CN106676395A - Corrosion resisting molybdenum-vanadium alloy steel and application of corrosion resisting molybdenum-vanadium alloy steel to drilling-in drill rod - Google Patents

Corrosion resisting molybdenum-vanadium alloy steel and application of corrosion resisting molybdenum-vanadium alloy steel to drilling-in drill rod Download PDF

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CN106676395A
CN106676395A CN201610548745.0A CN201610548745A CN106676395A CN 106676395 A CN106676395 A CN 106676395A CN 201610548745 A CN201610548745 A CN 201610548745A CN 106676395 A CN106676395 A CN 106676395A
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molybdenum
zirconium
titanium
vanadium
vanadium alloy
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吴舒晨
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/10Ferrous alloys, e.g. steel alloys containing cobalt
    • C22C38/105Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
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  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

The invention discloses corrosion resisting molybdenum-vanadium alloy steel and application of the corrosion resisting molybdenum-vanadium alloy steel to a drilling-in drill rod. The corrosion resisting molybdenum-vanadium alloy steel comprises, by mass percent, 0.38%-0.46% of carbon, 7.6%-8.4% of molybdenum, 2.8%-3.6% of vanadium, 1.1%-1.5% of nickel, 0.9%-1.5% of silicon, 0.06%-0.10% of rhenium, 0.8%-1.4% of manganese, 0.07%-0.09% of cobalt, 0.013%-0.017% of phosphorus, 0.44%-0.62% of chromium, 0.04%-0.08% of sulfur, 0.09%-0.15% of rubidium, 0.02%-0.04% of strontium, 0.014%-0.018% of gallium, 0.04%-0.06% of titanium and zirconium, and the balance iron, wherein the mass percent proportion of titanium to zirconium is 3-5:1. The provided molybdenum-vanadium alloy steel material is excellent in corrosion resisting performance and is suitable for preparing the drilling-in drill rod.

