CN104805677A - Novel fabric bleaching agent composition - Google Patents
Novel fabric bleaching agent composition Download PDFInfo
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- CN104805677A CN104805677A CN201510240741.1A CN201510240741A CN104805677A CN 104805677 A CN104805677 A CN 104805677A CN 201510240741 A CN201510240741 A CN 201510240741A CN 104805677 A CN104805677 A CN 104805677A
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- ethylene diamine
- tetraacetyl ethylene
- novel fabric
- hydrogen peroxide
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Abstract
The invention discloses a novel fabric bleaching agent composition. The novel fabric bleaching agent composition is prepared by the following components in parts by weight: 10 to 20 parts of polyvinyl alcohol, 10 to 20 parts of fatty alcohol sulfate, 3 to 5 parts of sodium hypochlorite, 2 to 4 parts of trisodium phosphate, 8 to 10 parts of mirabilite, and 0.2 to 0.6 part of tetraacetyl ethylene diamine; 4 to 8 parts of sodium hydroxide; 20 to 40 parts of hydrogen peroxide, 2 to 4 parts of anhydrous sodium metasilicate, 4 to 9 parts of tetraacetyl ethylene diamine, 1 to 3 parts of manganese sulfate, and 10 to 20 parts of water. The novel fabric bleaching agent composition has the advantages that the bleaching capability of a product is high, and the damage to fibers is avoided; the storage stability is high, and the acid-resistant and alkaline-resistant properties are realized; the preparation technology is simple, the obtaining of raw materials is easy, and the cost is low.
Description
Technical field
The present invention relates to a kind of fabric finishing agent, especially a kind of novel fabric bleach compositions.
Technical background
At present from the grand strategy of China's economic development, low-carbon economy as the important way of Transformation of Economic Growth just through whole textile industry, it is based on the theory of low consumption, low stain and low emission, is core with the innovation of economize energy technology and emissions reduction technology.The gas discharging of textiles in dyeing and finishing process, water resources consumption, energy resource consumption etc. are industry finally affects Comprehensive Assessment most fundamental basis on Product environment.There are some pressures or the regulation of voluntary or market to limit at present in the world, such as, required the information such as product identification carbon footprint.Therefore, one of the basic principle for whole dyeing and finishing industry sustainable development is exactly " decrement rule ", requires exactly to obtain maximum product function with minimum resource consumption.And for current dyeing & printing enterprise, the direct benefit of carrying out low-carbon dyeing and finishing is not only the environmental value that improve product, and reduce energy consumption, material consumption and discharge, namely namely reduce production cost.
The bleaching pre-treatment of usual cotton fiber adopts hydrogen peroxide bleaching method, and it has, and bleaching effect is better, retention of whiteness good, pollute less, the not advantage such as etching apparatus.The Basic Mechanism of hydrogen peroxide bleaching is: H
2o
2can generate the active ingredient HOO-of bleaching after decomposition, decomposition formula is: H
2o
2→ HOO-+H+.According to chemical reaction equilibrium principle, in bleaching working solution, add a certain amount of caustic soda, in energy and H+, promote the generation of HOO-.Meanwhile, usually need to add hydrogen peroxide stabilizer to control the hydrogen peroxide caused due to heavy metal ion catalytic action in traditional hydrogen peroxide method for bleaching to be ineffectually decomposed.So-called cold bleaching pre-treatment refers to and adopt special oxygen bleaching activator in the pre-treating method of routine, improve effective resolution ratio of hydrogen peroxide, thus improve the utilization rate of hydrogen peroxide, and make bleaching temperature be reduced to about 70 DEG C, while not affecting fabric whiteness, the problems such as the damage of reduction fabric fibre and weightlessness.Therefore how overcoming the deficiencies in the prior art is problems that current technical field of textile auxiliary agent needs solution badly.
Summary of the invention
To achieve these goals, the invention provides a kind of novel fabric bleach compositions.
