CN106673483A - Preparation method of high-viscosity anti-sliding ceramic tile adhesive - Google Patents

Preparation method of high-viscosity anti-sliding ceramic tile adhesive Download PDF

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Publication number
CN106673483A
CN106673483A CN201611030933.0A CN201611030933A CN106673483A CN 106673483 A CN106673483 A CN 106673483A CN 201611030933 A CN201611030933 A CN 201611030933A CN 106673483 A CN106673483 A CN 106673483A
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China
Prior art keywords
adhesive
lime
ceramic tile
straw
mixing
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CN201611030933.0A
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Chinese (zh)
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孙祎
张晶
赵玲玲
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Priority to CN201611030933.0A priority Critical patent/CN106673483A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin

Abstract

The invention relates to a preparation method of a high-viscosity anti-sliding ceramic tile adhesive, and belongs to the technical field of adhesives. The upper limit of water demand of the ceramic tile adhesive is improved by using the tackifying and thickening effects of prepared reinforced straw ashes to improve the anti-sliding performance, hydrophilic amino and carboxyl are provided for the adhesive by a fermentation liquid rich in the amino acid, the water retention capacity of the adhesive is significantly improved, the quantity of active groups in the adhesive is increased through compounding the hydrophilic amino and carboxyl, the chemical bonding force between the adhesive and a substrate is strengthened and the viscosity is improved. The prepared ceramic tile adhesive is high in water-retaining property, high in viscosity, convenient to use and low in dosage, and has a wide application prospect, and the problem that the anti-sliding performance of a ceramic tile is reduced due to the fact that a traditional ceramic tile adhesive easily generates hollowness is solved.

