CN106641099A - Durable driving belt - Google Patents

Durable driving belt Download PDF

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Publication number
CN106641099A
CN106641099A CN201610920962.8A CN201610920962A CN106641099A CN 106641099 A CN106641099 A CN 106641099A CN 201610920962 A CN201610920962 A CN 201610920962A CN 106641099 A CN106641099 A CN 106641099A
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CN
China
Prior art keywords
parts
rubber layer
layer
bonding
rubber
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Granted
Application number
CN201610920962.8A
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Chinese (zh)
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CN106641099B (en
Inventor
刘钰馨
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Rizhao Xinrui Investment Promotion Development Co ltd
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Guangxi Teachers College
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G1/00Driving-belts
    • F16G1/28Driving-belts with a contact surface of special shape, e.g. toothed
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04Homopolymers or copolymers of ethene
    • C09J123/08Copolymers of ethene
    • C09J123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G1/00Driving-belts
    • F16G1/06Driving-belts made of rubber
    • F16G1/08Driving-belts made of rubber with reinforcement bonded by the rubber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16GBELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
    • F16G1/00Driving-belts
    • F16G1/21Driving-belts built-up from superimposed layers, e.g. zig-zag folded
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a durable driving belt comprising a compressing rubber layer, a bonding rubber layer and a strengthening layer. The compressing rubber layer is connected with a power transmission assembly in a pressing mode, the bonding rubber layer bonds with the compressing rubber layer, and the strengthening layer is arranged between the compressing rubber layer and the bonding rubber layer, wherein the strengthening layer comprises composite fiber webs, first bonding rods, second bonding rods and strengthening cotton. The composite fiber webs are obtained by multiple fiber spinning solutions through the electrospinning technique. The first bonding rods and the second bonding rods are all obtained by smearing bonder on the outer portion of a plastic pipe. The driving belt has higher mechanical strength, flexibility is good, the abrasion resistance and heat resistance properties are excellent, the service life of the driving belt is greatly prolonged, and driving efficiency of the driving belt can be greatly improved.

Description

Durable transmission belt
Technical field
The present invention relates to mechanical driving device.It is more particularly related to a kind of durable transmission belt.
Background technology
Transmission belt is the core coupling component of electromechanical equipment power transmission, mainly by being set in power source on drive Power conduct to plant equipment.The species of transmission belt is extremely various and purposes is extremely wide, from greatly to the huge of several megawatts Type motor, the little micromachine to less than kilowatt, or even including including the precision optical machineries such as household electrical appliances, computer, robot all Too busy to get away transmission belt.
Transmission belt inevitably produces distortion, mechanical action of pullling and rub etc. in transmission process, in turn results in Transmission belt easily weares and teares, and in order to improve the intensity of transmission belt, extends transmission belt service life, and needs prepare transmission belt from improvement Wear-resisting, the durable and heat resistance of raw material is started with.The existing natural rubber of the raw material of transmission belt develops into synthetic rubber, existing Make transmission belt synthetic rubber is wear-resisting, heat-resisting, loss of properties on aging, mechanical strength is not high enough, the synthesis that some research and development are obtained Rubber reduces elastomeric flexible shape for its mechanical strength of raising simply so that the transmission belt that compression is obtained was once Easily peeling off phenomenon between spring layer;The seal face air permeability of another aspect transmission belt is poor so that transmission belt and drive Between the rub heat of generation be difficult to shed, accelerate the abrasion of transmission belt, and potential safety hazard is brought to electromechanical equipment.
Therefore, it is necessary to a kind of wear-resisting, heat-resisting and ageing-resistant performance of enhancing transmission belt is provided, while having good heat radiating The durable transmission belt of effect.
The content of the invention
It is an object of the invention to solve at least the above, and provide the advantage that at least will be described later.
It is a still further object of the present invention to provide a kind of durable transmission belt, it is by compression rubber layer and sticking rubber layer Between enhancement layer is set, to improve the mechanical strength of transmission belt, compared with existing reinforced-core, the present invention provide enhancement layer It is flexible also with good with compression rubber layer and sticking rubber layer adhesiving effect on the premise of the mechanical strength of enhancement layer is ensured Property good advantage so that transmission belt has more excellent physical and chemical performance.
In order to realize these purposes of the invention and further advantage, there is provided a kind of durable transmission belt, it include with The sticking rubber layer of the compression rubber layer of power transmission component crimping and the bonding of the compression rubber layer and it is arranged on described Enhancement layer between compression rubber layer and the sticking rubber layer, wherein,
The enhancement layer includes the composite fiber web being laid between the compression rubber layer and the sticking rubber layer, sets Put the multiple first bonding rods that can extend into inside the compression rubber layer on the first surface of the composite fiber web, set Put on the second surface of the composite fiber web can extend into inside the sticking rubber layer it is multiple second bonding rods with And the reinforcement cotton being filled in inside the composite fiber web grid, the reinforcement cotton is glass fibre cotton;
The preparation method of composite fibre is in the composite fiber web:Count by weight, take 10~18 parts of carbon fiber Spinning solution, 6~12 parts of sodium alginate fiber spinning solution, 20~30 parts of aramid fiber spinning solution and 0.1~0.3 part of dispersion Agent, after being sufficiently mixed uniformly 40 DEG C are heated to, and the particle diameter for being added thereto to 0.04~0.07 part is that the nanometer of 40~60nm is electric Stone and 0.01~0.05 part of rare earth metal yttrium, stir, and filter, deaeration, are then 45 by spinneret injection to temperature DEG C, in the calcium chloride solution that mass fraction is 5%, then through washing, drawing-off, obtain the composite fibre;
Arbitrary first bonding rod is one layer of the outer surface coating of the plastic tube in hollow a diameter of 0.5~0.8cm Thickness is that first binding agent of 0.2~0.5mm is obtained;First binding agent includes the raw material of following weight portion:240~250 Part polyvinyl acetate, 10~13 parts of diethylene glycol dibenzoate, 4~8 parts of polyacrylate, 11~17 parts poly- right Polyethylene terephthalate, 8~14 parts of dioctyl phthalate, 3~8 parts of polyacrylamide, 5~9 parts of cornstarch, 2~5 parts of palygorskite powder, 3~7 parts of sodium hydrogensulfite, 5~10 parts of kaolin, 6~12 parts of APES AEO with 7~13 parts;
Arbitrary second bonding rod is the outer surface coating one in the plastic tube in hollow a diameter of 0.5~0.8cm Thickness degree is that second binding agent of 0.2~0.5mm is obtained;Second binding agent includes the raw material of following weight portion:240~ 250 parts of vinylacetate, 9~12 parts of diethylene glycol dibenzoate, 10~13 parts of toluene di-isocyanate(TDI), 8~15 parts Allyl methacrylate, 8~14 parts of dibutyl phthalate, 3~8 parts of Pioloform, polyvinyl acetal, 2~6 parts of N- NMA, 10~15 parts of Methyol resorcinols, 1~3 part of precipitated calcium carbonate, 2~4 parts of bentonite, 0.5~ 1.2 parts of carbon black, 5~11 parts of nekal and 4~9 parts of Brij 35 sodium sulphate.
