CN106670474A - Preparation method of foam aluminum sandwich panel - Google Patents

Preparation method of foam aluminum sandwich panel Download PDF

Info

Publication number
CN106670474A
CN106670474A CN201611248905.6A CN201611248905A CN106670474A CN 106670474 A CN106670474 A CN 106670474A CN 201611248905 A CN201611248905 A CN 201611248905A CN 106670474 A CN106670474 A CN 106670474A
Authority
CN
China
Prior art keywords
preparation
foaming
expandable
precast body
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611248905.6A
Other languages
Chinese (zh)
Inventor
宋滨娜
章顺虎
戴志伟
田俊
洪玉鹏
马俊杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou University
Original Assignee
Suzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou University filed Critical Suzhou University
Priority to CN201611248905.6A priority Critical patent/CN106670474A/en
Publication of CN106670474A publication Critical patent/CN106670474A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/002Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature
    • B22F7/004Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature comprising at least one non-porous part
    • B22F7/006Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature comprising at least one non-porous part the porous part being obtained by foaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/11Making porous workpieces or articles
    • B22F3/1121Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers
    • B22F3/1125Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers involving a foaming process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/18Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by using pressure rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention provides a preparation method of a foam aluminum sandwich panel. The preparation method includes the steps that (1) aluminum-silicon alloy powder and a foaming agent are mixed evenly to obtain a mixture, wherein the foaming agent accounts for 0.4% to 1% of the total mass of the aluminum-silicon alloy powder and the foaming agent; (2) mixed powder is added into an aluminum pipe with one end closed, an inlet is closed, and a preformed unit is obtained; (3) the preformed unit is subject to cold rolling, and a prefabricated body capable of foaming is obtained; and (4) the prefabricated body capable of foaming is led into an ultrasonic field for collaborative foaming in the foaming process, and the foam aluminum sandwich panel is obtained. The preparation method has the beneficial effects of being controllable in preparation, low in cost, stable in structure, good in mechanical property and the like.

