CN106699322A - Nitrogen-supplementing embedded growth-promoting agent, and preparation method and application thereof - Google Patents

Nitrogen-supplementing embedded growth-promoting agent, and preparation method and application thereof Download PDF

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Publication number
CN106699322A
CN106699322A CN201510623647.4A CN201510623647A CN106699322A CN 106699322 A CN106699322 A CN 106699322A CN 201510623647 A CN201510623647 A CN 201510623647A CN 106699322 A CN106699322 A CN 106699322A
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nitrogen
growth accelerator
nitrogen type
growth
embedding
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Inventor
苏蔚潇
贠军贤
田兵
高云玲
张颂红
戴商
单李深
叶岩磊
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BEIJING FITWELL TECHNOLOGY Co Ltd
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BEIJING FITWELL TECHNOLOGY Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/40Protecting water resources
    • Y02A20/402River restoration

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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cultivation Of Plants (AREA)

Abstract

The invention especially relates to a nitrogen-supplementing embedded growth-promoting agent, and a preparation method and application thereof, belonging to the technical field of ecological and environmental protection. The nitrogen-supplementing embedded growth-promoting agent is porous particles and comprises an embedding medium skeleton, and nitrogen-source nutritional components and antioxidation components embedded in the embedding medium skeleton. The nitrogen-supplementing embedded growth-promoting agent has a highly-prosperous pore system and a great pore size; the mass transfer resistance of the nutritional components in pores is small and the nutritional components are utilized by plants and microbes after slow release in a wetland environment; so the loss of the nutritional components is reduced, the utilization rate of the growth-promoting agent is high in the process of plant and microbial restoration, and the growth-promoting agent is applied to cooperative plant and microbial restoration in river mouths or coastal wetland lacking in nitrogen. The preparation method for the nitrogen-supplementing embedded growth-promoting agent provided by the invention is simple and easily practicable; the prepared embedded growth-promoting agent has controllable uniform particle size and excellent performance; industrial scaling-up preparation of the agent can be realized; and the embedded growth-promoting agent has good application prospects in fields like marine ecological engineering and environmental protection.

Description

One kind mends nitrogen type embedding growth accelerator and its preparation method and application
Technical field
The present invention relates to ecological and environmental protection technical field, mended in particular to one kind Nitrogen type embedding growth accelerator and its preparation method and application.
Background technology
Estuary wetland and coastal tidal wetland are influenceed by Lu Yuan and extra large source pollutants, its Water body, vegetation, neritic organism, microorganism and whole ecosystem persistence deteriorate, and ecology is repaiied Multiple problem has been subject to most attention.Using the salt-tolerant plant and microorganism that are grown under littoral environment Collective effect, can greatly improve degraded repairing effect of the plant to wetland pollutant, be near Several years important development directions of wetland recovery project technology, are also to solve seashore wetland oil etc. The effective way of Organic Pollution.
However, the water body of estuary wetland and coastal tidal wetland is larger, salt content is high, Plant growing condition is harsh.Contained plant and microorganism growth process in these wetland soils The various nutrition compositions for needing are uneven, apply common fertilizer and are lost in wetland quickly, damage Lose it is big, the need for limiting plant growth and microbial metabolism, so as to have impact on plant with it is micro- The effect that biological synergetic is repaired.Although the existing tradition slow-release fertilizer of agriculture field and moisturizing technology, But mainly for land cereal crops plantation, be frequently not suitable for the growth of strand plant; It is embedding skeleton with the artificial synthesized macromolecular material such as polyethylene, polypropylene, polyvinyl alcohol Slow-release fertilizer, its fertiliser granulates compact structure, diffusion mass transfer of the nutrition composition in soil be poor, The quick growth of plant phase it is effective using being difficult, and these matrix scaffold materials soil from Right boundary is difficult degraded, often brings secondary environmental problems.
In view of this, it is special to propose the present invention.
The content of the invention
The first object of the present invention is to provide a kind of nitrogen type of mending to embed growth accelerator, with height Flourishing pore system is spent, aperture is big, and nutrition composition is small in intrapore resistance to mass tranfer, Utilized by plant and microorganism after slow release in Wetland Environment, it is possible to reduce nutrition composition It is lost in, the utilization rate during plant and microorganism remediation is high;The growth stimulator can be dropped completely Solution, and utilized by microorganism, it is to avoid secondary pollution problem, with good environmental benefit And security performance.