Preferably, described durable transmission belt, on the surface that the compression rubber layer is crimped with power transmission component The a plurality of sawtooth projection extended along its width is provided with, the section of arbitrary sawtooth projection is trapezoidal, the sawtooth projection Middle part be provided with T-shaped groove, the wear-resistant block of T-shaped is arranged with the T-shaped groove, two are offered on the sawtooth projection with institute The symmetrical v-depression group centered on T-shaped groove is stated, the groove group includes at least two continuous v-depressions;
The outer surface of the sawtooth projection and the wear-resistant block is coated with one layer of antistatic coating.
Preferably, described durable transmission belt, the raw material of the compression rubber layer are rubber composition, the rubber The preparation method of composition is comprised the following steps:
1) count by weight, take 80~90 parts ACM, 20~28 parts of butadiene rubber, 30~45 parts Chlorinated polyethylene rubber, 4~11 parts of SBS and 18~27 parts of silicon rubber input In banbury, be heated to 100~110 DEG C, add 1~3 part high-dispersion white carbon black, 4~9 parts of CNT, 5~11 parts Nano-cellulose whisker, 6~13 parts of microwax, 3~8 parts of Graphene and 1~3 part of nano-diamond powder, are kneaded 10~20min, obtains modified rubber composition;
2) by 5~10 parts of epoxy resin, 4~8 parts of phenolic resin, 2~6 parts of polyamide and 3~7 parts of wood The uniform hybrid resin of quality mixed with resin, under the stirring that rotating speed is 70~80rpm, sequentially adds in the hybrid resin 0.2~0.4 part of high-dispersion white carbon black, 0.5~0.9 part of CNT, 0.4~0.8 part of nano-cellulose whisker, 1~4 Part microwax, 0.3~0.9 part of Graphene, 0.2~0.6 part of nano-diamond powder and 1~4 part tourmaline crystalline substance ore deposit it is micro- Powder, is heated to 60~70 DEG C and continues to stir 30~40min, obtains modified resin compound;
3) the modified resin compound is divided into two equal portions, the modified rubber composition is placed in into banbury In be heated to 110~120 DEG C, described modified resin compound, 9~15 parts of the polyethers of the first equal portions are added thereto to successively Polyalcohol, 5~9 parts of stearic acid, 4~8 parts of nano zine oxide, 7~14 parts of isopropyl benzene hydroperoxide, 3~7 parts of poly- second Glycol double maleic amide, 0.2~0.5 part of accelerator, 0.4~0.9 part of antiaging agent and 0.2~0.6 part of softening agents, mix 10~20min of refining;
4) 140~160 DEG C are continuously heating to, add in banbury the second equal portions described modified resin compound, 0.4~0.7 part of Cosan, 0.2~0.5 part of plasticizer and 0.2~0.5 part of accelerator, knead 10~20min, obtain final product The rubber composition.
Preferably, described durable transmission belt, the sticking rubber layer is 8 by weight ratio:1:0.4:0.5 rubber Glue composition, silica, nylon staple peacekeeping glass are mixed to prepare.
Preferably, described durable transmission belt, it is 3 that the accelerator is weight ratio:1.2:1.5:2:1.8:The two of 0.8 Sulfuration tetrabenzyl autumn orchid loam, 2,2- dithio-bis-benzothiazoles, potassium stearate, 2- benzothiazolyl mercaptans, N- cyclohexyl -2- benzene And thiazolesulfenamide and cadmium diethyl dithiocarbamate are mixed to prepare.
Preferably, described durable transmission belt, the antiaging agent is 1 by weight ratio:1.5 N- isopropyl-N '-benzene Base p-phenylenediamine and 2,2,4- trimethyl -1,2- dihyaroquinoline condensates are mixed to prepare.
Preferably, described durable transmission belt, the plasticizer is di-n-octyl sebacate.
Preferably, described durable transmission belt, the softening agent is 1 by weight ratio:2:1.8:2.4:2.8:3 stone Wax, castor oil, rapeseed oil, coconut oil, haze tallow and pine tar are mixed to prepare.
