CN1066465A - Domestic bleaching water - Google Patents
Domestic bleaching water Download PDFInfo
- Publication number
- CN1066465A CN1066465A CN 91102935 CN91102935A CN1066465A CN 1066465 A CN1066465 A CN 1066465A CN 91102935 CN91102935 CN 91102935 CN 91102935 A CN91102935 A CN 91102935A CN 1066465 A CN1066465 A CN 1066465A
- Authority
- CN
- China
- Prior art keywords
- water
- sodium
- javelle
- essence
- bleaching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000004061 bleaching Methods 0.000 title claims abstract description 20
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000004902 Softening Agent Substances 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical group [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 16
- 239000001488 sodium phosphate Substances 0.000 claims description 9
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 9
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims 1
- 235000011008 sodium phosphates Nutrition 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 9
- 239000000796 flavoring agent Substances 0.000 abstract description 4
- 235000019634 flavors Nutrition 0.000 abstract description 4
- 230000001954 sterilising effect Effects 0.000 abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 241000322338 Loeseliastrum Species 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- 239000005708 Sodium hypochlorite Substances 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 241001460678 Napo <wasp> Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- VDQQXEISLMTGAB-UHFFFAOYSA-N chloramine T Chemical compound [Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 VDQQXEISLMTGAB-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- -1 peroxide trisodium phosphate Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 238000009898 sodium hypochlorite bleaching Methods 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 235000015193 tomato juice Nutrition 0.000 description 1
- 229960001479 tosylchloramide sodium Drugs 0.000 description 1
- 239000010924 used plastic bottle Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Coloring (AREA)
Abstract
The invention provides a kind of domestic bleaching water that is used to make fabric bleaching, be characterized in that in hypochlorous sodium be in the aqueous solution of main component, the essence that adds a spot of water-softening agent, stablizer and an amount of adjusting Javelle water smell constitutes.This product is made simple, and cost is low, and existing bleaching action has bactericidal potency again to fabric, and to baby diaper, old man's underpants, bed clothes go the flavor sterilization extremely effective, and it also is good merchantable brand that flavor is removed in the sterilization of toilet water drain.
Description
The present invention relates to a kind of SYNTHETIC OPTICAL WHITNER, particularly a kind of domestic bleaching water that is used for fabric bleaching.
Use various SYNTHETIC OPTICAL WHITNER in the printing and dyeing industry at present, they are chlorinated lime, sodium hypochlorite solution, high test bleaching powder, chloramine-T, clorox, Textone, hydrogen peroxide, sodium peroxide, Sodium peroxoborate etc.Its document has: " reagent handbook " (second edition) that Shanghai science tech publishing house publishes, " Chemicals handbook " (daily-use chemical industry) that Chemical Industry Press publishes, " chemistry (chemical industry medicine) voluminous dictionary " (the Duan Mugan chief editor) that Taiwan company limited of humane press publishes.These SYNTHETIC OPTICAL WHITNER all are in being applicable to that printing and dyeing industry is produced, and the working conditions harshness is not suitable for the family expenses bleaching of fabric.The SYNTHETIC OPTICAL WHITNER of Japanese Patent J58007498 is to adopt 60-40%(weight) the peroxide trisodium phosphate make paste with 40-60% hypochloric acid water solution (25%) stirring, get white powdery chlorinated lime through dry air, but production unit and technology are complicated, the product cost height.
Purpose of the present invention is exactly in order to overcome the problem that above-mentioned SYNTHETIC OPTICAL WHITNER exists, to provide a kind of production unit and technology simple, and low cost product is applicable to the Javelle water of family expenses.
The present invention's " domestic bleaching water " adopts following scheme implementation, and it is that hypochlorous sodium is the aqueous solution of main component, and add a spot of water-softening agent and make the stable stablizer of Javelle water on a small quantity, and the essence of an amount of adjusting Javelle water smell and constituting.