Description

A kind of preparation method of foam aluminum sandwich
Technical field
The present invention relates to a kind of preparation field of porous metal material, more particularly to a kind of preparation side of foam aluminum sandwich Method.
Background technology
Foam aluminum sandwich is a kind of advanced composite material (ACM) of structure-function integration, both macroscopically has sandwich structure Compound characteristics, and while foamed aluminium material own characteristic is given full play to, solve single foamed aluminium intensity relatively low, it is difficult to The problems such as connection, with light weight, energy absorbing efficiency is high, specific stiffness is higher the features such as, can be widely used in Aero-Space manufacture, track The fields such as traffic, sea-freight, military equipment.But the stability of foam, foam structure, size, the control of uniformity and reappearance The problems such as difference, constrains the development and its application of foam aluminum sandwich industrialization always, therefore the growth course of control foam and steady It is qualitative be foam aluminum sandwich preparation in one of the key issue to be solved.
At present, the preparation method of foam aluminum sandwich is broadly divided into two major classes, and a class is first to obtain foam metal bare board, then The method being attached by different connection methods from metal decking.There is the cleaning of foamed aluminium board connection surface in this kind of method The problems such as unnet, non-face contact of combination interface, and also there is non-refractory, easily in the battenboard that wherein prepared by bonding method Aging the shortcomings of);Another kind of is direct foaming, prepares expandable precast body reheating precast body and is foamed, infusion pending Foamed in the aluminum melt with certain viscosity while decomposition, foam aluminum sandwich is prepared in finally cooling, directly Foam aluminum sandwich is obtained to obtain, the foaming process of core belongs to the direct foaming of powder metallurgy in such method, due to its preformation Type, integration and the features such as shape only, have obtained the attention of numerous researchers.Made by " the direct foaming of powder metallurgy " The standby foam aluminium sandwich structure material with metallurgical bonding interface so that the bulk strength of battenboard is improved, and high temperature resistant is not It is easily aging, a kind of extremely potential advanced composite material (ACM) is had been considered as, it is also that porous foam metal material scale should Important development direction.But its foaming process is an extremely complex process, its control is directly connected to battenboard Quality.Nowadays the cell morphology of precise control battenboard, macrostructure and problem in terms of its basal body structure is strengthened always Fail thoroughly solution.
The current research both at home and abroad to the growth course and stability of foam is a lot, the main control method for proposing now Be introduce external substance come increase the viscosity and surface tension of melt so as to improve melt stability or addition Ca, Mg, SiC、Al2O3Deng solid particle and fiber etc..But, lacking for foam aluminum sandwich cell morphology, structure is effective with tissue Control device, and this is industrialized key point, it is necessary to a kind of effective method is improved.
The content of the invention
In view of this, the present invention provides a kind of Stability Analysis of Structures, and stomata is uniform, the foam aluminum sandwich of good mechanical properties Preparation method.
To solve above technical problem, the technical scheme is that using a kind of preparation method of foam aluminum sandwich, Including:
1), alusil alloy powder is well mixed with foaming agent, compound is obtained, wherein the foaming agent accounts for alusil alloy 0.4~1wt% of powder and the foaming agent gross mass;
2), in the aluminum pipe for adding one end to close the mixed-powder, and buckle closure will be entered close, obtain prefabricated component;
3), the prefabricated component is carried out cold rolling, obtains expandable precast body;
4) the expandable precast body, is imported into ultrasonic field coordination foaming control, foam aluminum sandwich is obtained.
Preferably, the alusil alloy Al:Si mass ratioes are (7~18):1.
Preferably, the foaming agent is titantium hydride.
Preferably, step 2) it is specially:
By the compound be placed in inwall cleaning after, and one end closing aluminium shape tube in after by other port suppress seal Close;The wall thickness of the aluminium shape tube is 1~2.5mm.
Preferably, step 3) it is specially:
The prefabricated component is cold rolling under the pressure that pressure is 30~100T, obtain expandable precast body;It is described cold rolling Reduction ratio is 60~80%.
Preferably, the sandwich layer powder relative density of the expandable precast body is more than 85%.
Preferably, step 4) it is specially:
The expandable precast body is foamed, ultrasonic field is imported in foaming process, obtained the battenboard that foams, it is described super The importing power of sound field is 100~1000W, and the time is 10~120s.