The present invention at least includes following beneficial effect:
1st, it is of the invention by arranging enhancement layer between compression rubber layer and sticking rubber layer, to improve the machinery of transmission belt Intensity, compared with existing reinforced-core, the enhancement layer that the present invention is provided includes that composite fiber web, the first bonding rod, second are glued Knot rod and reinforcement cotton, the fibrous raw material used by composite fiber web is through electrostatic spinning by composite fiber spinning liquid plus other auxiliary materials It is obtained, with preferable stretch-resistance and pliability;Enhancement layer is improved filled with cotton is strengthened in the grid inside of composite fiber web Mechanical strength;A surface of composite fiber web, other end difference energy are fixed respectively in one end of first bonding rod and the second bonding rod Enough stretch into inside compression rubber layer and sticking rubber layer so that adhere to more between enhancement layer and compression rubber layer and sticking rubber layer It is firm, it is to avoid transmission belt in the course of the work, the generation of peeling between layers, the enhancement layer that the present invention is provided with it is existing The heart yearn being embedded in rubber layer for having technology is compared, and the present invention also has on the premise of the mechanical strength of enhancement layer is ensured It is good with compression rubber layer and sticking rubber layer adhesiving effect, the good advantage of pliability;
2nd, arranging multiple sawtooth projections on a surface of the crimping of compression rubber layer can preferably engage with drive, carry High power transmission efficiency, arranges wear-resistant block on sawtooth projection, reduces the abrasion of transmission belt, extends the service life of transmission belt, Two groove groups on sawtooth projection, improve the ventilated performance between transmission belt and drive, can produce friction Heat is discharged in time, further reduces the abrasion of transmission belt, reduces potential safety hazard;
3rd, various rubber are mixed to prepare into according to a certain percentage modified rubber composition with various fillers, by various kinds of resin Modified resin compound is mixed to prepare according to a certain percentage with various fillers;Various fillers have small structure, Neng Goufen Dissipate strengthens the physical mechanical strength of rubber and resin in rubber and resin, while can be driven by obtained in rubber composition With internal breathability and the uniformity being heated, it is to avoid the phenomenon of the too high stripping cracking for causing of transmission belt inside local accumulated heat temperature Generation, the different modified and optimization to rubber performance is realized in the addition of modified resin compound, so as to improve transmission belt Elasticity, mechanical strength and pliability so that transmission belt has more preferably wearability, durability and ageing-resistant performance.
The further advantage of the present invention, target and feature embody part by description below, and part will also be by this The research of invention and practice and be understood by the person skilled in the art.
Description of the drawings
Fig. 1 is the structural representation of durable transmission belt of the present invention;
Fig. 2 is the structural representation of enhancement layer of the present invention;
Fig. 3 is the structural representation of sawtooth projection of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawings and embodiment the present invention is described in further detail, to make those skilled in the art's reference Specification word can be implemented according to this.
It should be appreciated that it is used herein such as " have ", "comprising" and " including " term do not allot one or many The presence or addition of individual other elements or its combination.
It should be noted that experimental technique described in following embodiments, if no special instructions, is conventional method, institute Reagent and material are stated, if no special instructions, is commercially obtained.
In describing the invention, term " horizontal ", " longitudinal direction ", " on ", it is D score, "front", "rear", "left", "right", " perpendicular Directly ", the orientation or position relationship of the instruction such as " level ", " top ", " bottom ", " interior ", " outward " is based on orientation shown in the drawings or position Relation is put, the description present invention is for only for ease of and is simplified description, be not to indicate or imply that the device or element of indication are necessary With specific orientation, with specific azimuth configuration and operation, therefore it is not considered as limiting the invention.
<Embodiment 1>
As shown in Figures 1 to 3, the present invention provides a kind of durable transmission belt, and it includes the compression crimped with power transmission component The sticking rubber layer 2 of the bonding of rubber layer 1 and the compression rubber layer 1 and it is arranged on the compression rubber layer 1 and described viscous Enhancement layer 3 between knot rubber layer 2,
Wherein, the enhancement layer 3 includes being laid in being combined between the compression rubber layer 1 and the sticking rubber layer 2 Fleece 31, be arranged on the first surface of the composite fiber web 31 can extend into it is many inside the compression rubber layer 1 It is individual first bonding rod 32, be arranged on can extend into the sticking rubber layer 2 on the second surface of the composite fiber web 31 Multiple second bonding rods 33 in portion and the reinforcement cotton being filled in inside the grid of the composite fiber web 31, the reinforcement cotton is glass Glass cellucotton;
The preparation method of composite fibre is in the composite fiber web 31:Count by weight, the carbon fiber for taking 10 parts spins Silk liquid, 6 parts of sodium alginate fiber spinning solution, 20 parts of aramid fiber spinning solution and 0.1 part of dispersant, are sufficiently mixed uniform After be heated to 40 DEG C, be added thereto to 0.04 part of particle diameter for 40nm nano-tourmaline and 0.01 part of rare earth metal yttrium, stir Mix uniform, filter, deaeration, then by spinneret injection to temperature is 45 DEG C, mass fraction is 5% calcium chloride solution, Again through washing, drawing-off, the composite fibre is obtained;
Arbitrary first bonding rod 32 is to coat a layer thickness in the outer surface of the plastic tube of hollow a diameter of 0.5cm The first binding agent for 0.2mm is obtained;First binding agent includes the raw material of following weight portion:240 parts of polyvinyl acetate Ester, 10 parts of diethylene glycol dibenzoate, 4 parts of polyacrylate, 11 parts of PET, 8 parts of adjacent benzene Diformazan dioctyl phthalate, 3 parts of polyacrylamide, 5 parts of cornstarch, 2 parts of palygorskite powder, 3 parts of sodium hydrogensulfite, 5 parts Kaolin, 6 parts of APES and 7 parts of AEO;
Arbitrary second bonding rod 33 is the outer surface coating thick layer in the plastic tube in hollow a diameter of 0.5cm Spend for 0.2mm the second binding agent be obtained;Second binding agent includes the raw material of following weight portion:240 parts of vinyl acetate Ester, 9 parts of diethylene glycol dibenzoate, 10 parts of toluene di-isocyanate(TDI), 8 parts of allyl methacrylate, 8 parts of adjacent benzene Dibutyl carboxylic acid, 3 parts of Pioloform, polyvinyl acetal, 2 parts of N hydroxymethyl acrylamide, 10 parts of Methyol resorcinols, 1 part Precipitated calcium carbonate, 2 parts of bentonite, 0.5 part of carbon black, 5 parts of nekal and 4 parts of dodecyl alcohol polyoxy second Alkene ether sodium sulfate.
