CN106675259A - Water-based cracked silver paint and preparation method thereof - Google Patents

Water-based cracked silver paint and preparation method thereof Download PDF

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Publication number
CN106675259A
CN106675259A CN201611161491.3A CN201611161491A CN106675259A CN 106675259 A CN106675259 A CN 106675259A CN 201611161491 A CN201611161491 A CN 201611161491A CN 106675259 A CN106675259 A CN 106675259A
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China
Prior art keywords
aqueous
water
silver
mixer
agent
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CN201611161491.3A
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Chinese (zh)
Inventor
冯鸿伟
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Jiangmen Lianyi Fine Chemical Co Ltd
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Jiangmen Lianyi Fine Chemical Co Ltd
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Priority to CN201611161491.3A priority Critical patent/CN106675259A/en
Publication of CN106675259A publication Critical patent/CN106675259A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a water-based cracked silver paint, comprising the following components by weight percentage: 60% to 70% of water-based acrylic emulsion, 0.02% to 0.1% of water-based defoaming agent, 0.1% to 0.5% of water-based leveling agent, 0.2% to 1% of water-based wetting agent, 0.1% to 1% of water-based surfactant, 10% to 25% of water solvent, 5% to 12% of water-based aluminum silver paste, 0.5% to 1% of water-based aluminum silver powder alignment agent, 1% to 3% of water-based thickener, and 2% to 5% of deionized water. The invention also discloses a preparation method of the water-based cracked silver paint. The water-based cracked silver paint provided by the invention has the advantages of being widely applicable to various substrates, having a plump paint film, fine hand feeling, and relatively high glossy degree and degree of simulation, and generating a cracking effect without a special additive.

