CN106693441A - Novel extraction device for extracting nickel sulfate from waste batteries - Google Patents
Novel extraction device for extracting nickel sulfate from waste batteries Download PDFInfo
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- CN106693441A CN106693441A CN201710151101.2A CN201710151101A CN106693441A CN 106693441 A CN106693441 A CN 106693441A CN 201710151101 A CN201710151101 A CN 201710151101A CN 106693441 A CN106693441 A CN 106693441A
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- agitating
- cylinder
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- plate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0446—Juxtaposition of mixers-settlers
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/10—Sulfates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/84—Recycling of batteries or fuel cells
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- Organic Chemistry (AREA)
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- Inorganic Chemistry (AREA)
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- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Abstract
The invention relates to an extraction device, in particular to a novel extraction device for extracting nickel sulfate from waste batteries, which aims at solving the technical problem of providing a novel extraction device for extracting nickel sulfate from waste batteries. To solve the technical problem, the novel extraction device for extracting nickel sulfate from waste batteries comprises a left liquid storage cylinder, a left liquid delivery pipe, a left valve, a mixing and stirring device, a right liquid storage cylinder, a right liquid delivery pipe, a right valve, a pressurizing device, a connecting pipe, a large check valve and the like, wherein the left liquid delivery pipe is connected with the left liquid storage cylinder, and the left valve is arranged on the left liquid delivery pipe; the mixing and stirring device is arranged at the right side of the left liquid delivery pipe, and the right liquid storage cylinder is arranged at the right side of the mixing and stirring device. The novel extraction device for extracting nickel sulfate from waste batteries has the advantage that by separating the mixing and stirring device and a standing box, the mixing liquid is stirred and stood.
Description
Technical field
Nickel sulfate is extracted from old and useless battery and is filled with novel extraction the present invention relates to a kind of extraction equipment, more particularly to one kind
Put.
Background technology
The material, such as recycling of lead-acid battery such as heavy metal and acid solution containing a large amount of reproducible utilizations in old and useless battery
Mainly based on scrap lead regeneration, also including the utilization for spent acid and plastic casing.At present, domestic waste vapour vehicle lead-acid
The metal recovery utilization rate of storage battery reaches about 80-85%.Estimate according to the insiders, based on 100,000 refuse batteries for the treatment of daily
Calculate, after removing various expenses, can make a profit 20,000 yuan or so；Calculated with 7,000,000,000 batteries, 50% utilization rate, annual return is up to 600,000,000
It is polynary.It can be seen that, benefit can be created completely in this field implement scale operation.Nickel sulfate has anhydride, six water things and seven water things
Three kinds.Commodity are generally six water things, there is two kinds of variants of α-type and β-type, and the former is blue four directions crystallization, and the latter is green monocline knot
It is brilliant.It is heated to losing six crystallizations water at 103 °C.It is soluble in water, ethanol, methyl alcohol are slightly soluble in, its aqueous solution is slightly soluble in acidity
Acid, ammoniacal liquor.Extraction, also known as solvent extraction or liquid-liquid extraction, also known as extracts, and is have different in a solvent using component in system
Solubility carrys out the unit operation of separating mixture.It is immiscible at two kinds using material（Or slightly soluble）Solvent in solubility
Or the difference of distribution coefficient, make a kind of method of the solute substance from another solvent is transferred in solvent.It is widely used in
The industry such as chemistry, metallurgy, food, is common to petroleum refining industry.
The existing extraction equipment that nickel sulfate is extracted from old and useless battery generally uses traditional structure, is all in extraction
Hybrid reaction and stewing process are carried out in container, causes mixed liquor to react uneven, effect of extracting difference efficiency is low, the product of extraction
Quality is low, is unfavorable for the production and development of enterprise.
The content of the invention
（1）The technical problem to be solved
The present invention generally uses traditional structure for the extraction equipment for overcoming the existing extraction nickel sulfate from old and useless battery,
All it is that hybrid reaction and stewing process are carried out in extraction container, causes mixed liquor to react uneven shortcoming, the present invention will be solved
Technical problem certainly is to provide one kind and nickel sulfate novel extraction apparatus is extracted from old and useless battery.
（2）Technical scheme
In order to solve the above-mentioned technical problem, nickel sulfate novel extraction is extracted from old and useless battery the invention provides such a
Device, include left liquid storage cylinder, left liquid pushing tube, left valve, mixed stirring device, right liquid storage cylinder, right liquid pushing tube, right valve, plus
Pressure device, connecting tube, big check valve, standing case, drain pipe, lower valve and receipts fluid cylinder；A left side is provided with below left liquid storage cylinder
Liquid pushing tube, left liquid pushing tube is connected with left liquid storage cylinder, and left valve is provided with left liquid pushing tube；Set on the right side of left liquid pushing tube
There is mixed stirring device, right liquid storage cylinder is provided with the right side of mixed stirring device, being provided with the right side below right liquid storage cylinder send
Liquid pipe, right liquid pushing tube is connected with right liquid storage cylinder, and right valve is provided with right liquid pushing tube；Set below mixed stirring device
Pressue device is equipped with, connecting tube is provided with below pressue device, big check valve is provided with connecting tube, in connecting tube
Lower section is provided with standing case, and connecting tube is connected with case is stood；Drain pipe, drain pipe and standing are provided with below standing case
Case is connected；Lower valve is provided with drain pipe, receipts fluid cylinder is provided with below drain pipe.
Preferably, mixed stirring device includes spherical container, circular agitating plate, rotary shaft, electric rotating machine, base plate, row
Liquid pipe and small check valve；Spherical container is arranged between left liquid pushing tube and right liquid pushing tube, and left liquid pushing tube and right liquid pushing tube are and ball
Describe that device is connected, left liquid pushing tube and right liquid pushing tube are connected with spherical container；Circular stirring is provided with spherical container
Plate, is provided with rotary shaft above circular agitating plate, and circular agitating plate is set to be fixedly connected with rotary shaft；In spherical container
Top be provided with hole, the hole that rotary shaft is set through spherical container top, rotary shaft is set to be flexibly connected with spherical container；
Electric rotating machine is provided with above rotary shaft, rotary shaft is connected with electric rotating machine；It is provided with out in the bottom of spherical container
Liquid mouthful, is provided with base plate in spherical container, and base plate is arranged on the lower section of circular agitating plate, and base plate is arranged on spherical container bottom
Liquid outlet top, base plate is set to be fixedly connected with the inwall of spherical container；Several discharging tubes are provided with base plate,
Discharging tube is arranged at the liquid outlet of spherical container bottom, and small check valve is provided with discharging tube.