The surface that the compression rubber layer 1 is crimped with power transmission component is provided with and a plurality of extends along its width Sawtooth projection 11, the section of arbitrary sawtooth projection 11 is trapezoidal, and the middle part of the sawtooth projection 11 is provided with T-shaped groove, institute The wear-resistant block 111 that T-shaped is arranged with T-shaped groove is stated, two is offered on the sawtooth projection 11 centered on the T-shaped groove Symmetrical v-depression group 112, the groove group include at least two continuous v-depressions;
The outer surface of the sawtooth projection 11 and the wear-resistant block 111 is coated with one layer of antistatic coating.
The raw material of the compression rubber layer 1 are rubber composition, and the preparation method of the rubber composition is including following Step:
1) count by weight, take 80 parts of ACM, 20 parts of butadiene rubber, 30 parts of haloflex rubber In glue, 4 parts of SBS and 18 parts of silicon rubber input banbury, 100 DEG C are heated to, Add 1 part of high-dispersion white carbon black, 4 parts of CNT, 5 parts of nano-cellulose whisker, 6 parts of microwax, 3 parts of graphite Alkene and 1 part of nano-diamond powder, carry out mixing 10min, obtain modified rubber composition;
2) by 5 parts of epoxy resin, 4 parts of phenolic resin, 2 parts of polyamide and the mixing of 3 parts of lignin resin Uniform hybrid resin, in the case where rotating speed is for the stirring of 70rpm, the high dispersive for sequentially adding 0.2 part in the hybrid resin is white Carbon black, 0.5 part of CNT, 0.4 part of nano-cellulose whisker, 1 part of microwax, 0.3 part of Graphene, 0.2 part Nano-diamond powder and 1 part of tourmaline crystalline substance ore deposit micro mist, are heated to 60 DEG C and continue to stir 30min, obtain modified resin compound;
3) the modified resin compound is divided into two equal portions, the modified rubber composition is placed in into banbury In be heated to 110 DEG C, be added thereto to successively the described modified resin compound of the first equal portions, 9 parts of PPG, 5 Part stearic acid, 4 parts of nano zine oxide, 7 parts of isopropyl benzene hydroperoxide, the double maleic amide of 3 parts of polyethylene glycol, 0.2 part Accelerator, 0.4 part of antiaging agent and 0.2 part of softening agent, knead 10min;
4) 140 DEG C are continuously heating to, add in banbury the second equal portions described modified resin compound, 0.4 part Cosan, 0.2 part of plasticizer and 0.2 part of accelerator, knead 10min, obtain final product the rubber composition;
Wherein, the accelerator is that weight ratio is 3:1.2:1.5:2:1.8:0.8 the curing tetrabenzyl autumn orchid loam, 2,2- Dithio-bis-benzothiazole, potassium stearate, 2- benzothiazolyl mercaptans, N cyclohexyl 2 benzothiazole sulfenamide and diethyl Base aminodithioformic acid cadmium is mixed to prepare;
The antiaging agent is 1 by weight ratio:1.5 N- isopropyl-N '-diphenyl-para-phenylene diamine and 2,2,4- trimethyls- 1,2- dihyaroquinoline condensate is mixed to prepare;
The plasticizer is di-n-octyl sebacate;
The softening agent is 1 by weight ratio:2:1.8:2.4:2.8:3 paraffin, castor oil, rapeseed oil, coconut oil, haze tallow It is mixed to prepare with pine tar.
The sticking rubber layer 2 is 8 by weight ratio:1:0.4:0.5 rubber composition, silica, nylon are short Fiber and glass are mixed to prepare.
<Embodiment 2>
As shown in Figures 1 to 3, the present invention provides a kind of durable transmission belt, and it includes the compression crimped with power transmission component The sticking rubber layer 2 of the bonding of rubber layer 1 and the compression rubber layer 1 and it is arranged on the compression rubber layer 1 and described viscous Enhancement layer 3 between knot rubber layer 2,
Wherein, the enhancement layer 3 includes being laid in being combined between the compression rubber layer 1 and the sticking rubber layer 2 Fleece 31, be arranged on the first surface of the composite fiber web 31 can extend into it is many inside the compression rubber layer 1 It is individual first bonding rod 32, be arranged on can extend into the sticking rubber layer 2 on the second surface of the composite fiber web 31 Multiple second bonding rods 33 in portion and the reinforcement cotton being filled in inside the grid of the composite fiber web 31, the reinforcement cotton is glass Glass cellucotton;
The preparation method of composite fibre is in the composite fiber web 31:Count by weight, the carbon fiber for taking 18 parts spins Silk liquid, 12 parts of sodium alginate fiber spinning solution, 30 parts of aramid fiber spinning solution and 0.3 part of dispersant, are sufficiently mixed 40 DEG C are heated to after even, the particle diameter for being added thereto to 0.07 part is the nano-tourmaline and 0.05 part of rare earth metal yttrium of 60nm, Stir, filter, deaeration, then by spinneret injection to temperature is 45 DEG C, mass fraction is 5% calcium chloride solution In, then through washing, drawing-off, obtain the composite fibre;
Arbitrary first bonding rod 32 is to coat a layer thickness in the outer surface of the plastic tube of hollow a diameter of 0.8cm The first binding agent for 0.5mm is obtained;First binding agent includes the raw material of following weight portion:250 parts of polyvinyl acetate Ester, 13 parts of diethylene glycol dibenzoate, 8 parts of polyacrylate, 17 parts of PET, 14 parts of adjacent benzene Diformazan dioctyl phthalate, 8 parts of polyacrylamide, 9 parts of cornstarch, 5 parts of palygorskite powder, 7 parts of sodium hydrogensulfite, 10 parts Kaolin, 12 parts of APES and 13 parts of AEO;
Arbitrary second bonding rod 33 is the outer surface coating thick layer in the plastic tube in hollow a diameter of 0.8cm Spend for 0.5mm the second binding agent be obtained;Second binding agent includes the raw material of following weight portion:250 parts of vinyl acetate Ester, 12 parts of diethylene glycol dibenzoate, 13 parts of toluene di-isocyanate(TDI), 15 parts of allyl methacrylate, 14 parts Dibutyl phthalate, 8 parts of Pioloform, polyvinyl acetal, 6 parts of N hydroxymethyl acrylamide, 15 parts of Methyol resorcinols, 3 Part precipitated calcium carbonate, 4 parts of bentonite, 1.2 parts of carbon black, 11 parts of nekal and 9 parts of dodecyl alcohol Polyethenoxy ether sodium sulfate.