The second object of the present invention is to provide a kind of described nitrogen type of mending to embed growth accelerator Preparation method, preparation method is simple, easy to operate, and embeds the size controlling of growth accelerator Uniformly, can parallel industrialize amplification to prepare, in the field such as marine ecology engineering and environmental protection Have broad application prospects.
The third object of the present invention is that the benefit nitrogen type described in offer embeds growth accelerator in river The purposes of the biological prosthetic aspect of mouth, Haikou or wetland.
In order to realize above-mentioned purpose of the invention, spy uses following technical scheme:
One kind mends nitrogen type embedding growth accelerator, and the benefit nitrogen type embedding growth accelerator is porous Grain, the porous particle include nitrogen source nutrition composition of embedding medium skeleton and its internal embedding and Antioxidant composition.
The benefit nitrogen type embedding growth accelerator that the present invention is provided, embedding skeleton has highly developed Pore system, aperture is big, and nitrogen source nutrition composition and antioxidant composition, battalion are embedded in skeleton Support component small in intrapore resistance to mass tranfer, in the Wetland Environment after slow release by plant and Microorganism utilizes, it is possible to reduce during the loss of nutrition composition, plant and microorganism remediation Utilization rate it is high, for nitrogen lack or the river mouth of deficiency or the plant of seashore wetland and microorganism Collaboration is repaired.
Further, the density for mending nitrogen type embedding growth accelerator is 1050~1070 kg/m3, particle diameter is 2~5mm, and aperture is 0.1~10 μm, and porosity is 63~85%.
The benefit nitrogen type embedding growth accelerator of the aperture and porosity can preferably store nitrogen source nutrition Component, and make the nutrition composition small in intrapore resistance to mass tranfer, reach preferably sustained release effect Really.
The particle diameter for mending nitrogen type embedding growth accelerator is 2~5mm.Such as in certain embodiments, The particle diameter for mending nitrogen type embedding growth accelerator is 2mm;In certain embodiments, nitrogen type bag is mended The particle diameter for burying growth accelerator is 3mm;In certain embodiments, nitrogen type embedding growth promotion is mended The particle diameter of agent is 4mm;In certain embodiments, the particle diameter that nitrogen type embeds growth accelerator is mended It is 5mm, etc..
The density for mending nitrogen type embedding growth accelerator is 1050~1070kg/m3.Such as in some realities Apply in example, the density for mending nitrogen type embedding growth accelerator is 1050kg/m3;In some embodiments In, the density for mending nitrogen type embedding growth accelerator is 1060kg/m3;In certain embodiments, The density for mending nitrogen type embedding growth accelerator is 1065kg/m3;In certain embodiments, nitrogen is mended The density of type embedding growth accelerator is 1070kg/m3
Preferably, the embedding medium skeleton reacts system by degradable host material and crosslinking agent Into.
Degradable host material can select marine natural material, and it is obtained with crosslinking agent reaction Porous particle as embedding skeleton.Due to selecting marine natural material, can be completely degraded, And utilized by microorganism, it is to avoid secondary pollution problem, with good environmental benefit and peace Full performance.In order to further reduce the infringement that marine natural material is caused to environment, ocean day Right material is preferably food-grade marine natural material.
Preferably, the crosslinking agent is calcium salt, more preferably calcium chloride.
Preferably, the embedding medium skeleton is alginate cross-linked gel;It is highly preferred that institute Alginate cross-linked gel is stated to be formed by the aqueous solution crosslinking of sodium alginate and calcium salt.
Sodium alginate may be made with the alginate of super large hole with the reactant aqueous solution of calcium salt Cross-linked gel, the function with excellent deposit and sustained release.
Verified through test of many times, appropriate antioxidant composition causes that obtained nitrogen type of mending is embedded Growth accelerator performance is more excellent, it is preferable that the antioxidant composition is in the benefit nitrogen type embedding The mass content of growth accelerator is 0.35%~0.8%.If antioxidant composition mass content is at some Can be 0.35% in embodiment, or 0.5%, or 0.6%, or 0.7%, or 0.8% etc..