Preferably, pressue device include pressurized tank, left push pedal, left expansion link, left cylinder, right push pedal, right expansion link and
Right cylinder；Pressurized tank is arranged on the lower section of spherical container, and inlet is provided with the top of pressurized tank, the feed liquor at the top of pressurized tank
Mouth is corresponding with the liquid outlet of spherical container bottom, and pressurized tank is connected with spherical container；In inlet at the top of pressurized tank
Discharging tube is provided with, left push pedal and right push pedal are provided with below discharging tube, left push pedal and right push pedal are arranged at pressurized tank
Inside, left push pedal and right push pedal are set to be flexibly connected with pressurized tank；Left expansion link is provided with the left of left push pedal, it is left
Expansion link is set to be fixedly connected with left push pedal, and hole is provided with the left side wall of pressurized tank, and left expansion link is left through pressurized tank
The hole set on the wall of side, is provided with left cylinder on the left of left expansion link, and left expansion link is connected with left cylinder；In right push pedal
Right side is provided with right expansion link, and right expansion link is set to be fixedly connected with right push pedal, and hole is provided with the right side wall of pressurized tank,
Right expansion link is provided with right cylinder, right expansion link and the right side through the hole of setting on pressurized tank right side wall on the right side of right expansion link
Cylinders connect；Connecting tube is arranged on the bottom of pressurized tank, and connecting tube is connected with pressurized tank.
Preferably, left agitating paddle, left agitating shaft, left stirring motor, right stirring motor, right agitating shaft and the right side is also included to stir
Mix oar；Left agitating paddle is arranged in left liquid storage cylinder, and left agitating shaft, left agitating paddle and left stirring are provided with above left agitating paddle
Axle is connected；Left stirring motor is provided with above left agitating shaft, left agitating shaft is connected with left stirring motor；Right agitating paddle
It is arranged in right liquid storage cylinder, right agitating shaft is provided with above right agitating paddle, right agitating paddle is connected with right agitating shaft；On the right side
Right stirring motor is provided with above agitating shaft, right agitating shaft is connected with right stirring motor.
Preferably, connecting plate I, bearing, connecting shaft, small agitating paddle I, small agitating paddle II, connecting plate II and arc are also included
Shape scrubbing brush；Connecting plate I is arranged on the front of circular agitating plate, and connecting plate I is set to be fixedly connected with circular agitating plate；In connection
The front of plate I is provided with bearing, and bearing is set to be fixedly connected with connecting plate I；Bearing holder (housing, cover) in connecting shaft, bearing and connecting shaft
It is set to be fixedly connected；Small agitating paddle I is provided with above connecting shaft, connecting shaft is connected with small agitating paddle I, in connecting shaft
Lower section be provided with small agitating paddle II, connecting shaft is connected with small agitating paddle II；The rear of circular agitating plate is provided with connection
Plate II, connecting plate II is set to be fixedly connected with circular agitating plate；The rear of connecting plate II is provided with arc scrubbing brush, connecting plate
II is set to be fixedly connected with arc scrubbing brush；Connecting plate I, bearing, connecting shaft, small agitating paddle I, small agitating paddle II, connecting plate II
With the inside that arc scrubbing brush is arranged at spherical container, arc scrubbing brush matches with the madial wall of spherical container.
Preferably, the rotating speed of left stirring motor and right stirring motor is disposed as 800-1200r/min, left cylinder and right gas
The cylinder diameter of cylinder is disposed as 50-300mm, and the stroke of left cylinder and right cylinder is disposed as 5-10m.
Operation principle：In the present apparatus, first be added to the solution containing nickel sulfate in left liquid storage cylinder by staff, then will
Extraction agent solution is added to right liquid storage cylinder, and by left liquid pushing tube and right liquid pushing tube two kinds of solution is transported into mixing respectively
In device, while carrying out uniform stirring to mixed liquor by mixed stirring device.Mixed liquor is mixed in mixed stirring device
After closing reaction, enter back into pressue device and be pressurized, make hybrid reaction more fully thoroughly, then entered by connecting tube again
Enter carries out the stewing process regular hour in standing case, and the nickel sulfate in the solution containing nickel sulfate is extracted in agent solution
Extractant is absorbed, and after mass transport process is finished, the extract containing nickel sulfate is formed on obvious with the raffinate for losing nickel sulfate
Lower leaf.Then staff opens lower valve, rests on the raffinate stood in case and is discharged in receipts fluid cylinder by drain pipe.
When raffinate discharge is finished, staff turns off lower valve, and new receipts fluid cylinder is then changed again, and staff opens down again
Valve, is discharged in new receipts fluid cylinder remaining extract in case is stood by drain pipe.
Because mixed stirring device includes spherical container, circular agitating plate, rotary shaft, electric rotating machine, base plate, discharging tube
With small check valve, left liquid pushing tube and right liquid pushing tube are connected with spherical container, and circular agitating plate is provided with spherical container,
Circular agitating plate is set to be fixedly connected with rotary shaft, and rotary shaft is connected with electric rotating machine, and base plate is arranged on spherical container bottom
The top of the liquid outlet in portion, is provided with several discharging tubes on base plate, and small check valve is provided with discharging tube, so work
Personnel can start electric rotating machine and be operated, and electric rotating machine drives circular agitating plate to mixed in spherical container by rotary shaft
Closing liquid carries out uniform stirring, it is agitated after mixed liquor flowed downward out by the discharging tube on base plate, small check valve is prevented from
Mixed liquor flows backwards.
Because pressue device includes pressurized tank, left push pedal, left expansion link, left cylinder, right push pedal, right expansion link and right gas
Cylinder, the inlet at the top of pressurized tank is corresponding with the liquid outlet of spherical container bottom, and pressurized tank is connected with spherical container, is adding
Discharging tube is provided with the inlet for pressing box top, left push pedal and right push pedal are arranged at the inside of pressurized tank, so work people
Member can be respectively started left cylinder and right cylinder is acted, and left cylinder drives left push pedal to be transported to the right by left expansion link
Dynamic, right cylinder drives right push pedal to be moved to the left by right expansion link.The left push pedal and right push pedal of relative motion are to discharging tube
The next mixed liquor of conveying is pressurized, and makes its reaction more fully thoroughly, and extrude discharge by connecting tube.