Preferably, the blowing temperature is 660~720 DEG C, and foamed time is 30~120s.
Preferably, the blowing temperature is 680~710 DEG C, and foamed time is 50~100s,
Preferably, the importing power of the ultrasonic field is 200~800W, and the time is 10~120s.
The invention provides a kind of preparation method of foam aluminum sandwich, including:1), by alusil alloy powder and foaming agent It is well mixed, obtain compound, wherein the foaming agent account for alusil alloy powder and the foaming agent gross mass 0.4~ 1wt%;2), in the aluminum pipe for adding one end to close the mixed-powder, and entrance is closed, obtains prefabricated component;3), will be described Prefabricated component carries out cold rolling, obtains expandable precast body;4), the expandable precast body is foamed in ultrasonic field, foam is obtained Aluminum sandwich panel.Preparation method of the invention passes through ultrasonic field coordination and foams with interference TiH2The function of decomposable process, promotes H2's Resolution ratio and utilization rate;Ultrasonic field is conducive to smashing big bubble in foaming process, makes bubble homoepitaxial, it is to avoid big is logical The abscess of hole and breakage is formed;Ultrasonic field can also obtain good performance effect, with controllable to matrix grain structure refinement The features such as standby, with low cost, Stability Analysis of Structures, preferable mechanical property, the extensive concern of researcher is caused in recent years.
The foam aluminum sandwich prepared by ultrasonic field coordination foaming process, proposition is corresponding with the method most preferably to be prepared Technological parameter, can prepare average pore size for 1~3mm, and the averag density of foam aluminum sandwich is 0.6~1.5g/cm3, bubble The sandwich layer averag density of foam aluminum sandwich panel is 0.2~0.8g/cm3Interface realize metallurgical binding and crystal grain is tiny, with equiaxial The quality material of brilliant tissue characteristic, the method is easy and effective, the production practices of the foam aluminum sandwich prepared to powder metallurgic method Certain directive function can be played, the method not only may apply to the foam metal material of Al-Si bases, also be in other metals The preparation of base foamed material provides a kind of new method, with broad prospect of application.
Brief description of the drawings
Fig. 1, for embodiment 1 prepare foam aluminum sandwich foaming structure schematic diagram;
Fig. 2, the microscopic appearance for the foaming initial stage of embodiment 1;
Fig. 3, for embodiment 2 prepare foam aluminum sandwich foaming structure schematic diagram;
Fig. 4, the microscopic appearance for the foaming initial stage of embodiment 2;
Fig. 5, for comparative example 1 prepare foam aluminum sandwich foaming structure schematic diagram;
Fig. 6, the microscopic appearance for the foaming initial stage of comparative example 1.
Specific embodiment
In order that those skilled in the art more fully understands technical scheme, with reference to specific embodiment The present invention is described in further detail.
It is the foam aluminum sandwich of 1mm that embodiment 1 prepares average pore size
Weigh the alusil alloy powder (Al of certain mass:Si mass percents:7:1) particle diameter is 50~200 μm, foaming agent Titanium hydride powders powder diameter is 50~150 μm, is well mixed with titanium hydride powders, and wherein titanium hydride powders account for the total matter of powder 0.4~1w.t.% of amount, the powder after being well mixed pours into inwall cleaning (electrochemical deoiling) and the wall thickness of one end closing is 1 In~2.5mm aluminium shape tubes, then other port is suppressed and is closed;Blank after powder filling is encapsulated uses 60 on milling train It is cold rolling that~80% rolling reduction ratio carries out single, and draught pressure is 30~100T, it is ensured that precast body sandwich layer powder relative density More than 85%, the composite plate obtained after rolling cuts into expandable precast body by along side;Expandable precast body is placed in induction furnace In foamed, import ultrasonic field in foaming process, the power that ultrasonic field is imported is 200~800W, and the time is 10~120s. Fig. 1 is sample in embodiment 1, and Fig. 2 is the microscopic appearance at foaming initial stage.
It is the foam aluminum sandwich of 2mm that embodiment 2 prepares average pore size
Weigh the alusil alloy powder (Al of certain mass:Si mass percents:11:1) particle diameter is 50~200 μm, foaming Agent titanium hydride powders powder diameter is 50~150 μm, is well mixed with titanium hydride powders, and wherein to account for powder total for titanium hydride powders 0.4~1w.t.% of quality, the powder after being well mixed pours into inwall cleaning (electrochemical deoiling) and the wall thickness of one end closing is In 1~2.5mm aluminium shape tubes, then other port is suppressed and is closed;Blank after powder filling is encapsulated is used on milling train It is cold rolling that 60~80% rolling reduction ratio carries out single, and draught pressure is 30~100T, it is ensured that precast body sandwich layer powder is relatively close Degree is more than 85%, and the composite plate obtained after rolling cuts into expandable precast body by along side;Expandable precast body is placed in sensing Foamed in stove, blowing temperature is 660~720 DEG C, and foamed time is 30~120s, and ultrasonic field is imported in foaming process, The power that ultrasonic field is imported is 200~800W, and the time is 10~120s.Fig. 3 is sample in embodiment 2, and Fig. 3 is the foaming initial stage Microscopic appearance.
