CN106653361B - A kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device - Google Patents

A kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device Download PDF

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Publication number
CN106653361B
CN106653361B CN201611008437.5A CN201611008437A CN106653361B CN 106653361 B CN106653361 B CN 106653361B CN 201611008437 A CN201611008437 A CN 201611008437A CN 106653361 B CN106653361 B CN 106653361B
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Prior art keywords
resin
capacitance
powder
power source
polypropylene film
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CN201611008437.5A
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CN106653361A (en
Inventor
胡忠胜
华玲萍
吴良军
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Anhui Feida Electrical Technology Co Ltd
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Anhui Feida Electrical Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/14Organic dielectrics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/224Housing; Encapsulation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/32Wound capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/33Thin- or thick-film capacitors 

Abstract

A kind of metallized polypropylene film of disclosure of the invention inhibits electromagnetic power source interference fixed capacity device, including capacitance, shell, pin, resin, the capacitance is set inside the housing, potting resin between shell and capacitance, the capacitance both ends are respectively welded a pin, and the pin all extends to housing exterior;The capacitance makees medium using polypropylene screen, and zinc, al deposition are had mercy on film as electrode roll with the method being evaporated in vacuo, and the resin is made by by following component:Epoxy resin, poly- 1 butene resins, modified sericite in powder, starch;The metallized polypropylene film of the present invention, which inhibits electromagnetic power source interference fixed capacity device, can bear overvoltage impact, have excellent flame retardant property, be widely used in the anti-interference occasions such as power supply cross-line road.