Description

A kind of preparation method of high viscosity resistant slide glue for tile
Technical field
The present invention relates to a kind of preparation method of high viscosity resistant slide glue for tile, belongs to adhesive technical field.
Background technology
Glue for tile is mainly used in the ornament materials such as sticking brick, face brick, floor tile also known as Ceramic Tiles binding agent, generally applicable In the facing decoration places of the buildings such as inside and outside metope, ground, bathroom, kitchen.It is high, water-fast, resistance to that it is mainly characterized by adhesive strength Freeze thawing, ageing-resistant performance be good and easy construction, is a kind of ideal binding material.It is the new material of modern decoration, replaces For conventional cement yellow sand, glue cohesive force is that the several times of cement mortar can effectively paste large-scale ceramic tile stone material, it is to avoid fall brick Risk.
Ceramic tile is one of facing material important in building industry.It not only provides the decorative surface of aesthstic entertaining, also has Functional advantage is for example water-fast, hard, health and the characteristics of be readily cleaned.Generally tapestry brick pastes the thickness sand using scene mixing Slurry, this method efficiency of construction is low, and material usage is big, and construction quality is difficult to ensure that, ceramic tile comes off the generation that often have.And adopt With novel thin layer tile paste technology the problems referred to above, efficiency of construction and quality can be overcome to greatly improve.This technology needs viscous Knot mortar has good water holding capacity, and the workability of long open assembly time and good anti-slipping property etc. and good bonding are strong Degree and flexibility etc..Research in the past is little to the concern of ultra fine sand cement mortar, and the ground such as Chongqing sand resource is mainly modulus of fineness and is less than 1.0 ultra fine sand, more than 95% mortar is ultra fine sand cement mortar in engineering.Ultra fine sand adhesive mortar water-retaining property, application property Difference, fragility is big, and toughness is low, poor durability, there is the potential safety hazard that ceramic tile comes off.Because anti-slipping property is poor, can open assembly time it is short, Thick-layer process for pasting construction can only be adopted, effect is low, waste big, therefore, for the research of high viscosity resistant slide glue for tile seems It is particularly important.
The content of the invention
The invention mainly solves the technical problem of:For mixing thick using scene more than at present common ceramic tile adhesive Layer mortar, efficiency of construction is low, and material usage is big, and poor water retention property is siphoned away with causing the excess moisture of glue for tile by basic unit, is made Into hollowing, the drawbacks of ceramic tile anti-slipping property is reduced, the present invention provides a kind of by rice straw and lime cream mixed fermentation system Straw muscle ash is obtained, then fermentation liquid is obtained in microbial action bottom fermentation with the fruit rich in aminoacid, by straw muscle ash and fermentation The method that ceramic tile adhesive is obtained final product after the raw material compounding such as liquid and sucrose slurry, the present invention is increased using the thickening of obtained straw muscle ash Thick effect improves the water requirement upper limit of glue for tile, and to increase its anti-slipping property energy, and the fermentation liquid for being rich in aminoacid is adhesive There is provided hydrophilic amino and carboxyl, adhesive water retention property is significantly improved, both are compounded and be increased in adhesive again Active group quantity, strengthens the Chemical bonding between adhesive and substrate, improves its cohesiveness, the obtained ceramic tile of the present invention Glue water-retaining property is strong, and stickiness is high, and easy to use, consumption is few, solves traditional glue for tile and is also easy to produce hollowing, enables ceramic tile anti-slipping property The problem of reduction, has broad application prospects.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1)It is put into after fresh cane is removed the peel in squeezer and squeezes, Caulis Sacchari sinensis juice is collected by filtration, by the Caulis Sacchari sinensis juice for obtaining and hydroxide Calcium is 10 in mass ratio:Filter after 1 mixing and remove filtering residue, obtain remove impurity Caulis Sacchari sinensis juice, finally remove impurity Caulis Sacchari sinensis juice is moved in iron pan, Boil and boil 15~20min, obtain sticky sucrose slurry, it is standby;
(2)In mass ratio it is 1:Reactant, by 5~10min of stirring reaction after quick lime and water mixing, is crossed 100 mesh sieves by 3, is removed Sandstone impurity obtains lime cream, is in mass ratio 2 by lime cream and 200 mesh fine sands:1 mixing and stirring is obtained lime paste;
(3)Rice straw is cut into into segment that length is 3~5cm with chopper and ceramic cylinder bottom is laid in, laying depth is 5~ 8cm, then the lime paste obtained above that tiles above the straw layer of laying, laying depth is controlled in 2~3cm, by that analogy, one The up laying of layer one layer of lime paste of rice straw, until stop after rice straw and lime paste respectively reach 5 layers, along ceramic cylinder Edge adds distilled water, and ceramic cylinder will be sealed till most last layer lime paste floods until the water surface, and the immersion at 30~35 DEG C is sent out Ferment 15~20 days, after fermentation ends, fermented product is filtered and removes filtrate, is obtained filtering residue and is straw muscle ash, standby;
(4)In mass ratio it is 2:1:3:5 will mix and be put into high pressure homogenize after the peeling of Fructus nephelii topengii, Fructus Ananadis comosi, Passifolra edulis and Fructus actinidiae chinensiss 20~30min is processed in machine, the homogeneous product for obtaining is proceeded in fermentation tank, be 10% access in homogeneous product by inoculum concentration Bacillus subtilises, sealed fermenter is simultaneously filtrated to get fermentation liquid after 9~10 days in 35~40 DEG C of bottom fermentations;
(5)Glutinous rice flour is put in ball grinder to grind and cross after 1~2h 200 mesh sieves, will sieve glutinous rice flour and step(3)Standby straw Stalk muscle ash, step(1)Standby sucrose slurry and above-mentioned fermentation liquid is put into sealing and standing 15~20 days in oak barrel after mixing, and obtains Base rubber;
(6)Count by weight, weigh 60~70 parts of base rubbers, 20~30 parts of polyacrylate dispersions, 10~15 parts of flyash according to In secondary loading batch mixer, discharge after insulated and stirred 30~40min of mixing at 65~70 DEG C, obtain final product high viscosity resistant slide.
