CN106638161A - Amber decoration wallpaper and preparation method thereof - Google Patents
Amber decoration wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106638161A CN106638161A CN201611250302.XA CN201611250302A CN106638161A CN 106638161 A CN106638161 A CN 106638161A CN 201611250302 A CN201611250302 A CN 201611250302A CN 106638161 A CN106638161 A CN 106638161A
- Authority
- CN
- China
- Prior art keywords
- amber
- wallpaper
- layer
- coating
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Paper (AREA)
Abstract
The invention provides amber decoration wallpaper which comprises a base material layer, a base coat, a pattern layer, a transparent resin coating and an amber decoration layer in sequential contact. The wallpaper provided by the invention has the advantages of water resistance, good mildew resistance, scrubbing resistance, rare color fading, relatively long service life and good comprehensive quality and is relatively environment-friendly; in addition, with a unique amber decoration effect, the wallpaper provided by the invention can meet the flexible and diverse needs of the market; moreover, in the amber decoration wallpaper, the outer layer coating the amber core has good transparency so that the pattern is clear; and meanwhile, with good a non-stick property, the surface of the wallpaper can be easily cleaned, and the smoothness of the outer layer is high.
Description
Technical field
The present invention relates to house decorative material technical field, more particularly to a kind of amber decorative wall paper and preparation method thereof.
Background technology
Wallpaper, is a kind of ornament materials of the paper on metope, and it has, and color is various, pattern is abundant and easy construction etc.
The characteristics of various other house decorative materials are incomparable, is widely used in the indoor dress of the buildings such as house, office and hotel
In repairing.Meanwhile, wallpaper as other ornament materials, constantly updates change, no with the development of society and economic civilization again
Wallpaper of the same period also tends to embody the aesthetic pursuit of the level of economic development, trend development and people at present.
At present, wallpaper common on market is typically coating or printed patterns decorative pattern on base stock base material, so as to form tool
There is the wallpaper of each colored pattern.However, these wallpaper waterproofs, mould proof, pollution resistance are poor, not scrubbing resistance, and pattern fugitive color makes wallpaper
Service life is shorter, has gradually been difficult to meet the pursuit that people live high-quality.In addition, as wallpaper is walked as ornament materials
Enter the life of people, people also have to its ornamental and aesthetic property and further pursue, and style, money of the different people to wallpaper
The pursuit of formula also tends to difference, it is accordingly required in particular to the wallpaper of unique visual effects can be presented to decorate the life of oneself, and above-mentioned
Conventional wallpaper be all often the composite pattern decorative pattern on base stock base material, more single, very flexible, it is impossible to meet market various
The demand of change.
Therefore, with the development in economic life and market, the new product with high-quality and flexible and diverse how is provided
Plant wallpaper has become the focus of each R＆D enterprise extensive concern in the industry.
The content of the invention
In view of this, it is wallpaper waterproof that the application is provided, anti-it is an object of the invention to provide a kind of amber decorative wall paper
Mould, pollution resistance is good, scrubbing resistance, not fugitive color, and service life is longer, with good integrated quality；In addition, the wallpaper has solely
Special amber decorative effect, disclosure satisfy that market flexible and diverse demand.
The invention provides a kind of amber decorative wall paper, including：
Substrate layer；
It is compound in the priming coat of the base material layer surface；
It is compound in the figure lamina of the base coating surface；
It is compound in the transparent resin coating on the figure lamina surface；
It is compound in the amber decorative layer on the transparent resin coating surface；
The transparent outer layer of the amber decorative layer is formed by the resin slurry including following components：
The heat stabilizer is the one kind or many in calcium stearate, zinc stearate, pentaerythrite and calcium-zinc composite stabilizing agent
Kind with the compound stabilizer of compound rare-earth stabilizer, or for environmentally friendly organic tin stabilizer；
The lubricant is one or more in fatty acid ester type emollients and compounded lubricant.
Preferably, the compound rare-earth stabilizer is that fatty acid rare earth stabilizer, salicylic acid rare-earth stabilizer, citric acid are dilute
One or more in soil stabilizer, tartaric acid rare earth stabilizer, malic acid rare-earth stabilizer and Carboxylic Ester Rare Earth Salt stabilizer；
The fatty acid ester type emollients are fatty glyceride, fatty acid pentaerythritol ester and aliphatic acid sorbitol ester
In one or more；
The compounded lubricant is Tissuemat E and stearic acid with mass ratio (0.1～0.6):(0.1～2.0) what is compounded answers
Close lubricant.
Preferably, in the compound stabilizer, the calcium stearate, zinc stearate, pentaerythrite and Ca Zn composite are stablized
One or more in agent is (0.5～3) with the mass ratio of rare-earth stabilizer:(1～5).
Preferably, the plasticizer is diethylene glycol dibenzoate and/or tributyl 2-acetylcitrate；
The antioxidant is pentaerythrite (2,4- di-tert-butyl-phenyls-phosphorous acid) ester, double (3,5- di-t-butyl -4- hydroxyls
Base benzyl monoethyl phosphate) one kind in calcium and 1,6- hexylene glycol double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic ester]
Or it is several.
Preferably, the viscosity of the resin slurry is 3000～10000cps.
Preferably, the amber decorative layer is less than or equal to the transparent tree with the contact area of the transparent resin coating
The area of the side surface contacted with amber decorative layer in fat coating.
Preferably, the substrate layer is nonwoven paper layers, coating ply of paper or linen-cotton chemical ＆ blended fabric layer.
Preferably, the priming coat is PVC systems resin slurry coating, ester-polyurethane resin emulsion coating, acrylic resin breast
Liquid coating or fluorocarbon resin emulsion coating.
Preferably, the transparent resin coating is acroleic acid polymerization emulsion coating.
Present invention also offers a kind of preparation method of wallpaper described in above-mentioned technical proposal, comprises the following steps：
A) primer, drying are coated with or are printed in base material layer surface, form priming coat；
B) in the base coating surface composite diagram line film layer, figure lamina is formed；
C) transparent resin coating, drying are coated with or are printed on the figure lamina surface, form transparent resin coating；
D) amber decorative layer is made on the transparent resin coating surface, obtains amber decorative wall paper.
The invention provides a kind of amber decorative wall paper, including the substrate layer, priming coat, figure lamina for contacting successively, transparent
Resinous coat and amber decorative layer, and the outer layer of amber decorative layer made using specific resin slurry.Compared with prior art,
Wallpaper waterproof that the present invention is provided, mould proof, pollution resistance are good, and scrubbing resistance, not fugitive color, service life is longer, with good comprehensive
Close quality, and more environmental protection；In addition, the wallpaper that the application is provided also has unique amber decorative effect, market is disclosure satisfy that
Flexible and diverse demand；And, in the amber decorative wall paper that the present invention is provided, the outer layer transparency for being wrapped in amber core is good, makes
Clear patterns, meanwhile, its non-stick is good, makes wallpaper surface easy to clean, and outer layer smoothness is high.
Description of the drawings
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
The accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this
Inventive embodiment, for those of ordinary skill in the art, on the premise of not paying creative work, can be with basis
The accompanying drawing of offer obtains other accompanying drawings.
The structural representation of the amber decorative wall paper that Fig. 1 is provided for one embodiment of the present of invention；
The structural representation of the amber decorative wall paper that Fig. 2 is provided for another embodiment of the present invention；
The structural representation of the amber decorative wall paper that Fig. 3 is provided for another embodiment of the present invention；
The structural representation of the amber decorative wall paper that Fig. 4 is provided for another embodiment of the present invention；
The structural representation of the amber decorative wall paper that Fig. 5 is provided for another embodiment of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
The invention provides a kind of amber decorative wall paper, including：
Substrate layer；
It is compound in the priming coat of the base material layer surface；
It is compound in the figure lamina of the base coating surface；
It is compound in the transparent resin coating on the figure lamina surface；
It is compound in the amber decorative layer on the transparent resin coating surface；
The transparent outer layer of the amber decorative layer is formed by the resin slurry including following components：
The heat stabilizer is the one kind or many in calcium stearate, zinc stearate, pentaerythrite and calcium-zinc composite stabilizing agent
Kind with the compound stabilizer of compound rare-earth stabilizer, or for environmentally friendly organic tin stabilizer；
The lubricant is one or more in fatty acid ester type emollients and compounded lubricant.
