CN106653909A - Solar photovoltaic cell back panel - Google Patents

Solar photovoltaic cell back panel Download PDF

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Publication number
CN106653909A
CN106653909A CN201611094521.3A CN201611094521A CN106653909A CN 106653909 A CN106653909 A CN 106653909A CN 201611094521 A CN201611094521 A CN 201611094521A CN 106653909 A CN106653909 A CN 106653909A
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CN
China
Prior art keywords
layer
fluoro
containing coating
basic unit
coating
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Pending
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CN201611094521.3A
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Chinese (zh)
Inventor
梁结平
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Individual
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Individual
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Priority to CN201611094521.3A priority Critical patent/CN106653909A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

The invention relates to a solar photovoltaic cell back panel and a fabrication method thereof, and belongs to the technical field of a solar photovoltaic cell back panel. The solar photovoltaic cell back panel comprises seven layers of structures which are sequentially arranged from top to bottom, a first fluorine-containing coating layer is coated between a lower surface of a first base layer and an upper surface of a second base layer, a second fluorine-containing coating layer is coated between a lower surface of the third base layer and an upper surface of a fourth base layer, and a PET layer is coated between a lower surface of the second base layer and an upper surface of the third base layer. A mixture formed by combining high-rigidity inorganic nanometer powder and silicon dioxide nanometer powder coated with a coupling agent is added into the fluorine-containing coating layers, thus, the rigidity of the coating layers is greatly improved, the scratch resistant performance is good, the surfaces of the coating layers of the back panel cannot be damaged during erasing a silicone sealant on the surface, the quality is ensured, and the service lifetime of a module is prolonged and is over 25 years.

Description

A kind of solar photovoltaic cell backplane
Technical field
The invention belongs to the technical field of solar panel backboard, and in particular to a kind of hardness is high, scratch resistant performance is good The solar photovoltaic cell backplane with fluoro-containing coating layer.
Background technology
Solar energy is the inexhaustible clean energy resource of nature, and in recent years, opto-electronic conversion Solar use takes Significant progress was obtained, technology constantly improves, and market is expanded rapidly.Because the photoelectric transformation efficiency of silicon solar cell is compared with other The solar cell of species is high, thus quickly grows, particularly by solar battery group composition of backboards polysilicon solar cell Into solar panel be increasingly becoming the market mainstream.
Used as the green replacement scheme of traditional production method of electric energy, photovoltaic cell component is utilized to sunshine and produces electricity Energy.Photovoltaic cell component is formed by various semiconductor element system assembles.But the photovoltaic module that prior art is used, due to applying Layer difference of hardness, before installing during silicone sealant on surface is wiped, may damage backboard coating surface, affect quality.
The content of the invention
For problems of the prior art, it is an object of the invention to provide a kind of hardness is high, scratch resistant performance is good The solar photovoltaic cell backplane with fluoro-containing coating layer.
In order to solve the above problems, the technical solution used in the present invention is:A kind of solar photovoltaic cell backplane, its feature Be include setting gradually from top to bottom the first basic unit, the first fluoro-containing coating layer, the second basic unit, pet layer, the 3rd basic unit, Two fluoro-containing coating layers and the seven-layer structure of the 4th basic unit, coating between first basic unit's lower surface and the second basic unit upper surface arranges the One fluoro-containing coating layer, coating between the 3rd basic unit's lower surface and the 4th basic unit upper surface arranges the second fluoro-containing coating layer, the second base Coating between the lower surface of layer and the upper surface of the 3rd basic unit arranges pet layer, and described the first fluoro-containing coating layer and second is fluorine-containing The nano-powder for improving hardness, in terms of high fluorine synthetic total coating weight, described addition nano-powder weight are added in dope layer Percentage is 1%~1.5%, and described the first fluoro-containing coating layer and the second fluoro-containing coating are by nano-powder, modified two fluorine-based paintings Material and three fluorine-based vinyl coating threes mix, and its weight percentage is:Three fluorine-based vinyl coatings 60~75%, change Property two fluorine-based coating 10~45%, nano-powder 1%~1.5%, the particle size diameter of fluoro-containing coating is 8~12 μm after mixing, the The thickness of one fluoro-containing coating layer and the second fluoro-containing coating layer is 18~30 μm.
Preferably, described nano-powder is the silicon dioxide nano powder of inorganic nanometer powder and cladding coupling agent Mixture, wherein the silicon dioxide nano powder percentage by weight of cladding coupling agent is 5%~10%, balance of inorganic nanometer-powder Body.
Preferably, described inorganic nanometer powder is the zirconium oxide mixed with arbitrary proportion, aluminum oxide, boron nitride it is mixed Compound.
Preferably, described silicon dioxide nano powder has coated coupling agent, described coupling agent is organosilicon, metatitanic acid Ester, any one in Aluminate, with coated silica nano-powder gross weight meter, the coupling agent addition accounts for weight hundred Divide than being 1.5%~2%.
Preferably, described pet layer is the three-layer co-extruded structure of A, B, C, integral thickness is 290~380 μm, wherein A layers For PET synthetic layers, 25%, the B layers for accounting for pet layer thickness are nanometer layer, and 50%, the C layers for accounting for pet layer thickness are flame-retardant layer, account for PET The 25% of thickness degree, described B layers nanometer layer is silica, titanium dioxide, aluminum oxide, the mixture of zinc oxide.
Preferably, described pet layer is the three-layer co-extruded structure of A, B, C, integral thickness is 300~350 μm.
Preferably, the first basic unit, the second basic unit, the 3rd basic unit, the 4th basic unit surface using plasma silication Titanium nano processing technology is processed, and then carries out the first fluoro-containing coating layer, pet layer, the coating of the second fluoro-containing coating layer, coating The high-accuracy coating line non-ripple paint-on techniques of Shi Caiyong, and fluoro-containing coating painting is attached on PET thin slices with roll coating model.
Preferably, the application speed of fluoro-containing coating is 20~35m/ minutes, application thickness is 18~30 μm, solidification temperature For 150~170 DEG C, curing agent adopts blocked isocyanate, and deblocking temperature is 90~130 DEG C.
Preferably, the application speed of fluoro-containing coating is 25m/ minutes, application thickness is 22~27 μm, and solidification temperature is 155 DEG C, deblocking temperature is 90~100 DEG C
The present invention using advanced fluoro-containing coating interconnection run through integration technology, plasma silication titanium nano processing technology and High-accuracy non-ripple paint-on technique makes the solar photovoltaic cell backplane of 7 Rotating fields, at using plasma titanium silicide nano Reason technical finesse, makes each layer surface hydrophiling, improves the adhesive force and caking property of each interlayer.The present invention is by fluoro-containing coating layer It is interior to add the mixture combined by the silicon dioxide nano powder of inorganic nanometer powder and cladding coupling agent, substantially increase The hardness of coating, scratch resistant performance is good, wipe surface on silicone sealant when, backboard coating surface will not be damaged, quality has Ensure, increased the service life of component, make assembly life-span more than 25 years.
Description of the drawings
Fig. 1 is the structural representation of the present invention.
In figure:The basic units of 1- first, 2- the first fluoro-containing coating layers, the basic units of 3- second, 4-PET layers, the basic units of 5- the 3rd, 6- second Fluoro-containing coating layer, the basic units of 7- the 4th.
Specific embodiment
Present disclosure is further illustrated below by embodiment, protection scope of the present invention is not limited to following realities Apply example.
As shown in figure 1, a kind of solar photovoltaic cell backplane, it is characterised in that including first for setting gradually from top to bottom Basic unit (1), the first fluoro-containing coating layer (2), the second basic unit (3), pet layer (4), the 3rd basic unit (5), the second fluoro-containing coating layer (6) With the seven-layer structure of the 4th basic unit (7), coating setting first between the first basic unit (1) lower surface and the second basic unit (3) upper surface Fluoro-containing coating layer (2), coating between the 3rd basic unit's (5) lower surface and the 4th basic unit (7) upper surface arranges the second fluoro-containing coating layer (6), coating arranges pet layer (4) between the upper surface of the lower surface of the second basic unit (3) and the 3rd basic unit (5), and described first contains The nano-powder for improving hardness is added in fluoro coatings layer (2) and the second fluoro-containing coating layer (6), with high fluorine synthetic total coating weight Meter, described addition nano-powder percentage by weight is 1%~1.5%, and described the first fluoro-containing coating layer (2) and second is fluorine-containing Coating (6) is mixed by nano-powder, modified two fluorine-based coating and three fluorine-based vinyl coating threes, its weight percentage For:Three fluorine-based vinyl coatings 60~75%, be modified two fluorine-based coating 10~45%, nano-powder 1%~1.5%, after mixing The particle size diameter of fluoro-containing coating is 8~12 μm, and the thickness of the first fluoro-containing coating layer (2) and the second fluoro-containing coating layer (6) is 18 ~30 μm.
Nano-powder used by patent of the present invention is the silicon dioxide nano powder of inorganic nanometer powder and cladding coupling agent Mixture, wherein cladding coupling agent silicon dioxide nano powder percentage by weight be 5%~10%, balance of inorganic nano Powder.Described inorganic nanometer powder is with the zirconium oxide of arbitrary proportion mixing, aluminum oxide, the mixture of boron nitride.Described Silicon dioxide nano powder has coated coupling agent, and described coupling agent is organosilicon, titanate esters, any one in Aluminate, With coated silica nano-powder gross weight meter, the coupling agent addition accounts for percentage by weight for 1.5%~2%.
The thickness of described the first basic unit, the second basic unit, the 3rd basic unit and the 4th basic unit is 1~30nm, and preferred thickness is 6 ~12nm, described pet layer (4) is the three-layer co-extruded structure of A, B, C, and integral thickness is 290~380 μm, and integral thickness is preferably 300~350 μm, wherein A layers are PET synthetic layers, and 25%, the B layers for accounting for pet layer (4) thickness are nanometer layer, account for pet layer (4) thickness 50%, C layers be flame-retardant layer, account for the 25% of pet layer (4) thickness, described B layers nanometer layer is silica, titanium dioxide, oxygen Change aluminium, the mixture of zinc oxide.
Wherein, the first basic unit (1), the second basic unit (3), the 3rd basic unit (5), the 4th basic unit (7) surface using etc. from Daughter titanium silicide nano treatment technology is processed, and then carries out the first fluoro-containing coating layer (2), pet layer (4), the second fluorine-containing painting The coating of the bed of material (6), adopts high-accuracy coating line non-ripple paint-on technique during coating, and with roll coating model by fluoro-containing coating Painting is attached on PET thin slices.The application speed of fluoro-containing coating is 20~35m/ minutes, and application thickness is 18~30 μm, solidification temperature For 150~170 DEG C, curing agent adopts blocked isocyanate, and deblocking temperature is 90~130 DEG C, the painting of preferred fluoro-containing coating Dress speed is 25m/ minutes, and application thickness is 22~27 μm, and solidification temperature is 155 DEG C, and deblocking temperature is 90~100 DEG C.
The present invention in fluoro-containing coating layer by adding by the silica nanometer of inorganic nanometer powder and cladding coupling agent The mixture that powder is combined, substantially increases the hardness of coating, and scratch resistant performance is good, the silicone sealant on erasing surface When, backboard coating surface will not be damaged, quality is guaranteed, increased the service life of component, makes assembly life-span more than 25 years.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (9)

1. a kind of solar photovoltaic cell backplane, it is characterised in that including the first basic unit (1) for setting gradually from top to bottom, first Fluoro-containing coating layer (2), the second basic unit (3), pet layer (4), the 3rd basic unit (5), the second fluoro-containing coating layer (6) and the 4th basic unit (7) Seven-layer structure, between the first basic unit (1) lower surface and the second basic unit (3) upper surface coating arrange the first fluoro-containing coating layer (2), Coating between 3rd basic unit's (5) lower surface and the 4th basic unit (7) upper surface arranges the second fluoro-containing coating layer (6), the second basic unit (3) Lower surface and the upper surface of the 3rd basic unit (5) between coating pet layer (4) is set, described the first fluoro-containing coating layer (2) and the The nano-powder for improving hardness, in terms of high fluorine synthetic total coating weight, described addition nanometer are added in two fluoro-containing coating layers (6) Powder percentage by weight is 1%~1.5%, and described the first fluoro-containing coating layer (2) and the second fluoro-containing coating (6) are by nano powder Body, modified two fluorine-based coating and three fluorine-based vinyl coating threes mix, and its weight percentage is:Three fluorine-based vinyl Coating 60~75%, be modified two fluorine-based coating 10~45%, nano-powder 1%~1.5%, and the granularity of fluoro-containing coating is straight after mixing Footpath is 8~12 μm, and the thickness of the first fluoro-containing coating layer (2) and the second fluoro-containing coating layer (6) is 18~30 μm.
2. a kind of solar photovoltaic cell backplane according to claim 1, it is characterised in that described nano-powder is nothing The mixture of the silicon dioxide nano powder of machine nano-powder and cladding coupling agent, wherein the silica nanometer of cladding coupling agent Powder percentage by weight is 5%~10%, balance of inorganic nanometer powder.
3. a kind of solar photovoltaic cell backplane according to claim 2, it is characterised in that described inorganic nanometer powder It is with the zirconium oxide of arbitrary proportion mixing, aluminum oxide, the mixture of boron nitride.
4. a kind of solar photovoltaic cell backplane according to claim 2, it is characterised in that described silica nanometer Powder has coated coupling agent, and described coupling agent is organosilicon, titanate esters, any one in Aluminate, to coat titanium dioxide Silicon nano power body gross weight meter, the coupling agent addition accounts for percentage by weight for 1.5%~2%.
5. a kind of solar photovoltaic cell backplane according to claim 1, it is characterised in that described pet layer (4) is A, The three-layer co-extruded structure of B, C, integral thickness is 290~380 μm, and wherein A layers are PET synthetic layers, account for the 25% of pet layer (4) thickness, B layers are nanometer layer, and 50%, the C layers for accounting for pet layer (4) thickness are flame-retardant layer, account for the 25% of pet layer (4) thickness, and described B layers are received Rice layer is silica, titanium dioxide, aluminum oxide, the mixture of zinc oxide.
6. a kind of solar photovoltaic cell backplane according to claim 5, it is characterised in that described pet layer (4) is A, The three-layer co-extruded structure of B, C, integral thickness is 300~350 μm.
7. a kind of solar photovoltaic cell backplane according to claim 1, it is characterised in that the first basic unit (1), second Basic unit (3), the 3rd basic unit (5), the surface using plasma titanium silicide nano treatment technology of the 4th basic unit (7) are processed, Then the first fluoro-containing coating layer (2), pet layer (4), the coating of the second fluoro-containing coating layer (6) are carried out, high-accuracy painting is adopted during coating Overgrowth producing line non-ripple paint-on technique, and fluoro-containing coating painting is attached on PET thin slices with roll coating model.
8. a kind of solar photovoltaic cell backplane according to claim 7, it is characterised in that the application speed of fluoro-containing coating For 20~35m/ minutes, application thickness is 18~30 μm, and solidification temperature is 150~170 DEG C, and curing agent adopts enclosed type isocyanic acid Ester, deblocking temperature is 90~130 DEG C.
9. a kind of solar photovoltaic cell backplane according to claim 8, it is characterised in that the application speed of fluoro-containing coating For 25m/ minutes, application thickness is 22~27 μm, and solidification temperature is 155 DEG C, and deblocking temperature is 90~100 DEG C.
CN201611094521.3A 2016-12-01 2016-12-01 Solar photovoltaic cell back panel Pending CN106653909A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109968768A (en) * 2017-12-28 2019-07-05 宁波长阳科技股份有限公司 A kind of insulating heat-conductive solar cell backboard

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102005492A (en) * 2010-08-30 2011-04-06 杭州联合新材科技股份有限公司 High-fluorine mixcrystal coating solar photovoltaic cell back panel and manufacture method thereof
CN102005491A (en) * 2010-08-30 2011-04-06 杭州联合新材科技股份有限公司 High-fluorine mixcrystal coating solar photovoltaic cell back film and manufacturing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102005492A (en) * 2010-08-30 2011-04-06 杭州联合新材科技股份有限公司 High-fluorine mixcrystal coating solar photovoltaic cell back panel and manufacture method thereof
CN102005491A (en) * 2010-08-30 2011-04-06 杭州联合新材科技股份有限公司 High-fluorine mixcrystal coating solar photovoltaic cell back film and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109968768A (en) * 2017-12-28 2019-07-05 宁波长阳科技股份有限公司 A kind of insulating heat-conductive solar cell backboard

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Application publication date: 20170510