The application process of the present invention:The tile base that need to bond first shows to clean out, then is in mass ratio 4:5:2, High viscosity resistant slide glue for tile and bonding mortar prepared by the present invention is stirred with water with motor stirrer, and standing 5~ 10min, makes rubber cement, then applies the glue for tile for scraping that thickness is 2~6mm in basic unit with gear scraper plate, then toward having been coated with ceramic tile Tiling in the basic unit of glue, after patch block with rubber hammer beat it is tight after, stand maintenance 1~2 day after.After testing, 15 are hung After~20min, the stretching adhesive strength of glue for tile is 1.15~1.25MPa, and comprcssive strength is 18~22MPa, while after solidification Occur without hollowing phenomenon and sliding phenomenon.
The invention has the beneficial effects as follows:
(1)Ceramic tile adhesive prepared by the present invention is in terms of improving cohesive force, anti-shrink cracking, resistant slide and lifting weatherability four To improve simultaneously the performance of ceramic tile adhesive, the workabilities such as glue for tile water conservation, viscosity can be significantly improved;
(2)Ceramic tile adhesive prepared by the present invention has good water reducing and strength increasing, reduces cracking risk, the work of optimization gap structure With.
Specific embodiment
It is put into after fresh cane is removed the peel in squeezer and squeezes, Caulis Sacchari sinensis juice is collected by filtration, by the Caulis Sacchari sinensis juice for obtaining and hydrogen-oxygen It is 10 to change calcium in mass ratio:Filter after 1 mixing and remove filtering residue, obtain remove impurity Caulis Sacchari sinensis juice, finally remove impurity Caulis Sacchari sinensis juice is moved into into iron pan In, boil and boil 15~20min, sticky sucrose slurry is obtained, it is in mass ratio 1:3 by quick lime and water mixing after stirring reaction 5~10min, by reactant 100 mesh sieves are crossed, and are removed sandstone impurity and are obtained lime cream, by lime cream and 200 mesh fine sands in mass ratio For 2:1 mixing and stirring is obtained lime paste;Rice straw is cut into into segment that length is 3~5cm with chopper and pottery is laid in Porcelain Jar bottom, laying depth is 5~8cm, then the lime paste obtained above that tiles above the straw layer of laying, laying depth control System is in 2~3cm, by that analogy, the up laying of one layer of rice straw, one layer of lime paste, until rice straw and lime paste respectively reach Stop to after 5 layers, along ceramic cylinder edge distilled water is added, will be till most last layer lime paste flood until the water surface, sealing pottery Porcelain Jar, soaking fermentation 15~20 days at 30~35 DEG C after fermentation ends, fermented product are filtered and remove filtrate, obtain filtering residue i.e. It is in mass ratio 2 for straw muscle ash:1:3:5 will mix and be put into high pressure after the peeling of Fructus nephelii topengii, Fructus Ananadis comosi, Passifolra edulis and Fructus actinidiae chinensiss 20~30min is processed in homogenizer, the homogeneous product for obtaining is proceeded in fermentation tank, be 10% in homogeneous product by inoculum concentration Access bacillus subtilises, sealed fermenter is simultaneously filtrated to get fermentation liquid after 9~10 days in 35~40 DEG C of bottom fermentations;By glutinous rice flour It is put in ball grinder grinds and cross after 1~2h 200 mesh sieves, sieving, glutinous rice flour and straw muscle is grey, sucrose is starched and above-mentioned fermentation liquid is mixed Sealing and standing 15~20 days in oak barrel are put into after conjunction, base rubber is obtained;Count by weight, weigh 60~70 parts of base rubbers, 20~ 30 parts of polyacrylate dispersions, 10~15 parts of flyash are sequentially loaded in batch mixer, the insulated and stirred mixing 30 at 65~70 DEG C Discharge after~40min, obtain final product high viscosity resistant slide glue for tile.
Example 1
It is put into after fresh cane is removed the peel in squeezer and squeezes, Caulis Sacchari sinensis juice is collected by filtration, by the Caulis Sacchari sinensis juice for obtaining and calcium hydroxide In mass ratio it is 10:Filter after 1 mixing and remove filtering residue, obtain remove impurity Caulis Sacchari sinensis juice, finally remove impurity Caulis Sacchari sinensis juice is moved in iron pan, boil Boiling boils 15min, obtains sticky sucrose slurry, is in mass ratio 1:3 by stirring reaction 5min after quick lime and water mixing, will be anti- Answer thing to cross 100 mesh sieves, remove sandstone impurity and obtain lime cream, be in mass ratio 2 by lime cream and 200 mesh fine sands:1 mixes Lime paste is uniformly obtained;Rice straw is cut into into segment that length is 3cm with chopper and ceramic cylinder bottom, laying depth is laid in For 5cm, then the lime paste obtained above that tiles above the straw layer of laying, laying depth is controlled in 2cm, by that analogy, one The up laying of layer one layer of lime paste of rice straw, until stop after rice straw and lime paste respectively reach 5 layers, along ceramic cylinder Edge adds distilled water, and ceramic cylinder, the soaking fermentation 15 at 30 DEG C will be sealed till most last layer lime paste floods until the water surface My god, after fermentation ends, fermented product is filtered and removes filtrate, obtain filtering residue and be straw muscle ash, it is in mass ratio 2:1:3:5 will be red Mix and be put in high pressure homogenizer after the peeling of Mao Dan, Fructus Ananadis comosi, Passifolra edulis and Fructus actinidiae chinensiss and process 20min, the homogenizing for obtaining is produced Thing is proceeded in fermentation tank, and bacillus subtilises are accessed in homogeneous product for 10% by inoculum concentration, sealed fermenter and at 35 DEG C Fermentation is filtrated to get fermentation liquid after 9 days;By glutinous rice flour be put in ball grinder grind 1h after cross 200 mesh sieves, will sieve glutinous rice flour and Sealing and standing 15 days in oak barrel are put into after straw muscle ash, sucrose slurry and the mixing of above-mentioned fermentation liquid, base rubber is obtained;By weight Meter, weighs 60 parts of base rubbers, 20 parts of polyacrylate dispersions, 10 parts of flyash and is sequentially loaded in batch mixer, is incubated at 65 DEG C and stirs Mix and discharged after mixing 30min, obtain final product high viscosity resistant slide glue for tile.