Because also including left agitating paddle, left agitating shaft, left stirring motor, right stirring motor, right agitating shaft and right stirring
Oar, left agitating paddle is arranged in left liquid storage cylinder, and left agitating paddle is connected with left agitating shaft, and left agitating shaft is connected with left stirring motor
Connect, right agitating paddle is arranged in right liquid storage cylinder, right agitating paddle is connected with right agitating shaft, right agitating shaft is connected with right stirring motor
Connect, so staff can be respectively started left stirring motor and right stirring motor is operated, left stirring motor is stirred by a left side
Mixing axle drives left agitating paddle to be stirred the solution in left liquid storage cylinder, prevents it to be deposited on casing wall, and right stirring motor passes through
Right agitating shaft drives right agitating paddle to be stirred the solution in right liquid storage cylinder, prevents it to be deposited on casing wall.
Because also including connecting plate I, bearing, connecting shaft, small agitating paddle I, small agitating paddle II, connecting plate II and arc
Brush, connecting plate I is set to be fixedly connected with circle agitating plate, and bearing is set to be fixedly connected with connecting plate I, bearing and connecting shaft
Be set to be fixedly connected, connecting shaft is connected with small agitating paddle I, connecting shaft is connected with small agitating paddle II, connecting plate II with circle
Shape agitating plate is set to be fixedly connected, and connecting plate II is set to be fixedly connected with arc scrubbing brush, arc scrubbing brush and spherical container
Madial wall matches, thus small agitating paddle I and small agitating paddle II mixed liquor in spherical container can be carried out it is more uniform
Stirring, arc scrubbing brush can be cleaned to the inwall of spherical container, prevent impurity to be deposited on inwall, be that follow-up work is carried
For facility.
Because the rotating speed of left stirring motor and right stirring motor is disposed as 800-1200r/min, run more smart
It is accurate accurate, facilitate staff to adjust its rotating speed.The cylinder diameter of left cylinder and right cylinder is disposed as 50-300mm, left cylinder and the right side
The stroke of cylinder is disposed as 5-10m, so operation is more steady reliable, can be applied to various working.
（3）Beneficial effect
It is provided by the present invention one kind from old and useless battery extract nickel sulfate novel extraction apparatus, using mixed stirring device with
The mode that case is separate is stood, mixed liquor is stirred respectively and stewing process, mixing effect is good, stewing process efficiency high, and
With pressue device, mixed liquor can be pressurized, greatly improve the efficiency of mixed liquor reaction, simple structure is used
It is convenient, it is easy to maintenance and repair.
Brief description of the drawings
Fig. 1 is main view figure structure schematic representation of the invention.
Fig. 2 is the main view figure structure schematic representation of mixed stirring device of the invention.
Fig. 3 is the main view figure structure schematic representation of pressue device of the invention.
Fig. 4 is the main view figure structure schematic representation of left stirring motor of the invention.
Fig. 5 is the left view figure structure schematic representation of arc scrubbing brush of the invention.
Mark in accompanying drawing for：The left liquid storage cylinders of 1-, the left liquid pushing tubes of 2-, the left valves of 3-, 4- mixed stirring devices, the right liquid storages of 5-
Cylinder, the right liquid pushing tubes of 6-, the right valves of 7-, 8- pressue devices, 9- connecting tubes, the big check valves of 10-, 11- standing casees, 12- drain pipes,
13- lower valves, 14- receives fluid cylinder, and the left agitating paddles of 15-, the left agitating shafts of 16-, the left stirring motors of 17-, the right stirring motors of 18-, 19- is right
Agitating shaft, the right agitating paddles of 20-, 21- connecting plates I, 22- bearings, 23- connecting shafts, the small agitating paddles I of 24-, the small agitating paddles II of 25-,
26- connecting plates II, 27- arc scrubbing brushes, 41- spherical containers, 42- circle agitating plates, 43- rotary shafts, 44- electric rotating machines, 45- bottoms
Plate, 46- discharging tubes, the small check valves of 47-, 81- pressurized tanks, the left push pedals of 82-, the left expansion links of 83-, 84- left cylinders, the right push pedals of 85-,
The right expansion links of 86-, 87- right cylinders.
Specific embodiment
The present invention is further illustrated with reference to the accompanying drawings and examples.
Embodiment 1
One kind extracts nickel sulfate novel extraction apparatus from old and useless battery, as Figure 1-5, includes a left liquid storage cylinder 1, left side and send
It is liquid pipe 2, left valve 3, mixed stirring device 4, right liquid storage cylinder 5, right liquid pushing tube 6, right valve 7, pressue device 8, connecting tube 9, big
Check valve 10, standing case 11, drain pipe 12, lower valve 13 and receipts fluid cylinder 14；The lower section of left liquid storage cylinder 1 is provided with left liquid pushing tube
2, left liquid pushing tube 2 is connected with left liquid storage cylinder 1, and left valve 3 is provided with left liquid pushing tube 2；Set on the right side of left liquid pushing tube 2
There is mixed stirring device 4, the right side of mixed stirring device 4 is provided with right liquid storage cylinder 5, be provided with the lower section of right liquid storage cylinder 5
Right liquid pushing tube 6, right liquid pushing tube 6 is connected with right liquid storage cylinder 5, and right valve 7 is provided with right liquid pushing tube 6；Filled mixing
The lower section for putting 4 is provided with pressue device 8, and the lower section of pressue device 8 is provided with connecting tube 9, and big list is provided with connecting tube 9
To valve 10, the lower section of connecting tube 9 is provided with standing case 11, connecting tube 9 is connected with case 11 is stood；Standing the lower section of case 11
Drain pipe 12 is provided with, drain pipe 12 is connected with case 11 is stood；Lower valve 13 is provided with drain pipe 12, in drain pipe 12
Lower section be provided with receipts fluid cylinder 14.
Embodiment 2
One kind extracts nickel sulfate novel extraction apparatus from old and useless battery, as Figure 1-5, includes a left liquid storage cylinder 1, left side and send
It is liquid pipe 2, left valve 3, mixed stirring device 4, right liquid storage cylinder 5, right liquid pushing tube 6, right valve 7, pressue device 8, connecting tube 9, big
Check valve 10, standing case 11, drain pipe 12, lower valve 13 and receipts fluid cylinder 14；The lower section of left liquid storage cylinder 1 is provided with left liquid pushing tube
2, left liquid pushing tube 2 is connected with left liquid storage cylinder 1, and left valve 3 is provided with left liquid pushing tube 2；Set on the right side of left liquid pushing tube 2
There is mixed stirring device 4, the right side of mixed stirring device 4 is provided with right liquid storage cylinder 5, be provided with the lower section of right liquid storage cylinder 5
Right liquid pushing tube 6, right liquid pushing tube 6 is connected with right liquid storage cylinder 5, and right valve 7 is provided with right liquid pushing tube 6；Filled mixing
The lower section for putting 4 is provided with pressue device 8, and the lower section of pressue device 8 is provided with connecting tube 9, and big list is provided with connecting tube 9
To valve 10, the lower section of connecting tube 9 is provided with standing case 11, connecting tube 9 is connected with case 11 is stood；Standing the lower section of case 11
Drain pipe 12 is provided with, drain pipe 12 is connected with case 11 is stood；Lower valve 13 is provided with drain pipe 12, in drain pipe 12
Lower section be provided with receipts fluid cylinder 14.
Mixed stirring device 4 includes spherical container 41, circular agitating plate 42, rotary shaft 43, electric rotating machine 44, base plate
45th, discharging tube 46 and small check valve 47；Spherical container 41 is arranged between left liquid pushing tube 2 and right liquid pushing tube 6, the He of left liquid pushing tube 2
Right liquid pushing tube 6 is connected with spherical container 41, and left liquid pushing tube 2 and right liquid pushing tube 6 are connected with spherical container 41；Spherical
Circular agitating plate 42 is provided with container 41, the top of circular agitating plate 42 is provided with rotary shaft 43, circular agitating plate 42 with
Rotary shaft 43 is set to be fixedly connected；The top of spherical container 41 is provided with hole, rotary shaft 43 passes through the top of spherical container 41
The hole of setting, rotary shaft 43 is set to be flexibly connected with spherical container 41；The top of rotary shaft 43 is provided with electric rotating machine 44,
Rotary shaft 43 is connected with electric rotating machine 44；The bottom of spherical container 41 is provided with liquid outlet, is set in spherical container 41
There is base plate 45, base plate 45 is arranged on the lower section of circular agitating plate 42, and base plate 45 is arranged on the liquid outlet of the bottom of spherical container 41
Top, base plate 45 is set to be fixedly connected with the inwall of spherical container 41；Several discharging tubes 46 are provided with base plate 45, are arranged
Liquid pipe 46 is arranged at the liquid outlet of the bottom of spherical container 41, and small check valve 47 is provided with discharging tube 46.
Embodiment 3
One kind extracts nickel sulfate novel extraction apparatus from old and useless battery, as Figure 1-5, includes a left liquid storage cylinder 1, left side and send
It is liquid pipe 2, left valve 3, mixed stirring device 4, right liquid storage cylinder 5, right liquid pushing tube 6, right valve 7, pressue device 8, connecting tube 9, big
Check valve 10, standing case 11, drain pipe 12, lower valve 13 and receipts fluid cylinder 14；The lower section of left liquid storage cylinder 1 is provided with left liquid pushing tube
2, left liquid pushing tube 2 is connected with left liquid storage cylinder 1, and left valve 3 is provided with left liquid pushing tube 2；Set on the right side of left liquid pushing tube 2
There is mixed stirring device 4, the right side of mixed stirring device 4 is provided with right liquid storage cylinder 5, be provided with the lower section of right liquid storage cylinder 5
Right liquid pushing tube 6, right liquid pushing tube 6 is connected with right liquid storage cylinder 5, and right valve 7 is provided with right liquid pushing tube 6；Filled mixing
The lower section for putting 4 is provided with pressue device 8, and the lower section of pressue device 8 is provided with connecting tube 9, and big list is provided with connecting tube 9
To valve 10, the lower section of connecting tube 9 is provided with standing case 11, connecting tube 9 is connected with case 11 is stood；Standing the lower section of case 11
Drain pipe 12 is provided with, drain pipe 12 is connected with case 11 is stood；Lower valve 13 is provided with drain pipe 12, in drain pipe 12
Lower section be provided with receipts fluid cylinder 14.
Mixed stirring device 4 includes spherical container 41, circular agitating plate 42, rotary shaft 43, electric rotating machine 44, base plate
45th, discharging tube 46 and small check valve 47；Spherical container 41 is arranged between left liquid pushing tube 2 and right liquid pushing tube 6, the He of left liquid pushing tube 2
Right liquid pushing tube 6 is connected with spherical container 41, and left liquid pushing tube 2 and right liquid pushing tube 6 are connected with spherical container 41；Spherical
Circular agitating plate 42 is provided with container 41, the top of circular agitating plate 42 is provided with rotary shaft 43, circular agitating plate 42 with
Rotary shaft 43 is set to be fixedly connected；The top of spherical container 41 is provided with hole, rotary shaft 43 passes through the top of spherical container 41
The hole of setting, rotary shaft 43 is set to be flexibly connected with spherical container 41；The top of rotary shaft 43 is provided with electric rotating machine 44,
Rotary shaft 43 is connected with electric rotating machine 44；The bottom of spherical container 41 is provided with liquid outlet, is set in spherical container 41
There is base plate 45, base plate 45 is arranged on the lower section of circular agitating plate 42, and base plate 45 is arranged on the liquid outlet of the bottom of spherical container 41
Top, base plate 45 is set to be fixedly connected with the inwall of spherical container 41；Several discharging tubes 46 are provided with base plate 45, are arranged
Liquid pipe 46 is arranged at the liquid outlet of the bottom of spherical container 41, and small check valve 47 is provided with discharging tube 46.