The object of the invention is to be achieved through the following technical solutions:
A kind of novel fabric bleach compositions, it is made up of the component mix and blend of following parts by weight: polyvinyl alcohol 10-20 part, fatty alcohol sulfate 10-20 part, clorox 3-5 part, tertiary sodium phosphate 2-4 part, saltcake 8-10 part, tetraacetyl ethylene diamine 0.2-0.6 part; NaOH 4-8 part; Hydrogen peroxide 20-40 part, anhydrous sodium metasilicate 2-4 part, tetraacetyl ethylene diamine 4-9 part, manganese sulfate 1-3 part, water 10-20 part.
One of preferred version: it is obtained by the component of following parts by weight: polyvinyl alcohol 10 parts, fatty alcohol sulfate 10 parts, clorox 3 parts, tertiary sodium phosphate 2 parts, 8 parts, saltcake, tetraacetyl ethylene diamine 0.2 part; 4 parts, NaOH; 20 parts, hydrogen peroxide, anhydrous sodium metasilicate 2 parts, tetraacetyl ethylene diamine 4 parts, manganese sulfate 1 part, 10 parts, water.
Preferred version two: it is obtained by the component of following parts by weight: polyvinyl alcohol 20 parts, fatty alcohol sulfate 20 parts, clorox 5 parts, tertiary sodium phosphate 4 parts, 10 parts, saltcake, tetraacetyl ethylene diamine 0.6 part; 8 parts, NaOH; 40 parts, hydrogen peroxide, anhydrous sodium metasilicate 4 parts, tetraacetyl ethylene diamine 9 parts, manganese sulfate 3 parts, 20 parts, water.
Preferred version three: it is obtained by the component of following parts by weight: polyvinyl alcohol 12 parts, fatty alcohol sulfate 12 parts, clorox 4 parts, tertiary sodium phosphate 3 parts, 9 parts, saltcake, tetraacetyl ethylene diamine 0.3 part; 5 parts, NaOH; 25 parts, hydrogen peroxide, anhydrous sodium metasilicate 3 parts, tetraacetyl ethylene diamine 5 parts, manganese sulfate 2 parts, 12 parts, water.
Preferred version four: it is obtained by the component of following parts by weight: polyvinyl alcohol 18 parts, fatty alcohol sulfate 18 parts, clorox 4 parts, tertiary sodium phosphate 3 parts, 9 parts, saltcake, tetraacetyl ethylene diamine 0.5 part; 7 parts, NaOH; 30 parts, hydrogen peroxide, anhydrous sodium metasilicate 3 parts, tetraacetyl ethylene diamine 7 parts, manganese sulfate 2 parts, 18 parts, water.
Its preparation method is: by weight ratio, each component is mixed, after stirring finished product.
The present invention has following beneficial effect:
Product bleaching power prepared by the present invention is strong, does not damage fiber; Storage stability is strong, acid and alkali resistance etc.; Preparation technology is simple, and raw material is easy to get, with low cost.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Embodiment 1
A kind of novel fabric bleach compositions, it is made up of the component mix and blend of following parts by weight: polyvinyl alcohol 10 parts, fatty alcohol sulfate 10 parts, clorox 3 parts, tertiary sodium phosphate 2 parts, 8 parts, saltcake, tetraacetyl ethylene diamine 0.2 part; 4 parts, NaOH; 20 parts, hydrogen peroxide, anhydrous sodium metasilicate 2 parts, tetraacetyl ethylene diamine 4 parts, manganese sulfate 1 part, 10 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Embodiment 2
A kind of novel fabric bleach compositions, it is made up of the component mix and blend of following parts by weight: polyvinyl alcohol 20 parts, fatty alcohol sulfate 20 parts, clorox 5 parts, tertiary sodium phosphate 4 parts, 10 parts, saltcake, tetraacetyl ethylene diamine 0.6 part; 8 parts, NaOH; 40 parts, hydrogen peroxide, anhydrous sodium metasilicate 4 parts, tetraacetyl ethylene diamine 9 parts, manganese sulfate 3 parts, 20 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Embodiment 3
A kind of novel fabric bleach compositions, it is made up of the component mix and blend of following parts by weight: polyvinyl alcohol 12 parts, fatty alcohol sulfate 12 parts, clorox 4 parts, tertiary sodium phosphate 3 parts, 9 parts, saltcake, tetraacetyl ethylene diamine 0.3 part; 5 parts, NaOH; 25 parts, hydrogen peroxide, anhydrous sodium metasilicate 3 parts, tetraacetyl ethylene diamine 5 parts, manganese sulfate 2 parts, 12 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Embodiment 4
A kind of novel fabric bleach compositions, it is made up of the component mix and blend of following parts by weight: polyvinyl alcohol 18 parts, fatty alcohol sulfate 18 parts, clorox 4 parts, tertiary sodium phosphate 3 parts, 9 parts, saltcake, tetraacetyl ethylene diamine 0.5 part; 7 parts, NaOH; 30 parts, hydrogen peroxide, anhydrous sodium metasilicate 3 parts, tetraacetyl ethylene diamine 7 parts, manganese sulfate 2 parts, 18 parts, water.