The main body of Javelle water of the present invention is a clorox, and following reaction is arranged after it is water-soluble:
Hypochlorous acid decomposes again:
The oxidation capacity of newborn oxygen is very strong, destroys pigment group and bleaches, but also destroy fiber, and the main bleaching action of clorox is that hypochlorous acid is to pigment addition that key rises, therefore sodium hypochlorite bleaching is effective, and very little to fiber loss, its chemical reaction is:
For satisfying various water quality, the requirement of prolonged preservation is in the aqueous solution of main component in hypochlorous sodium (NaClO), in addition the stablizer and the essence of less water tenderizer, Javelle water.General trisodium phosphate (the Na that adopts
4P
2O
710H
2O), Sodium hexametaphosphate 99 (NaPO
4)
xAnd tertiary sodium phosphate (Na
3PO
4) be the water softening agent.
(the weight meter) composed as follows of domestic bleaching water of the present invention:
Clorox: 60%-83%, three kinds of water-softening agents: trisodium phosphate, Sodium hexametaphosphate 99, tertiary sodium phosphate respectively are 0.05%-1%, and Javelle water stablizer sodium hydroxide is 0.5%-2%, essence 0.01%-0.02%, its surplus is a water.
Concrete method for making is with water-softening agent, and stablizer and essence add respectively by formula rate in the aqueous solution of the clorox that has prepared, stirs, and fully dissolving is Javelle water, can put into dark-coloured vial or Plastic Bottle packing and preserve.
The present invention's " domestic bleaching water " has good bleaching action to fabric, general commercially available white dyes there is no bleaching action and just sends out blue streak and give bright-coloured sensation, at present at the commercially available chlorinated lime in chemical industry shop, produce precipitation of calcium carbonate during bleaching, the variable xanthochromia of fabric is hard, and the clorox generation is sodium hydroxide, solubleness is big, soluble in water with the yellow soda ash of carbon dioxide generating, in solution, can produce shock absorption, so the reduction of the pH value of solution is less, this product can be used plastic bottle, existing bleaching action has bactericidal potency again to fabric, therefore except that general washing keep fabric white clean bright-coloured, to baby diaper, old man's underpants, bed clothes go the flavor sterilization extremely effective, and to the toilet, it also is good merchantable brand that flavor is removed in the sterilization of sewer line.Domestic bleaching water of the present invention has production unit and preparation technology simple, operation easily, advantage such as product cost is low.
Embodiment one
Javelle water weight is formed proportioning: clorox 65%, and trisodium phosphate 0.9%, hexa metaphosphoric acid 0.5%, tertiary sodium phosphate 0.1%, sodium hydroxide 1.8%, soap sandal essence 0.01%, its surplus 31.69% is a water.
At first by required proportioning preparation aqueous sodium hypochlorite solution, and then respectively trisodium phosphate, Sodium hexametaphosphate 99, tertiary sodium phosphate, sodium hydroxide, the essence of required ratio is added in the aqueous sodium hypochlorite solution that has prepared, stirring fully, dissolving is Javelle water.This Javelle water for preparing after being diluted to 2% concentration, being used for washing and being polluted bleaching washing on the calico by soy sauce, blood, tomato juice, prepared Chinese ink etc., and wash temperature is 25-30 ℃, and 2.5 hours hold-times, it is fine that stain is eliminated effect.
As this Javelle water is diluted at 1/100 o'clock, the calico detergent bleach is had the effect that obviously bleaches, and the experiment of above-mentioned two kinds of situations is to the equal not damaged of fabric fibre.
Embodiment two
Javelle water weight is formed proportioning: clorox 80%, and trisodium phosphate 0.1%, Sodium hexametaphosphate 99 0.9%, tertiary sodium phosphate 0.6%, sodium hydroxide 0.8%, soap sandal essence 0.02%, its surplus 17.58% is a water.
Compound method is with embodiment one.Javelle water is eliminated effect and identical with embodiment 1 to the calico washing effect to stain.
Embodiment three
Javelle water weight is formed proportioning: clorox 70%, and trisodium phosphate 0.1%, hexa metaphosphoric acid 0.1%, tertiary sodium phosphate 0.8%, sodium hydroxide 0.5%, soap sandal essence 0.01%, its surplus 28.49% is a water.
