CN110118234A - A kind of flexibility oil resistant paper-base friction wafer and preparation method thereof - Google Patents

A kind of flexibility oil resistant paper-base friction wafer and preparation method thereof Download PDF

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Publication number
CN110118234A
CN110118234A CN201910242947.6A CN201910242947A CN110118234A CN 110118234 A CN110118234 A CN 110118234A CN 201910242947 A CN201910242947 A CN 201910242947A CN 110118234 A CN110118234 A CN 110118234A
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CN
China
Prior art keywords
flexible
fiber
carbon fiber
oil resistant
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910242947.6A
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Chinese (zh)
Inventor
彭鹏
张杨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANTONG WANDA FRICTION MATERIAL Co Ltd
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NANTONG WANDA FRICTION MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANTONG WANDA FRICTION MATERIAL Co Ltd filed Critical NANTONG WANDA FRICTION MATERIAL Co Ltd
Priority to CN201910242947.6A priority Critical patent/CN110118234A/en
Publication of CN110118234A publication Critical patent/CN110118234A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/002Methods
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/14Anti-slip materials; Abrasives
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • F16D69/023Composite materials containing carbon and carbon fibres or fibres made of carbonizable material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02Composition of linings ; Methods of manufacturing
    • F16D69/025Compositions based on an organic binder
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0034Materials; Production methods therefor non-metallic
    • F16D2200/0052Carbon
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0034Materials; Production methods therefor non-metallic
    • F16D2200/0056Elastomers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/006Materials; Production methods therefor containing fibres or particles
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16DCOUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00Materials; Production methods therefor
    • F16D2200/0082Production methods therefor

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention provides a kind of flexible oil resistant paper-base friction wafer and preparation method thereof, the material including following mass fraction: compounding agent: 0.8~1.2;Sulphur: 2.5~5.5;Filler: 44~73;Flexible adhesives: 8~12;Brittle adhesive: 10~20;Nitrile rubber: 10~14;Flexible reinforced fiber: 0.3~1;Carbon fiber: 0.5~2.Oil resistant paper-base friction wafer provided by the invention and its production method can guarantee the oil resistivity of friction material, be consistent before the frictional behaviour and immersion oil after friction plate immersion oil, while ensure that the stable frictional behaviour of paper-base friction wafer and higher coefficient of friction.The present invention is using flexible reinforced fiber and the preferable carbon fiber of frictional behaviour as reinforcing fiber, use flexible adhesives and brittle adhesive as bonding agent simultaneously, the performance complement of flexible reinforced fiber and carbon fiber improves the flexibility of paper friction material, while also improving the friction and wear behavior of paper friction material.