The surface that the compression rubber layer 1 is crimped with power transmission component is provided with and a plurality of extends along its width Sawtooth projection 11, the section of arbitrary sawtooth projection 11 is trapezoidal, and the middle part of the sawtooth projection 11 is provided with T-shaped groove, institute The wear-resistant block 111 that T-shaped is arranged with T-shaped groove is stated, two is offered on the sawtooth projection 11 centered on the T-shaped groove Symmetrical v-depression group 112, the groove group include at least two continuous v-depressions;
The outer surface of the sawtooth projection 11 and the wear-resistant block 111 is coated with one layer of antistatic coating.
The raw material of the compression rubber layer 1 are rubber composition, and the preparation method of the rubber composition is including following Step:
1) count by weight, take 90 parts of ACM, 28 parts of butadiene rubber, 45 parts of haloflex rubber In glue, 11 parts of SBS and 27 parts of silicon rubber input banbury, 110 are heated to DEG C, add 3 parts high-dispersion white carbon black, 9 parts of CNT, 11 parts of nano-cellulose whisker, 13 parts of microwax, 8 parts Graphene and 3 parts of nano-diamond powder, carry out mixing 20min, obtain modified rubber composition;
2) by 10 parts of epoxy resin, 8 parts of phenolic resin, 6 parts of polyamide and the mixing of 7 parts of lignin resin Uniform hybrid resin, in the case where rotating speed is for the stirring of 80rpm, the high dispersive for sequentially adding 0.4 part in the hybrid resin is white Carbon black, 0.9 part of CNT, 0.8 part of nano-cellulose whisker, 4 parts of microwax, 0.9 part of Graphene, 0.6 part Nano-diamond powder and 4 parts of tourmaline crystalline substance ore deposit micro mist, are heated to 70 DEG C and continue to stir 40min, obtain modified resin compound;
3) the modified resin compound is divided into two equal portions, the modified rubber composition is placed in into banbury In be heated to 120 DEG C, be added thereto to successively the described modified resin compound of the first equal portions, 15 parts of PPG, 9 Part stearic acid, 8 parts of nano zine oxide, 14 parts of isopropyl benzene hydroperoxide, the double maleic amide of 7 parts of polyethylene glycol, 0.5 part Accelerator, 0.9 part of antiaging agent and 0.6 part of softening agent, knead 20min;
4) 160 DEG C are continuously heating to, add in banbury the second equal portions described modified resin compound, 0.7 part Cosan, 0.5 part of plasticizer and 0.5 part of accelerator, knead 20min, obtain final product the rubber composition;
Wherein, the accelerator is that weight ratio is 3:1.2:1.5:2:1.8:0.8 the curing tetrabenzyl autumn orchid loam, 2,2- Dithio-bis-benzothiazole, potassium stearate, 2- benzothiazolyl mercaptans, N cyclohexyl 2 benzothiazole sulfenamide and diethyl Base aminodithioformic acid cadmium is mixed to prepare;
The antiaging agent is 1 by weight ratio:1.5 N- isopropyl-N '-diphenyl-para-phenylene diamine and 2,2,4- trimethyls- 1,2- dihyaroquinoline condensate is mixed to prepare;
The plasticizer is di-n-octyl sebacate;
The softening agent is 1 by weight ratio:2:1.8:2.4:2.8:3 paraffin, castor oil, rapeseed oil, coconut oil, haze tallow It is mixed to prepare with pine tar.
The sticking rubber layer 2 is 8 by weight ratio:1:0.4:0.5 rubber composition, silica, nylon are short Fiber and glass are mixed to prepare.
<Embodiment 3>
As shown in Figures 1 to 3, the present invention provides a kind of durable transmission belt, and it includes the compression crimped with power transmission component The sticking rubber layer 2 of the bonding of rubber layer 1 and the compression rubber layer 1 and it is arranged on the compression rubber layer 1 and described viscous Enhancement layer 3 between knot rubber layer 2,
Wherein, the enhancement layer 3 includes being laid in being combined between the compression rubber layer 1 and the sticking rubber layer 2 Fleece 31, be arranged on the first surface of the composite fiber web 31 can extend into it is many inside the compression rubber layer 1 It is individual first bonding rod 32, be arranged on can extend into the sticking rubber layer 2 on the second surface of the composite fiber web 31 Multiple second bonding rods 33 in portion and the reinforcement cotton being filled in inside the grid of the composite fiber web 31, the reinforcement cotton is glass Glass cellucotton;
The preparation method of composite fibre is in the composite fiber web 31:Count by weight, the carbon fiber for taking 14 parts spins Silk liquid, 9 parts of sodium alginate fiber spinning solution, 25 parts of aramid fiber spinning solution and 0.2 part of dispersant, are sufficiently mixed uniform After be heated to 40 DEG C, be added thereto to 0.06 part of particle diameter for 50nm nano-tourmaline and 0.03 part of rare earth metal yttrium, stir Mix uniform, filter, deaeration, then by spinneret injection to temperature is 45 DEG C, mass fraction is 5% calcium chloride solution, Again through washing, drawing-off, the composite fibre is obtained;
Arbitrary first bonding rod 32 is to coat a layer thickness in the outer surface of the plastic tube of hollow a diameter of 0.7cm The first binding agent for 0.4mm is obtained;First binding agent includes the raw material of following weight portion:245 parts of polyvinyl acetate Ester, 12 parts of diethylene glycol dibenzoate, 6 parts of polyacrylate, 14 parts of PET, 11 parts of adjacent benzene Diformazan dioctyl phthalate, 6 parts of polyacrylamide, 7 parts of cornstarch, 4 parts of palygorskite powder, 5 parts of sodium hydrogensulfite, 8 parts Kaolin, 9 parts of APES and 10 parts of AEO;
Arbitrary second bonding rod 33 is the outer surface coating thick layer in the plastic tube in hollow a diameter of 0.7cm Spend for 0.4mm the second binding agent be obtained;Second binding agent includes the raw material of following weight portion:245 parts of vinyl acetate Ester, 11 parts of diethylene glycol dibenzoate, 12 parts of toluene di-isocyanate(TDI), 12 parts of allyl methacrylate, 11 parts Dibutyl phthalate, 6 parts of Pioloform, polyvinyl acetal, 4 parts of N hydroxymethyl acrylamide, 13 parts of Methyol resorcinols, 2 Part precipitated calcium carbonate, 3 parts of bentonite, 0.9 part of carbon black, 8 parts of nekal and 7 parts of dodecyl alcohol it is poly- Oxygen ethene ether sodium sulfate.
The surface that the compression rubber layer 1 is crimped with power transmission component is provided with and a plurality of extends along its width Sawtooth projection 11, the section of arbitrary sawtooth projection 11 is trapezoidal, and the middle part of the sawtooth projection 11 is provided with T-shaped groove, institute The wear-resistant block 111 that T-shaped is arranged with T-shaped groove is stated, two is offered on the sawtooth projection 11 centered on the T-shaped groove Symmetrical v-depression group 112, the groove group include at least two continuous v-depressions;
The outer surface of the sawtooth projection 11 and the wear-resistant block 111 is coated with one layer of antistatic coating.
The raw material of the compression rubber layer 1 are rubber composition, and the preparation method of the rubber composition is including following Step:
1) count by weight, take 85 parts of ACM, 24 parts of butadiene rubber, 38 parts of haloflex rubber In glue, 8 parts of SBS and 23 parts of silicon rubber input banbury, 105 DEG C are heated to, Add 2 parts of high-dispersion white carbon black, 7 parts of CNT, 8 parts of nano-cellulose whisker, 10 parts of microwax, 6 parts of stone Black alkene and 2 parts of nano-diamond powder, carry out mixing 15min, obtain modified rubber composition;
2) by 8 parts of epoxy resin, 6 parts of phenolic resin, 4 parts of polyamide and the mixing of 5 parts of lignin resin Uniform hybrid resin, in the case where rotating speed is for the stirring of 75rpm, the high dispersive for sequentially adding 0.3 part in the hybrid resin is white Carbon black, 0.7 part of CNT, 0.6 part of nano-cellulose whisker, 3 parts of microwax, 0.6 part of Graphene, 0.4 part Nano-diamond powder and 3 parts of tourmaline crystalline substance ore deposit micro mist, are heated to 65 DEG C and continue to stir 35min, obtain modified resin compound;
3) the modified resin compound is divided into two equal portions, the modified rubber composition is placed in into banbury In be heated to 115 DEG C, be added thereto to successively the described modified resin compound of the first equal portions, 12 parts of PPG, 7 Part stearic acid, 6 parts of nano zine oxide, 11 parts of isopropyl benzene hydroperoxide, the double maleic amide of 5 parts of polyethylene glycol, 0.4 part Accelerator, 0.7 part of antiaging agent and 0.4 part of softening agent, knead 15min;
4) 150 DEG C are continuously heating to, add in banbury the second equal portions described modified resin compound, 0.6 part Cosan, 0.4 part of plasticizer and 0.4 part of accelerator, knead 15min, obtain final product the rubber composition;
Wherein, the accelerator is that weight ratio is 3:1.2:1.5:2:1.8:0.8 the curing tetrabenzyl autumn orchid loam, 2,2- Dithio-bis-benzothiazole, potassium stearate, 2- benzothiazolyl mercaptans, N cyclohexyl 2 benzothiazole sulfenamide and diethyl Base aminodithioformic acid cadmium is mixed to prepare;
The antiaging agent is 1 by weight ratio:1.5 N- isopropyl-N '-diphenyl-para-phenylene diamine and 2,2,4- trimethyls- 1,2- dihyaroquinoline condensate is mixed to prepare;
The plasticizer is di-n-octyl sebacate;
The softening agent is 1 by weight ratio:2:1.8:2.4:2.8:3 paraffin, castor oil, rapeseed oil, coconut oil, haze tallow It is mixed to prepare with pine tar.
The sticking rubber layer 2 is 8 by weight ratio:1:0.4:0.5 rubber composition, silica, nylon are short Fiber and glass are mixed to prepare.
<Embodiment 4>
A kind of transmission belt, different from embodiment 3 are that the enhancement layer 3 is layed in compressing rubber for the multiple of routine Heart yearn between layer 1 and sticking rubber layer 2, remaining condition and parameter are with embodiment 3.
<Embodiment 5>
A kind of transmission belt, different from embodiment 3 are, the compression rubber layer 1 contact with power transmission component one Without sawtooth projection 11, remaining condition and parameter are with embodiment 3 on surface.