Compound method such as embodiment one.Javelle water is eliminated effect and identical with embodiment 1 to calico detergent bleach effect to stain.
Claims (3)
1, a kind of domestic bleaching water is characterized in that it is that hypochlorous sodium is the aqueous solution of main component, adds a spot of water-softening agent and makes the stable stablizer of Javelle water on a small quantity and the essence of an amount of adjusting Javelle water smell and constituting.
2, Javelle water according to claim 1 is characterized in that said water-softening agent is trisodium phosphate, Sodium hexametaphosphate 99, tertiary sodium phosphate, and the stablizer of Javelle water is a sodium hydroxide, and essence is soap sandal essence.
3, domestic bleaching water according to claim 2, the weight composition proportioning that it is characterized in that it is clorox 60%-83%, three kinds of water-softening agent trisodium phosphates, Sodium hexametaphosphate 99, tertiary sodium phosphates respectively are 0.05%-1%, Javelle water stablizer sodium hydroxide is 0.5%-2%, soap sandal essence is 0.01%-0.02%, and its surplus is a water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91102935 CN1066465A (en) | 1991-05-08 | 1991-05-08 | Domestic bleaching water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91102935 CN1066465A (en) | 1991-05-08 | 1991-05-08 | Domestic bleaching water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1066465A true CN1066465A (en) | 1992-11-25 |
Family
ID=4905814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91102935 Pending CN1066465A (en) | 1991-05-08 | 1991-05-08 | Domestic bleaching water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1066465A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050630C (en) * | 1996-05-03 | 2000-03-22 | 王国范 | Combined liquid detergent |
| CN1062009C (en) * | 1996-10-21 | 2001-02-14 | 谢体生 | Disinfactant for anti-rust |
| CN104499266A (en) * | 2014-12-15 | 2015-04-08 | 民勤县家兴节能服务有限公司 | Pretreatment method of waste cotton clothes |
| CN104805677A (en) * | 2015-05-12 | 2015-07-29 | 湖州吉昌丝绸有限公司 | Novel fabric bleaching agent composition |
| CN107484771A (en) * | 2017-09-30 | 2017-12-19 | 蚌埠科卫消毒药剂有限公司 | A kind of 84 thimerosals and preparation method thereof |
| CN107593763A (en) * | 2017-10-13 | 2018-01-19 | 吉林省富生医疗器械有限公司 | A kind of thimerosal of haemodialysis control unit and preparation method thereof |
| CN113103391A (en) * | 2021-04-28 | 2021-07-13 | 圣象（江苏）木业研究有限公司 | Wood decolorant and using method thereof |
| CN115926903A (en) * | 2022-12-28 | 2023-04-07 | 中山市明新环保科技有限公司 | Stable plastic yellow removing agent and preparation method thereof |
-
1991
- 1991-05-08 CN CN 91102935 patent/CN1066465A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1050630C (en) * | 1996-05-03 | 2000-03-22 | 王国范 | Combined liquid detergent |
| CN1062009C (en) * | 1996-10-21 | 2001-02-14 | 谢体生 | Disinfactant for anti-rust |
| CN104499266A (en) * | 2014-12-15 | 2015-04-08 | 民勤县家兴节能服务有限公司 | Pretreatment method of waste cotton clothes |
| CN104805677A (en) * | 2015-05-12 | 2015-07-29 | 湖州吉昌丝绸有限公司 | Novel fabric bleaching agent composition |
| CN107484771A (en) * | 2017-09-30 | 2017-12-19 | 蚌埠科卫消毒药剂有限公司 | A kind of 84 thimerosals and preparation method thereof |
| CN107593763A (en) * | 2017-10-13 | 2018-01-19 | 吉林省富生医疗器械有限公司 | A kind of thimerosal of haemodialysis control unit and preparation method thereof |
| CN113103391A (en) * | 2021-04-28 | 2021-07-13 | 圣象（江苏）木业研究有限公司 | Wood decolorant and using method thereof |
| CN115926903A (en) * | 2022-12-28 | 2023-04-07 | 中山市明新环保科技有限公司 | Stable plastic yellow removing agent and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |