CN106675431A - Two-sided edge sealing adhesive tape arranged between upper glass and lower glass of solar double-glass assembly - Google Patents

Two-sided edge sealing adhesive tape arranged between upper glass and lower glass of solar double-glass assembly Download PDF

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Publication number
CN106675431A
CN106675431A CN201611256811.3A CN201611256811A CN106675431A CN 106675431 A CN106675431 A CN 106675431A CN 201611256811 A CN201611256811 A CN 201611256811A CN 106675431 A CN106675431 A CN 106675431A
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CN
China
Prior art keywords
resin
glass
curing agent
edge sealing
parts
Prior art date
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Pending
Application number
CN201611256811.3A
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Chinese (zh)
Inventor
周琪权
陈洪野
芋野昌三
吴小平
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Cybrid Technologies Inc
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Cybrid Technologies Inc
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Publication date
Application filed by Cybrid Technologies Inc filed Critical Cybrid Technologies Inc
Priority to CN201611256811.3A priority Critical patent/CN106675431A/en
Publication of CN106675431A publication Critical patent/CN106675431A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/132—Phenols containing keto groups, e.g. benzophenones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J127/12—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J127/12—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09J127/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J127/12—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09J127/18—Homopolymers or copolymers of tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09J133/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C09J183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber
    • C09J7/243—Ethylene or propylene polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/26—Porous or cellular plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/322—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/24—Presence of a foam
    • C09J2400/243—Presence of a foam in the substrate
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2423/00—Presence of polyolefin
    • C09J2423/04—Presence of homo or copolymers of ethene
    • C09J2423/046—Presence of homo or copolymers of ethene in the substrate
    • C—CHEMISTRY; METALLURGY
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    • C09J2423/00—Presence of polyolefin
    • C09J2423/16—Presence of ethen-propene or ethene-propene-diene copolymers
    • C09J2423/166—Presence of ethen-propene or ethene-propene-diene copolymers in the substrate
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    • C09J2427/00—Presence of halogenated polymer
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    • C09J2427/006—Presence of halogenated polymer in the substrate
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    • C09J2475/006—Presence of polyurethane in the substrate
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a two-sided edge sealing adhesive tape arranged between upper glass and lower glass of a solar double-glass assembly. The two-sided edge sealing adhesive tape comprises a substrate layer and adhesive layers formed on two surfaces of the substrate layer. Each adhesive layer comprises raw materials in parts by weight as follows: 50-200 parts of matrix resin, 0.1-10 parts of a curing agent, 0-20 parts of an antioxidant and 0-20 parts of an ultraviolet absorber, wherein the matrix resin is selected from one or a mixture of polytetrafluoroethylene fluorocarbon resin, polyvinyl-difluoride fluorocarbon resin, perfluoro resin, fluorine-containing acrylic resin, fluoro-silicone resin, epoxy resin and acrylic resin; the curing agent is a mixture of two or more of an isocyanate curing agent, an imidazole curing agent, a hydrazide curing agent, an amino resin curing agent, an amine curing agent and a dicyanodiamide curing agent, and at least one of the curing agents is a latent curing agent. The adhesive tape has microviscosity before use, and the curing agent can further perform thorough curing under high temperature during lamination.

