CN113659194B - High-stability lithium ion power battery electrolyte - Google Patents
High-stability lithium ion power battery electrolyte Download PDFInfo
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- CN113659194B CN113659194B CN202110765448.2A CN202110765448A CN113659194B CN 113659194 B CN113659194 B CN 113659194B CN 202110765448 A CN202110765448 A CN 202110765448A CN 113659194 B CN113659194 B CN 113659194B
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- 239000003792 electrolyte Substances 0.000 title claims abstract description 26
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 239000003381 stabilizer Substances 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 9
- 230000000996 additive effect Effects 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 39
- 230000007246 mechanism Effects 0.000 claims description 32
- 238000005303 weighing Methods 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- -1 solute Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Abstract
Description
技术领域technical field
本发明涉及电解液生产技术领域,特别涉及一种高稳定的锂离子动力电池电解液。The invention relates to the technical field of electrolyte production, in particular to a highly stable electrolyte for lithium-ion power batteries.
背景技术Background technique
电解液是一个意义广泛的名词,用于不同行业其代表的内容相差较大。有生物体内的电解液(也称电解质),也有应用于电池行业的电解液,以及电解电容器、超级电容器等行业的电解液。Electrolyte is a term with a wide range of meanings. It is used in different industries to represent different contents. There are electrolytes (also called electrolytes) in living organisms, electrolytes used in the battery industry, and electrolytes in electrolytic capacitors, supercapacitors and other industries.
现有的电解液制作设备在进行使用的过程中不能定量的加入所需的原料,降低了原料混合的质量,而且现有的制作设备在进行使用的过程中不能将原料进行充分的搅拌混合,会出现死角无法进行搅拌的问题,不方便人们进行使用。The existing electrolyte production equipment cannot quantitatively add the required raw materials in the process of use, which reduces the quality of raw material mixing, and the existing production equipment cannot fully stir and mix the raw materials in the process of use, There will be a problem that the dead angle cannot be stirred, which is inconvenient for people to use.
因此,发明一种高稳定的锂离子动力电池电解液来解决上述问题很有必要。Therefore, it is necessary to invent a highly stable lithium-ion power battery electrolyte to solve the above problems.
发明内容Contents of the invention
本发明提出的一种高稳定的锂离子动力电池电解液,解决了现有技术中不能将原料进行充分混合的问题。The invention proposes a highly stable electrolyte solution for lithium ion power batteries, which solves the problem that raw materials cannot be fully mixed in the prior art.
为实现上述目的,本发明提供如下技术方案:一种高稳定的锂离子动力电池电解液,所述的锂离子动力电池电解液由溶质、溶剂、添加剂和稳定剂组成,按照质量百分比,溶质16%、溶剂76%、添加剂3.8%、电解液稳定剂4.2%。In order to achieve the above object, the present invention provides the following technical solution: a highly stable lithium ion power battery electrolyte, the lithium ion power battery electrolyte is composed of a solute, a solvent, an additive and a stabilizer, and according to the mass percentage, the
一种电解液制作设备,包括搅拌箱,所述搅拌箱的顶部安装有支架,所述支架的顶部安装有原料箱,所述支架的内部安装有称重机构,所述搅拌箱的顶部安装有上料机构,所述搅拌箱的内部安装有搅拌机构,所述搅拌箱的一侧安装有进液口。An electrolyte production equipment, comprising a stirring box, a support is installed on the top of the stirring box, a raw material box is installed on the top of the support, a weighing mechanism is installed inside the support, and a A feeding mechanism, a stirring mechanism is installed inside the stirring box, and a liquid inlet is installed on one side of the stirring box.
优选的,所述称重机构包括安装在支架内部的支撑板和安装在支撑板顶部的称重器,所述称重器的顶部安装有称重瓶,所述支架的一侧安装有称重控制器。Preferably, the weighing mechanism includes a support plate installed inside the bracket and a weighing device installed on the top of the support plate, a weighing bottle is installed on the top of the weighing device, and a weighing bottle is installed on one side of the bracket. controller.
优选的,所述上料机构包括安装在支撑板顶部的抽取泵和安装在搅拌箱顶部的连接管,所述连接管的底部贯穿于搅拌箱延伸至搅拌箱的内部、且安装有多个进液管,多个所述进液管的底部均开设有出液口,所述抽取泵的进口通过软管和称重瓶连通,所述抽取泵的出口通过水管与连接件和连接管连通,所述搅拌箱的内部安装有用于带动连接管进行旋转的旋转机构。Preferably, the feeding mechanism includes a suction pump installed on the top of the support plate and a connecting pipe installed on the top of the stirring box, the bottom of the connecting pipe extends through the stirring box to the inside of the stirring box, and is equipped with a plurality of feeding Liquid pipes, the bottoms of the plurality of liquid inlet pipes are all provided with liquid outlets, the inlet of the extraction pump communicates with the weighing bottle through a hose, and the outlet of the extraction pump communicates with the connector and the connecting pipe through a water pipe, A rotating mechanism for driving the connecting pipe to rotate is installed inside the mixing box.