Comparative example 1
Weigh the alusil alloy powder (Al of certain mass:Si mass percents:7:1) particle diameter is 50~200 μm, foaming agent Titanium hydride powders powder diameter is 50~150 μm, is well mixed with titanium hydride powders, and wherein titanium hydride powders account for the total matter of powder 0.4~1w.t.% of amount, the powder after being well mixed pours into inwall cleaning (electrochemical deoiling) and the wall thickness of one end closing is 1 In~2.5mm aluminium shape tubes, then other port is suppressed and is closed;Blank after powder filling is encapsulated uses 60 on milling train It is cold rolling that~80% rolling reduction ratio carries out single, and draught pressure is 30~100T, it is ensured that precast body sandwich layer powder relative density More than 85%, the composite plate obtained after rolling cuts into expandable precast body by along side;Expandable precast body is placed in induction furnace In foamed, blowing temperature be 660~720 DEG C, foamed time is 30~120s.Fig. 5 is sample in comparative example 1, and Fig. 6 is hair The microscopic appearance at bubble initial stage.
By the comparing of Fig. 1,3 and Fig. 5 can be seen that using the inventive method prepare foam aluminum sandwich aperture compared with It is the continuous macropore of homogeneous and no appearance, illustrates that product prepared by the preparation method of present invention offer solves existing skill really Art problem.Contrast according further to Fig. 2,4 and 6 is it is also seen that from microcosmic point, its aperture is also comparatively homogeneous.So this The preparation method enhancing macrostructure and its basal body structure for providing are invented, because aperture is homogeneous, without continuous not of uniform size Hole occurs, so its stress is more uniform, be not in defect point, improve the mechanical property of foam aluminum sandwich.
The above is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred embodiment is not construed as Limitation of the invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch and also should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of preparation method of foam aluminum sandwich, it is characterised in that including:
1), alusil alloy powder is well mixed with foaming agent, compound is obtained, wherein the foaming agent accounts for alusil alloy powder With 0.4~1wt% of the foaming agent gross mass;
2), in the aluminum pipe for adding one end to close the mixed-powder, and entrance is closed, obtains prefabricated component;
3), that the prefabricated component carried out into single is cold rolling, obtains expandable precast body;
4) the expandable precast body, is imported into ultrasonic field coordination foaming, foam aluminum sandwich is obtained.
2. preparation method according to claim 1, it is characterised in that the alusil alloy Al:Si mass ratioes for (7~ 18):1。
3. preparation method according to claim 1, it is characterised in that the foaming agent is titantium hydride.
4. preparation method according to claim 1, it is characterised in that step 2) it is specially:
By the compound be placed in inwall cleaning after, and one end closing aluminium shape tube in after by other port suppress close; The wall thickness of the aluminium shape tube is 1~2.5mm.
5. preparation method according to claim 1, it is characterised in that step 3) it is specially:
The prefabricated component is cold rolling under the pressure that pressure is 30~100T, obtain expandable precast body;The cold rolling pressure Rate is 60~80%.
6. preparation method according to claim 1, it is characterised in that the sandwich layer powder of the expandable precast body is relatively close Degree is more than 85%.
7. preparation method according to claim 1, it is characterised in that step 4) it is specially:
The expandable precast body is foamed, ultrasonic field Collaborative Control is imported in foaming process, obtained foam battenboard, institute The importing power of ultrasonic field is stated for 100~1000W, the time is 10~120s.
8. preparation method according to claim 7, it is characterised in that the blowing temperature is 660~720 DEG C, during foaming Between be 30~120s.
9. preparation method according to claim 8, it is characterised in that the blowing temperature is 680~710 DEG C, during foaming Between be 50~100s.
10. preparation method according to claim 7, it is characterised in that the importing power of the ultrasonic field is 200~ 800W, the time is 10~120s.
CN201611248905.6A 2016-12-29 2016-12-29 Preparation method of foam aluminum sandwich panel Pending CN106670474A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611248905.6A CN106670474A (en) 2016-12-29 2016-12-29 Preparation method of foam aluminum sandwich panel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611248905.6A CN106670474A (en) 2016-12-29 2016-12-29 Preparation method of foam aluminum sandwich panel

