additive Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- 238000010058 rubber compounding Methods 0.000 claims description 7
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 6
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 3
- 125000001246 bromo group Chemical class Br* 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002216 antistatic agent Substances 0.000 abstract 2
- 238000004073 vulcanization Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/017—Antistatic agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses superconductor thermal ethylene propylene diene methylene rubber, which is prepared from the following components: 100 parts of ethylene propylene diene methylene rubber, 60 to 70 parts of carbon black, 30 to 40 parts of special type zinc oxide, 5 to 8 parts of antistatic agent, 2 to 5 parts of stearic acid, 5 to 10 parts of antimonous oxide, 10 to 20 parts of decabromodiphenyl ether, 2 to 4 parts of vulcanizing agent, and 1 part of homogenizing agent. Through adding the special type zinc oxide, the antistatic agent and the vulcanizing agent, the thermal conductivity can be greatly improved, and the rubber produced by the invention not only has beneficial thermal conductivity but also has excellent elasticity.
Description
Technical field
The present invention relates to field of rubber technology, more particularly to a kind of heat superconducting ethylene propylene diene rubber.
Background technology
In past several years, ethylene propylene diene rubber is obtained a wide range of applications in various mechanical rubber goods, due to rubber
Glue has an insulating properties in itself, thus most heat conductive rubber electrical insulation capability, be finally by the insulating properties of particle filled composite
Determine, the filler for nonisulated type heat conductive rubber is often metal powder, graphite, carbon black, carbon fiber etc., the spy of this kind of filler
Point is, with good thermal conductivity, material is obtained heat conductivility high, but also cause the exhausted of material simultaneously
Edge hydraulic performance decline even turns into conductive material, therefore, solve the problems, such as that this class is particularly important.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of heat superconducting ethylene propylene diene rubber, by being added with special type
Zinc oxide, antistatic additive and vulcanizing agent can be greatly improved heat conductivility.
In order to solve the above problems, the invention provides a kind of heat superconducting ethylene propylene diene rubber, the rubber compounding is included：
100 parts of ethylene propylene diene rubber, carbon black 60-70 parts, extraordinary 30-40 parts of zinc oxide, antistatic additive 5-8 parts, stearic acid 2-5 parts, three
Aoxidize two antimony 5-10 parts, deca-BDE 10-20 parts, vulcanizing agent 2-4 parts, 1 part of homogenizing agents.
Further improvement is that：The rubber compounding is included：Ethylene propylene diene rubber 100, carbon black 70, extraordinary zinc oxide 40
Part, 8 parts of antistatic additive, 5 parts of stearic acid, 10 parts of antimony oxide, 20 parts of deca-BDE, 4 parts of vulcanizing agent, 1 part of homogenizing agent.
Further improvement is that：The vulcanizing agent uses oxide DCP.
The beneficial effects of the invention are as follows：Extraordinary zinc oxide is added with, the thermal conductivity factor of rubber, heat transfer property can be increased
It is good, while no blooming, not sending out coloured silk；Using antistatic, electrostatic can be in time derived, improve heat transfer property, use peroxide DCP
Vulcanization, up to 200 DEG C, not only heat conductivility is beneficial while elastic splendid for the rubber of present invention production for rubber heat resistance.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention is further described below in conjunction with embodiment, the present embodiment
It is only used for explaining the present invention, is not intended to limit the scope of the present invention..
Implement row one
This implementation row provide a kind of heat superconducting ethylene propylene diene rubber, and the rubber compounding is included：100 parts of ethylene propylene diene rubber,
70 parts of carbon black, extraordinary 40 parts of zinc oxide, 8 parts of antistatic additive, 5 parts of stearic acid, 10 parts of antimony oxide, 20 parts of deca-BDE,
4 parts of vulcanizing agent, 1 part of homogenizing agent, add up to 294 parts.
Implement row two
This implementation row provide a kind of heat superconducting ethylene propylene diene rubber, and the rubber compounding is included：100 parts of ethylene propylene diene rubber, charcoal
Black 60 parts, extraordinary 30 parts of zinc oxide, 5 parts of antistatic additive, 2 parts of stearic acid, 5 parts of antimony oxide, 10 parts of deca-BDE, vulcanization
2 parts of agent, 1 part of homogenizing agent, add up to 215 parts.
Implement row three
This implementation row provide a kind of heat superconducting ethylene propylene diene rubber, and the rubber compounding is included：100 parts of ethylene propylene diene rubber, charcoal
Black 65 parts, extraordinary 35 parts of zinc oxide, 6 parts of antistatic additive, 3 parts of stearic acid, 7 parts of antimony oxide, 15 parts of deca-BDE, vulcanization
3 parts of agent, 1 part of homogenizing agent, add up to 262 parts.