Preparation method is: by weight ratio, each component is mixed, after stirring finished product.
Claims (5)
1. a novel fabric bleach compositions, is characterized in that it is obtained by the component of following parts by weight: polyvinyl alcohol 10-20 part, fatty alcohol sulfate 10-20 part, clorox 3-5 part, tertiary sodium phosphate 2-4 part, saltcake 8-10 part, tetraacetyl ethylene diamine 0.2-0.6 part; NaOH 4-8 part; Hydrogen peroxide 20-40 part, anhydrous sodium metasilicate 2-4 part, tetraacetyl ethylene diamine 4-9 part, manganese sulfate 1-3 part, water 10-20 part.
2. a kind of novel fabric bleach compositions according to claim 1, is characterized in that it is obtained by the component of following parts by weight: polyvinyl alcohol 10 parts, fatty alcohol sulfate 10 parts, clorox 3 parts, tertiary sodium phosphate 2 parts, 8 parts, saltcake, tetraacetyl ethylene diamine 0.2 part; 4 parts, NaOH; 20 parts, hydrogen peroxide, anhydrous sodium metasilicate 2 parts, tetraacetyl ethylene diamine 4 parts, manganese sulfate 1 part, 10 parts, water.
3. a kind of novel fabric bleach compositions according to claim 1, is characterized in that it is obtained by the component of following parts by weight: polyvinyl alcohol 20 parts, fatty alcohol sulfate 20 parts, clorox 5 parts, tertiary sodium phosphate 4 parts, 10 parts, saltcake, tetraacetyl ethylene diamine 0.6 part; 8 parts, NaOH; 40 parts, hydrogen peroxide, anhydrous sodium metasilicate 4 parts, tetraacetyl ethylene diamine 9 parts, manganese sulfate 3 parts, 20 parts, water.
4. a kind of novel fabric bleach compositions according to claim 1, is characterized in that it is obtained by the component of following parts by weight: polyvinyl alcohol 12 parts, fatty alcohol sulfate 12 parts, clorox 4 parts, tertiary sodium phosphate 3 parts, 9 parts, saltcake, tetraacetyl ethylene diamine 0.3 part; 5 parts, NaOH; 25 parts, hydrogen peroxide, anhydrous sodium metasilicate 3 parts, tetraacetyl ethylene diamine 5 parts, manganese sulfate 2 parts, 12 parts, water.