Description

A kind of two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass
Technical field
The invention belongs to area of solar cell, is related to a kind of two-sided edge sealing adhesive band, and in particular to one kind inserts solar energy Two-sided edge sealing adhesive band in the middle of solar double-glass assemblies levels glass.
Background technology
It is all kinds of photovoltaic cell products of protection in double-glass solar energy assembly, is designed with special outer sealing edge adhesive tape Reinforcement by connection glass edge, prevents the impact of steam and oxygen to cell piece.The most of DeGrains of existing such adhesive tape, patch The property covered is bad, and aging rear yielding, corner is easily raised because of overlap；And in lamination process, the spilling of glued membrane can shadow Outward appearance is rung, needs to carry out the process such as bound edge.
The content of the invention
The invention aims to overcome the deficiencies in the prior art and provide one kind and insert solar energy solar double-glass assemblies levels Two-sided edge sealing adhesive band in the middle of glass.
To reach above-mentioned purpose, the technical solution adopted in the present invention is：One kind inserts solar energy solar double-glass assemblies levels Two-sided edge sealing adhesive band in the middle of glass, it includes substrate layer and is formed in the adhesive layer on the surface of the substrate layer two, the glue Glutinous layer includes the raw material components of following parts by weight：50~200 parts of matrix resin, 0.1~10 part of firming agent, antioxidant 0~20 0~20 part of part and ultraviolet absorber；Described matrix resin is selected from politef fluorocarbon resin, poly- difluoroethylene fluorine carbon tree One or more composition in fat, perfluorinated resin, fluoroacrylic resin, fluorine silicon resin, epoxy resin and acrylic resin Mixture；The firming agent be selected from isocyanates system firming agent, imidazole curing agent, hydrazides firming agent, amine resin firming agent, The mixture of two or more compositions in amine curing agent and cyanamid dimerization system firming agent, wherein at least one is latency Firming agent.
Optimally, the adhesive layer includes the raw material components of following parts by weight：80~150 parts of matrix resin, firming agent 1 2~10 parts of~5 parts, 2~10 parts of antioxidant and ultraviolet absorber.
Further, the antioxidant is in aromatic amine antioxidant, Hinered phenols antioxidant and auxiliary antioxidant The mixture of one or more composition.
Further, the ultraviolet absorber is selected from salicylic acid esters, benzophenone class, benzotriazole and group-substituted acrylonitrile In one or more combination thing.
Further, the thickness of the adhesive layer is 50~120 μm.
Further, the substrate layer is the foam of PE, PU, EPDM or PVC material.
Further, the thickness of the substrate layer is 300~600 μm.
Further, the adhesive layer is will to be coated in the base material layer surface after its raw material components mixing, be subsequently placed at 30~60 DEG C of ripenings are obtained for 10~80 hours.
Because above-mentioned technical proposal is used, the present invention has compared with prior art following advantages：The present invention inserts the sun Two-sided edge sealing adhesive band in the middle of energy solar double-glass assemblies levels glass, the adhesive layer of employing has, Jing big with photovoltaic glass bonding force Peeling force decay after burn-in test is little, while having color inhibition and having excellent weather resistance, can avoid what docile sex chromosome mosaicism caused Block water oxygen problem；It will not produce deformation in hot pressing, can effectively prevent the spilling of glued membrane, with excellent resistance to Time, resistance to elevated temperatures；Substrate layer is foam, and it can play bradyseism effect in hot pressing.
Description of the drawings
Fig. 1 is the structural representation of the two-sided edge sealing adhesive band that the present invention is inserted in the middle of solar energy solar double-glass assemblies levels glass Figure.
Specific embodiment
