CN106680178A - Gold plated layer pore detection method on silver-magnesium-nickel material - Google Patents
Gold plated layer pore detection method on silver-magnesium-nickel material Download PDFInfo
- Publication number
- CN106680178A CN106680178A CN201611193074.7A CN201611193074A CN106680178A CN 106680178 A CN106680178 A CN 106680178A CN 201611193074 A CN201611193074 A CN 201611193074A CN 106680178 A CN106680178 A CN 106680178A
- Authority
- CN
- China
- Prior art keywords
- silver
- nickel material
- detection method
- gold plated
- plated layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000001514 detection method Methods 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 title claims abstract description 25
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000010931 gold Substances 0.000 title claims abstract description 20
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 20
- RVTCUHAROXJTBC-UHFFFAOYSA-N [Mg].[Ni].[Ag] Chemical compound [Mg].[Ni].[Ag] RVTCUHAROXJTBC-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000011148 porous material Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 claims abstract description 24
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000007747 plating Methods 0.000 claims abstract description 8
- ATTFYOXEMHAYAX-UHFFFAOYSA-N magnesium nickel Chemical compound [Mg].[Ni] ATTFYOXEMHAYAX-UHFFFAOYSA-N 0.000 claims description 20
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 17
- 238000007654 immersion Methods 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000001035 drying Methods 0.000 abstract 1
- 230000000007 visual effect Effects 0.000 abstract 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 9
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- -1 potassium ferricyanide Chemical compound 0.000 description 1
- 238000000275 quality assurance Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N15/00—Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
- G01N15/08—Investigating permeability, pore-volume, or surface area of porous materials
- G01N15/088—Investigating volume, surface area, size or distribution of pores; Porosimetry
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
The invention discloses a gold plated layer pore detection method on a silver-magnesium-nickel material. After being soaked by a sodium sulphide solution, a gold plated part of the silver-magnesium-nickel material is taken out to be cleaned and is put into the air to perform still standing for 10 to 20min; then, drying and observation are performed; next, visual checking or observation under a microscope being 20 to 30 times is performed. During the process detection, the judging errors are small. The process is simple; the part plating quality guarantee performance is high; the production site control is easy.
Description
Technical field
The present invention relates to Gold plated Layer hole detection method on a kind of silver-colored magnesium nickel material, the little silver of particularly a kind of decision errors
Gold plated Layer hole detection method on magnesium nickel material.
Background technology
The development advanced by leaps and bounds with the information age, electronic component products volume of production are continued to increase.As electronic component
The craft of gilding quality of core process technology, is increasingly taken seriously.Gold-plated quality is directly connected to the matter of electronic product
Amount ensures which directly affects the reliability and stability of product.Class silver magnesium nickel material plating used in as electronic devices and components
Gold, the porosity of its coating have a strong impact on the functional characteristic of product.As contact resistance is big, often change colour etc..Therefore, quality assurance
Porosity detection is most important.
At present, the detection method without silver-colored magnesium nickel material gold-plating layer porosity, conventional is contrast reference.Often plated with iron material nickel plating
Gold, then with the potassium ferricyanide or potassium ferrocyanide mounting method detecting porosity, due to potassium ferrocyanide and the characteristic reaction of silver
Sensitivity is poor, is often compared detection with the gold-plated coating of iron-based nickel plating to its corresponding plated thickness detection porosity.Often
Method presses JB2112-77《The metal cladding porosity method of inspection, moistening reagent paper post method》, standard sample nickel plating is gold-plated
（With Gold plated Layer on silver-colored magnesium nickel material in same thickness range）Afterwards, potassium ferrocyanide solution is stained with reagent paper, be pasted on standard sample,
Repeatedly, then examine under a microscope coating surface hot spot, it was demonstrated that the presence of porosity.So detection occurs sentencing often
Determine error big, part quality of coating protection is low.And necessary professional's operation, it is poor that production scene controls.
The content of the invention
It is an object of the present invention to provide Gold plated Layer hole detection method on a kind of silver-colored magnesium nickel material, present invention process inspection
During survey, decision errors are little, process is simple, and part quality of coating protection is high.Production scene is easy to control.
The present invention employs the following technical solutions realization：
Gold plated Layer hole detection method on a kind of silver-colored magnesium nickel material, the plating metal parts Jing sodium sulfide solutions of silver-colored magnesium nickel material are soaked
Afterwards, take out cleaning, in air it is quiet put 10-20min after, be dried, observation, then visually or in 20-30 times of basis of microscopic observation,
.