The tile base that need to bond first shows to clean out, then is in mass ratio 4:5:2, height prepared by the present invention is glued Property resistant slide glue for tile and bonding mortar stirred with motor stirrer with water, stand 5min, make rubber cement, then scraped with gear It is the glue for tile of 2mm that plate is applied in basic unit and scrapes thickness, then toward tiling in the basic unit for have been coated with glue for tile, rubber is used after patch block Hammer beat it is tight after, stand maintenance 1 day after.After testing, hang after 15min, the stretching adhesive strength of glue for tile is 1.15MPa, comprcssive strength is 18MPa, while occurring without hollowing phenomenon and sliding phenomenon after solidification.
Example 2
It is put into after fresh cane is removed the peel in squeezer and squeezes, Caulis Sacchari sinensis juice is collected by filtration, by the Caulis Sacchari sinensis juice for obtaining and calcium hydroxide In mass ratio it is 10:Filter after 1 mixing and remove filtering residue, obtain remove impurity Caulis Sacchari sinensis juice, finally remove impurity Caulis Sacchari sinensis juice is moved in iron pan, boil Boiling boils 20min, obtains sticky sucrose slurry, is in mass ratio 1:3 by stirring reaction 10min after quick lime and water mixing, will Reactant crosses 100 mesh sieves, removes sandstone impurity and obtains lime cream, is in mass ratio 2 by lime cream and 200 mesh fine sands:1 mixing is stirred Mix uniformly prepared lime paste;Rice straw is cut into into segment that length is 5cm with chopper and ceramic cylinder bottom is laid in, laying is thick Spend for 8cm, then the lime paste obtained above that tiles above the straw layer of laying, laying depth control in 3cm, by that analogy, The up laying of one layer of rice straw, one layer of lime paste, until stop after rice straw and lime paste respectively reach 5 layers, along ceramics Cylinder edge adds distilled water, and ceramic cylinder, the soaking fermentation at 35 DEG C will be sealed till most last layer lime paste floods until the water surface 20 days, after fermentation ends, fermented product is filtered and removes filtrate, obtained filtering residue and be straw muscle ash, be in mass ratio 2:1:3:5 will Mix and be put in high pressure homogenizer after the peeling of Fructus nephelii topengii, Fructus Ananadis comosi, Passifolra edulis and Fructus actinidiae chinensiss and process 30min, by the homogenizing for obtaining Product is proceeded in fermentation tank, and bacillus subtilises are accessed in homogeneous product for 10% by inoculum concentration, sealed fermenter and at 40 DEG C Bottom fermentation is filtrated to get fermentation liquid after 10 days;Glutinous rice flour is put in ball grinder to grind and cross after 2h 200 mesh sieves, by the glutinous rice flour that sieves Sealing and standing 20 days in oak barrel are put into after straw muscle ash, sucrose slurry and the mixing of above-mentioned fermentation liquid, base rubber is obtained;By weight Number meter, weighs 70 parts of base rubbers, 30 parts of polyacrylate dispersions, 15 parts of flyash and is sequentially loaded in batch mixer, is incubated at 70 DEG C Discharge after stirring mixing 40min, obtain final product high viscosity resistant slide glue for tile.
The tile base that need to bond first shows to clean out, then is in mass ratio 4:5:2, height prepared by the present invention is glued Property resistant slide glue for tile and bonding mortar stirred with motor stirrer with water, stand 8min, make rubber cement, then scraped with gear It is the glue for tile of 4mm that plate is applied in basic unit and scrapes thickness, then toward tiling in the basic unit for have been coated with glue for tile, rubber is used after patch block Hammer beat it is tight after, stand maintenance 1 day after.After testing, hang after 18min, the stretching adhesive strength of glue for tile is 1.20MPa, comprcssive strength is 20MPa, while occurring without hollowing phenomenon and sliding phenomenon after solidification.
Example 3
It is put into after fresh cane is removed the peel in squeezer and squeezes, Caulis Sacchari sinensis juice is collected by filtration, by the Caulis Sacchari sinensis juice for obtaining and calcium hydroxide In mass ratio it is 10:Filter after 1 mixing and remove filtering residue, obtain remove impurity Caulis Sacchari sinensis juice, finally remove impurity Caulis Sacchari sinensis juice is moved in iron pan, boil Boiling boils 18min, obtains sticky sucrose slurry, is in mass ratio 1:3 by stirring reaction 8min after quick lime and water mixing, will be anti- Answer thing to cross 100 mesh sieves, remove sandstone impurity and obtain lime cream, be in mass ratio 2 by lime cream and 200 mesh fine sands:1 mixes Lime paste is uniformly obtained;Rice straw is cut into into segment that length is 4cm with chopper and ceramic cylinder bottom, laying depth is laid in For 7cm, then the lime paste obtained above that tiles above the straw layer of laying, laying depth is controlled in 3cm, by that analogy, one The up laying of layer one layer of lime paste of rice straw, until stop after rice straw and lime paste respectively reach 5 layers, along ceramic cylinder Edge adds distilled water, and ceramic cylinder, the soaking fermentation 18 at 33 DEG C will be sealed till most last layer lime paste floods until the water surface My god, after fermentation ends, fermented product is filtered and removes filtrate, obtain filtering residue and be straw muscle ash, it is in mass ratio 2:1:3:5 will be red Mix and be put in high pressure homogenizer after the peeling of Mao Dan, Fructus Ananadis comosi, Passifolra edulis and Fructus actinidiae chinensiss and process 25min, the homogenizing for obtaining is produced Thing is proceeded in fermentation tank, and bacillus subtilises are accessed in homogeneous product for 10% by inoculum concentration, sealed fermenter and at 38 DEG C Fermentation is filtrated to get fermentation liquid after 10 days;By glutinous rice flour be put in ball grinder grind 2h after cross 200 mesh sieves, will sieve glutinous rice flour and Sealing and standing 18 days in oak barrel are put into after straw muscle ash, sucrose slurry and the mixing of above-mentioned fermentation liquid, base rubber is obtained;By weight Meter, weighs 65 parts of base rubbers, 25 parts of polyacrylate dispersions, 13 parts of flyash and is sequentially loaded in batch mixer, is incubated at 68 DEG C and stirs Mix and discharged after mixing 35min, obtain final product high viscosity resistant slide glue for tile.
The tile base that need to bond first shows to clean out, then is in mass ratio 4:5:2, height prepared by the present invention is glued Property resistant slide glue for tile and bonding mortar stirred with motor stirrer with water, stand 10min, make rubber cement, then use gear It is the glue for tile of 6mm that scraper plate is applied in basic unit and scrapes thickness, then toward tiling in the basic unit for have been coated with glue for tile, rubber is used after patch block Glue hammer beat it is tight after, stand maintenance 2 days after.After testing, hang after 20min, the stretching adhesive strength of glue for tile is 1.25MPa, comprcssive strength is 22MPa, while occurring without hollowing phenomenon and sliding phenomenon after solidification.