The two-sided edge sealing adhesive band that the present invention is inserted in the middle of solar energy solar double-glass assemblies levels glass, it include substrate layer 1 with And the adhesive layer 2 on 1 liang of surface of the substrate layer is formed in, the adhesive layer 2 includes the raw material components of following parts by weight：Matrix 0~20 part of 50~200 parts of resin, 0.1~10 part of firming agent, 0~20 part of antioxidant and ultraviolet absorber；Described matrix resin Be selected from politef fluorocarbon resin, poly- difluoroethylene fluorocarbon resin, perfluorinated resin, fluoroacrylic resin, fluorine silicon resin, The mixture of one or more composition in epoxy resin and acrylic resin；The firming agent is selected from the solidification of isocyanates system Two kinds in agent, imidazole curing agent, hydrazides firming agent, amine resin firming agent, amine curing agent and cyanamid dimerization system firming agent Or the mixture of various compositions, wherein at least one is latent curing agent；There is microviscosity using front adhesive tape, during lamination High temperature can be further such that firming agent completion of cure；It will not produce deformation in hot pressing, can effectively prevent glue The spilling of film, with excellent weather-proof, resistance to elevated temperatures.When adhesive layer 2 includes the raw material components of following parts by weight：Matrix tree When 2~10 parts of 80~150 parts of fat, 1~5 part of firming agent, 2~10 parts of antioxidant and ultraviolet absorber, two-sided edge sealing adhesive band Performance is more excellent.Above-mentioned antioxidant selected from aromatic amine antioxidant (such as dihydroquinoline, diphenylamines and p-phenylenediamine compound, its Derivant or polymer etc.), Hinered phenols antioxidant is (such as 2,6- three-level butyl -4- methylphenols, double (3,5- three-level butyl -4- Hydroxy phenyl) thioether, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propanoic acid) pentaerythritol esters etc.) and auxiliary antioxidant is (such as Double Lauryl Alcohol esters, double ten four carbon alcohols esters and double octadecanol esters etc.) in one or more composition mixture.Uv absorption Agent is selected from salicylic acid esters (such as phenyl salicylate), benzophenone class (such as UV-531, UV-9) and benzotriazole (such as UVP-327) In one or more combination thing.The thickness of adhesive layer 2 is preferably 50~120 μm.Substrate layer 1 be preferably PE, PU, EPDM or The foam of PVC materials, so can play bradyseism effect in hot pressing.The thickness of substrate layer 1 is preferably 300~600 μm. Adhesive layer 2 preferably will be coated in the surface of substrate layer 1 after its raw material components mixing, be subsequently placed at 30~60 DEG C of ripenings 10~80 little When be obtained.
The preferred embodiment of the invention is described in detail below in conjunction with accompanying drawing.
The two-sided edge sealing adhesive band of the embodiment 1- embodiment 14 of table 1
Embodiment 1 to the matrix resin component used in embodiment 14 is politef fluorocarbon resin；Curing agent component For the mixture that isocyanates system firming agent (Asahi Chemical Industry, E402-B80T) and amine curing agent (LHB-236) are constituted, they Mass ratio is 1：1；Antioxidant is 1010, and ultraviolet absorber is UV-531.
The two-sided edge sealing adhesive band of embodiment 15-19 of table 2
Base material layer surface will be coated in after each raw material mix homogeneously in embodiment 1 to 7, be subsequently placed at 30~60 DEG C of ripenings Two-sided edge sealing adhesive band (final products bond respectively mould release membrance, such as PET mould release membrances after being obtained on its surface) is obtained within 10~80 hours, Its final performance is tested, is listed in Table 3 below.
The performance test of base material layer surface is coated in after each raw material mix homogeneously in the embodiment 1 to 7 of table 3
Above-described embodiment technology design only to illustrate the invention and feature, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and implement according to this, can not be limited the scope of the invention with this.It is all according to the present invention Equivalence changes or modification that spirit is made, all should be included within the scope of the present invention.