Gold plated Layer hole detection method on aforesaid silver-colored magnesium nickel material, the sodium sulfide solution are so prepared：Go by every 1L
Ionized water adds 50g sodium sulfide, stirs, obtains final product.
Gold plated Layer hole detection method on aforesaid silver-colored magnesium nickel material, in immersion process, sodium sulfide solution temperature is 15-35
℃。
Gold plated Layer hole detection method on aforesaid silver-colored magnesium nickel material, sodium sulfide solution soak time are 5-20min.
With prior art ratio, the inventive method has the advantages that：
1st, during present invention detection, directly detected with part, i.e., directly part is placed in sodium sulfide solution and is soaked, Ran Houjing
Put, clean, being dried, then examining under a microscope corrosion of coating point.Therefore, the method operation is improved than mounting method operating efficiency
More than 10 times, and it is easy, therefore be easily applied to produce control.
, the inventive method decision errors it is little, applicant takes same batch qualified parts sample respectively, uses potassium ferrocyanide respectively
Being detected with the inventive method, in 100 times of basis of microscopic observation, as a result seen Fig. 1 and Fig. 2. Fig. 1 is potassium ferrocyanide detection
When observe result figure, Fig. 2 is to observe result figure when the inventive method is detected.Subsequently, applicant randomly selects 3 aforementioned ferrous irons
Potassium cyanide is detected as qualified part, observes, as a result see Fig. 3, Fig. 4 and Fig. 5 under Electronic Speculum under amplifying 1000 times, as seen from the figure,
Space is clearly present.Applicant randomly selects 3 aforementioned the inventive method and is detected as qualified part simultaneously, transfers in Electronic Speculum
Observe under big 1000 times, as a result see Fig. 6, Fig. 7 and Fig. 8, as seen from the figure, tight is present.It follows that detection method
It is less than existing detection method decision errors.
, this method cancel comparison and detection decision method, directly detected with electroplated component, and detected there is easy, field
Ground is less demanding, only needs beaker and microscope, and operator's skill set requirements are low, easily realize production scene control, it is ensured that coating matter
The concordance and stability of amount.And existing application technology, need calibrated bolck, reagent paper, beaker, reagent paper stickup to require smooth（Must not
It is crooked, not so paste deficiency of time）, paste bubble-free etc..
Description of the drawings
Fig. 1 is result figure when being detected with potassium ferrocyanide；
Fig. 2 is result figure when being detected with the inventive method；
Fig. 3 is to be detected as the result figure that qualified sample amplifies 1000 times under Electronic Speculum with potassium ferrocyanide（Sampling 1）；
Fig. 4 is to be detected as the result figure that qualified sample amplifies 1000 times under Electronic Speculum with potassium ferrocyanide（Sampling 2）；
Fig. 5 is to be detected as the result figure that qualified sample amplifies 1000 times under Electronic Speculum with potassium ferrocyanide（Sampling 3）；
Fig. 6 is to be detected as the result figure that qualified sample amplifies 1000 times under Electronic Speculum with the inventive method（Sampling 1-1）；
Fig. 7 is to be detected as the result figure that qualified sample amplifies 1000 times under Electronic Speculum with the inventive method（Sampling 1-2）；
Fig. 8 is to be detected as the result figure that qualified sample amplifies 1000 times under Electronic Speculum with the inventive method（Sampling 1-3）.
The present invention is further illustrated by the following examples, but not as limitation of the present invention.
Specific embodiment
Embodiment 1.
Gold plated Layer hole detection method on a kind of silver-colored magnesium nickel material, by the gold-plated of 1.5 μm of silver-colored magnesium nickel materials of plated thickness ＜
During Part temperature is 15-35 DEG C of sodium sulfide solution, after immersion 5min, take out, air collect it is quiet put 10min, be dried, then 25
Basis of microscopic observation again, should be less than 0.1mm without stain or local discolouration discoloration2, quantity must not be unnecessary 3 points, you can.
The sodium sulfide solution is so prepared：50g sodium sulfide is added by every 1L deionized waters, is stirred, is obtained final product.
Embodiment 2.
Gold plated Layer hole detection method on a kind of silver-colored magnesium nickel material, by the gold-plated of 1.5 μm of silver-colored magnesium nickel materials of plated thickness ＞
During Part temperature is 15-35 DEG C of sodium sulfide solution, after immersion 20min, take out, air collect it is quiet put 10min, be dried, Ran Hou
30 times of basis of microscopic observation, should be less than 0.1mm without stain or local discolouration discoloration2, quantity must not be unnecessary 3 points, you can.