所述旋转机构包括开设在搅拌箱内部的空腔和安装在空腔内部的主动齿轮,所述连接管的外部安装有与主动齿轮相互啮合的从动齿轮,所述搅拌箱的顶部安装有用于带动主动齿轮进行旋转的旋转电机。The rotating mechanism includes a cavity provided inside the mixing box and a driving gear installed inside the cavity, a driven gear intermeshed with the driving gear is installed on the outside of the connecting pipe, and the top of the mixing box is installed for A rotating motor that drives the driving gear to rotate.
所述搅拌机构包括安装在连接管底部的旋转柱和套设在旋转柱外部的两个搅拌叶,所述旋转柱的外部转动连接有两个连接杆,两个所述连接杆的外部均安装有多个旋转杆,两个所述连接杆的两端均安装有第一齿轮,所述搅拌箱的内壁安装有与两个第一齿轮相互啮合的第二齿轮,所述搅拌箱的内部安装有用于带动两个搅拌叶进行移动的移动机构。The stirring mechanism includes a rotating column installed at the bottom of the connecting pipe and two stirring blades sleeved on the outside of the rotating column. The outer rotation of the rotating column is connected with two connecting rods. There are a plurality of rotating rods, first gears are installed at both ends of the two connecting rods, the inner wall of the mixing box is equipped with a second gear that meshes with the two first gears, and the inside of the mixing box is installed There is a moving mechanism for moving the two stirring blades.
所述移动机构包括安装在连接杆两侧的套筒和套设在两个套筒内部的移动杆,两个所述套筒的内部均安装有支撑杆,两个所述支撑杆的外部均安装有第三齿轮,两个所述支撑杆的一端均安装有旋转盘,两个所述旋转盘的一侧均安装有推杆,两个所述移动杆的一端均安装有移动板,两个所述推杆的一端分别和两个移动板的一侧铰接,所述连接杆的外部安装有与两个第三齿轮相互啮合的第四齿轮,两个所述移动杆的一端分别和两个搅拌叶的两侧固定连接。The moving mechanism includes sleeves installed on both sides of the connecting rod and a moving rod sleeved inside the two sleeves. Support rods are installed inside the two sleeves, and the outside of the two support rods are A third gear is installed, a rotating disk is installed at one end of the two supporting rods, a push rod is installed at one side of the two rotating disks, a moving plate is installed at one end of the two moving rods, and both One end of each of the push rods is respectively hinged to one side of the two moving plates, and a fourth gear meshing with the two third gears is installed on the outside of the connecting rod, and one end of the two moving rods is respectively connected to the two moving plates. Both sides of a stirring blade are fixedly connected.
所述原料箱的底部安装有出料管,所述出料管的外部安装有阀门,所述出料管的底部贯穿于支架延伸至称重瓶的正上方。A discharge pipe is installed at the bottom of the raw material box, and a valve is installed on the outside of the discharge pipe, and the bottom of the discharge pipe runs through the bracket and extends directly above the weighing bottle.
本发明的技术效果和优点:Technical effect and advantage of the present invention:
1、通过设有的称重机构可以对注入的原料进行称重,以便进行定量注入,提高原料混合的效果,而且当旋转电机进行旋转的过程中会带动主动齿轮进行旋转,通过主动齿轮和从动齿轮的配合使用连接管会进行旋转,当连接管进行旋转的过程中会带动进液管进行旋转,从而会将原料旋转喷洒在搅拌箱的内部,这样可以满足均匀喷洒的要求,避免一次性注入降低混合的效果,提高了混合的效率。1. The injected raw materials can be weighed through the equipped weighing mechanism, so as to carry out quantitative injection and improve the effect of raw material mixing, and when the rotating motor rotates, it will drive the driving gear to rotate, through the driving gear and the slave The use of the moving gear with the use of the connecting pipe will rotate. When the connecting pipe rotates, it will drive the liquid inlet pipe to rotate, so that the raw material will be rotated and sprayed inside the mixing box, which can meet the requirements of uniform spraying and avoid one-time use. Injection reduces the effect of mixing and improves the efficiency of mixing.