Claims (8)

1. a kind of two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass, it includes substrate layer（1）And It is formed in the substrate layer（1）The adhesive layer on two surfaces（2）, it is characterised in that：The adhesive layer（2）Including following parts by weight Raw material components：0 ~ 20 part of 50 ~ 200 parts of matrix resin, 0.1 ~ 10 part of firming agent, 0 ~ 20 part of antioxidant and ultraviolet absorber； Described matrix resin is selected from politef fluorocarbon resin, poly- difluoroethylene fluorocarbon resin, perfluorinated resin, fluorine-containing tree The mixture of one or more composition in fat, fluorine silicon resin, epoxy resin and acrylic resin；The firming agent is selected from different Cyanate system firming agent, imidazole curing agent, hydrazides firming agent, amine resin firming agent, amine curing agent and cyanamid dimerization system consolidate The mixture of two or more compositions in agent, wherein at least one is latent curing agent.
2. the two-sided edge sealing adhesive band inserted according to claim 1 in the middle of solar energy solar double-glass assemblies levels glass, its feature It is：The adhesive layer（2）Including the raw material components of following parts by weight：It is 80 ~ 150 parts of matrix resin, 1 ~ 5 part of firming agent, anti- 2 ~ 10 parts of 2 ~ 10 parts of oxygen agent and ultraviolet absorber.
3. the two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass according to claim 1 or claim 2, it is special Levy and be：The antioxidant is selected from one or more in aromatic amine antioxidant, Hinered phenols antioxidant and auxiliary antioxidant The mixture of composition.
4. the two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass according to claim 1 or claim 2, it is special Levy and be：The ultraviolet absorber selected from salicylic acid esters, benzophenone class, benzotriazole and substituted acrylonitrile apoplexy due to endogenous wind one kind or Several compositionss.
5. the two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass according to claim 1 or claim 2, it is special Levy and be：The adhesive layer（2）Thickness be 50 ~ 120 μm.
6. the two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass according to claim 1 or claim 2, it is special Levy and be：The substrate layer（1）For the foam of PE, PU, EPDM or PVC material.
7. the two-sided edge sealing adhesive band inserted according to claim 6 in the middle of solar energy solar double-glass assemblies levels glass, its feature It is：The substrate layer（1）Thickness be 300 ~ 600 μm.
8. the two-sided edge sealing adhesive band inserted in the middle of solar energy solar double-glass assemblies levels glass according to claim 1 or claim 2, it is special Levy and be：The adhesive layer（2）It is will to be coated in the substrate layer after its raw material components mixing（1）Surface, is subsequently placed at 30 ~ 60 DEG C ripening is obtained for 10 ~ 80 hours.
CN201611256811.3A 2016-12-30 2016-12-30 Two-sided edge sealing adhesive tape arranged between upper glass and lower glass of solar double-glass assembly Pending CN106675431A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294475A (en) * 2018-08-29 2019-02-01 苏州赛伍应用技术股份有限公司 A kind of photovoltaic component frame adhesive tape and its preparation method and application that blocks water
CN110373129A (en) * 2019-03-14 2019-10-25 湖南鼎一致远科技发展有限公司 A kind of adhesive tape and preparation method thereof
CN113583588A (en) * 2021-08-27 2021-11-02 杭州福斯特应用材料股份有限公司 Photovoltaic module packaging adhesive film and photovoltaic module
CN113652176A (en) * 2021-10-18 2021-11-16 太仓金煜电子材料有限公司 Thick adhesive type double-sided adhesive tape, preparation method thereof, notebook computer fan edge pasting method and notebook computer

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Publication number Priority date Publication date Assignee Title
CN1203620A (en) * 1995-12-08 1998-12-30 大金工业株式会社 Fluoroadhesive and adhesive film and laminate prepared therefrom
CN205528574U (en) * 2016-03-11 2016-08-31 苏州赛伍应用技术有限公司 Two -sided banding sticky tape among embedding solar energy dual glass assembly

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1203620A (en) * 1995-12-08 1998-12-30 大金工业株式会社 Fluoroadhesive and adhesive film and laminate prepared therefrom
CN205528574U (en) * 2016-03-11 2016-08-31 苏州赛伍应用技术有限公司 Two -sided banding sticky tape among embedding solar energy dual glass assembly

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294475A (en) * 2018-08-29 2019-02-01 苏州赛伍应用技术股份有限公司 A kind of photovoltaic component frame adhesive tape and its preparation method and application that blocks water
CN109294475B (en) * 2018-08-29 2021-11-12 苏州赛伍应用技术股份有限公司 Water-blocking adhesive tape for photovoltaic module frame and preparation method and application thereof
CN110373129A (en) * 2019-03-14 2019-10-25 湖南鼎一致远科技发展有限公司 A kind of adhesive tape and preparation method thereof
CN113583588A (en) * 2021-08-27 2021-11-02 杭州福斯特应用材料股份有限公司 Photovoltaic module packaging adhesive film and photovoltaic module
CN113652176A (en) * 2021-10-18 2021-11-16 太仓金煜电子材料有限公司 Thick adhesive type double-sided adhesive tape, preparation method thereof, notebook computer fan edge pasting method and notebook computer

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