Pressue device 8 includes pressurized tank 81, left push pedal 82, left expansion link 83, left cylinder 84, right push pedal 85, right flexible
Bar 86 and right cylinder 87；Pressurized tank 81 is arranged on the lower section of spherical container 41, and the top of pressurized tank 81 is provided with inlet, plus
The inlet at the top of pressure case 81 is corresponding with the liquid outlet of the bottom of spherical container 41, and pressurized tank 81 is connected with spherical container 41；
Discharging tube 46 is provided with the inlet at the top of pressurized tank 81, the lower section of discharging tube 46 is provided with left push pedal 82 and right push pedal
85, left push pedal 82 and right push pedal 85 are arranged at the inside of pressurized tank 81, and left push pedal 82 and right push pedal 85 set with pressurized tank 81
It is set to flexible connection；The left side of left push pedal 82 is provided with left expansion link 83, left expansion link 83 is set to fix with left push pedal 82
Connection, is provided with hole on the left side wall of pressurized tank 81, and left expansion link 83 passes through the hole set on the left side wall of pressurized tank 81, on a left side
The left side of expansion link 83 is provided with left cylinder 84, and left expansion link 83 is connected with left cylinder 84；Set on the right side of right push pedal 85
There is right expansion link 86, right expansion link 86 is set to be fixedly connected with right push pedal 85, and hole is provided with the right side wall of pressurized tank 81,
Right expansion link 86 is provided with right cylinder 87 through the hole of setting on the right side wall of pressurized tank 81 on the right side of right expansion link 86, and the right side is stretched
Contracting bar 86 is connected with right cylinder 87；Connecting tube 9 is arranged on the bottom of pressurized tank 81, and connecting tube 9 is connected with pressurized tank 81.
Embodiment 4
One kind extracts nickel sulfate novel extraction apparatus from old and useless battery, as Figure 1-5, includes a left liquid storage cylinder 1, left side and send
It is liquid pipe 2, left valve 3, mixed stirring device 4, right liquid storage cylinder 5, right liquid pushing tube 6, right valve 7, pressue device 8, connecting tube 9, big
Check valve 10, standing case 11, drain pipe 12, lower valve 13 and receipts fluid cylinder 14；The lower section of left liquid storage cylinder 1 is provided with left liquid pushing tube
2, left liquid pushing tube 2 is connected with left liquid storage cylinder 1, and left valve 3 is provided with left liquid pushing tube 2；Set on the right side of left liquid pushing tube 2
There is mixed stirring device 4, the right side of mixed stirring device 4 is provided with right liquid storage cylinder 5, be provided with the lower section of right liquid storage cylinder 5
Right liquid pushing tube 6, right liquid pushing tube 6 is connected with right liquid storage cylinder 5, and right valve 7 is provided with right liquid pushing tube 6；Filled mixing
The lower section for putting 4 is provided with pressue device 8, and the lower section of pressue device 8 is provided with connecting tube 9, and big list is provided with connecting tube 9
To valve 10, the lower section of connecting tube 9 is provided with standing case 11, connecting tube 9 is connected with case 11 is stood；Standing the lower section of case 11
Drain pipe 12 is provided with, drain pipe 12 is connected with case 11 is stood；Lower valve 13 is provided with drain pipe 12, in drain pipe 12
Lower section be provided with receipts fluid cylinder 14.
Mixed stirring device 4 includes spherical container 41, circular agitating plate 42, rotary shaft 43, electric rotating machine 44, base plate
45th, discharging tube 46 and small check valve 47；Spherical container 41 is arranged between left liquid pushing tube 2 and right liquid pushing tube 6, the He of left liquid pushing tube 2
Right liquid pushing tube 6 is connected with spherical container 41, and left liquid pushing tube 2 and right liquid pushing tube 6 are connected with spherical container 41；Spherical
Circular agitating plate 42 is provided with container 41, the top of circular agitating plate 42 is provided with rotary shaft 43, circular agitating plate 42 with
Rotary shaft 43 is set to be fixedly connected；The top of spherical container 41 is provided with hole, rotary shaft 43 passes through the top of spherical container 41
The hole of setting, rotary shaft 43 is set to be flexibly connected with spherical container 41；The top of rotary shaft 43 is provided with electric rotating machine 44,
Rotary shaft 43 is connected with electric rotating machine 44；The bottom of spherical container 41 is provided with liquid outlet, is set in spherical container 41
There is base plate 45, base plate 45 is arranged on the lower section of circular agitating plate 42, and base plate 45 is arranged on the liquid outlet of the bottom of spherical container 41
Top, base plate 45 is set to be fixedly connected with the inwall of spherical container 41；Several discharging tubes 46 are provided with base plate 45, are arranged
Liquid pipe 46 is arranged at the liquid outlet of the bottom of spherical container 41, and small check valve 47 is provided with discharging tube 46.
Pressue device 8 includes pressurized tank 81, left push pedal 82, left expansion link 83, left cylinder 84, right push pedal 85, right flexible
Bar 86 and right cylinder 87；Pressurized tank 81 is arranged on the lower section of spherical container 41, and the top of pressurized tank 81 is provided with inlet, plus
The inlet at the top of pressure case 81 is corresponding with the liquid outlet of the bottom of spherical container 41, and pressurized tank 81 is connected with spherical container 41；
Discharging tube 46 is provided with the inlet at the top of pressurized tank 81, the lower section of discharging tube 46 is provided with left push pedal 82 and right push pedal
85, left push pedal 82 and right push pedal 85 are arranged at the inside of pressurized tank 81, and left push pedal 82 and right push pedal 85 set with pressurized tank 81
It is set to flexible connection；The left side of left push pedal 82 is provided with left expansion link 83, left expansion link 83 is set to fix with left push pedal 82
Connection, is provided with hole on the left side wall of pressurized tank 81, and left expansion link 83 passes through the hole set on the left side wall of pressurized tank 81, on a left side
The left side of expansion link 83 is provided with left cylinder 84, and left expansion link 83 is connected with left cylinder 84；Set on the right side of right push pedal 85
There is right expansion link 86, right expansion link 86 is set to be fixedly connected with right push pedal 85, and hole is provided with the right side wall of pressurized tank 81,
Right expansion link 86 is provided with right cylinder 87 through the hole of setting on the right side wall of pressurized tank 81 on the right side of right expansion link 86, and the right side is stretched
Contracting bar 86 is connected with right cylinder 87；Connecting tube 9 is arranged on the bottom of pressurized tank 81, and connecting tube 9 is connected with pressurized tank 81.