Verified through test of many times, both ensure to carry as far as possible many nitrogen source nutrition compositions, and Good slow release effect is reached, while being dropped the porous particle that nutrition composition is released Solution absorbs, it is preferable that the nitrogen source nutrition composition is in the benefit nitrogen type embedding growth accelerator Mass content is 7.2%~33%.In certain embodiments, nitrogen source nutrition composition mass content It is 7.2%;In certain embodiments, nitrogen source nutrition composition mass content is 8%;At some In embodiment, nitrogen source nutrition composition mass content is 12%;In certain embodiments, nitrogen source Nutrition composition mass content is 15%;In certain embodiments, nitrogen source nutrition composition quality contains Measure is 20%;In certain embodiments, nitrogen source nutrition composition mass content is 25%;One In a little embodiments, nitrogen source nutrition composition mass content is 30%;In certain embodiments, nitrogen Source nutrition composition mass content is 33%.
Nitrogen source nutrition composition is correspondingly selected according to different biological demands, is such as used to plant The nitrogen source of thing and microorganism then selects to be applied to the nitrogen source of plant and microorganism.Preferably, institute Nitrogen source nutrition composition is stated for urea.It is readily susceptible to absorb nitrogen source by plant and microorganism, with more Mend its demand to nitrogen source.
In order to further coordinate between embedding medium skeleton, nitrogen source nutrition composition and antioxidant composition Effect relation, it is preferable that the embedding medium skeleton is in the benefit nitrogen type embedding growth accelerator Mass content be 2%~6%.The size of size, porosity according to aperture, at some In embodiment, the mass content of embedding medium skeleton is 2%;In certain embodiments, embed The mass content of agent skeleton is 3%;In certain embodiments, the quality of embedding medium skeleton contains Measure is 5%;In certain embodiments, the mass content of embedding medium skeleton is 6%, etc..
In addition, mending nitrogen type embeds growth accelerator except comprising antioxidant composition, nitrogen source nutrition group Divide with outside embedding medium skeleton, also include moisture, i.e., balance of water.
Present invention also offers the preparation method for mending nitrogen type embedding growth accelerator, including following step Suddenly:
Host material, nitrogen source nutrition composition and the antioxidant composition that embedding medium skeleton will be prepared add Water is made suspension, freezing and crystallizing pore is then carried out in the solution of crosslinking agent and crosslinking is anti- Should, obtain the benefit nitrogen type embedding growth accelerator;
Wherein, in suspension:The mass concentration of host material is 1%~3%, nitrogen source nutrition Constituent mass concentration is 6%~15%, and antioxidant composition mass concentration is 0.1%~0.5%;
Cross-linking agent solution mass concentration is 3%~30%, and the volume of the cross-linking agent solution is outstanding 10~100 times of supernatant liquid volume, cross-linking reaction time is 0.5~10h.
What the present invention was provided mends the preparation method that nitrogen type embeds growth accelerator, first by matrix material Material, nitrogen source nutrition composition and antioxidant composition add water and are made the suspension of certain concentration, so that Each component is distributed homogeneous, then crosslinked dose of crosslinked action again, and obtained benefit nitrogen type embedding promotees Growth stimulator uniform component, nutrition composition is small in intrapore resistance to mass tranfer, in Wetland Environment Utilized by plant and microorganism after slow release, reduce the loss of nutrition composition.And the party Method is simple, easy to operate.
Preferably, the crosslinking agent is calcium salt, more preferably calcium chloride.
The content of each composition is controlled according to demand, such as in certain embodiments, in suspension: The mass concentration of host material is 1%, and nitrogen source nutrition composition mass concentration is 6%, anti-oxidant Constituent mass concentration is 0.1%;Cross-linking agent solution mass concentration is 10%, cross-linking agent solution Volume is 20 times of suspension vol, and cross-linking reaction time is 5h.
In certain embodiments, in suspension:The mass concentration of host material is 2%, nitrogen Source nutrition composition mass concentration is 8%, and antioxidant composition mass concentration is 0.3%;Crosslinking agent Concentration of polymer solution is 3%, and the volume of cross-linking agent solution is 50 times of suspension vol, is handed over The connection reaction time is 0.5h.
In certain embodiments, in suspension:The mass concentration of host material is 1.5%, nitrogen Source nutrition composition mass concentration is 10%, and antioxidant composition mass concentration is 0.4%;Crosslinking agent Concentration of polymer solution is 30%, and the volume of cross-linking agent solution is 10 times of suspension vol, Cross-linking reaction time is 3h.
