CN106905567A - A kind of conductive rubber - Google Patents

A kind of conductive rubber Download PDF

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Publication number
CN106905567A
CN106905567A CN201510970408.6A CN201510970408A CN106905567A CN 106905567 A CN106905567 A CN 106905567A CN 201510970408 A CN201510970408 A CN 201510970408A CN 106905567 A CN106905567 A CN 106905567A
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CN
China
Prior art keywords
parts
rubber
conductive
conductive rubber
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510970408.6A
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Chinese (zh)
Inventor
彭志成
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Individual
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Individual
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Publication date
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Priority to CN201510970408.6A priority Critical patent/CN106905567A/en
Publication of CN106905567A publication Critical patent/CN106905567A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to elastomeric material, specifically a kind of conductive rubber.It is by the material composition of following parts by weight:Natural rubber 25-45 parts, butadiene-styrene rubber 15-25 parts, nitrile rubber 15-25 parts, hydrogenated nitrile-butadiene rubber 15-25 parts, XNBR 10-15 parts, graphene oxide 3-5 parts of electroplate, vulcanizing system 8-12 parts, coupling agent 15-20 parts, fire retardant 10-15 parts, conductive powder body 15-20 parts, colouring agent 3-5 parts, antioxidant 1-3 parts, plasticizer 0.5-0.8 parts, surfactant 0.5-0.8 parts, ethyl acetate 15-25 parts, nano silicon 15-20 parts, nano-aluminium oxide Al2O325-35 parts.The conductive rubber that the present invention is provided, with excellent electric conductivity and shield effectiveness, excellent electric insulating quality and good gas permeability, good oxidative resistance and resistant of high or low temperature, ageing-resistant performance are good.

Description

A kind of conductive rubber
Technical field
The present invention relates to elastomeric material, specifically a kind of conductive rubber.
Background technology
Conductive rubber is that conductive particle is evenly distributed in silicon rubber by glass silvering, aluminium is silver-plated, silver-colored etc., and conduction is made by pressure Particle is contacted, and reaches good electric conductivity.Military and commercial have application.Its Main Function is to seal and be electromagnetically shielded. Product can be molded or extrusion molding, have on chip or other punching shapes available.Shielding properties is up to 120dB (10GHz). It is divided into CONSIL-NC (silicon rubber is filled out in graphite nickel plating) CONSIL-V silver filled silicon rubber extrusions pad) (aluminium is silver-plated for CONSIL-A Filling out silicon rubber) CONSIL-N (nickel is silver-plated to fill out silicon rubber) CONSIL-C (copper is silver-plated to fill out silicon rubber) SC-CONSIL (fill out by graphite (fine silver fills out silicon rubber CONSIL-II (silver fills out silicon rubber molded gasket) etc. to silicon rubber CONSIL-R.
The content of the invention
Big the invention provides a kind of tensile strength in order to solve the above problems, high conductivity is low to be exceeded and oozes threshold values, high performance leads Electric rubber.
Technical scheme is as follows:
A kind of conductive rubber, is by the material composition of following parts by weight:Natural rubber 25-45 parts, butadiene-styrene rubber 15-25 parts, Nitrile rubber 15-25 parts, hydrogenated nitrile-butadiene rubber 15-25 parts, XNBR 10-15 parts, the graphite oxide of electroplate Alkene 3-5 parts, vulcanizing system 8-12 parts, coupling agent 15-20 parts, fire retardant 10-15 parts, conductive powder body 15-20 parts, Toner 3-5 parts, antioxidant 1-3 parts, plasticizer 0.5-0.8 parts, surfactant 0.5-0.8 parts, ethyl acetate 15-25 Part, nano silicon 15-20 parts, nano-aluminium oxide Al2O325-35 parts.
Further, above-mentioned conductive rubber, state conductive powder body for acetylene carbon black, in superb abrasion resistant carbon black N220, surfactant It is carboxymethylcellulose calcium.
Beneficial effects of the present invention:
Compared with prior art, the conductive rubber that the present invention is provided, with excellent electric conductivity and shield effectiveness, excellent is electric Insulating properties and good gas permeability, good oxidative resistance and resistant of high or low temperature, ageing-resistant performance are good.
Specific embodiment
Embodiment 1
A kind of conductive rubber, is by the material composition of following parts by weight:25 parts of natural rubber, 15 parts of butadiene-styrene rubber, butyronitrile 15 parts of rubber, 15 parts of hydrogenated nitrile-butadiene rubber, 10 parts of XNBR, 3 parts of the graphene oxide of electroplate, vulcanization body Be 8 parts, 15 parts of coupling agent, 10 parts of fire retardant, 15 parts of conductive powder body, 3 parts of colouring agent, 1 part of antioxidant, plasticizer 0.5 part, 0.5 part of surfactant, 15 parts of ethyl acetate, 15 parts of nano silicon, nano-aluminium oxide Al2O325 Part.
Further, above-mentioned conductive rubber, state conductive powder body for acetylene carbon black, in superb abrasion resistant carbon black N220, surfactant It is carboxymethylcellulose calcium.
Embodiment 2
A kind of conductive rubber, is by the material composition of following parts by weight:45 parts of natural rubber, 25 parts of butadiene-styrene rubber, butyronitrile 25 parts of rubber, 25 parts of hydrogenated nitrile-butadiene rubber, 15 parts of XNBR, 5 parts of the graphene oxide of electroplate, vulcanization body Be 12 parts, 20 parts of coupling agent, 15 parts of fire retardant, 120 parts of conductive powder body, 5 parts of colouring agent, 3 parts of antioxidant, 0.8 part of plasticizer, 0.8 part of surfactant, 25 parts of ethyl acetate, 20 parts of nano silicon, nano-aluminium oxide Al2O335 parts.
Further, above-mentioned conductive rubber, state conductive powder body for acetylene carbon black, in superb abrasion resistant carbon black N220, surfactant It is carboxymethylcellulose calcium.
Embodiment 3
A kind of conductive rubber, is by the material composition of following parts by weight:35 parts of natural rubber, 20 parts of butadiene-styrene rubber, butyronitrile 20 parts of rubber, 20 parts of hydrogenated nitrile-butadiene rubber, 12 parts of XNBR, 4 parts of the graphene oxide of electroplate, vulcanization body Be 10 parts, 18 parts of coupling agent, 12 parts of fire retardant, the wechat public platform of conductive powder body 1 log in 8 parts, 4 parts of colouring agent, 2 parts of oxidant, 0.7 part of plasticizer, 0.6 part of surfactant, 20 parts of ethyl acetate, 18 parts of nano silicon, receive Rice alundum (Al2O3) Al2O330Part.
Further, above-mentioned conductive rubber, state conductive powder body for acetylene carbon black, in superb abrasion resistant carbon black N220, surfactant It is carboxymethylcellulose calcium.