Also include left agitating paddle 15, left agitating shaft 16, left stirring motor 17, right stirring motor 18, the and of right agitating shaft 19
Right agitating paddle 20；Left agitating paddle 15 is arranged in left liquid storage cylinder 1, and the top of left agitating paddle 15 is provided with left agitating shaft 16, left
Agitating paddle 15 is connected with left agitating shaft 16；The top of left agitating shaft 16 is provided with left stirring motor 17, left agitating shaft 16 with
Left stirring motor 17 is connected；Right agitating paddle 20 is arranged in right liquid storage cylinder 5, and the top of right agitating paddle 20 is provided with right stirring
Axle 19, right agitating paddle 20 is connected with right agitating shaft 19；The top of right agitating shaft 19 is provided with right stirring motor 18, right stirring
Axle 19 is connected with right stirring motor 18.
Also include connecting plate I 21, bearing 22, connecting shaft 23, small agitating paddle I 24, small agitating paddle II 25, connecting plate II 26
With arc scrubbing brush 27；Connecting plate I 21 is arranged on the front of circular agitating plate 42, and connecting plate I 21 is set to circular agitating plate 42
It is fixedly connected；The front of connecting plate I 21 is provided with bearing 22, bearing 22 is set to be fixedly connected with connecting plate I 21；Bearing 22
It is enclosed within connecting shaft 23, bearing 22 is set to be fixedly connected with connecting shaft 23；The top of connecting shaft 23 is provided with small agitating paddle I
24, connecting shaft 23 is connected with small agitating paddle I 24, and the lower section of connecting shaft 23 is provided with small agitating paddle II 25, connecting shaft 23 with
Small agitating paddle II 25 is connected；The rear of circular agitating plate 42 is provided with connecting plate II 26, connecting plate II 26 is stirred with circular
Plate 42 is set to be fixedly connected；The rear of connecting plate II 26 is provided with arc scrubbing brush 27, connecting plate II 26 and arc scrubbing brush 27
It is set to be fixedly connected；Connecting plate I 21, bearing 22, connecting shaft 23, small agitating paddle I 24, small agitating paddle II 25, connecting plate II 26
With the inside that arc scrubbing brush 27 is arranged at spherical container 41, arc scrubbing brush 27 matches with the madial wall of spherical container 41.
The rotating speed of left stirring motor 17 and right stirring motor 18 is disposed as 800-1200r/min, left cylinder 84 and right gas
The cylinder diameter of cylinder 87 is disposed as 50-300mm, and the stroke of left cylinder 84 and right cylinder 87 is disposed as 5-10m.
Operation principle：In the present apparatus, first be added to the solution containing nickel sulfate in left liquid storage cylinder 1 by staff, then
Extraction agent solution is added to right liquid storage cylinder 5, and by left liquid pushing tube 2 and right liquid pushing tube 6 is transported to two kinds of solution respectively mixed
Close in agitating device 4, while carrying out uniform stirring to mixed liquor by mixed stirring device 4.Mixed liquor is in mixed stirring device 4
After inside carrying out hybrid reaction, enter back into and be pressurized in pressue device 8, make hybrid reaction more fully thoroughly, then lead to again
Cross connecting tube 9 enter into standing case 11 in carry out the stewing process regular hour, the nickel sulfate quilt in the solution containing nickel sulfate
Extractant in extraction agent solution absorbs, after mass transport process is finished, the extract containing nickel sulfate and the raffinate for losing nickel sulfate
Liquid forms significantly upper lower leaf.Then staff opens lower valve 13, rests on the raffinate stood in case 11 and passes through
Liquid pipe 12 is discharged in receipts fluid cylinder 14.When raffinate discharge is finished, staff turns off lower valve 13, then changes again new
Receipts fluid cylinder 14, staff opens lower valve 13 again, is discharged to by drain pipe 12 remaining extract in case 11 is stood
In new receipts fluid cylinder 14.
Because mixed stirring device 4 includes spherical container 41, circular agitating plate 42, rotary shaft 43, electric rotating machine 44, bottom
Plate 45, discharging tube 46 and small check valve 47, left liquid pushing tube 2 and right liquid pushing tube 6 are connected with spherical container 41, in spherical container
Circular agitating plate 42 is provided with 41, circular agitating plate 42 is set to be fixedly connected with rotary shaft 43, rotary shaft 43 and electric rotating
Machine 44 is connected, and base plate 45 is arranged on the top of the liquid outlet of the bottom of spherical container 41, and several rows are provided with base plate 45
Liquid pipe 46, is provided with small check valve 47 on discharging tube 46, so staff can start electric rotating machine 44 and be operated, rotation
Rotating motor 44 drives the circular agitating plate 42 uniform stirring is carried out to the mixed liquor in spherical container 41 by rotary shaft 43, agitated
Mixed liquor afterwards is flowed downward out by the discharging tube 46 on base plate 45, and small check valve 47 is prevented from mixed liquor refluence.
Because pressue device 8 includes pressurized tank 81, left push pedal 82, left expansion link 83, left cylinder 84, right push pedal 85, the right side
Expansion link 86 and right cylinder 87, the inlet at the top of pressurized tank 81 are corresponding with the liquid outlet of the bottom of spherical container 41, pressurized tank
81 are connected with spherical container 41, and discharging tube 46, left push pedal 82 and right push pedal are provided with the inlet at the top of pressurized tank 81
85 inside for being arranged at pressurized tank 81, so staff can be respectively started left cylinder 84 and right cylinder 87 is acted,
Left cylinder 84 drives left push pedal 82 to be moved to the right by left expansion link 83, and right cylinder 87 drives the right side to push away by right expansion link 86
Plate 85 is moved to the left.The left push pedal 82 and right push pedal 85 of relative motion increase to the mixed liquor that the conveying of discharging tube 46 comes
Pressure, makes its reaction more fully thoroughly, and discharge by the extruding of connecting tube 9.