In certain embodiments, in suspension:The mass concentration of host material is 3%, nitrogen Source nutrition composition mass concentration is 15%, and antioxidant composition mass concentration is 0.5%;Crosslinking agent Concentration of polymer solution is 10%, and the volume of cross-linking agent solution is 100 times of suspension vol, Cross-linking reaction time is 10h.
Further, the suspension is prepared first with micro passage reaction turns into size uniform Hanging drop, then freezing and crystallizing pore and cross-linking reaction are carried out in cross-linking agent solution.
By the hanging drop that size uniform is prepared into micro passage reaction so that final system The size controlling of the embedding growth accelerator for obtaining is uniform, can parallel industrialize amplification and prepare, in sea The field such as foreign ecological engineering and environmental protection has broad application prospects.
Growth accelerator is embedded at river mouth, Haikou or wet present invention also offers described benefit nitrogen type The purposes of the biological prosthetic aspect on ground.
Further, it is described it is biological prosthetic be the collaboration reparation of plant and microorganism.
The benefit nitrogen type embedding growth accelerator that the present invention is provided, according to the difference of use environment, tool There are different slow release effects, such as used in the very big waters of current, then nitrogen source battalion therein Foster component constantly is sustained out, and nitrogen source nutrition composition therein is lost in comparatively fast, typically exists Nitrogen source nutrition composition therein can be lost within more than 5 days;And in the water of current very little Domain uses, then maintain certain concentration, nitrogen therein after nitrogen source nutrition composition sustained release therein Source nutrition composition is lost in slower;And used in soil, then nitrogen source nutrition composition therein delays Certain concentration is maintained after releasing, nitrogen source nutrition composition therein is lost in slower, nitrogen source therein Nutrition composition can maintain some months.
Compared with prior art, beneficial effects of the present invention are:
(1) present invention provide benefit nitrogen type embedding growth accelerator can provide plant growth and Microbial metabolism need nitrogen nutrition component, can be used for nitrogen lack or deficiency river mouth or The plant of seashore wetland and microorganism collaboration are repaired.
(2) what the present invention was provided mends the nitrogen source nutrition composition in nitrogen type embedding growth accelerator It is embedded among embedding medium skeleton, by plant and micro- after slow release in the Wetland Environment Biological utilisation, it is possible to reduce the loss of nutrition composition;Meanwhile, the benefit that the present invention is provided Nitrogen type embedding growth accelerator has highly developed pore system, and aperture is big, nutrition group Divide, utilization rate plant and microorganism remediation during small in intrapore resistance to mass tranfer It is high.
(3) the benefit nitrogen type embedding growth accelerator matrix scaffold material that the present invention is provided is profit It is prepared from food-grade natural material from ocean, biological safety is excellent, It is pollution-free, can be degradable, and utilized by microorganism, it is to avoid secondary pollution problem, With good environmental benefit and security performance.
(4) preparation method of the benefit nitrogen type embedding growth accelerator that the present invention is provided is simple, It is easy to operate, and the size controlling of embedding growth accelerator is uniform, excellent performance, and energy Preparation is amplified in parallel industrialization, is had in the field such as marine ecology engineering and environmental protection Wide application prospect.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but this Art personnel will be understood that, the following example is merely to illustrate the present invention, without that should regard It is limitation the scope of the present invention.Unreceipted actual conditions person in embodiment, according to normal condition Or the condition of manufacturer's suggestion is carried out.Agents useful for same or the unreceipted production firm person of instrument, For can be by the conventional products of commercially available acquisition.
Embodiment 1
Nitrogen type embedding growth accelerator is mended to be prepared as follows:
3L is contained the water in suspension of sodium alginate 1%, urea 6%, antioxidant 0.28% Solution, it is equal as size to be prepared with parallel microchannel reactor under the flow velocity of 180cm/min Even hanging drop, in 30L 30%Ca2+Solution (CaCl2) in carry out freezing and crystallizing pore and Cross-linking reaction 0.5h, dries through follow-up appropriateness, obtains mending nitrogen type embedding growth accelerator.
The benefit nitrogen type embedding growth accelerator density 1050kg/m for obtaining3, particle diameter 2mm, aperture 0.5~10 μm, porosity 71~85%, nitrogen component mass content 7.2%, containing anti-oxidant Agent constituent mass content is 0.45%, embedding medium skeleton content 2%, balance of water.
