CN106191689A - A kind of corrosion-resistant molybdenum rubidium alloy steel and the application in creeping into drilling rod thereof - Google Patents

A kind of corrosion-resistant molybdenum rubidium alloy steel and the application in creeping into drilling rod thereof Download PDF

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Publication number
CN106191689A
CN106191689A CN201610548465.XA CN201610548465A CN106191689A CN 106191689 A CN106191689 A CN 106191689A CN 201610548465 A CN201610548465 A CN 201610548465A CN 106191689 A CN106191689 A CN 106191689A
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rubidium
molybdenum
cadmium
palladium
alloy steel
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吴舒晨
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/10Ferrous alloys, e.g. steel alloys containing cobalt
    • C22C38/105Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
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  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a kind of corrosion-resistant molybdenum rubidium alloy steel and the application in creeping into drilling rod thereof, its chemical composition and mass percent be: carbon 0.38~0.46%, molybdenum 5.6~6.2%, rubidium 2.6~3.4%, manganese 0.8~1.2%, rhenium 0.05~0.09%, gallium 0.012~0.018%, zirconium 0.35~0.45%, silicon 0.5~1.5%, nickel 1.0~1.6%, strontium 0.02~0.06%, cobalt 0.06~0.08%, rhodium 0.07~0.17%, phosphorus 0.010~0.014%, sulfur 0.07~0.09%, palladium and cadmium totally 0.07~0.09%, the ratio of mass percent shared by palladium and cadmium is 6~8:1, remaining is ferrum.The molybdenum rubidium-base alloy Steel material excellent anti-corrosion performance that the present invention provides, is suitable for preparation and creeps into drilling rod.