Because also including left agitating paddle 15, left agitating shaft 16, left stirring motor 17, right stirring motor 18, right agitating shaft
19 and right agitating paddle 20, left agitating paddle 15 is arranged in left liquid storage cylinder 1, and left agitating paddle 15 is connected with left agitating shaft 16, and a left side is stirred
Mix axle 16 to be connected with left stirring motor 17, right agitating paddle 20 is arranged in right liquid storage cylinder 5, right agitating paddle 20 and right agitating shaft 19
It is connected, right agitating shaft 19 is connected with right stirring motor 18, so staff can be respectively started the He of left stirring motor 17
Right stirring motor 18 is operated, and left stirring motor 17 is driven in 15 pairs of left liquid storage cylinders 1 of left agitating paddle by left agitating shaft 16
Solution is stirred, and prevents it to be deposited on casing wall, and right stirring motor 18 drives 20 pairs of right sides of right agitating paddle by right agitating shaft 19
Solution in liquid storage cylinder 5 is stirred, and prevents it to be deposited on casing wall.
Because also including connecting plate I 21, bearing 22, connecting shaft 23, small agitating paddle I 24, small agitating paddle II 25, connecting plate
II 26 and arc scrubbing brush 27, connecting plate I 21 is set to be fixedly connected with circular agitating plate 42, and bearing 22 is set with connecting plate I 21
To be fixedly connected, bearing 22 is set to be fixedly connected with connecting shaft 23, and connecting shaft 23 is connected with small agitating paddle I 24, connecting shaft
23 are connected with small agitating paddle II 25, and connecting plate II 26 is set to be fixedly connected with circular agitating plate 42, connecting plate II 26 and arc
Shape scrubbing brush 27 is set to be fixedly connected, and arc scrubbing brush 27 matches with the madial wall of spherical container 41, so the He of small agitating paddle I 24
Small agitating paddle II 25 can carry out more uniform stirring to the mixed liquor in spherical container 41, and arc scrubbing brush 27 can be to spherical
The inwall of container 41 is cleaned, and prevents impurity to be deposited on inwall, for follow-up work provides facility.
Because the rotating speed of left stirring motor 17 and right stirring motor 18 is disposed as 800-1200r/min, operation is more
Plus it is precisely accurate, facilitate staff to adjust its rotating speed.The cylinder diameter of left cylinder 84 and right cylinder 87 is disposed as 50-300mm, left
The stroke of cylinder 84 and right cylinder 87 is disposed as 5-10m, so operation is more steady reliable, can be applied to various working.
Embodiment described above only expresses the preferred embodiment of the present invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, some deformations, improvement can also be made and substituted, these belong to this hair
Bright protection domain.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (6)
1. one kind extracts nickel sulfate novel extraction apparatus from old and useless battery, it is characterised in that include left liquid storage cylinder（1）、
Left liquid pushing tube（2）, left valve（3）, mixed stirring device（4）, right liquid storage cylinder（5）, right liquid pushing tube（6）, right valve（7）, pressurization
Device（8）, connecting tube（9）, big check valve（10）, stand case（11）, drain pipe（12）, lower valve（13）With receipts fluid cylinder（14）；
In left liquid storage cylinder（1）Lower section be provided with left liquid pushing tube（2）, left liquid pushing tube（2）With left liquid storage cylinder（1）It is connected, in left liquor charging
Pipe（2）On be provided with left valve（3）；In left liquid pushing tube（2）Right side be provided with mixed stirring device（4）, filled mixing
Put（4）Right side be provided with right liquid storage cylinder（5）, in right liquid storage cylinder（5）Lower section be provided with right liquid pushing tube（6）, right liquid pushing tube（6）
With right liquid storage cylinder（5）It is connected, in right liquid pushing tube（6）On be provided with right valve（7）；In mixed stirring device（4）Lower section set
It is equipped with pressue device（8）, in pressue device（8）Lower section be provided with connecting tube（9）, in connecting tube（9）On be provided with it is big unidirectional
Valve（10）, in connecting tube（9）Lower section be provided with standing case（11）, connecting tube（9）With standing case（11）It is connected；Standing case
（11）Lower section be provided with drain pipe（12）, drain pipe（12）With standing case（11）It is connected；In drain pipe（12）On be provided with
Lower valve（13）, in drain pipe（12）Lower section be provided with receipts fluid cylinder（14）.
2. one kind according to claim 1 extracts nickel sulfate novel extraction apparatus from old and useless battery, it is characterised in that
Mixed stirring device（4）Include spherical container（41）, circular agitating plate（42）, rotary shaft（43）, electric rotating machine（44）, base plate
（45）, discharging tube（46）With small check valve（47）；Spherical container（41）It is arranged on left liquid pushing tube（2）With right liquid pushing tube（6）Between,
Left liquid pushing tube（2）With right liquid pushing tube（6）And spherical container（41）It is connected, left liquid pushing tube（2）With right liquid pushing tube（6）And ball
Describe device（41）It is connected；In spherical container（41）Inside it is provided with circular agitating plate（42）, in circular agitating plate（42）Top
It is provided with rotary shaft（43）, circular agitating plate（42）With rotary shaft（43）It is set to be fixedly connected；In spherical container（41）Top
Portion is provided with hole, rotary shaft（43）Through spherical container（41）The hole that top is set, rotary shaft（43）With spherical container（41）If
It is set to flexible connection；In rotary shaft（43）Top be provided with electric rotating machine（44）, rotary shaft（43）With electric rotating machine（44）Phase
Connection；In spherical container（41）Bottom be provided with liquid outlet, in spherical container（41）Inside it is provided with base plate（45）, base plate（45）
It is arranged on circular agitating plate（42）Lower section, base plate（45）It is arranged on spherical container（41）The top of the liquid outlet of bottom, base plate
（45）With spherical container（41）Inwall be set to be fixedly connected；In base plate（45）On be provided with several discharging tubes（46）, row
Liquid pipe（46）It is arranged on spherical container（41）At the liquid outlet of bottom, in discharging tube（46）On be provided with small check valve（47）.