Description

A kind of corrosion-resistant molybdenum vanadium alloy and its application in drilling drilling rod
Technical field
The invention belongs to drilling rod field, and in particular to a kind of corrosion-resistant molybdenum vanadium alloy and its answering in drilling drilling rod With.
Background technology
Steel is the general designation of iron-carbon alloy.In actual production, steel often contains different alloy units according to the difference of purposes Element, the mankind are quite long to the application of steel and research history, but before the Bessemerizing invention of 19th century, steel is produced All it is the inefficient work of a high cost.Nowadays, steel is become in the world using most with its cheap price, reliable performance One of material, be composition indispensable in building industry, manufacturing industry and people's daily life.It may be said that steel is modern society Material base.But steel self character has shortcoming, density is high, heavier, and than being easier to be corroded, comparison is crisp to be easily broken off.
In practical application, drilling drilling rod needs have higher decay resistance with steel.
The content of the invention
It is an object of the invention to provide a kind of corrosion-resistant molybdenum vanadium alloy and its application in drilling drilling rod.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of corrosion-resistant molybdenum vanadium alloy, its chemical composition and mass percent are:Carbon 0.38~0.46%, molybdenum 7.6~ 8.4%, vanadium 2.8~3.6%, nickel 1.1~1.5%, silicon 0.9~1.5%, rhenium 0.06~0.10%, manganese 0.8~1.4%, cobalt 0.07~0.09%, phosphorus 0.013~0.017%, chromium 0.44~0.62%, sulfur 0.04~0.08%, rubidium 0.09~0.15%, strontium 0.02~0.04%, gallium 0.014~0.018%, titanium and zirconium totally 0.04~0.06%, the ratio of mass percent shared by titanium and zirconium For 3~5:1, remaining is ferrum.
Further, the corrosion-resistant molybdenum vanadium alloy chemical composition and mass percent are:Carbon 0.42%, molybdenum 8.0%, Vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, the ratio of titanium and zirconium mass percent is 4: 1, remaining is ferrum.
Further, the corrosion-resistant molybdenum vanadium alloy chemical composition and mass percent are:Carbon 0.38%, molybdenum 7.6%, Vanadium 2.8%, nickel 1.1%, silicon 0.9%, rhenium 0.06%, manganese 0.8%, cobalt 0.07%, phosphorus 0.013%, chromium 0.44%, sulfur 0.04%, rubidium 0.09%, strontium 0.02%, gallium 0.014%, titanium and zirconium totally 0.04%, the ratio of mass percent shared by titanium and zirconium For 3:1, remaining is ferrum.
Further, the corrosion-resistant molybdenum vanadium alloy chemical composition and mass percent are:Carbon 0.46%, molybdenum 8.4%, Vanadium 3.6%, nickel 1.5%, silicon 1.5%, rhenium 0.10%, manganese 1.4%, cobalt 0.09%, phosphorus 0.017%, chromium 0.62%, sulfur 0.08%, rubidium 0.15%, strontium 0.04%, gallium 0.018%, titanium and zirconium totally 0.06%, the ratio of mass percent shared by titanium and zirconium For 5:1, remaining is ferrum.
Application of the above-mentioned corrosion-resistant molybdenum vanadium alloy in drilling drilling rod is prepared.
Advantages of the present invention:
The molybdenum vanadium-base alloy Steel material excellent anti-corrosion performance that the present invention is provided, is suitable for preparing drilling drilling rod.
Specific embodiment
The essentiality content of the present invention is further illustrated with reference to embodiment, but the present invention is not limited with this and protect model Enclose.Although being explained in detail to the present invention with reference to preferred embodiment, it will be understood by those within the art that, can be right Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1:Molybdenum vanadium-base alloy Steel material
Chemical composition and mass percent are:Carbon 0.42%, molybdenum 8.0%, vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, the ratio of mass percent shared by titanium and zirconium is 4:1, remaining is ferrum.
Embodiment 2:Molybdenum vanadium-base alloy Steel material
Chemical composition and mass percent are:Carbon 0.38%, molybdenum 7.6%, vanadium 2.8%, nickel 1.1%, silicon 0.9%, rhenium 0.06%, manganese 0.8%, cobalt 0.07%, phosphorus 0.013%, chromium 0.44%, sulfur 0.04%, rubidium 0.09%, strontium 0.02%, gallium 0.014%, titanium and zirconium totally 0.04%, the ratio of mass percent shared by titanium and zirconium is 3:1, remaining is ferrum.
Embodiment 3:Molybdenum vanadium-base alloy Steel material
Chemical composition and mass percent are:Carbon 0.46%, molybdenum 8.4%, vanadium 3.6%, nickel 1.5%, silicon 1.5%, rhenium 0.10%, manganese 1.4%, cobalt 0.09%, phosphorus 0.017%, chromium 0.62%, sulfur 0.08%, rubidium 0.15%, strontium 0.04%, gallium 0.018%, titanium and zirconium totally 0.06%, the ratio of mass percent shared by titanium and zirconium is 5:1, remaining is ferrum.
Embodiment 4:Molybdenum vanadium-base alloy Steel material
Chemical composition and mass percent are:Carbon 0.42%, molybdenum 8.0%, vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, the ratio of mass percent shared by titanium and zirconium is 3:1, remaining is ferrum.
Embodiment 5:Molybdenum vanadium-base alloy Steel material
Chemical composition and mass percent are:Carbon 0.42%, molybdenum 8.0%, vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, the ratio of mass percent shared by titanium and zirconium is 5:1, remaining is ferrum.
Embodiment 6:Comparative example
Chemical composition and mass percent are:Carbon 0.42%, molybdenum 8.0%, vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, the ratio of mass percent shared by titanium and zirconium is 2:1, remaining is ferrum.
Embodiment 7:Comparative example
Chemical composition and mass percent are:Carbon 0.42%, molybdenum 8.0%, vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, the ratio of mass percent shared by titanium and zirconium is 6:1, remaining is ferrum.
Embodiment 8:Effect example
The steel alloy of the embodiment 1~7 to preparing has carried out corrosion-resistant test.By the Steel material of embodiment 1~7 point In not being put into the potassium hydroxide solution of the NaCl solution of 5wt%, the sulfuric acid solution of 10wt% and 10wt%, minute is 1 year.
As a result see the table below.
The NaCl solution of 5wt% The sulfuric acid solution of 10wt% The potassium hydroxide of 10wt%
Embodiment 1 0.0002mm/ 0.001mm/ 0.001mm/
Embodiment 4 0.0002mm/ 0.001mm/ 0.001mm/
Embodiment 5 0.0002mm/ 0.001mm/ 0.001mm/
Embodiment 6 0.0010mm/ 0.013mm/ 0.009mm/
Embodiment 7 0.0012mm/ 0.015mm/ 0.013mm/
Embodiment 2,3 test results and embodiment 4,5 are basically identical.
The molybdenum vanadium-base alloy Steel material excellent anti-corrosion performance that the present invention is provided, is suitable for preparing drilling drilling rod.
The effect of above-described embodiment indicate that the present invention essentiality content, but not with this limit the present invention protection Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent, Without deviating from the essence and protection domain of technical solution of the present invention.