Claims (1)

1. a kind of preparation method of high viscosity resistant slide glue for tile, it is characterised in that concrete preparation process is:
(1)It is put into after fresh cane is removed the peel in squeezer and squeezes, Caulis Sacchari sinensis juice is collected by filtration, by the Caulis Sacchari sinensis juice for obtaining and hydroxide Calcium is 10 in mass ratio:Filter after 1 mixing and remove filtering residue, obtain remove impurity Caulis Sacchari sinensis juice, finally remove impurity Caulis Sacchari sinensis juice is moved in iron pan, Boil and boil 15~20min, obtain sticky sucrose slurry, it is standby;
(2)In mass ratio it is 1:Reactant, by 5~10min of stirring reaction after quick lime and water mixing, is crossed 100 mesh sieves by 3, is removed Sandstone impurity obtains lime cream, is in mass ratio 2 by lime cream and 200 mesh fine sands:1 mixing and stirring is obtained lime paste;
(3)Rice straw is cut into into segment that length is 3~5cm with chopper and ceramic cylinder bottom is laid in, laying depth is 5~ 8cm, then the lime paste obtained above that tiles above the straw layer of laying, laying depth is controlled in 2~3cm, by that analogy, one The up laying of layer one layer of lime paste of rice straw, until stop after rice straw and lime paste respectively reach 5 layers, along ceramic cylinder Edge adds distilled water, and ceramic cylinder will be sealed till most last layer lime paste floods until the water surface, and the immersion at 30~35 DEG C is sent out Ferment 15~20 days, after fermentation ends, fermented product is filtered and removes filtrate, is obtained filtering residue and is straw muscle ash, standby;
(4)In mass ratio it is 2:1:3:5 will mix and be put into high pressure homogenize after the peeling of Fructus nephelii topengii, Fructus Ananadis comosi, Passifolra edulis and Fructus actinidiae chinensiss 20~30min is processed in machine, the homogeneous product for obtaining is proceeded in fermentation tank, be 10% access in homogeneous product by inoculum concentration Bacillus subtilises, sealed fermenter is simultaneously filtrated to get fermentation liquid after 9~10 days in 35~40 DEG C of bottom fermentations;
(5)Glutinous rice flour is put in ball grinder to grind and cross after 1~2h 200 mesh sieves, will sieve glutinous rice flour and step(3)Standby straw Stalk muscle ash, step(1)Standby sucrose slurry and above-mentioned fermentation liquid is put into sealing and standing 15~20 days in oak barrel after mixing, and obtains Base rubber;
(6)Count by weight, weigh 60~70 parts of base rubbers, 20~30 parts of polyacrylate dispersions, 10~15 parts of flyash according to In secondary loading batch mixer, discharge after insulated and stirred 30~40min of mixing at 65~70 DEG C, obtain final product high viscosity resistant slide ceramic tile Glue.
CN201611030933.0A 2016-11-22 2016-11-22 Preparation method of high-viscosity anti-sliding ceramic tile adhesive Pending CN106673483A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602049A (en) * 2017-09-16 2018-01-19 常州富思通管道有限公司 A kind of preparation method of high-strength waterproof clay sculpture material
CN107746239A (en) * 2017-10-16 2018-03-02 孙建忠 A kind of preparation method of high bond strength cement mortar
CN108218314A (en) * 2017-12-30 2018-06-29 姜向军 A kind of preparation method of high plasticity bone porcelain pug
CN111154408A (en) * 2020-01-10 2020-05-15 林培双 Preparation method of antibacterial high-strength ceramic tile glue
CN113620653A (en) * 2021-09-03 2021-11-09 科顺民用建材有限公司 Microbial emulsion, composition thereof, preparation method and application thereof, and microbial self-repairing high-temperature-resistant tile glue