Description

A kind of corrosion-resistant molybdenum rubidium alloy steel and the application in creeping into drilling rod thereof
Technical field
The invention belongs to drilling rod field, be specifically related to a kind of corrosion-resistant molybdenum rubidium alloy steel and answering in creeping into drilling rod thereof With.
Background technology
Steel is the general designation of iron-carbon alloy.In actual production, steel often contains different alloy units according to the difference of purposes Element, the mankind are the longest to application and the research history of steel, but until the Bessemerizing invention of 19th century, producing of steel It is all the work of a high cost poor efficiency.Nowadays, steel becomes use in the world at most with its cheap price, reliable performance One of material, be composition indispensable in building industry, manufacturing industry and people's daily life.It may be said that Gang Shi modern society Material base.But steel self character exists shortcoming, density is high, and heavier, ratio is easier to be corroded, and compares the most crisp being easily broken off.
In actual application, creeping into drilling rod steel needs have higher decay resistance.
Summary of the invention
It is an object of the invention to provide a kind of corrosion-resistant molybdenum rubidium alloy steel and the application in creeping into drilling rod thereof.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of corrosion-resistant molybdenum rubidium alloy steel, its chemical composition and mass percent be: carbon 0.38~0.46%, molybdenum 5.6~ 6.2%, rubidium 2.6~3.4%, manganese 0.8~1.2%, rhenium 0.05~0.09%, gallium 0.012~0.018%, zirconium 0.35~ 0.45%, silicon 0.5~1.5%, nickel 1.0~1.6%, strontium 0.02~0.06%, cobalt 0.06~0.08%, rhodium 0.07~ 0.17%, phosphorus 0.010~0.014%, sulfur 0.07~0.09%, palladium and cadmium totally 0.07~0.09%, quality hundred shared by palladium and cadmium The ratio of proportion by subtraction is 6~8:1, and remaining is ferrum.
Further, described corrosion-resistant molybdenum rubidium alloy steel chemical composition and mass percent be: carbon 0.42%, molybdenum 5.9%, Rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, nickel 1.3%, strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, the ratio of mass percent shared by palladium and cadmium For 7:1, remaining is ferrum.
Further, described corrosion-resistant molybdenum rubidium alloy steel chemical composition and mass percent be: carbon 0.38%, molybdenum 5.6%, Rubidium 2.6%, manganese 0.8%, rhenium 0.05%, gallium 0.012%, zirconium 0.35%, silicon 0.5%, nickel 1.0%, strontium 0.02%, cobalt 0.06%, rhodium 0.07%, phosphorus 0.010%, sulfur 0.07%, palladium and cadmium totally 0.07%, the ratio of mass percent shared by palladium and cadmium For 6:1, remaining is ferrum.
Further, described corrosion-resistant molybdenum rubidium alloy steel chemical composition and mass percent be: carbon 0.46%, molybdenum 6.2%, Rubidium 3.4%, manganese 1.2%, rhenium 0.09%, gallium 0.018%, zirconium 0.45%, silicon 1.5%, nickel 1.6%, strontium 0.06%, cobalt 0.08%, rhodium 0.17%, phosphorus 0.014%, sulfur 0.09%, palladium and cadmium totally 0.09%, the ratio of mass percent shared by palladium and cadmium For 8:1, remaining is ferrum.
Above-mentioned corrosion-resistant molybdenum rubidium alloy steel creeps into the application in drilling rod in preparation.
Advantages of the present invention:
The molybdenum rubidium-base alloy Steel material excellent anti-corrosion performance that the present invention provides, is suitable for preparation and creeps into drilling rod.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: molybdenum rubidium-base alloy Steel material
Carbon 0.42%, molybdenum 5.9%, rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, Nickel 1.3%, strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, palladium and cadmium institute The ratio accounting for mass percent is 7:1, and remaining is ferrum.
Embodiment 2: molybdenum rubidium-base alloy Steel material
Carbon 0.38%, molybdenum 5.6%, rubidium 2.6%, manganese 0.8%, rhenium 0.05%, gallium 0.012%, zirconium 0.35%, silicon 0.5%, Nickel 1.0%, strontium 0.02%, cobalt 0.06%, rhodium 0.07%, phosphorus 0.010%, sulfur 0.07%, palladium and cadmium totally 0.07%, palladium and cadmium institute The ratio accounting for mass percent is 6:1, and remaining is ferrum.
Embodiment 3: molybdenum rubidium-base alloy Steel material
Carbon 0.46%, molybdenum 6.2%, rubidium 3.4%, manganese 1.2%, rhenium 0.09%, gallium 0.018%, zirconium 0.45%, silicon 1.5%, Nickel 1.6%, strontium 0.06%, cobalt 0.08%, rhodium 0.17%, phosphorus 0.014%, sulfur 0.09%, palladium and cadmium totally 0.09%, palladium and cadmium institute The ratio accounting for mass percent is 8:1, and remaining is ferrum.
Embodiment 4: molybdenum rubidium-base alloy Steel material
Carbon 0.42%, molybdenum 5.9%, rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, Nickel 1.3%, strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, palladium and cadmium institute The ratio accounting for mass percent is 6:1, and remaining is ferrum.
Embodiment 5: molybdenum rubidium-base alloy Steel material
Carbon 0.42%, molybdenum 5.9%, rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, Nickel 1.3%, strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, palladium and cadmium institute The ratio accounting for mass percent is 8:1, and remaining is ferrum.
Embodiment 6: comparative example
Carbon 0.42%, molybdenum 5.9%, rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, Nickel 1.3%, strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, palladium and cadmium institute The ratio accounting for mass percent is 5:1, and remaining is ferrum.
Embodiment 7: comparative example
Carbon 0.42%, molybdenum 5.9%, rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, Nickel 1.3%, strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, palladium and cadmium institute The ratio accounting for mass percent is 9:1, and remaining is ferrum.
Embodiment 8: effect example
The steel alloy of embodiment 1~7 has been carried out corrosion-resistant test.The Steel material of embodiment 1~7 is respectively put into In the potassium hydroxide solution of the NaCl solution of 5wt%, the sulfuric acid solution of 10wt% and 10wt%, minute is 1 year.
Result see table.
The NaCl solution of 5wt% The sulfuric acid solution of 10wt% The potassium hydroxide of 10wt%
Embodiment 1 0.0001mm/ 0.001mm/ 0.001mm/
Embodiment 4 0.0003mm/ 0.003mm/ 0.002mm/
Embodiment 5 0.0003mm/ 0.003mm/ 0.002mm/
Embodiment 6 0.0012mm/ 0.014mm/ 0.010mm/
Embodiment 7 0.0012mm/ 0.015mm/ 0.011mm/
Embodiment 2,3 test result is basically identical with embodiment 4,5.
The molybdenum rubidium-base alloy Steel material excellent anti-corrosion performance that the present invention provides, is suitable for preparation and creeps into drilling rod.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent, Essence and protection domain without deviating from technical solution of the present invention.