The seashore wetland that obtained benefit nitrogen type embedding growth accelerator delivers oil pollution is planted Thing cooperates with wetland reparation with microorganism, and the plant for selecting to give birth to 20~25 plants then respectively is sample This, 3~3.5 square metres of area is one group, applies to mend nitrogen type embedding growth accelerator 100g growth-promotings Agent long/square metre.
Available nitrogen increases by 158%, the rate of release 2 of available nitrogen in treatment post analysis wetland soil Mg/kg soil/day, about 1 times of microbial biomass increase in wetland soil after a week.
Embodiment 2
Nitrogen type embedding growth accelerator is mended to be prepared as follows:
600ml is contained the suspension of sodium alginate 3%, urea 15%, antioxidant 0.1% The aqueous solution, size is turned into be prepared with parallel microchannel reactor under the flow velocity of 50cm/min Uniform hanging drop, in 60L 15%Ca2+Solution (CaCl2) in carry out freezing and crystallizing pore With cross-linking reaction 10h, dried through follow-up appropriateness, obtain mending nitrogen type embedding growth accelerator.
Obtained benefit nitrogen type embedding growth accelerator density 1070kg/m3, particle diameter 5mm, aperture 0.1~5 μm, porosity 63~80%, nitrogen component mass content 33%, containing anti-oxidant Agent constituent mass content is 0.35%, embedding medium skeleton content 6%, balance of water.
The seashore wetland that obtained benefit nitrogen type embedding growth accelerator delivers oil pollution is planted Thing cooperates with wetland reparation with microorganism, and the plant for selecting to give birth to 25 plants or so then respectively is sample This, 3.5 square metres of area is one group, applies to mend nitrogen type embedding growth accelerator 100g growth promotions Agent/square metre.
Available nitrogen increases by 123%, the rate of release of available nitrogen in treatment post analysis wetland soil 2.2mg/kg soil/day, about 1 times of microbial biomass increase in wetland soil after a week.
Embodiment 3
Nitrogen type embedding growth accelerator is mended to be prepared as follows:
5L is contained the water in suspension of sodium alginate 2%, urea 13%, antioxidant 0.5% Solution, it is equal as size to be prepared with parallel microchannel reactor under the flow velocity of 300cm/min Even hanging drop, in 60L 3%Ca2+Solution (CaCl2) in carry out freezing and crystallizing pore and Cross-linking reaction 5h, dries through follow-up appropriateness, obtains mending nitrogen type embedding growth accelerator.
Obtained benefit nitrogen type embedding growth accelerator density 1060kg/m3, particle diameter 4mm, aperture 0.1~10 μm, porosity 68~85%, nitrogen component mass content 18%, containing anti-oxidant Agent constituent mass content is 0.8%, embedding medium skeleton content 3%, balance of water.
The seashore wetland that obtained benefit nitrogen type embedding growth accelerator delivers oil pollution is planted Thing cooperates with wetland reparation with microorganism, and the plant for selecting to give birth to 20 plants or so then respectively is sample This, 3 square metres of area is one group, applies to mend nitrogen type embedding growth accelerator 50g growth accelerators / square metre.
Available nitrogen increases by 47%, the rate of release 1.9 of available nitrogen in treatment post analysis wetland soil Mg/kg soil/day, about 1.2 times of microbial biomass increase in wetland soil after a week.
Embodiment 4
Nitrogen type embedding growth accelerator is mended to be prepared as follows:
1L is contained the water in suspension of sodium alginate 2%, urea 12%, antioxidant 0.2% Solution, it is equal as size to be prepared with parallel microchannel reactor under the flow velocity of 200cm/min Even hanging drop, in 50L 15%Ca2+Solution (CaCl2) in carry out freezing and crystallizing pore and Cross-linking reaction 1h, dries through follow-up appropriateness, obtains mending nitrogen type embedding growth accelerator.
Obtained benefit nitrogen type embedding growth accelerator density 1062kg/m3, particle diameter 3.5mm, hole 0.1~10 μm of footpath, porosity 65~84%, nitrogen component mass content 25%, containing antioxygen Agent constituent mass content is 0.5%, embedding medium skeleton content 3.5%, balance of water.
The seashore wetland that obtained benefit nitrogen type embedding growth accelerator delivers oil pollution is planted Thing cooperates with wetland reparation with microorganism, and the plant for selecting to give birth to 20 plants or so then respectively is sample This, 3 square metres of area is one group, applies to mend nitrogen type embedding growth accelerator 80g growth accelerators / square metre.