3. one kind according to claim 2 extracts nickel sulfate novel extraction apparatus from old and useless battery, it is characterised in that
Pressue device（8）Include pressurized tank（81）, left push pedal（82）, left expansion link（83）, left cylinder（84）, right push pedal（85）, it is right
Expansion link（86）And right cylinder（87）；Pressurized tank（81）It is arranged on spherical container（41）Lower section, in pressurized tank（81）Top
It is provided with inlet, pressurized tank（81）The inlet and spherical container at top（41）The liquid outlet of bottom is corresponding, pressurized tank
（81）With spherical container（41）It is connected；In pressurized tank（81）Discharging tube is provided with the inlet at top（46）, in discharging tube
（46）Lower section be provided with left push pedal（82）With right push pedal（85）, left push pedal（82）With right push pedal（85）It is arranged at pressurized tank
（81）Inside, left push pedal（82）With right push pedal（85）And pressurized tank（81）It is set to be flexibly connected；In left push pedal（82）'s
Left side is provided with left expansion link（83）, left expansion link（83）With left push pedal（82）It is set to be fixedly connected, in pressurized tank（81）'s
Hole, left expansion link are provided with left side wall（83）Through pressurized tank（81）The hole set on left side wall, in left expansion link（83）'s
Left side is provided with left cylinder（84）, left expansion link（83）With left cylinder（84）It is connected；In right push pedal（85）Right side be provided with
Right expansion link（86）, right expansion link（86）With right push pedal（85）It is set to be fixedly connected, in pressurized tank（81）Right side wall on set
It is equipped with hole, right expansion link（86）Through pressurized tank（81）The hole set on right side wall, in right expansion link（86）Right side be provided with
Right cylinder（87）, right expansion link（86）With right cylinder（87）It is connected；Connecting tube（9）It is arranged on pressurized tank（81）Bottom, even
Adapter（9）With pressurized tank（81）It is connected.
4. one kind according to claim 3 extracts nickel sulfate novel extraction apparatus from old and useless battery, it is characterised in that
Also include left agitating paddle（15）, left agitating shaft（16）, left stirring motor（17）, right stirring motor（18）, right agitating shaft（19）
With right agitating paddle（20）；Left agitating paddle（15）It is arranged on left liquid storage cylinder（1）It is interior, in left agitating paddle（15）Top be provided with a left side and stir
Mix axle（16）, left agitating paddle（15）With left agitating shaft（16）It is connected；In left agitating shaft（16）Top be provided with it is left stirring electricity
Machine（17）, left agitating shaft（16）With left stirring motor（17）It is connected；Right agitating paddle（20）It is arranged on right liquid storage cylinder（5）It is interior,
Right agitating paddle（20）Top be provided with right agitating shaft（19）, right agitating paddle（20）With right agitating shaft（19）It is connected；Stirred on the right side
Mix axle（19）Top be provided with right stirring motor（18）, right agitating shaft（19）With right stirring motor（18）It is connected.
5. one kind according to claim 4 extracts nickel sulfate novel extraction apparatus from old and useless battery, it is characterised in that
Also include connecting plate I（21）, bearing（22）, connecting shaft（23）, small agitating paddle I（24）, small agitating paddle II（25）, connecting plate II
（26）With arc scrubbing brush（27）；Connecting plate I（21）It is arranged on circular agitating plate（42）Front, connecting plate I（21）Stirred with circle
Mix plate（42）It is set to be fixedly connected；In connecting plate I（21）Front be provided with bearing（22）, bearing（22）With connecting plate I
（21）It is set to be fixedly connected；Bearing（22）It is enclosed within connecting shaft（23）On, bearing（22）With connecting shaft（23）It is set to the company of fixation
Connect；In connecting shaft（23）Top be provided with small agitating paddle I（24）, connecting shaft（23）With small agitating paddle I（24）It is connected, even
Spindle（23）Lower section be provided with small agitating paddle II（25）, connecting shaft（23）With small agitating paddle II（25）It is connected；Stirred in circle
Mix plate（42）Rear be provided with connecting plate II（26）, connecting plate II（26）With circular agitating plate（42）It is set to be fixedly connected；
In connecting plate II（26）Rear be provided with arc scrubbing brush（27）, connecting plate II（26）With arc scrubbing brush（27）It is set to the company of fixation
Connect；Connecting plate I（21）, bearing（22）, connecting shaft（23）, small agitating paddle I（24）, small agitating paddle II（25）, connecting plate II（26）
With arc scrubbing brush（27）It is arranged at spherical container（41）Inside, arc scrubbing brush（27）With spherical container（41）Madial wall phase
Matching.
6. one kind according to claim 5 extracts nickel sulfate novel extraction apparatus from old and useless battery, it is characterised in that
Left stirring motor（17）With right stirring motor（18）Rotating speed be disposed as 800-1200r/min, left cylinder（84）And right cylinder
（87）Cylinder diameter be disposed as 50-300mm, left cylinder（84）And right cylinder（87）Stroke be disposed as 5-10m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710151101.2A CN106693441A (en) | 2017-03-14 | 2017-03-14 | Novel extraction device for extracting nickel sulfate from waste batteries |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710151101.2A CN106693441A (en) | 2017-03-14 | 2017-03-14 | Novel extraction device for extracting nickel sulfate from waste batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106693441A true CN106693441A (en) | 2017-05-24 |
Family
ID=58918182
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710151101.2A Pending CN106693441A (en) | 2017-03-14 | 2017-03-14 | Novel extraction device for extracting nickel sulfate from waste batteries |
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| Country | Link |
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| CN (1) | CN106693441A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987714A (en) * | 2017-04-10 | 2017-07-28 | 赣州科源甬致科技有限公司 | One kind extracts the nickel sulfate energy-saving extraction equipment of vibration from old and useless battery |
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| CN105435728A (en) * | 2015-12-25 | 2016-03-30 | 常州市金坛翰广科技有限公司 | Reaction kettle with movable stirring structure |
| CN205462598U (en) * | 2015-12-28 | 2016-08-17 | 山西农业大学 | Breaker is used in little algae grease extraction |
| CN205870871U (en) * | 2016-08-03 | 2017-01-11 | 邱文斌 | Spherical concrete mixing device |
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| JPH04296390A (en) * | 1991-03-26 | 1992-10-20 | Mitsubishi Petrochem Co Ltd | Method for removing mercury and mercury compound in hydrocarbon oil |
| JPH09150002A (en) * | 1995-11-29 | 1997-06-10 | Shin Etsu Chem Co Ltd | Refining method for silicone oil |
| KR20000055132A (en) * | 1999-02-03 | 2000-09-05 | 유현식 | Purification method of residual solvent in food additives |
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| CN106987714A (en) * | 2017-04-10 | 2017-07-28 | 赣州科源甬致科技有限公司 | One kind extracts the nickel sulfate energy-saving extraction equipment of vibration from old and useless battery |
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Application publication date: 20170524 |