Description

A kind of flexibility oil resistant paper-base friction wafer and preparation method thereof
Technical field
The present invention relates to friction plate technical fields, and in particular to a kind of flexibility oil resistant paper-base friction wafer and preparation method thereof.
Background technique
Friction material is mainly made of fiber, binder, filler, frictional property regulator, generallys use the mode of papermaking It manufactures, so referred to as paper friction material.Since it is with coefficient of friction height, stable friction performance, static and dynamic friction coefficient Than adjustable, wear resistance is good, many excellent performances such as high advantage of energy absorption capability and be widely used in all kinds of heavy In type vehicle and engineering truck tool.Traditional clutch surface is mainly used for dry clutch, is not suitable for making for wet clutch With.Publication No. CN104829888A, in the application for a patent for invention of entitled oil resistant paper-base friction wafer and its production method, oil resistant Paper-base friction wafer increases the oil resistance of manufactured friction plate by using nitrile rubber, while ensure that other objects of friction plate Rationality energy and mechanical performance, coefficient of friction with higher and frictional behaviour is consistent in the case where immersion oil.But fourth Nitrile glue has the disadvantages of lower temperature resistance is poor, ozone resistance is poor, and insulation performance is inferior, and elasticity is slightly lower, leads to the flexibility of foregoing invention It is poor.
Summary of the invention
Goal of the invention: being directed to the above-mentioned prior art, proposes a kind of flexible oil resistant paper-base friction wafer and preparation method thereof, both had There is good friction polishing machine, and there is preferable flexibility.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of flexibility oil resistant paper-base friction wafer, the material including following mass fraction: compounding agent: 0.8~1.2;Sulphur: 2.5~5.5;Filler: 44~73;Flexible adhesives: 8~12;Brittle adhesive: 10~20;Nitrile rubber: 10~14;Flexibility increases Strong fiber: 0.3~1;Carbon fiber: 0.5~2.
Preferably, the flexible reinforced fiber is Kevlar fiber, carbon fiber oxidization fiber or Kevlar fiber and carbon fiber Oxidization fiber composite fibre.
Preferably, the carbon fiber is asphalt base carbon fiber, polyacrylonitrile-based carbon fibre or asphalt base carbon fiber and poly- third Alkene itrile group carbon fiber composite fibre.
Preferably, the flexible adhesives are nitrile rubber, butadiene-styrene rubber, fluorubber or silicon rubber.
Preferably, the brittle adhesive is phenolic resin, cashew nut oil modified alkyd resin, acrylonitrile butadiene rubber modified phenolic aldehyde Resin or boron glue phenol-formaldehyde resin modified.
A kind of production method of flexibility oil resistant paper-base friction wafer, includes the following steps:
Step 1: nitrile rubber being put into mixer and is plasticated;
Step 2: by the compounding agent, sulphur, filler, flexible adhesives, brittle adhesive, flexible reinforced fiber, carbon fiber Peacekeeping plasticate after nitrile rubber be put into mixer carry out be kneaded form rubber compound;
Step 3: the rubber compound being moved in opening rubber mixing machine, and the rubber compound is made to pass through the open refining The roll shaft of glue machine forms film;
Step 4: winding upper film outside the film and be isolated.
Preferably, step 2 includes:
Step 2.1: the flexible adhesives being added in the mixer, to 1~2min of flexible adhesives pressurization;
Step 2.2: the brittle adhesive being added in the mixer, to 1~2min of brittle adhesive pressurization;
Step 2.3: the compounding agent is then added, 1~1.5min is added to the compounding agent;
Step 2.4: the filler is added, to the filler pressurization 3min pine 0.5min, repressurization 2min pine 0.5min;
Step 2.4: adding the sulphur, wait blanking after 20~25m.
The utility model has the advantages that oil resistant paper-base friction wafer provided by the invention and its production method can guarantee the oil resistant of friction material Property is consistent before the frictional behaviour and immersion oil after friction plate immersion oil, while ensure that the stable frictional behaviour of paper-base friction wafer With higher coefficient of friction.The present invention uses flexible reinforced fiber and the preferable carbon fiber of frictional behaviour as reinforcing fiber, together When use flexible adhesives and brittle adhesive as bonding agent, the performance complement of flexible reinforced fiber and carbon fiber improves paper The flexibility of base frication material, while also improving the friction and wear behavior of paper friction material.
Specific embodiment
Below with reference to embodiment, the present invention will be further described.
Embodiment one:
A kind of flexible oil resistant paper-base friction wafer provided by the invention, the material including following mass fraction: compounding agent: 0.8 ~1.2;Sulphur: 2.5~5.5;Filler: 44~73;Flexible adhesives: 8~12;Brittle adhesive: 10~20;Nitrile rubber: 10 ~14;Flexible reinforced fiber: 0.3~1;Carbon fiber: 0.5~2.
By the present invention in that with nitrile rubber increase made of friction plate oil resistance, while ensure that friction plate its His physical property and mechanical performance, coefficient of friction with higher and frictional behaviour is consistent in the case where immersion oil.
Optionally, the compounding agent includes the material of following mass fraction: promotor: 0.4~0.6;Anti-aging agent: 0.4~ 0.6。
Optionally, the filler includes the material of following mass fraction: zinc oxide: 1.5~3.5;Carbon black: 6~10;Stone Ink: 6~10;Chromite powder: 6~10;Petroleum coke powder: 3~5;Blanc fixe: 16~20;Coumarone: 2.5~5.5;Two fourths Ester: 0.8~3.5;Molybdenum disulfide: 2.5~5.5.Filler is indispensable component part in friction material, increases above-mentioned quality The filler of score can improve the physical property and mechanical performance of friction plate, adjust frictional behaviour and reduce the life of friction material Produce cost.
Optionally, the flexible reinforced fiber is Kevlar fiber, carbon fiber oxidization fiber or Kevlar fiber and carbon fiber Oxidization fiber composite fibre.
Optionally, the carbon fiber is asphalt base carbon fiber, polyacrylonitrile-based carbon fibre or asphalt base carbon fiber and poly- third Alkene itrile group carbon fiber composite fibre.