The present invention is added with extraordinary zinc oxide, can increase the thermal conductivity factor of rubber, and heat transfer property is good, while no blooming,
Do not send out coloured silk；Using antistatic, electrostatic can be in time derived, improve heat transfer property, vulcanized using peroxide DCP, rubber is heat-resisting
, up to 200 DEG C, not only heat conductivility is beneficial while elastic splendid for the rubber of present invention production for performance.
Claims (3)
1. a kind of heat superconducting ethylene propylene diene rubber, it is characterised in that the rubber compounding is included：100 parts of ethylene propylene diene rubber, charcoal
Black 60-70 parts, extraordinary 30-40 parts of zinc oxide, antistatic additive 5-8 parts, stearic acid 2-5 parts, antimony oxide 5-10 parts, ten bromines two
Phenylate 10-20 parts, vulcanizing agent 2-4 parts, 1 part of homogenizing agent.
2. a kind of heat superconducting ethylene propylene diene rubber as claimed in claim 1, it is characterised in that：The rubber compounding is included：Three
100 parts of first EP rubbers, 70 parts of carbon black, extraordinary 40 parts of zinc oxide, 8 parts of antistatic additive, 5 parts of stearic acid, 10 parts of antimony oxide,
20 parts of deca-BDE, 4 parts of vulcanizing agent, 1 part of homogenizing agent.
3. a kind of heat superconducting ethylene propylene diene rubber as described in claim 1 and 2 is any, it is characterised in that：The vulcanizing agent is adopted
Use oxide DCP.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072729.5A CN106700281A (en) | 2016-11-29 | 2016-11-29 | Superconductor thermal ethylene propylene diene methylene rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611072729.5A CN106700281A (en) | 2016-11-29 | 2016-11-29 | Superconductor thermal ethylene propylene diene methylene rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106700281A true CN106700281A (en) | 2017-05-24 |
Family
ID=58934202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611072729.5A Pending CN106700281A (en) | 2016-11-29 | 2016-11-29 | Superconductor thermal ethylene propylene diene methylene rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106700281A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845177A (en) * | 2010-04-30 | 2010-09-29 | 惠州市成琳橡胶制品有限公司 | Ethylene-propylene-diene monomer (EPDM) flame-retardant rubber for automobile and preparation method thereof |
| CN102504417A (en) * | 2011-10-24 | 2012-06-20 | 中特华星电缆股份有限公司 | Antimonous oxide and decabromodiphenyl ether-modified ternary ethylene-propylene rubber |
| CN102504358A (en) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | High-heat-conductivity rubber composite material and preparation method thereof |
| CN102924829A (en) * | 2012-11-08 | 2013-02-13 | 沈阳化工大学 | Zinc oxide pre-dispersion master colloidal particle and preparation method thereof |
| CN103254511A (en) * | 2012-02-20 | 2013-08-21 | 中国石油化工股份有限公司 | Ethylene-propylene-diene monomer |
| CN104403211A (en) * | 2014-11-09 | 2015-03-11 | 衡水百金复合材料科技有限公司 | Ethylene propylene diene monomer rubber with low-temperature vulcanization property and waterstop as well as manufacturing method of waterstop |
-
2016
- 2016-11-29 CN CN201611072729.5A patent/CN106700281A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845177A (en) * | 2010-04-30 | 2010-09-29 | 惠州市成琳橡胶制品有限公司 | Ethylene-propylene-diene monomer (EPDM) flame-retardant rubber for automobile and preparation method thereof |
| CN102504417A (en) * | 2011-10-24 | 2012-06-20 | 中特华星电缆股份有限公司 | Antimonous oxide and decabromodiphenyl ether-modified ternary ethylene-propylene rubber |
| CN102504358A (en) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | High-heat-conductivity rubber composite material and preparation method thereof |
| CN103254511A (en) * | 2012-02-20 | 2013-08-21 | 中国石油化工股份有限公司 | Ethylene-propylene-diene monomer |
| CN102924829A (en) * | 2012-11-08 | 2013-02-13 | 沈阳化工大学 | Zinc oxide pre-dispersion master colloidal particle and preparation method thereof |
| CN104403211A (en) * | 2014-11-09 | 2015-03-11 | 衡水百金复合材料科技有限公司 | Ethylene propylene diene monomer rubber with low-temperature vulcanization property and waterstop as well as manufacturing method of waterstop |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170524 |
|
| RJ01 | Rejection of invention patent application after publication |