Available nitrogen increases by 59.5%, the rate of release of available nitrogen in treatment post analysis wetland soil 1.6mg/kg soil/day, about 1.3 times of microbial biomass increase in wetland soil after a week.
In above-described embodiment, the mobility size of the current according to waters is mended the embedding of nitrogen type and is promoted The deenergized period of growth stimulator is 5~90 days.
The benefit nitrogen type embedding growth accelerator that the present invention is provided has the interconnected hole system of prosperity System, host material safety and can be degradable;Nitrogen source nutrition composition is embedded in skeleton and is resisted Oxidation component, nutrition composition is small in intrapore resistance to mass tranfer, is slowly released in Wetland Environment Utilized by plant and microorganism after putting, it is possible to reduce the loss of nutrition composition, plant and micro- life Utilization rate in thing repair process is high, is suitable to promote to plant in the wetlands such as river mouth, beach beach Thing cooperates with restoration of the ecosystem process with rhizosphere microbial, marine ecology engineering, soil remediation and Field of environment protection has broad prospect of application.
Although illustrate and describing the present invention with specific embodiment, but will be appreciated that Can make without departing from the spirit and scope of the present invention many other changes and Modification.It is, therefore, intended that including belonging in the scope of the invention in the following claims All such changes and modifications.

Claims (10)

1. it is a kind of to mend nitrogen type embedding growth accelerator, it is characterised in that the benefit nitrogen type embedding Growth accelerator is porous particle, and the porous particle includes embedding medium skeleton and its internal embedding Nitrogen source nutrition composition and antioxidant composition.
2. benefit nitrogen type according to claim 1 embeds growth accelerator, it is characterised in that The density for mending nitrogen type embedding growth accelerator is 1050~1070kg/m3, particle diameter is 2~5 Mm, aperture is 0.1~10 μm, and porosity is 63~85%.
3. the benefit nitrogen type according to claim any one of 1-2 embeds growth accelerator, its It is characterised by, the embedding medium skeleton is made up of degradable host material with crosslinking agent reaction; Preferably, the embedding medium skeleton is alginate cross-linked gel;It is highly preferred that the sea Alginates cross-linked gel is formed by the aqueous solution crosslinking of sodium alginate and calcium salt.
4. benefit nitrogen type according to claim 1 embeds growth accelerator, it is characterised in that Mass content of the antioxidant composition in the benefit nitrogen type embedding growth accelerator be 0.35%~0.8%.
5. benefit nitrogen type according to claim 1 embeds growth accelerator, it is characterised in that The nitrogen source nutrition composition is in the mass content of the benefit nitrogen type embedding growth accelerator 7.2%~33%;The nitrogen source nutrition composition is preferably urea.
6. benefit nitrogen type according to claim 1 embeds growth accelerator, it is characterised in that The embedding medium skeleton the benefit nitrogen type embedding growth accelerator mass content for 2%~ 6%.
7. the preparation side that nitrogen type embeds growth accelerator is mended described in any one of claim 1-6 Method, it is characterised in that comprise the following steps:
Host material, nitrogen source nutrition composition and the antioxidant composition that embedding medium skeleton will be prepared add Water is made suspension, freezing and crystallizing pore is then carried out in the solution of crosslinking agent and crosslinking is anti- Should, obtain the benefit nitrogen type embedding growth accelerator;
Wherein, in suspension:The mass concentration of host material is 1%~3%, nitrogen source nutrition Constituent mass concentration is 6%~15%, and antioxidant composition mass concentration is 0.1%~0.5%;
Cross-linking agent solution mass concentration is 3%~30%, and the volume of the cross-linking agent solution is institute State suspension vol 10~100 times, cross-linking reaction time is 0.5~10h.
8. preparation method according to claim 7, it is characterised in that the suspension Liquid prepares the hanging drop as size uniform first with micro passage reaction, then in crosslinking agent Freezing and crystallizing pore and cross-linking reaction are carried out in solution.
9. the benefit nitrogen type described in any one of claim 1-8 embeds growth accelerator in river mouth, sea The purposes of the biological prosthetic aspect of mouth or wetland.
10. purposes according to claim 9, it is characterised in that described biological prosthetic It is the collaboration reparation of plant and microorganism.
CN201510623647.4A 2015-09-25 2015-09-25 Nitrogen-supplementing embedded growth-promoting agent, and preparation method and application thereof Pending CN106699322A (en)

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Application publication date: 20170524