2、通过第四齿轮和第三齿轮的配合,支撑杆会进行旋转,从而会带动旋转盘进行旋转,当旋转盘进行旋转的过程中会使推杆形成往复循环的运动,通过推杆的往复运动可以带动移动杆进行上下移动,从而搅拌叶会进行上下移动,这样可以对搅拌箱的内部进行全方位的搅拌,避免搅拌出现死角,提高了混合的均匀性,更加方便人们进行使用。 2. Through the cooperation of the fourth gear and the third gear, the support rod will rotate, which will drive the rotating disk to rotate. When the rotating disk rotates, the push rod will form a reciprocating cycle. Through the reciprocating movement of the push rod The movement can drive the moving rod to move up and down, so that the mixing blade will move up and down, so that the inside of the mixing box can be stirred in all directions, avoiding dead ends in the mixing, improving the uniformity of mixing, and making it more convenient for people to use.
附图说明Description of drawings
图1为本发明的整体结构示意图。Figure 1 is a schematic diagram of the overall structure of the present invention.
图2为本发明的局部结构示意图。Fig. 2 is a schematic diagram of a partial structure of the present invention.
图3为本发明的俯视剖视结构示意图。Fig. 3 is a top view sectional structural schematic diagram of the present invention.
图4为本发明的图1中A处的放大结构示意图。FIG. 4 is a schematic diagram of an enlarged structure at A in FIG. 1 of the present invention.
图5为本发明的图2中B处的放大结构示意图。FIG. 5 is a schematic diagram of an enlarged structure at B in FIG. 2 of the present invention.
图中:1、搅拌箱;2、支架;3、进液口;4、原料箱;5、支撑板;6、称重器;7、称重瓶;8、移动板;9、抽取泵;10、进液管;11、旋转柱;12、搅拌叶;13、移动杆;14、旋转杆;15、连接杆;16、套筒;17、第一齿轮;18、第二齿轮;19、第三齿轮;20、旋转电机;21、主动齿轮;22、连接管;23、从动齿轮;24、空腔;25、推杆;26、第四齿轮;27、支撑杆;28、旋转盘;29、出料管。In the figure: 1. Stirring box; 2. Bracket; 3. Liquid inlet; 4. Raw material box; 5. Support plate; 6. Weighing device; 7. Weighing bottle; 8. Moving plate; 10. Inlet pipe; 11. Rotating column; 12. Stirring blade; 13. Moving rod; 14. Rotating rod; 15. Connecting rod; 16. Sleeve; 17. First gear; 18. Second gear; 19. The third gear; 20, rotating motor; 21, driving gear; 22, connecting pipe; 23, driven gear; 24, cavity; 25, push rod; 26, fourth gear; 27, support rod; 28, rotating disk ; 29, discharge pipe.
实施方式Implementation
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, not all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.
本发明提供了如图1-5所示的一种高稳定的锂离子动力电池电解液,锂离子动力电池电解液由溶质、溶剂、添加剂和稳定剂组成,按照质量百分比,溶质16%、溶剂76%、添加剂3.8%、电解液稳定剂4.2%。The present invention provides a highly stable lithium-ion power battery electrolyte as shown in Figures 1-5. The lithium-ion power battery electrolyte is composed of solute, solvent, additive and stabilizer. According to mass percentage, 16% solute, solvent 76%, additive 3.8%, electrolyte stabilizer 4.2%.
一种电解液制作设备,包括搅拌箱1,搅拌箱1的顶部安装有支架2,支架2的顶部安装有原料箱4,支架2的内部安装有称重机构,搅拌箱1的顶部安装有上料机构,搅拌箱1的内部安装有搅拌机构,搅拌箱1的一侧安装有进液口3。An electrolyte production equipment, comprising a
称重机构包括安装在支架2内部的支撑板5和安装在支撑板5顶部的称重器6,称重器6的顶部安装有称重瓶7,支架2的一侧安装有称重控制器,通过设有的称重机构可以对注入的原料进行称重,以便进行定量注入,提高原料混合的效果。The weighing mechanism includes a
上料机构包括安装在支撑板5顶部的抽取泵9和安装在搅拌箱1顶部的连接管22,连接管22的底部贯穿于搅拌箱1延伸至搅拌箱1的内部、且安装有多个进液管10,多个进液管10的底部均开设有出液口,抽取泵9的进口通过软管和称重瓶7连通,抽取泵9的出口通过水管与连接件和连接管22连通,搅拌箱1的内部安装有用于带动连接管22进行旋转的旋转机构,当旋转电机进行旋转的过程中会带动主动齿轮21进行旋转,通过主动齿轮21和从动齿轮23的配合使用连接管22会进行旋转,当连接管22进行旋转的过程中会带动进液管10进行旋转,从而会将溶质旋转喷洒在搅拌箱1的内部,这样可以满足均匀喷洒的要求,避免一次性注入降低混合的效果。The feeding mechanism includes a suction pump 9 installed on the top of the
旋转机构包括开设在搅拌箱1内部的空腔24和安装在空腔24内部的主动齿轮21,连接管22的外部安装有与主动齿轮21相互啮合的从动齿轮23,搅拌箱1的顶部安装有用于带动主动齿轮21进行旋转的旋转电机20。The rotating mechanism includes a
搅拌机构包括安装在连接管22底部的旋转柱11和套设在旋转柱11外部的两个搅拌叶12,旋转柱11的外部转动连接有两个连接杆15,两个连接杆15的外部均安装有多个旋转杆14,两个连接杆15的两端均安装有第一齿轮17,搅拌箱1的内壁安装有与两个第一齿轮17相互啮合的第二齿轮18,搅拌箱1的内部安装有用于带动两个搅拌叶12进行移动的移动机构。The stirring mechanism includes a
移动机构包括安装在连接杆15两侧的套筒16和套设在两个套筒16内部的移动杆13,两个套筒16的内部均安装有支撑杆27,两个支撑杆27的外部均安装有第三齿轮19,两个支撑杆27的一端均安装有旋转盘28,两个旋转盘28的一侧均安装有推杆25,两个移动杆13的一端均安装有移动板8,两个推杆25的一端分别和两个移动板8的一侧铰接,连接杆15的外部安装有与两个第三齿轮19相互啮合的第四齿轮26,两个移动杆13的一端分别和两个搅拌叶12的两侧固定连接,通过第四齿26轮和第三齿轮19的配合,支撑杆27会进行旋转,从而会带动旋转盘28进行旋转,当旋转盘28进行旋转的过程中会使推杆25形成往复循环的运动,通过推杆25的往复运动可以带动移动杆13进行上下移动,从而搅拌叶12会进行上下移动,这样可以对搅拌箱1的内部进行全方位的搅拌,避免搅拌出现死角,提高了混合的均匀性,更加方便人们进行使用。The moving mechanism includes a
原料箱4的底部安装有出料管29,出料管29的外部安装有阀门,出料管29的底部贯穿于支架2延伸至称重瓶7的正上方。A
本发明工作原理:在具体的实施过程中,可以首先将所需的溶剂通过进液口3注入到搅拌箱1的内部,然后依次定量的注入溶质、添加剂和稳定剂,首先按照一定的质量比将溶质注入到原料箱4,注入到原料箱4中的溶质会通过出料管29进入到称重瓶7的内部,然后通过称重瓶7进行称重,当称重的量达到一定程度时,出料管29外部的阀门会将其进行关闭,此时抽取泵9会将称重瓶7内部的溶质通过软管抽入到水管中,然后通过水管流入到连接管22中,通过连接管22流入到进液管10中,最后通过多个出液口流出,同时旋转电机20会带动主动齿轮21进行旋转,通过主动齿轮21和从动齿轮23的配合使用连接管22会进行旋转,当连接管22进行旋转的过程中会带动进液管10进行旋转,从而会将溶质旋转喷洒在搅拌箱1的内部,这样可以满足均匀喷洒的要求,避免一次性注入降低混合的效果,当连接管22进行旋转的过程中会带动旋转柱11进行旋转,通过旋转柱11可以带动连接杆15进行旋转,当连接杆15进行旋转的过程中可以带动安装在连接杆15一端的第一齿轮17进行移动,通过第一齿轮17和第二齿轮18的配合,连接杆15会进行自转,当连接杆15进行自转的过程中会带动第四齿轮26进行旋转,通过第四齿轮26和第三齿轮19的配合,支撑杆27会进行旋转,从而会带动旋转盘28进行旋转,当旋转盘28进行旋转的过程中会使推杆25形成往复循环的运动,通过推杆25的往复运动可以带动移动杆13进行上下移动,从而搅拌叶12会进行上下移动,这样可以对搅拌箱1的内部进行全方位的搅拌,避免出现死角,提高了混合的均匀性,当溶质注入完成之后,按照上述流程依次对添加剂和稳定剂进行注入,更加有效的提高了混合的质量,可以使溶剂、溶质、添加剂和稳定剂进行充分的混合。Working principle of the present invention: in the specific implementation process, the required solvent can be injected into the inside of the stirring
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。Finally, it should be noted that: the above is only a preferred embodiment of the present invention, and is not intended to limit the present invention. Although the present invention has been described in detail with reference to the foregoing embodiments, for those skilled in the art, it still It is possible to modify the technical solutions recorded in the foregoing embodiments, or to perform equivalent replacements on some of the technical features. Any modifications, equivalent replacements, improvements, etc. within the spirit and principles of the present invention shall include Within the protection scope of the present invention.
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