Referring to Fig. 1, the structural representation of the amber decorative wall paper that Fig. 1 is provided for one embodiment of the present of invention, wherein, 1
For substrate layer, 2 is priming coat, and 3 is figure lamina, and 4 is transparent resin coating, and 5 is amber decorative layer.
Substrate layer 1 is the matrix of the amber decorative wall paper, and it is conventional wallpaper base material in this area.In the present invention
Some embodiments in, substrate layer 1 can be nonwoven paper layers, coating ply of paper or linen-cotton chemical ＆ blended fabric layer.The present invention is to the base
The source of material layer, without specifically limited, is general commercially available.In some embodiments of the invention, the thickness of substrate layer 1 can be with
For 0.05～0.2mm.
Priming coat 2 is compound in the surface of substrate layer 1, has compaction to substrate layer 1, reduces the expansion and contraction of substrate layer, also
Wallpaper water resistance can be improved.In some embodiments of the invention, priming coat 2 can be PVC systems resin slurry coating, poly- ammonia
Ester resin emulsion coating, emulsion acrylic resin coating or fluorocarbon resin emulsion coating；Wherein, PVC systems resin slurry, poly-
The source of urethane resin emulsion, emulsion acrylic resin and fluorocarbon resin emulsion is not particularly limited, and is general commercially available, example
Such as, the ester-polyurethane resin emulsion can be the B-612 purchased from German BASF, the emulsion acrylic resin can be purchased from
The Acronal DS 3502 of German BASF.The present invention is compound in the mode on the surface of substrate layer 1 to priming coat 2 does not have special limit
System, in certain embodiments, priming coat 2 can be coated with and be compound in the surface of substrate layer 1；In further embodiments, priming coat 2 is gone back
Can print and be compound in the surface of substrate layer 1.The present invention is not particularly limited to the type of priming coat 2, in certain embodiments, bottom
Coating 2 can be plane priming coat；In further embodiments, priming coat 2 can also be embossment priming coat, and multilayer can be presented
Secondary, fine and smooth grain effect.In some embodiments of the invention, the thickness of priming coat 2 can be 0.02～0.5mm.
Figure lamina 3 is compound in the surface of priming coat 2, and each colored pattern can be presented, and it is by the way that figure line slurry is fabricated to into figure
Case film layer is compound in the surface of priming coat 2 and obtains.The present invention is not particularly limited to the figure line slurry, using conventional in this area
Figure line slurry, such as in certain embodiments, the conventional figure line slurry that film-forming resin can be adopted to be formulated with mill base.
The present invention is not particularly limited to figure lamina 3 with the complex method of priming coat 2, in some embodiments of the invention, can adopt
With the conventional mode of printing such as mode such as cylinder, gravure or convex print in the surface recombination figure lamina 3 of priming coat 2；In other embodiments
In, can also be using inkjet printing or Freehandhand-drawing mode in the surface recombination figure lamina 3 of priming coat 2.Some enforcements that the present invention is provided
In example, the thickness of figure lamina 3 can be 0.02～0.1mm.
The present invention between substrate layer 1 and figure lamina 3 arrange priming coat 2, on the one hand can compact substrate layer, reduce base material
Expansion and contraction, and improve water resistance；On the other hand, additionally it is possible to strengthen the adhesive force of figure lamina, make figure lamina difficult for drop-off, moreover it is possible to
Strengthen the pattern expressive force of figure lamina.
Transparent resin coating 4 is compound in the surface of figure lamina 3, and it can make wallpaper have excellent light resistance, good guarantor
Light colour retention and excellent water-fast chemical resistance etc., extend the service life of wallpaper.In some embodiments of the invention, thoroughly
Bright resinous coat 4 can be clear acrylic polymerized emulsion coating；In certain embodiments, the acroleic acid polymerization emulsion can be with
It is purchased from German BASF678 clear acrylic emulsions.In some embodiments of the invention, transparent tree
The thickness of fat coating 4 can be 0.05～0.1mm.