Claims (5)

1. a kind of corrosion-resistant molybdenum vanadium alloy, it is characterised in that its chemical composition and mass percent are:Carbon 0.38~ 0.46%, molybdenum 7.6~8.4%, vanadium 2.8~3.6%, nickel 1.1~1.5%, silicon 0.9~1.5%, rhenium 0.06~0.10%, manganese 0.8~1.4%, cobalt 0.07~0.09%, phosphorus 0.013~0.017%, chromium 0.44~0.62%, sulfur 0.04~0.08%, rubidium 0.09~0.15%, strontium 0.02~0.04%, gallium 0.014~0.018%, titanium and zirconium totally 0.04~0.06%, shared by titanium and zirconium The ratio of mass percent is 3~5:1, remaining is ferrum.
2. corrosion-resistant molybdenum vanadium alloy according to claim 1, it is characterised in that chemical composition and mass percent are: Carbon 0.42%, molybdenum 8.0%, vanadium 3.2%, nickel 1.3%, silicon 1.2%, rhenium 0.08%, manganese 1.1%, cobalt 0.08%, phosphorus 0.015%, Chromium 0.53%, sulfur 0.06%, rubidium 0.12%, strontium 0.03%, gallium 0.016%, titanium and zirconium totally 0.05%, quality hundred shared by titanium and zirconium The ratio for dividing ratio is 4:1, remaining is ferrum.
3. corrosion-resistant molybdenum vanadium alloy according to claim 1, it is characterised in that chemical composition and mass percent are: Carbon 0.38%, molybdenum 7.6%, vanadium 2.8%, nickel 1.1%, silicon 0.9%, rhenium 0.06%, manganese 0.8%, cobalt 0.07%, phosphorus 0.013%, Chromium 0.44%, sulfur 0.04%, rubidium 0.09%, strontium 0.02%, gallium 0.014%, titanium and zirconium totally 0.04%, quality hundred shared by titanium and zirconium The ratio for dividing ratio is 3:1, remaining is ferrum.
4. corrosion-resistant molybdenum vanadium alloy according to claim 1, it is characterised in that chemical composition and mass percent are: Carbon 0.46%, molybdenum 8.4%, vanadium 3.6%, nickel 1.5%, silicon 1.5%, rhenium 0.10%, manganese 1.4%, cobalt 0.09%, phosphorus 0.017%, Chromium 0.62%, sulfur 0.08%, rubidium 0.15%, strontium 0.04%, gallium 0.018%, titanium and zirconium totally 0.06%, quality hundred shared by titanium and zirconium The ratio for dividing ratio is 5:1, remaining is ferrum.
5. application of the arbitrary corrosion-resistant molybdenum vanadium alloy of Claims 1 to 4 in drilling drilling rod is prepared.
CN201610548745.0A 2016-07-11 2016-07-11 Corrosion resisting molybdenum-vanadium alloy steel and application of corrosion resisting molybdenum-vanadium alloy steel to drilling-in drill rod Pending CN106676395A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001042524A2 (en) * 1999-12-07 2001-06-14 The Timken Company Low carbon, low chromium carburizing high speed steels

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001042524A2 (en) * 1999-12-07 2001-06-14 The Timken Company Low carbon, low chromium carburizing high speed steels

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张其枢: "《不锈钢焊接技术》", 31 July 2015, 机械工业出版社 *
陆宝山: "《模具材料与热处理》", 31 January 2016 *

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Application publication date: 20170517