Description

A kind of aqueous crackle silver paint and preparation method thereof
Technical field
The present invention relates to a kind of aqueous crackle silver paint and preparation method thereof.
Background technology
Water paint arises at the historic moment as the product of New Times and progressively replaces oil paint to enter application market, with market It is continually changing, consumer also increasingly focuses on after it is coated in product surface while water paint environmental protection is pursued, product appearance Aesthetic property and art polytropy, existing common real color or semi-transparent color have no longer been contented just to, because water paint Development time it is shorter, some shortcomings are also there are compared with traditional oil paint, it is impossible to general on various base materials, in product The paint film appearance effect aspect that surface is formed is even more relatively simple, wants to reach special effect and has to rely on special efficacy auxiliary agent and could reach Arrive, but the existing water paint special efficacy auxiliary agent development time is shorter, and special efficacy auxiliary agent species extremely lacks, and does not have in prior art The advantages of having one kind simultaneously to have emulator and glossiness height, feel fine and smooth, and various base materials can be applied to Water paint.
The content of the invention
Present invention seek to address that above-mentioned mentioned technical problem, there is provided one kind can be widely used in various base materials, paint Film is plentiful, and feel is fine and smooth, and glossiness, emulator are higher, and also need not can crack effect using special efficacy auxiliary agent Aqueous crackle silver paint and preparation method thereof.
The present invention is realized by following technical scheme:A kind of aqueous crackle silver paint, including following percentage by weight Component:
Aqueous acrylic emulsion 60%~70%,
Aqueous defoamer 0.02%~0.1%,
Aqueous levelling agent 0.1%~0.5%,
Aqueous wetting agent 0.2%~1%,
Aqueous tenside 0.1%~1%,
Aqueous solvent 10%~25%,
Water aluminum-silver slurry 5%~12%,
Aqueous aluminium silver powder arranges agent 0.5%~1%,
Water-based thickener 1%~3%,
Deionized water 2%~5%.
The present invention also provides the preparation method of above-mentioned aqueous crackle silver paint, comprises the following steps successively:
(1)Aqueous acrylic emulsion is added and is stirred in mixer;
(2)Respectively by aqueous solvent, aqueous wetting agent, aqueous tenside, aqueous levelling agent and aqueous under stirring The arrangement agent of aluminium silver powder is added and stirred in mixer;
(3)Water aluminum-silver slurry and aqueous solvent are added in mixer;
(4)Aqueous defoamer is added under stirring in mixer;
(5)Water-based thickener is added under the mixing speed of 2500~3000r/min in mixer;
(6)Deionized water is added under stirring in mixer.
Preferably, it is described to add before water aluminum-silver slurry and aqueous solvent, it is first that aqueous aluminium silver powder is uniform with aqueous solution Mixing.
Preferably, after the aqueous aluminium silver powder uniformly mixes with aqueous solution, to stand and add mixer after 0.5~3h In.
Preferably, during the addition water-based thickener, gradually mixing speed is promoted to into 2500~3000r/min.
Preferably, after the addition deionized water, 10~30min is stirred under the mixing speed of 2500~3000r/min.
Beneficial effect is:Compared with prior art, a kind of aqueous crackle silver paint of the present invention, can be widely used in various bases Material, the paint film formed after product surface coating is more plentiful, and feel is finer and smoother, and glossiness, emulator are higher, and not Need also crack effect using special efficacy auxiliary agent, the preparation method of the aqueous crackle silver paint of the present invention, technique is simpler, Production efficiency is higher.
Specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.It should be understood that following examples are merely to illustrate this Invention is not for restriction the scope of the present invention.
Embodiment 1:
A kind of aqueous crackle silver paint of the present embodiment, including the component of following percentage by weight:Aqueous acrylic emulsion 70%, water Property defoamer 0.02%, aqueous levelling agent 0.1%, aqueous wetting agent 0.2%, aqueous tenside 0.1%, aqueous solvent 21.08%th, water aluminum-silver slurry 5%, the arrangement agent 0.5% of aqueous aluminium silver powder, water-based thickener 1%, deionized water 2%.
The preparation method of the aqueous crackle silver paint in the present embodiment, comprises the following steps successively:(1)By aqueous acrylamide yogurt Liquid is added and is stirred in mixer;(2)Respectively by aqueous solvent, aqueous wetting agent, aqueous surfactant under stirring The arrangement agent of agent, aqueous levelling agent and aqueous aluminium silver powder is added and stirred in mixer;(3)Aqueous aluminium silver is added in mixer Slurry and aqueous solvent;(4)Water-based thickener is added under stirring in mixer;(5)Stirring in 2500~3000r/min Mix and add aqueous defoamer in mixer under speed;(6)Deionized water is added under stirring in mixer.
Aqueous solvent, aqueous wetting agent, aqueous tenside, aqueous levelling agent and aqueous are added in the state of stirring Aluminium silver powder arranges agent, can cause sufficiently can uniformly mix between the solvent after adding.
When adding water-based thickener, gradually mixing speed can be promoted to into 2500~3000r/min, i.e., it is slow on one side Water-based thickener is added in mixer, and lifting mixing speed while stirring progressively.
After adding deionized water, 10~30min can be stirred under the mixing speed of 2500~3000r/min, so may be used So that the aqueous crackle silver paint of the present invention is more uniform, fine and smooth.
After the completion of adding ionized water and stirring, to mixer in aqueous silking paint test, and will after the assay was approved Aqueous silking paint carry out packaging and approved sample keep on file.
Embodiment 2:
A kind of aqueous crackle silver paint of the present embodiment, including the component of following percentage by weight:Aqueous acrylic emulsion 60%, water It is property defoamer 0.1%, aqueous levelling agent 0.5%, aqueous wetting agent 1%, aqueous tenside 1%, aqueous solvent 16.4%, aqueous Aluminum paste 12%, the arrangement agent 1% of aqueous aluminium silver powder, water-based thickener 3%, deionized water 5%.
The preparation method reference implementation example 1 of the aqueous crackle silver paint of the present embodiment, here is no longer repeated.
Embodiment 3:
A kind of aqueous crackle silver paint of the present embodiment, including the component of following percentage by weight:Aqueous acrylic emulsion 67.8%, Aqueous defoamer 0.05%, aqueous levelling agent 0.2%, aqueous wetting agent 0.5%, aqueous tenside 0.6%, aqueous solvent 16.8%th, water aluminum-silver slurry 8%, the arrangement agent 0.8% of aqueous aluminium silver powder, water-based thickener 1.6%, deionized water 3.65%.
The preparation method reference implementation example 1 of the aqueous crackle silver paint of the present embodiment, here is no longer repeated.
The aqueous crackle silver paint of the present invention arranges the facilitation of agent so that aqueous in spraying by aqueous aluminium silver powder Aluminium silver powder in aluminum paste it is smooth, smooth be arranged in coating surface so that paint film is more plentiful, and acrylic emulsion half into Paint film is partially soft after film, at normal temperatures cannot direct film-forming, by the characteristics of with reference to silver powder, at normal temperatures rate of drying is fast, making Obtain paint film lower floor and be dried slow upper strata fast drying drive silver layer appearance tear shape lines so that the silver-colored paint of the aqueous crackle of the present invention can To crack effect.
Aqueous acrylic emulsion in the present invention with the addition of emulsifying agent in preparation process so that in aqueous acrylic emulsion Acrylic monomers formed meshy arrangement structure so that the connection between acrylic monomers is more firm.Using monomer net The performance of shape arrangement, just can make it and arrange if to interrupt its arrangement and must together interrupt cancellated each tie point Disconnect, and not fracture just occur as the linear alignment only need to arbitrarily interrupt one section of whole strand so that paint film into Preferably complete ground top can be covered in after type, and adhesive force is higher.Glass, ceramics, metal need not thus be considered Etc. the surface tension size in substrate material so that the aqueous crackle silver paint of the present invention can be applied to the base of various unlike materials Material.
Before water aluminum-silver slurry and aqueous solvent is added, first aqueous aluminium silver powder uniformly can be mixed with aqueous solution, After aqueous aluminium silver powder uniformly mixes with aqueous solution, can stand added in mixer after 0.5~3h, and existing technique is being given birth to When producing aqueous crackle silver paint, technical staff is generally directly to add aqueous aluminium silver powder and aqueous solution to aqueous acrylamide yogurt It is stirred in liquid, but the aqueous crackle silver paint in the present invention is in production, can mix in aqueous aluminium silver powder and aqueous solution Stirring so as to after uniform mixing, soak certain hour, mixed aqueous aluminium silver powder and aqueous solution are being added into people's aqueous acrylamide In yogurt liquid, aqueous silver-colored aluminium powder can be so set sufficiently to carry out basic wetting, so that aqueous silver-colored aluminium powder is in film forming defensive position Feel finer and smoother, visual simulation Du Genggao, and it is more glossy.
Above example is only not limited to illustrate technical scheme, all without departing from the present invention Any modification of spirit and scope or equivalent, it all should cover in the range of technical solution of the present invention.