Claims (3)

1. a kind of conductive rubber, it is characterised in that be by the material composition of following parts by weight:Natural rubber 25-45 parts, fourth 15-25 parts of benzene rubber, nitrile rubber 15-25 parts, hydrogenated nitrile-butadiene rubber 15-25 parts, XNBR 10-15 parts, table Face silver-plated graphene oxide 3-5 parts, vulcanizing system 8-12 parts, coupling agent 15-20 parts, fire retardant 10-15 parts, conduction Powder 15-20 parts, colouring agent 3-5 parts, antioxidant 1-3 parts, plasticizer 0.5-0.8 parts, surfactant 0.5-0.8 Part, ethyl acetate 15-25 parts, nano silicon 15-20 parts, nano-aluminium oxide Al2O325-35 parts.
2. as claimed in claim 1, a kind of conductive rubber, it is characterised in that the conductive powder body be acetylene carbon black, in it is superb Abrasion resistant carbon black N220.
3. as claimed in claim 1, a kind of conductive rubber, it is characterised in that the surfactant is carboxymethylcellulose calcium.
CN201510970408.6A 2015-12-22 2015-12-22 A kind of conductive rubber Pending CN106905567A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510970408.6A CN106905567A (en) 2015-12-22 2015-12-22 A kind of conductive rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510970408.6A CN106905567A (en) 2015-12-22 2015-12-22 A kind of conductive rubber

Publications (1)

Publication Number Publication Date
CN106905567A true CN106905567A (en) 2017-06-30

Family

ID=59200674

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510970408.6A Pending CN106905567A (en) 2015-12-22 2015-12-22 A kind of conductive rubber

Country Status (1)

Country Link
CN (1) CN106905567A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286398A (en) * 2017-08-01 2017-10-24 合肥安力电力工程有限公司 A kind of flame-retardant conductive rubber and preparation method thereof
CN107417997A (en) * 2017-09-29 2017-12-01 徐州九鼎机电总厂 A kind of rubber composite of high content graphene
CN107674267A (en) * 2017-11-06 2018-02-09 方文成 A kind of conductive rubber and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107286398A (en) * 2017-08-01 2017-10-24 合肥安力电力工程有限公司 A kind of flame-retardant conductive rubber and preparation method thereof
CN107417997A (en) * 2017-09-29 2017-12-01 徐州九鼎机电总厂 A kind of rubber composite of high content graphene
CN107674267A (en) * 2017-11-06 2018-02-09 方文成 A kind of conductive rubber and preparation method thereof

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Application publication date: 20170630