Publications (1)

Publication Number Publication Date
CN106670474A true CN106670474A (en) 2017-05-17

Family

ID=58872591

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611248905.6A Pending CN106670474A (en) 2016-12-29 2016-12-29 Preparation method of foam aluminum sandwich panel

Country Status (1)

Country Link
CN (1) CN106670474A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108526466A (en) * 2018-04-10 2018-09-14 安徽宏志建材科技有限公司 Core material for sandwich panel and preparation method thereof
CN108705084A (en) * 2018-05-22 2018-10-26 东北大学 A kind of preparation method of industrial large scale foam aluminum sandwich
CN112522694A (en) * 2020-11-17 2021-03-19 东北大学 Foamed aluminum sandwich plate surface blackening foaming method based on rapid heat transfer
CN114273657A (en) * 2020-10-01 2022-04-05 通用汽车环球科技运作有限责任公司 Metal foam extrusion process and articles made therefrom

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5564064A (en) * 1995-02-03 1996-10-08 Mcdonnell Douglas Corporation Integral porous-core metal bodies and in situ method of manufacture thereof
CN1410200A (en) * 2002-11-16 2003-04-16 昆明理工大学 Preparation of foamed metal sandwich board using clad rolling method
US20070151697A1 (en) * 2003-04-16 2007-07-05 Wittebrood Adrianus J Preform for foamed sheet product and foamed product manufactured therefrom
DE102007006156B3 (en) * 2007-02-07 2008-06-26 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Making composite with component bonded to foamed body, for e.g. reinforcement, introduces thermally-foamable pressing into cavity of component, deforms, bonds and heats
CN101818278A (en) * 2010-05-14 2010-09-01 大连海事大学 Device and method for preparing porous foam metal by metal melt inflation process
CN101905326A (en) * 2010-07-22 2010-12-08 东北大学 Method for manufacturing foamed aluminum sandwich plate
CN102389976A (en) * 2011-11-28 2012-03-28 苏州大学 Preparation method of foamed aluminum and alloy sandwich plate
CN104384830A (en) * 2014-10-27 2015-03-04 丹阳市国美汽配有限公司 Method for manufacturing foamed aluminum and alloy sandwich plate for automobile bumper
CN104451230A (en) * 2014-11-17 2015-03-25 界首市一鸣新材料科技有限公司 Improved process for producing foamed aluminum by adopting ultrasonic melt-foaming method
CN105642671A (en) * 2016-01-11 2016-06-08 昆明理工大学 Preparation method of sandwich board with aluminium alloy foam core

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5564064A (en) * 1995-02-03 1996-10-08 Mcdonnell Douglas Corporation Integral porous-core metal bodies and in situ method of manufacture thereof
CN1410200A (en) * 2002-11-16 2003-04-16 昆明理工大学 Preparation of foamed metal sandwich board using clad rolling method
US20070151697A1 (en) * 2003-04-16 2007-07-05 Wittebrood Adrianus J Preform for foamed sheet product and foamed product manufactured therefrom
DE102007006156B3 (en) * 2007-02-07 2008-06-26 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Making composite with component bonded to foamed body, for e.g. reinforcement, introduces thermally-foamable pressing into cavity of component, deforms, bonds and heats
CN101818278A (en) * 2010-05-14 2010-09-01 大连海事大学 Device and method for preparing porous foam metal by metal melt inflation process
CN101905326A (en) * 2010-07-22 2010-12-08 东北大学 Method for manufacturing foamed aluminum sandwich plate
CN102389976A (en) * 2011-11-28 2012-03-28 苏州大学 Preparation method of foamed aluminum and alloy sandwich plate
CN104384830A (en) * 2014-10-27 2015-03-04 丹阳市国美汽配有限公司 Method for manufacturing foamed aluminum and alloy sandwich plate for automobile bumper
CN104451230A (en) * 2014-11-17 2015-03-25 界首市一鸣新材料科技有限公司 Improved process for producing foamed aluminum by adopting ultrasonic melt-foaming method
CN105642671A (en) * 2016-01-11 2016-06-08 昆明理工大学 Preparation method of sandwich board with aluminium alloy foam core