Claims (5)

1. a corrosion-resistant molybdenum rubidium alloy steel, it is characterised in that its chemical composition and mass percent be: carbon 0.38~ 0.46%, molybdenum 5.6~6.2%, rubidium 2.6~3.4%, manganese 0.8~1.2%, rhenium 0.05~0.09%, gallium 0.012~ 0.018%, zirconium 0.35~0.45%, silicon 0.5~1.5%, nickel 1.0~1.6%, strontium 0.02~0.06%, cobalt 0.06~ 0.08%, rhodium 0.07~0.17%, phosphorus 0.010~0.014%, sulfur 0.07~0.09%, palladium and cadmium totally 0.07~0.09%, palladium With cadmium shared by the ratio of mass percent be 6~8:1, remaining is ferrum.
Corrosion-resistant molybdenum rubidium alloy steel the most according to claim 1, it is characterised in that chemical composition and mass percent be: Carbon 0.42%, molybdenum 5.9%, rubidium 3.0%, manganese 1.0%, rhenium 0.07%, gallium 0.015%, zirconium 0.40%, silicon 1.0%, nickel 1.3%, Strontium 0.04%, cobalt 0.07%, rhodium 0.12%, phosphorus 0.012%, sulfur 0.08%, palladium and cadmium totally 0.08%, quality hundred shared by palladium and cadmium The ratio of proportion by subtraction is 7:1, and remaining is ferrum.
Corrosion-resistant molybdenum rubidium alloy steel the most according to claim 1, it is characterised in that chemical composition and mass percent be: Carbon 0.38%, molybdenum 5.6%, rubidium 2.6%, manganese 0.8%, rhenium 0.05%, gallium 0.012%, zirconium 0.35%, silicon 0.5%, nickel 1.0%, Strontium 0.02%, cobalt 0.06%, rhodium 0.07%, phosphorus 0.010%, sulfur 0.07%, palladium and cadmium totally 0.07%, quality hundred shared by palladium and cadmium The ratio of proportion by subtraction is 6:1, and remaining is ferrum.
Corrosion-resistant molybdenum rubidium alloy steel the most according to claim 1, it is characterised in that chemical composition and mass percent be: Carbon 0.46%, molybdenum 6.2%, rubidium 3.4%, manganese 1.2%, rhenium 0.09%, gallium 0.018%, zirconium 0.45%, silicon 1.5%, nickel 1.6%, Strontium 0.06%, cobalt 0.08%, rhodium 0.17%, phosphorus 0.014%, sulfur 0.09%, palladium and cadmium totally 0.09%, quality hundred shared by palladium and cadmium The ratio of proportion by subtraction is 8:1, and remaining is ferrum.
5. the arbitrary described corrosion-resistant molybdenum rubidium alloy steel of Claims 1 to 4 creeps into the application in drilling rod in preparation.
CN201610548465.XA 2016-07-11 2016-07-11 A kind of corrosion-resistant molybdenum rubidium alloy steel and the application in creeping into drilling rod thereof Pending CN106191689A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005139485A (en) * 2003-11-05 2005-06-02 Nippon Steel Corp Steel sheet to be hot-formed
CN101275207A (en) * 2007-03-27 2008-10-01 宝山钢铁股份有限公司 H2S-corrosion-resistant tool joint for petroleum drill pipe and hot treatment method thereof
EP2476772A1 (en) * 2011-01-13 2012-07-18 Rovalma, S.A. High thermal diffusivity and high wear resistance tool steel
CN104532149A (en) * 2014-12-22 2015-04-22 江阴兴澄特种钢铁有限公司 Round steel with high strength and toughness and hydrogen sulfide stress corrosion resistance for drilling tool and manufacturing method of round steel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005139485A (en) * 2003-11-05 2005-06-02 Nippon Steel Corp Steel sheet to be hot-formed
CN101275207A (en) * 2007-03-27 2008-10-01 宝山钢铁股份有限公司 H2S-corrosion-resistant tool joint for petroleum drill pipe and hot treatment method thereof
EP2476772A1 (en) * 2011-01-13 2012-07-18 Rovalma, S.A. High thermal diffusivity and high wear resistance tool steel
CN104532149A (en) * 2014-12-22 2015-04-22 江阴兴澄特种钢铁有限公司 Round steel with high strength and toughness and hydrogen sulfide stress corrosion resistance for drilling tool and manufacturing method of round steel

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
姚天扬等: "《大学化学下》", 30 May 2014, 南京大学出版社 *
胡隆伟等主编: "《紧固件材料手册》", 30 December 2014, 北京:中国宇航出版社 *

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