<Embodiment 6>
A kind of transmission belt, different from embodiment 3 are that the raw material of the compression rubber layer 1 are conventional rubber, such as Neoprene, remaining condition and parameter are with embodiment 3.
<Comparative example 1>
Performance test is carried out to the transmission belt of the embodiment of the present invention 1~6, as a result as shown in table 1:
As shown in Table 1, the various performances of the transmission belt of the embodiment of the present invention 1~3 are significantly better than the offer of embodiment 4~6 The pliability of the transmission belt that the performance of transmission belt, especially embodiment 3 are provided is good, and the heat-resistant anti-fatigue time is long, i.e., with higher Mechanical strength, embodiment 4 is that middle enhancement layer 3 is different from the difference of embodiment 3, illustrates what the embodiment of the present invention 3 was provided The tensile resistance of enhancement layer 3 is good by obtained in composite fiber web 31 is as matrix, on the premise of transmission belt mechanical strength is ensured, The overall flexibility of transmission belt is improve, with more excellent physical and chemical performance;Embodiment 5 exists with the difference of embodiment 3 It is different from the structure design on the surface that power transmission component is contacted in compression rubber layer 1, as shown in Table 1, in pressure in embodiment 3 One surface of contracting rubber layer 1 arranges sawtooth projection 11, and arranges wear-resistant block 111 at the middle part of sawtooth projection 11, and both sides arrange logical The v-depression group 112 of the penetrating gas of wind, can very well improve the heat dispersion of transmission belt, and the heat-resistant anti-fatigue for extending transmission belt is produced The time of crackle;Embodiment 6 is with the difference of embodiment 3, the raw material rubber used by compression rubber layer 1 and sticking rubber layer 2 The difference of glue, adds resin compound in the rubber composition that embodiment 3 is provided, improve wear-resisting, the heat resistance of transmission belt, Filler mixture is separately added into rubber composition and resin compound, is conducive to improving the being heated evenly property inside transmission belt, And then the overall physical and chemical performance of raising transmission belt.
Number of devices described herein and treatment scale are the explanations for simplifying the present invention.To the present invention application, Modifications and variations will be readily apparent to persons skilled in the art.
Although embodiment of the present invention is disclosed as above, it is not restricted to listed in specification and embodiment With, it can be applied to completely various suitable the field of the invention, for those skilled in the art, can be easily Other modification is realized, therefore under the universal limited without departing substantially from claim and equivalency range, the present invention is not limited In specific details and shown here as the legend with description.

Claims (8)

1. a kind of durable conveyer belt, it includes the compression rubber layer crimped with power transmission component and the compression rubber layer The sticking rubber layer of bonding and the enhancement layer being arranged between the compression rubber layer and the sticking rubber layer, its feature exists In,
The enhancement layer includes the composite fiber web being laid between the compression rubber layer and the sticking rubber layer, is arranged on On the first surface of the composite fiber web can extend into inside the compression rubber layer it is multiple first bonding rods, be arranged on Multiple second bondings that can extend into inside the sticking rubber layer on the second surface of the composite fiber web and are filled out rods The reinforcement cotton filled inside the composite fiber web grid, the reinforcement cotton is glass fibre cotton;
The preparation method of composite fibre is in the composite fiber web:Count by weight, take 10~18 parts of carbon fiber spinning Liquid, 6~12 parts of sodium alginate fiber spinning solution, 20~30 parts of aramid fiber spinning solution and 0.1~0.3 part of dispersant, Be sufficiently mixed it is uniform after be heated to 40 DEG C, the particle diameter for being added thereto to 0.04~0.07 part be the nano-tourmaline of 40~60nm and 0.01~0.05 part of rare earth metal yttrium, stirs, and filters, deaeration, is then 45 DEG C, matter by spinneret injection to temperature Amount fraction is in 5% calcium chloride solution, then through washing, drawing-off, obtains the composite fibre;
Arbitrary first bonding rod is to coat a layer thickness in the outer surface of the plastic tube of hollow a diameter of 0.5~0.8cm The first binding agent for 0.2~0.5mm is obtained;First binding agent includes the raw material of following weight portion:240~250 parts Polyvinyl acetate, 10~13 parts of diethylene glycol dibenzoate, 4~8 parts of polyacrylate, 11~17 parts poly- to benzene two Formic acid second diester, 8~14 parts of dioctyl phthalate, 3~8 parts of polyacrylamide, 5~9 parts of cornstarch, 2~5 The palygorskite powder, 3~7 parts of sodium hydrogensulfite, 5~10 parts of kaolin, 6~12 parts of APES and 7 of part ~13 parts of AEO;
Arbitrary second bonding rod is the outer surface coating thick layer in the plastic tube in hollow a diameter of 0.5~0.8cm Spend for 0.2~0.5mm the second binding agent be obtained;Second binding agent includes the raw material of following weight portion:240~250 parts Vinylacetate, 9~12 parts of diethylene glycol dibenzoate, 10~13 parts of toluene di-isocyanate(TDI), 8~15 parts of methyl Allyl acrylate, 8~14 parts of dibutyl phthalate, 3~8 parts of Pioloform, polyvinyl acetal, 2~6 parts of N- methylols Acrylamide, 10~15 parts of Methyol resorcinols, 1~3 part of precipitated calcium carbonate, 2~4 parts of bentonite, 0.5~1.2 part Carbon black, 5~11 parts of nekal and 4~9 parts of Brij 35 sodium sulphate.
2. durable transmission belt as claimed in claim 1, it is characterised in that the compression rubber layer is crimped with power transmission component A surface be provided with a plurality of sawtooth projection extended along its width, the section of arbitrary sawtooth projection is trapezoidal, institute State and T-shaped groove is provided with the middle part of sawtooth projection, the wear-resistant block of T-shaped is arranged with the T-shaped groove, open up on the sawtooth projection There are two symmetrical v-depression groups centered on the T-shaped groove, the groove group includes that at least two continuous V-arrangements are recessed Groove;
The outer surface of the sawtooth projection and the wear-resistant block is coated with one layer of antistatic coating.