The sodium sulfide solution is so prepared：50g sodium sulfide is added by every 1L deionized waters, is stirred, is obtained final product.
Claims (4)
1. Gold plated Layer hole detection method on a kind of silver-colored magnesium nickel material, it is characterised in that：By the plating metal parts Jing of silver-colored magnesium nickel material
After sodium sulfide solution immersion, take out cleaning, in air it is quiet put 10-20min after, be dried, observation, then visually or at 20-30 times
Basis of microscopic observation, you can.
2. Gold plated Layer hole detection method on silver-colored magnesium nickel material according to claim 1, it is characterised in that：The sodium sulfide
Solution is so prepared：50g sodium sulfide is added by every 1L deionized waters, is stirred, is obtained final product.
3. Gold plated Layer hole detection method on silver-colored magnesium nickel material according to claim 1, it is characterised in that：In immersion process
Sodium sulfide solution temperature is 15-35 DEG C.
4. Gold plated Layer hole detection method on silver-colored magnesium nickel material according to claim 1, it is characterised in that：Sodium sulfide solution
Soak time is 5-20min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611193074.7A CN106680178A (en) | 2016-12-21 | 2016-12-21 | Gold plated layer pore detection method on silver-magnesium-nickel material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611193074.7A CN106680178A (en) | 2016-12-21 | 2016-12-21 | Gold plated layer pore detection method on silver-magnesium-nickel material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106680178A true CN106680178A (en) | 2017-05-17 |
Family
ID=58870179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611193074.7A Pending CN106680178A (en) | 2016-12-21 | 2016-12-21 | Gold plated layer pore detection method on silver-magnesium-nickel material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106680178A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108007924A (en) * | 2017-11-09 | 2018-05-08 | 江苏稳润光电科技有限公司 | A kind of method of detection support quality of coating |
| CN114808060A (en) * | 2021-05-19 | 2022-07-29 | 上海亿尚金属有限公司 | Efficient roll-to-roll electroplating process for metal material and application of efficient roll-to-roll electroplating process |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1764818A1 (en) * | 1990-12-25 | 1992-09-30 | Пермское производственное объединение "Моторостроитель" им.Я.М.Свердлова | Method for checking porosity of articles produced by powder metallurgy process |
| CN102313690A (en) * | 2010-07-07 | 2012-01-11 | 宝山钢铁股份有限公司 | Rotating disk electrode method for quantitative testing of porosity of tinned steel plate |
| CN102636423A (en) * | 2011-02-12 | 2012-08-15 | 宝山钢铁股份有限公司 | Detection method of tin plate porosity |
| CN102914492A (en) * | 2012-10-18 | 2013-02-06 | 北京邮电大学 | Method for determining porosity of gold plating layer by utilizing sulfite solution |
| CN103308439A (en) * | 2013-06-18 | 2013-09-18 | 北京科技大学 | Method for evaluating effective porosity of metal corrosion product film |
-
2016
- 2016-12-21 CN CN201611193074.7A patent/CN106680178A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1764818A1 (en) * | 1990-12-25 | 1992-09-30 | Пермское производственное объединение "Моторостроитель" им.Я.М.Свердлова | Method for checking porosity of articles produced by powder metallurgy process |
| CN102313690A (en) * | 2010-07-07 | 2012-01-11 | 宝山钢铁股份有限公司 | Rotating disk electrode method for quantitative testing of porosity of tinned steel plate |
| CN102636423A (en) * | 2011-02-12 | 2012-08-15 | 宝山钢铁股份有限公司 | Detection method of tin plate porosity |
| CN102914492A (en) * | 2012-10-18 | 2013-02-06 | 北京邮电大学 | Method for determining porosity of gold plating layer by utilizing sulfite solution |
| CN103308439A (en) * | 2013-06-18 | 2013-09-18 | 北京科技大学 | Method for evaluating effective porosity of metal corrosion product film |
Non-Patent Citations (1)
| Title |
|---|
| 张丽丽 等: "银在硫化钠溶液中的变色行为", 《装备环境工程》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108007924A (en) * | 2017-11-09 | 2018-05-08 | 江苏稳润光电科技有限公司 | A kind of method of detection support quality of coating |
| CN114808060A (en) * | 2021-05-19 | 2022-07-29 | 上海亿尚金属有限公司 | Efficient roll-to-roll electroplating process for metal material and application of efficient roll-to-roll electroplating process |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170517 |