Optionally, the flexible adhesives are nitrile rubber, butadiene-styrene rubber, fluorubber or silicon rubber.
Optionally, the brittle adhesive is phenolic resin, cashew nut oil modified alkyd resin, acrylonitrile butadiene rubber modified phenolic aldehyde Resin or boron glue phenol-formaldehyde resin modified.
It can guarantee paper friction material coefficient of friction with higher and stabilization using the bonding agent of above-mentioned mass fraction Frictional behaviour, the friction plate produced can be widely applied in all kinds of heavy vehicles and engineering truck.Increased using flexibility Strong fiber and the preferable carbon fiber of frictional behaviour use flexible adhesives and brittle adhesive as viscous as reinforcing fiber Connect agent, the performance complement of flexible reinforced fiber and carbon fiber improves the flexibility of paper friction material, while also improving paper The friction and wear behavior of base frication material.
Embodiment two:
The present invention also provides a kind of production methods of above-mentioned flexible oil resistant paper-base friction wafer, comprising steps of
Step 1: nitrile rubber being put into mixer and is plasticated;
Step 2: by the compounding agent, sulphur, filler, flexible adhesives, brittle adhesive, flexible reinforced fiber, carbon fiber Peacekeeping plasticate after nitrile rubber be put into mixer carry out be kneaded form rubber compound;
Step 3: the rubber compound being moved in opening rubber mixing machine, and the rubber compound is made to pass through the open refining The roll shaft of glue machine forms film;
Step 4: winding upper film outside the film and be isolated.
Production method in the present invention is the production method for above-mentioned material, and the paper-base friction wafer produced, which has, to rub It wipes high coefficient, stable friction performance and still there is certain frictional behaviour in the case where immersion oil.
Optionally, in the step 1, number of plasticating is at least 3 times, and the nitrile rubber is into glue speed are as follows: 2~2.5m/ Min, plastic discharge thickness are as follows: 2.5mm~3.5mm.
Nitrile rubber belongs to high molecular material, its molecular weight is very high, and most valuable performance is exactly high resiliency.But this height Elasticity also brings very big difficulty to product manufacturing simultaneously.In processing, major part mechanical performance is consumed by elastic deformation, simultaneously It is difficult various shape needed for obtaining product.So in order to meet the needs of various machining processes, it is right under certain condition Raw rubber is machined, is heat-treated or is added certain chemical assistants, make its by tough elastic stage be changed into it is soft and just In the mecystasis of processing;So plasticating to it after nitrile rubber is added in mixer, at least need to plasticate 3 times, and It is carried out with above-mentioned impregnation speed, to guarantee the thickness and its performance for reaching manufacture friction plate needs of plastic emitting.
Optionally, step 2 includes:
Step 2.1: the flexible adhesives being added in the mixer, to 1~2min of flexible adhesives pressurization;
Step 2.2: the brittle adhesive being added in the mixer, to 1~2min of brittle adhesive pressurization;
Step 2.3: the compounding agent is then added, 1~1.5min is added to the compounding agent;
Step 2.4: the filler is added, to the filler pressurization 3min pine 0.5min, repressurization 2min pine 0.5min;
Step 2.4: adding the sulphur, wait blanking after 20~25m.
Raw material are kneaded by above-mentioned steps, it is therefore an objective to the rubber compound of uniform quality be made, do for subsequent forming processing It is good to prepare, and improve the service performance of rubber product, improve process industrial art performance and save raw rubber and reduce cost.It was kneaded It needs to carry out according to the method described above in journey, otherwise will appear that compounding agent dispersion is uneven, sizing material plasticity is too low or excessively high, it is burnt Phenomena such as burning, bloom, cannot proceed normally the processes such as calendering, extrusion, filter glue, vulcanization, and end properties is caused to decline.
Optionally, the roll shaft spacing of the opening rubber mixing machine is adjusted to minimum value, and the rubber compound passes through the roll shaft Number be 2~3 times.
Optionally, the size of the film are as follows: wide 570mm, thick 6.0mm.It is kneaded and needs to convert rubber compound to opening later It puts in formula rubber mixing machine, by the quenched minimum of spacing between its roll shaft, so that the rubber compound by roll shaft 2~3 times, is formed above-mentioned The thickness for the film that we need.
In the various embodiments described above of the present invention, the serial number and/or sequencing of embodiment are merely convenient of description, do not represent reality Apply the superiority and inferiority of example.It all emphasizes particularly on different fields to the description of each embodiment, there is no the part being described in detail in some embodiment, may refer to it The associated description of his embodiment.
It should be emphasized that term "comprises/comprising" refers to the presence of feature, element, step or component when using herein, but simultaneously It is not excluded for the presence or additional of one or more other features, element, step or component.
Finally, it should be noted that although the present invention and its advantage have been described in detail above it should be appreciated that not Can be carried out in the case where beyond the spirit and scope of the present invention being defined by the claims appended hereto various changes, substitution and Transformation.Moreover, the scope of the present invention is not limited only to the specific reality of process, equipment described in specification, means, method and steps Apply example.One of ordinary skilled in the art holds from the disclosure it will be readily understood that can be used according to the present invention The row function essentially identical to corresponding embodiment described herein obtains the result essentially identical with it, existing and future Process, equipment, means, method or step to be developed.Therefore, the attached claims purport includes in the range of them Such process, equipment, means, method or step.