5. a kind of novel fabric bleach compositions according to claim 1, is characterized in that it is obtained by the component of following parts by weight: polyvinyl alcohol 18 parts, fatty alcohol sulfate 18 parts, clorox 4 parts, tertiary sodium phosphate 3 parts, 9 parts, saltcake, tetraacetyl ethylene diamine 0.5 part; 7 parts, NaOH; 30 parts, hydrogen peroxide, anhydrous sodium metasilicate 3 parts, tetraacetyl ethylene diamine 7 parts, manganese sulfate 2 parts, 18 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510240741.1A CN104805677A (en) | 2015-05-12 | 2015-05-12 | Novel fabric bleaching agent composition |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510240741.1A CN104805677A (en) | 2015-05-12 | 2015-05-12 | Novel fabric bleaching agent composition |
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| CN104805677A true CN104805677A (en) | 2015-07-29 |
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| CN201510240741.1A Pending CN104805677A (en) | 2015-05-12 | 2015-05-12 | Novel fabric bleaching agent composition |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105970385A (en) * | 2016-06-30 | 2016-09-28 | 江苏华信亚麻纺织有限公司 | Copper-ammonia fiber and linen blended wet-spinning process method |
| CN107299521A (en) * | 2016-04-08 | 2017-10-27 | 中国石化仪征化纤有限责任公司 | For polyamidoester fibre and its bleaching agent and its normal temperature method for bleaching of fabric |
| CN107484771A (en) * | 2017-09-30 | 2017-12-19 | 蚌埠科卫消毒药剂有限公司 | A kind of 84 thimerosals and preparation method thereof |
| CN107815848A (en) * | 2017-12-12 | 2018-03-20 | 佛山早稻田环保节能科技有限公司 | A kind of fabric bleaching agent |
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|---|---|---|---|---|
| CN1047099A (en) * | 1989-05-11 | 1990-11-21 | 王铎 | High efficient liquid bleacher |
| CN1066465A (en) * | 1991-05-08 | 1992-11-25 | 中国科学院生物物理研究所 | Domestic bleaching water |
| JP2007308596A (en) * | 2006-05-18 | 2007-11-29 | Kao Corp | Liquid bleaching agent composition and method for producing the same |
| CN102978896A (en) * | 2012-11-21 | 2013-03-20 | 吴江市得可利纺织品有限公司 | Fabric bleaching agent |
| CN103243537A (en) * | 2013-05-21 | 2013-08-14 | 海安县联发张氏色织有限公司 | Fabric bleaching agent |
| CN103541211A (en) * | 2013-10-28 | 2014-01-29 | 湖州金塔地纺织厂 | Fabric bleaching agent |
| CN103628300A (en) * | 2013-12-18 | 2014-03-12 | 江苏鹏飞海太机械有限公司 | Fabric bleaching agent |
| CN103696227A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Bleaching agent for fabric and preparation method thereof |
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2015
- 2015-05-12 CN CN201510240741.1A patent/CN104805677A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1047099A (en) * | 1989-05-11 | 1990-11-21 | 王铎 | High efficient liquid bleacher |
| CN1066465A (en) * | 1991-05-08 | 1992-11-25 | 中国科学院生物物理研究所 | Domestic bleaching water |
| JP2007308596A (en) * | 2006-05-18 | 2007-11-29 | Kao Corp | Liquid bleaching agent composition and method for producing the same |
| CN102978896A (en) * | 2012-11-21 | 2013-03-20 | 吴江市得可利纺织品有限公司 | Fabric bleaching agent |
| CN103243537A (en) * | 2013-05-21 | 2013-08-14 | 海安县联发张氏色织有限公司 | Fabric bleaching agent |
| CN103541211A (en) * | 2013-10-28 | 2014-01-29 | 湖州金塔地纺织厂 | Fabric bleaching agent |
| CN103696227A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Bleaching agent for fabric and preparation method thereof |
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|---|
| 徐以俊等: "《石油化工关联行业概览-精细化学品（一）》", 30 June 1992 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107299521A (en) * | 2016-04-08 | 2017-10-27 | 中国石化仪征化纤有限责任公司 | For polyamidoester fibre and its bleaching agent and its normal temperature method for bleaching of fabric |
| CN105970385A (en) * | 2016-06-30 | 2016-09-28 | 江苏华信亚麻纺织有限公司 | Copper-ammonia fiber and linen blended wet-spinning process method |
| CN107484771A (en) * | 2017-09-30 | 2017-12-19 | 蚌埠科卫消毒药剂有限公司 | A kind of 84 thimerosals and preparation method thereof |
| CN107815848A (en) * | 2017-12-12 | 2018-03-20 | 佛山早稻田环保节能科技有限公司 | A kind of fabric bleaching agent |
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Application publication date: 20150729 |