Description

A kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device
Technical field
The present invention relates to capacitor areas, inhibit electromagnetic power source interference with admittedly more particularly to a kind of metallized polypropylene film Determine capacitor.
Background technology
Thin film capacitor is to work as electrode with metal foil, by itself and poly- ethyl ester, polypropylene, the modelings such as polystyrene or makrolon Expect film, after being overlapped from both ends, be wound into the capacitor of cylindric construction;Among all plastic film capacitances, poly- third The characteristic of alkene (PP) capacitance is the most notable, and capacitor made from polypropylene film is with its percent thermal shrinkage is low, performance is stable, resistance to height It is warm, high pressure resistant, prevent the remarkable advantages such as breakdown so that the use scope of capacitor made from polypropylene film is more and more wider.Electricity Hold the heart that fuse is capacitor, therefore capacitor manufacture fuse material must have high frequency tolerant, high temperature resistant can bear high current A kind of polymeric membrane of impact makees medium, just can guarantee that complete machine works steadily in the long term.But existing polypropylene film capacitance Device is under the conditions of high frequency or high impulse in use, by the pulse current of capacitor capacitor self-heating can be made to lead and Wen Sheng The problems such as causing the increase of self-healing point, pressure-resistant reduction, the lost of life, after long-term work, easy aging, working performance reduces, and existing Some metallized polypropylene films are not strong for the interference free performance of electromagnetic power source, the performance of strong influence capacitor.
The content of the invention
The object of the present invention is to provide a kind of metallized polypropylene films to inhibit electromagnetic power source interference fixed capacity device, passes through Following technical scheme is realized:
A kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device, including capacitance, shell, pin, tree Fat, the capacitance are set inside the housing, and potting resin between shell and capacitance, the capacitance both ends are respectively welded one and draw Foot, the pin all extend to housing exterior;The capacitance makees medium using polypropylene screen, and will with the method being evaporated in vacuo Zinc, al deposition are had mercy on film as electrode roll, and the resin is made by weight of following component:Epoxy resin 32, Poly 1-butene resin 5, modified sericite in powder 1, starch 0.5.
Further, capacitor and pin weld gilding layer.
Further, the polypropylene screen is made by weight of following component:Acrylic resin 28, olive mountain flour 1, Rosin 3, cumyl peroxide 0.4, its preparation method are:By rosin mass concentration be 1.26% citric acid solution in 30min is impregnated at 48 DEG C, then, filtering, naturally dry, then mixed with acrylic resin, molten condition is heated to, is kept the temperature 12min, then olive mountain flour is added, after stirring 5min, cumyl peroxide is added, after stirring 35min, is squeezed out, obtained It is non-stretched, then that non-stretched progress is biaxial stretch-formed, obtain polypropylene screen.
Further, the pin is CP lines.
Further, the modified sericite in powder is made by weight of following component:Sericite in powder 135, sepiolite Powder 3, enuatrol 2, activated zinc oxide 2, neopelex 1, the preparation method of potassium peroxydisulfate 0.03 are:There to be sericite Powder and sepiolite powder add in the 3-5 times of methanol solution measured and impregnate 2h after mixing, then add activated zinc oxide, dodecyl Benzene sulfonic acid sodium salt and enuatrol, then 2-3h is ground in grinder, methanol is recycled, is heated to 140 DEG C, keeps the temperature 15min, it is then natural It is cooled to room temperature, grinds 40min, cross 800 mesh to get required modified sericite in powder.
Further, the preparation method of the resin is:By epoxy resin, poly 1-butene resin, modified sericite in powder, shallow lake Powder is uniformly admixed together by each parts by weight, and the mass concentration for then adding epoxy resin quality 10% at 62 DEG C again is 4.5% Hydrogen peroxide after stirring evenly, is heated to 78 DEG C, stirs 40min with 500r/min rotating speeds, is finally filtered, washs, dries, .
Further, the shell is made of PBT plastic, and anti-flammability grade is 94-V0.
After testing, horizontal percent thermal shrinkage during 20min is stood at 350 DEG C of the polypropylene film that prepared by the present invention< 0.125%, transverse tensile strength 224-233MPa, longitudinal tensile strength 187-195MPa, wetting tension 33-35mN/ m。
The beneficial effects of the invention are as follows:The metallized polypropylene film of the present invention inhibits electromagnetic power source interference fixed capacity device Can bear overvoltage impact, have excellent flame retardant property, be widely used in the anti-interference occasions such as power supply cross-line road, suitable for It will not cause surge occasion during capacitor failure, if power supply cross-line connects, the pulse of more than 2.5KV, present invention system can be born Standby polypropylene film stretch resistance energy, heat-resisting ability are excellent, can reduce loss factor, have high proof voltage, excellent Singing characteristic improves more than 38% compared to the ordinary polypropylene film service life, and remarkable in economical benefits, the present invention can inhibit poly- Polypropylene film capacitor is under the conditions of high frequency or high impulse in use, can send out capacitor itself by the pulse current of capacitor Heat and the speed of Wen Sheng, so as to the significantly more efficient normal use for having ensured capacitor, capacitor performance of the invention is stable, storage Deposit that the time is long, and oxidation resistance is strong, high-frequency loss is small.
Description of the drawings
A kind of metallized polypropylene films of Fig. 1 inhibit electromagnetic power source interference fixed capacity device structure chart.
Including:Capacitance 1, resin 2, pin 3, shell 4.
Specific embodiment
A kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device, including capacitance 1, shell 4, pin 3, Resin 2, the capacitance 1 are arranged on inside shell 4, potting resin 2 between shell 4 and capacitance 1, and 1 both ends of capacitance are welded respectively A pin 3 is connected to, the pin 3 is all extended to outside shell 4;The capacitance makees medium using polypropylene screen, and uses vacuum The method of evaporation haves mercy on zinc, al deposition on film as electrode roll, and the resin is made by weight of following component: Epoxy resin 32, poly 1-butene resin 5, modified sericite in powder 1, starch 0.5.
Further, capacitor and pin weld gilding layer.
Further, the polypropylene screen is made by weight of following component:Acrylic resin 28, olive mountain flour 1, Rosin 3, cumyl peroxide 0.4, its preparation method are:By rosin mass concentration be 1.26% citric acid solution in 30min is impregnated at 48 DEG C, then, filtering, naturally dry, then mixed with acrylic resin, molten condition is heated to, is kept the temperature 12min, then olive mountain flour is added, after stirring 5min, cumyl peroxide is added, after stirring 35min, is squeezed out, obtained It is non-stretched, then that non-stretched progress is biaxial stretch-formed, obtain polypropylene screen.
Further, the pin is CP lines.
Further, the modified sericite in powder is made by weight of following component:Sericite in powder 135, sepiolite Powder 3, enuatrol 2, activated zinc oxide 2, neopelex 1, the preparation method of potassium peroxydisulfate 0.03 are:There to be sericite Powder and sepiolite powder add in the 3-5 times of methanol solution measured and impregnate 2h after mixing, then add activated zinc oxide, dodecyl Benzene sulfonic acid sodium salt and enuatrol, then 2-3h is ground in grinder, methanol is recycled, is heated to 140 DEG C, keeps the temperature 15min, it is then natural It is cooled to room temperature, grinds 40min, cross 800 mesh to get required modified sericite in powder.
Further, the preparation method of the resin is:By epoxy resin, poly 1-butene resin, modified sericite in powder, shallow lake Powder is uniformly admixed together by each parts by weight, and the mass concentration for then adding epoxy resin quality 10% at 62 DEG C again is 4.5% Hydrogen peroxide after stirring evenly, is heated to 78 DEG C, stirs 40min with 500r/min rotating speeds, is finally filtered, washs, dries, .
Further, the shell is made of PBT plastic, and anti-flammability grade is 94-V0.
After testing, horizontal percent thermal shrinkage during 20min is stood at 350 DEG C of the polypropylene film that prepared by the present invention< 0.125%, transverse tensile strength 224-233MPa, longitudinal tensile strength 187-195MPa, wetting tension 33-35mN/ m。
Metallized polypropylene film of the present invention inhibits electromagnetic power source interference fixed capacity device performance:
- 40 DEG C to+110 DEG C of operating temperature range
Rated voltage 275/310V
Maximum continuous DC voltage 630V
0.01 μ of μ F -10 F of capacitance swing
Insulation resistance >=15000M Ω.