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108526466A (en) * 2018-04-10 2018-09-14 安徽宏志建材科技有限公司 Core material for sandwich panel and preparation method thereof
CN108705084A (en) * 2018-05-22 2018-10-26 东北大学 A kind of preparation method of industrial large scale foam aluminum sandwich
WO2019223022A1 (en) * 2018-05-22 2019-11-28 东北大学 Method for manufacturing large industrial-sized aluminum composite panels
CN114273657A (en) * 2020-10-01 2022-04-05 通用汽车环球科技运作有限责任公司 Metal foam extrusion process and articles made therefrom
CN112522694A (en) * 2020-11-17 2021-03-19 东北大学 Foamed aluminum sandwich plate surface blackening foaming method based on rapid heat transfer
CN112522694B (en) * 2020-11-17 2021-12-07 东北大学 Foamed aluminum sandwich plate surface blackening foaming method based on rapid heat transfer

Similar Documents

Publication Publication Date Title
CN106670474A (en) Preparation method of foam aluminum sandwich panel
CN102002607B (en) Method for preparing foamed aluminum by foaming melt
CN104046826B (en) A kind of foam magnesium sill and preparation method thereof
CN107760933A (en) A kind of 3D printing strengthens Al alloy powder and preparation method thereof with in-situ nano complex phase ceramic
CN102031429B (en) High-Fe-V-Si heat-resistant aluminum alloy material and preparation method thereof
CN106435283A (en) Rare earth high-strength foam aluminum prepared through melt foaming method and preparation process of rare earth high-strength foam aluminum
CN102086023B (en) In-situ synthesis method combining sol-gel with thermit reaction and FeNiCrTi/NiAl-Al2O3 nano composite material synthesized by method
CN106064242A (en) A kind of SPS of employing prepares the method for SiC particle enhanced aluminum-based composite material
CN112680643B (en) Rare earth Y-containing self-foaming porous magnesium alloy and preparation method thereof
CN109763012A (en) The preparation method of flux foaming enhancing foamed aluminium composite foamable agent
CN104805324B (en) Method for preparing foam zinc-based material through powder metallurgic method
CN102021504A (en) Magnesium-based amorphous/porous titanium double-phase three-dimensional communicated composite material and preparation method thereof
CN106967910B (en) A kind of high intensity Al-Zn-Mg line aluminium alloys and preparation method thereof
CN104894408A (en) Refining method for aluminum alloy
CN109868395A (en) A kind of high hardness material and preparation method thereof
CN105855550A (en) Technology method for filling bearable molded body structure with rare earth foamed aluminum
CN101705405B (en) Magnesium base spherical quasicrystal master alloy and preparation method thereof
CN108149160A (en) A kind of high impact toughness foamed aluminium and its production technology based on A356 aluminium alloys
CN110846545B (en) Metal ceramic composite material produced from powdered quartz ore and used for 3D printing and preparation method thereof
CN110093527B (en) Preparation method of high-strength closed-cell foamed aluminum with polyhedral cell structure
CN108179300B (en) A kind of preparation method of foam magnesium sandwich plate
CN101705407B (en) Magnesium base spherical quasicrystal master alloy and preparation method thereof
CN105002388A (en) La2O3 modified Al-TiO2-C grain refiner, preparation method thereof and commercial-purity aluminum refining method
CN104388729A (en) Aluminum alloy compound inoculant and preparation method thereof
CN106222500A (en) A kind of aluminum matrix composite and preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170517