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104386934A (en) * 2014-10-20 2015-03-04 华南理工大学 Method for preparing grey plaster used paper strip mixed lime mortar material by adopting celluloses
CN106045438A (en) * 2016-05-27 2016-10-26 广东省岭南民间工艺研究院 Lime model environment-friendly building material and preparation method and application thereof
CN106082875A (en) * 2016-06-25 2016-11-09 仇颖超 A kind of preparation method of anti-hollowing sag resistance glue for tile

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104386934A (en) * 2014-10-20 2015-03-04 华南理工大学 Method for preparing grey plaster used paper strip mixed lime mortar material by adopting celluloses
CN106045438A (en) * 2016-05-27 2016-10-26 广东省岭南民间工艺研究院 Lime model environment-friendly building material and preparation method and application thereof
CN106082875A (en) * 2016-06-25 2016-11-09 仇颖超 A kind of preparation method of anti-hollowing sag resistance glue for tile

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602049A (en) * 2017-09-16 2018-01-19 常州富思通管道有限公司 A kind of preparation method of high-strength waterproof clay sculpture material
CN107746239A (en) * 2017-10-16 2018-03-02 孙建忠 A kind of preparation method of high bond strength cement mortar
CN108218314A (en) * 2017-12-30 2018-06-29 姜向军 A kind of preparation method of high plasticity bone porcelain pug
CN111154408A (en) * 2020-01-10 2020-05-15 林培双 Preparation method of antibacterial high-strength ceramic tile glue
CN113620653A (en) * 2021-09-03 2021-11-09 科顺民用建材有限公司 Microbial emulsion, composition thereof, preparation method and application thereof, and microbial self-repairing high-temperature-resistant tile glue
CN113620653B (en) * 2021-09-03 2022-03-04 科顺民用建材有限公司 Microbial emulsion, composition thereof, preparation method and application thereof, and microbial self-repairing high-temperature-resistant tile glue

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Application publication date: 20170517