3. durable transmission belt as claimed in claim 2, it is characterised in that the raw material of the compression rubber layer are building rubber compound Thing, the preparation method of the rubber composition is comprised the following steps:
1) count by weight, take 80~90 parts of ACM, 20~28 parts of butadiene rubber, 30~45 parts of chlorination Polyethylene rubber, 4~11 parts of SBS and the input banburying of 18~27 parts of silicon rubber In machine, 100~110 DEG C are heated to, add 1~3 part of high-dispersion white carbon black, 4~9 parts of CNT, 5~11 parts of nanometer Cellulose whiskers, 6~13 parts of microwax, 3~8 parts of Graphene and 1~3 part of nano-diamond powder, carry out mixing 10~ 20min, obtains modified rubber composition;
2) by 5~10 parts of epoxy resin, 4~8 parts of phenolic resin, 2~6 parts of polyamide and 3~7 parts of lignin The uniform hybrid resin of mixed with resin, under the stirring that rotating speed is 70~80rpm, in the hybrid resin 0.2 is sequentially added ~0.4 part of high-dispersion white carbon black, 0.5~0.9 part of CNT, 0.4~0.8 part of nano-cellulose whisker, 1~4 part Microwax, 0.3~0.9 part of Graphene, the tourmaline crystalline substance ore deposit micro mist of 0.2~0.6 part of nano-diamond powder and 1~4 part, It is heated to 60~70 DEG C to continue to stir 30~40min, obtains modified resin compound;
3) the modified resin compound is divided into two equal portions, the modified rubber composition is placed in banbury and is added Heat is added thereto to successively described modified resin compound, 9~15 parts of the polyether polyols of the first equal portions to 110~120 DEG C Alcohol, 5~9 parts of stearic acid, 4~8 parts of nano zine oxide, 7~14 parts of isopropyl benzene hydroperoxide, 3~7 parts of polyethylene glycol Double maleic amides, 0.2~0.5 part of accelerator, 0.4~0.9 part of antiaging agent and 0.2~0.6 part of softening agent, mixing 10 ~20min;
4) 140~160 DEG C are continuously heating to, add in banbury the second equal portions described modified resin compound, 0.4~ 0.7 part of Cosan, 0.2~0.5 part of plasticizer and 0.2~0.5 part of accelerator, knead 10~20min, obtain final product the rubber Glue composition.
4. durable transmission belt as claimed in claim 3, it is characterised in that the sticking rubber layer is 8 by weight ratio:1:0.4: 0.5 rubber composition, silica, nylon staple peacekeeping glass are mixed to prepare.
5. durable transmission belt as claimed in claim 4, it is characterised in that it is 3 that the accelerator is weight ratio:1.2:1.5:2: 1.8:0.8 curing tetrabenzyl autumn orchid loam, 2,2- dithio-bis-benzothiazoles, potassium stearate, 2- benzothiazolyl mercaptans, N- Cyclohexyl -2-[4-morpholinodithio sulfenamide and cadmium diethyl dithiocarbamate are mixed to prepare.
6. durable conveyer belt as claimed in claim 5, it is characterised in that the antiaging agent is 1 by weight ratio:1.5 N- Isopropyl-N '-diphenyl-para-phenylene diamine and 2,2,4- trimethyl -1,2- dihyaroquinoline condensates are mixed to prepare.
7. durable conveyer belt as claimed in claim 6, it is characterised in that the plasticizer is di-n-octyl sebacate.
8. durable conveyer belt as claimed in claim 7, it is characterised in that the softening agent is 1 by weight ratio:2:1.8:2.4: 2.8:3 paraffin, castor oil, rapeseed oil, coconut oil, haze tallow and pine tar are mixed to prepare.
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CN107880826A (en) * 2017-10-31 2018-04-06 枞阳县新天地高新材料有限公司 A kind of preparation method of resistance to oxidation lignin glue
CN108049032A (en) * 2017-11-24 2018-05-18 湖州织里创塑塑料科技有限公司 A kind of preparation method of the non-woven fabrics with strong negative ion releasing function
CN110017356A (en) * 2019-04-12 2019-07-16 江南大学 Nanometer transmission device
CN110205832A (en) * 2019-06-18 2019-09-06 中国民航大学 Two-sided grid aerogel heat-proof felt is taken in a kind of fire-fighting of good air permeability
CN111734784A (en) * 2020-06-12 2020-10-02 苏州塔莱泰传动科技股份有限公司 Anti-static PU spiral synchronous belt and preparation method thereof
CN113635645A (en) * 2021-08-02 2021-11-12 江阴市斯强传动科技有限公司 Microfiber elastic belt and manufacturing method thereof
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TWI762640B (en) * 2017-06-19 2022-05-01 日商阪東化學股份有限公司 Transmission belt
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CN110017356A (en) * 2019-04-12 2019-07-16 江南大学 Nanometer transmission device
CN110205832A (en) * 2019-06-18 2019-09-06 中国民航大学 Two-sided grid aerogel heat-proof felt is taken in a kind of fire-fighting of good air permeability
CN110205832B (en) * 2019-06-18 2021-07-23 中国民航大学 Double-faced grid aerogel heat insulation felt with good air permeability for firefighting clothes
CN111734784A (en) * 2020-06-12 2020-10-02 苏州塔莱泰传动科技股份有限公司 Anti-static PU spiral synchronous belt and preparation method thereof
CN113635645A (en) * 2021-08-02 2021-11-12 江阴市斯强传动科技有限公司 Microfiber elastic belt and manufacturing method thereof

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