Claims (6)

1. a kind of aqueous crackle silver is painted, it is characterised in that including the component of following percentage by weight:
Aqueous acrylic emulsion 60%~70%,
Aqueous defoamer 0.02%~0.1%,
Aqueous levelling agent 0.1%~0.5%,
Aqueous wetting agent 0.2%~1%,
Aqueous tenside 0.1%~1%,
Aqueous solvent 10%~25%,
Water aluminum-silver slurry 5%~12%,
Aqueous aluminium silver powder arranges agent 0.5%~1%,
Water-based thickener 1%~3%,
Deionized water 2%~5%.
2. the preparation method that aqueous crackle silver according to claim 1 is painted, it is characterised in that comprise the following steps successively:
(1)Aqueous acrylic emulsion is added and is stirred in mixer;
(2)Respectively by aqueous solvent, aqueous wetting agent, aqueous tenside, aqueous levelling agent and aqueous under stirring The arrangement agent of aluminium silver powder is added and stirred in mixer;
(3)Water aluminum-silver slurry and aqueous solvent are added in mixer;
(4)Aqueous defoamer is added under stirring in mixer;
(5)Water-based thickener is added under the mixing speed of 2500~3000r/min in mixer;
(6)Deionized water is added under stirring in mixer.
3. the preparation method that aqueous crackle silver according to claim 2 is painted, it is characterised in that the addition water aluminum-silver slurry Before aqueous solvent, first aqueous aluminium silver powder is uniformly mixed with aqueous solution.
4. according to described in claim 3 aqueous crackle silver paint preparation method, it is characterised in that the aqueous aluminium silver powder with it is aqueous Solution uniformly after mixing, stands and added in mixer after 0.5~3h.
5. the preparation method that aqueous crackle silver according to claim 2 is painted, it is characterised in that the addition water-based thickener When, gradually mixing speed is promoted to into 2500~3000r/min.
6. the preparation method that aqueous crackle silver according to claim 2 is painted, it is characterised in that the addition deionized water Afterwards, 10~30min is stirred under the mixing speed of 2500~3000r/min.
CN201611161491.3A 2016-12-15 2016-12-15 Water-based cracked silver paint and preparation method thereof Pending CN106675259A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611161491.3A CN106675259A (en) 2016-12-15 2016-12-15 Water-based cracked silver paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611161491.3A CN106675259A (en) 2016-12-15 2016-12-15 Water-based cracked silver paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106675259A true CN106675259A (en) 2017-05-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057501A (en) * 2017-06-19 2017-08-18 安徽康瑞高科新材料技术工程有限公司 One kind applies water aluminum powder paint
CN108047848A (en) * 2017-12-30 2018-05-18 西安经建油漆股份有限公司 A kind of environment-friendly type aqueous one-component aluminium color coating and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104610820A (en) * 2015-01-13 2015-05-13 武汉怡可漆科技有限公司 Water-based crack lacquer as well as preparation method and construction method thereof
CN105062263A (en) * 2015-08-05 2015-11-18 肇庆市彩信装饰材料有限公司 Aqueous eco-friendly aluminum powder metal paint and preparation method thereof
CN105153846A (en) * 2015-10-14 2015-12-16 芜湖春风新材料有限公司 Water-based 3C single-component air-drying aluminum paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104610820A (en) * 2015-01-13 2015-05-13 武汉怡可漆科技有限公司 Water-based crack lacquer as well as preparation method and construction method thereof
CN105062263A (en) * 2015-08-05 2015-11-18 肇庆市彩信装饰材料有限公司 Aqueous eco-friendly aluminum powder metal paint and preparation method thereof
CN105153846A (en) * 2015-10-14 2015-12-16 芜湖春风新材料有限公司 Water-based 3C single-component air-drying aluminum paint and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
吴海霞等: "《精细化工生产技术》", 31 August 2013, 中国石化出版社 *
陈中华等: "水性铝银浆金属外墙涂料的研制", 《化学建材》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057501A (en) * 2017-06-19 2017-08-18 安徽康瑞高科新材料技术工程有限公司 One kind applies water aluminum powder paint
CN108047848A (en) * 2017-12-30 2018-05-18 西安经建油漆股份有限公司 A kind of environment-friendly type aqueous one-component aluminium color coating and preparation method thereof

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