Claims (5)

1. a kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device, which is characterized in that including capacitance, outside Shell, pin, resin, the capacitance are set inside the housing, and potting resin between shell and capacitance, the capacitance both ends are welded respectively A pin is connected to, the pin all extends to housing exterior;The capacitance makees medium using polypropylene screen, and with being evaporated in vacuo Method zinc, al deposition are had mercy on film as electrode roll, the resin is made by weight of following component:Epoxy Resin 32, poly 1-butene resin 5, modified sericite in powder 1, starch 0.5;The modified sericite in powder by weight by below into Divide and be made:Sericite in powder 135, sepiolite powder 3, enuatrol 2, activated zinc oxide 2, neopelex 1, potassium peroxydisulfate 0.03 preparation method is:To there are sericite in powder and sepiolite powder to add in the 3-5 times of methanol solution measured after mixing and impregnate 2h, Then activated zinc oxide, neopelex and enuatrol are added, then 2-3h is ground in grinder, methanol is recycled, adds Heat keeps the temperature 15min, then cooled to room temperature to 140 DEG C, grinds 40min, crosses 800 mesh to get required modified sericite Powder;The preparation method of the resin is:Epoxy resin, poly 1-butene resin, modified sericite in powder, starch is equal by each parts by weight Even admixed together, the mass concentration for then adding epoxy resin quality 10% at 62 DEG C again is 4.5% hydrogen peroxide, is stirred evenly Afterwards, 78 DEG C are heated to, 40min is stirred with 500r/min rotating speeds, is finally filtered, washs, dries, you can.
2. a kind of metallized polypropylene film according to claim 1 inhibits electromagnetic power source interference fixed capacity device, special Sign is, capacitor and pin weld gilding layer.
3. a kind of metallized polypropylene film according to claim 1 inhibits electromagnetic power source interference fixed capacity device, special Sign is that the polypropylene screen is made by weight of following component:Acrylic resin 28, olive mountain flour 1, rosin 3, peroxide Change diisopropylbenzene (DIPB) 0.4, its preparation method is:Rosin is impregnated in mass concentration is 1.26% citric acid solution at 48 DEG C 30min, then, filtering, naturally dry, then mixed with acrylic resin, molten condition is heated to, 12min is kept the temperature, then adds olive Olive mountain flour after stirring 5min, adds cumyl peroxide, after stirring 35min, is squeezed out, obtain non-stretched, then will Non-stretched progress is biaxial stretch-formed, obtains polypropylene screen.
4. a kind of metallized polypropylene film according to claim 1 inhibits electromagnetic power source interference fixed capacity device, special Sign is that the pin is CP lines.
5. a kind of metallized polypropylene film according to claim 1 inhibits electromagnetic power source interference fixed capacity device, special Sign is that the shell is made of PBT plastic, and anti-flammability grade is 94-V0.
CN201611008437.5A 2016-11-16 2016-11-16 A kind of metallized polypropylene film inhibits electromagnetic power source interference fixed capacity device Active CN106653361B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3608932A1 (en) * 2018-08-07 2020-02-12 TDK Electronics AG Housing for an electronic component with an inner receptacle and an outer casing

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109273264A (en) * 2018-08-21 2019-01-25 安徽飞达电气科技有限公司 A kind of high-voltage mutual inductor high voltage thin film capacitor

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201421778Y (en) * 2009-06-18 2010-03-10 扬州日精电子有限公司 Metallized film large-capacity capacitor

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201421778Y (en) * 2009-06-18 2010-03-10 扬州日精电子有限公司 Metallized film large-capacity capacitor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
环氧树脂分类,应用领域及市场前景;肖艳;《化学工业》;20140921;正文第19-24页 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3608932A1 (en) * 2018-08-07 2020-02-12 TDK Electronics AG Housing for an electronic component with an inner receptacle and an outer casing

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