Claims (7)

1. a kind of flexibility oil resistant paper-base friction wafer, which is characterized in that the material including following mass fraction: compounding agent: 0.8~ 1.2;Sulphur: 2.5~5.5;Filler: 44~73;Flexible adhesives: 8~12;Brittle adhesive: 10~20;Nitrile rubber: 10~ 14;Flexible reinforced fiber: 0.3~1;Carbon fiber: 0.5~2.
2. a kind of flexible oil resistant paper-base friction wafer according to claim 1, which is characterized in that the flexible reinforced fiber is Kevlar fiber, carbon fiber oxidization fiber or Kevlar fiber and carbon fiber oxidization fiber composite fibre.
3. a kind of flexible oil resistant paper-base friction wafer according to claim 1, which is characterized in that the carbon fiber is asphaltic base Carbon fiber, polyacrylonitrile-based carbon fibre or asphalt base carbon fiber and polyacrylonitrile-based carbon fibre composite fibre.
4. a kind of flexible oil resistant paper-base friction wafer according to claim 1, which is characterized in that the flexible adhesives are fourth Fine rubber, butadiene-styrene rubber, fluorubber or silicon rubber.
5. a kind of flexible oil resistant paper-base friction wafer according to claim 1, which is characterized in that the brittle adhesive is phenol Urea formaldehyde, cashew nut oil modified alkyd resin, nitrile rubber modified phenolic resin or boron glue phenol-formaldehyde resin modified.
6. the production method of flexibility oil resistant paper-base friction wafer described in a kind of claim 1, which comprises the steps of:
Step 1: nitrile rubber being put into mixer and is plasticated;
Step 2: by the compounding agent, sulphur, filler, flexible adhesives, brittle adhesive, flexible reinforced fiber, carbon fiber and Nitrile rubber after plasticating, which is put into mixer be kneaded, forms rubber compound;
Step 3: the rubber compound being moved in opening rubber mixing machine, and the rubber compound is made to pass through the opening rubber mixing machine Roll shaft formed film;
Step 4: winding upper film outside the film and be isolated.
7. the production method of flexibility oil resistant paper-base friction wafer according to claim 6, which is characterized in that step 2 includes:
Step 2.1: the flexible adhesives being added in the mixer, to 1~2min of flexible adhesives pressurization;
Step 2.2: the brittle adhesive being added in the mixer, to 1~2min of brittle adhesive pressurization;
Step 2.3: the compounding agent is then added, 1~1.5min is added to the compounding agent;
Step 2.4: the filler is added, to the filler pressurization 3min pine 0.5min, repressurization 2min pine 0.5min;
Step 2.4: adding the sulphur, wait blanking after 20~25m.
CN201910242947.6A 2019-03-28 2019-03-28 A kind of flexibility oil resistant paper-base friction wafer and preparation method thereof Pending CN110118234A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110760108A (en) * 2019-11-22 2020-02-07 石家庄硕若科技有限公司 Preparation method of rubber powder with functions of reducing friction and noise
CN111911572A (en) * 2020-08-11 2020-11-10 北京浦然轨道交通科技股份有限公司 Flame-retardant friction body, brake pad/brake shoe and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101024760A (en) * 2007-02-14 2007-08-29 西北工业大学 Flexible-paper-base friction material
CN102207146A (en) * 2011-05-23 2011-10-05 杭州东江摩擦材料有限公司 Carbon-paper-based friction plate and manufacturing method thereof
CN202023870U (en) * 2011-04-19 2011-11-02 杭州萧山红旗摩擦材料有限公司 Paper-based friction plate for tractor
CN102305255A (en) * 2010-12-17 2012-01-04 重庆意华科技开发有限责任公司 Paper-based friction plate and manufacturing method thereof
CN104829888A (en) * 2015-05-08 2015-08-12 南通万达摩擦材料有限公司 Oil-resistant paper-base friction plate and production method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101024760A (en) * 2007-02-14 2007-08-29 西北工业大学 Flexible-paper-base friction material
CN102305255A (en) * 2010-12-17 2012-01-04 重庆意华科技开发有限责任公司 Paper-based friction plate and manufacturing method thereof
CN202023870U (en) * 2011-04-19 2011-11-02 杭州萧山红旗摩擦材料有限公司 Paper-based friction plate for tractor
CN102207146A (en) * 2011-05-23 2011-10-05 杭州东江摩擦材料有限公司 Carbon-paper-based friction plate and manufacturing method thereof
CN104829888A (en) * 2015-05-08 2015-08-12 南通万达摩擦材料有限公司 Oil-resistant paper-base friction plate and production method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110760108A (en) * 2019-11-22 2020-02-07 石家庄硕若科技有限公司 Preparation method of rubber powder with functions of reducing friction and noise
CN111911572A (en) * 2020-08-11 2020-11-10 北京浦然轨道交通科技股份有限公司 Flame-retardant friction body, brake pad/brake shoe and preparation method thereof

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