Amber decorative layer 5 is compound in the surface of transparent resin coating 4, and it can not only make wallpaper that unique amber decoration is presented
Effect, overcomes that wallpaper on market is single, very flexible defect, meets the demand of market flexible and diverse, additionally it is possible to which auxiliary is carried
The performance such as the water resistant of high wallpaper, mould proof.
In the present invention, the amber core in amber decorative layer 5 is the amber core of broad sense；Some enforcements for such as providing in the present invention
In example, the amber core in amber decorative layer 5 can be insect specimen, other zoological specimens or plant specimen；In some embodiments
In, amber core can also be handicraft；In certain embodiments, amber core can also be 3 D pattern, and the 3 D pattern can
Think printing or home built 3 D pattern.In some embodiments that the present invention is provided, the thickness of amber core can be 0.05
～0.5mm.In some embodiments that the present invention is provided, the transparent outer layer in amber decorative layer 5 is transparent PVC resin slurry bag
Covering layer.In some embodiments that the present invention is provided, the thickness of the transparent outer layer in amber decorative layer 5 can be 0.1～2.0mm.
In the present invention, the thickness of amber core and the thickness of transparent outer layer refer to thickness of the amber core peak away from transparent resin coating 4 and
Thickness of the transparent outer layer peak away from transparent resin coating 4.
In some embodiments of the present invention, amber decorative layer 5 is less than transparent resin with the contact area of transparent resin coating 4
The area of the side surface contacted with amber decorative layer 5 in coating 4, as shown in Fig. 2 wherein, amber decorative layer 5 is wrapped its structure
One or more independent amber bodies are included, the amber body includes amber core 501 and transparent outer layer 502, and the dispersion of amber body is pasted
In the surface of transparent resin coating 4, the amber decorative layer 5 with overall amber decorative effect is formed；It not only brings the amber of uniqueness
Amber decorative effect, moreover it is possible to which auxiliary improves water resistant, the fungicidal properties of wallpaper.
In other embodiments of the present invention, amber decorative layer 5 can also be waited with the contact area of transparent resin coating 4
The area of the side surface contacted with amber decorative layer 5 in transparent resin coating 4, its structure can with as shown in figure 3, its
In, amber decorative layer 5 includes one or more independent amber cores 501 and is coated on all surfaces of amber core 501 and is covered in
The dispersion of the transparent outer layer 502 on the surface of transparent resin coating 4, i.e. amber core 501 is pasted on the surface of transparent resin coating 4, transparent outer
Layer 502 coats the whole surface of transparent resin coating 4, not only makes the transparent slurry of the surface of amber core 501 coating outer layer, also makes transparent
The surface of resinous coat 4 is not interspersed the region of amber core 501 and is also coated with the transparent slurry of outer layer, makes the entirety of transparent resin coating 4
Surface is all covered with transparent outer layer 502, can further improve water resistant, anti-mildew, not scrubbing resistance, the performance such as fugitive color of wallpaper,
Lift wallpaper quality.The present invention is not particularly limited to the surface structure form of amber decorative layer 5, such as in certain embodiments,
The surface of amber decorative layer 5 is planar configuration, in plane effect, as shown in Figure 3；In certain embodiments, amber decorative layer 5
Surface can be cambered surface structure, in cambered surface effect, as shown in Figure 4；In further embodiments, the surface of amber decorative layer 5 is also
Sag and swell can be distributed as according to amber core, in male and fomale(M＆F) effect, as shown in Figure 5.
The invention provides a kind of amber decorative wall paper, substrate layer, priming coat, the figure lamina, thoroughly for contacting successively is provided with
Bright resinous coat and amber decorative layer, it arranges priming coat between substrate layer and figure lamina, and sets successively on figure lamina surface
Transparent resin coating and amber decorative layer are put, pattern adhesive force are also advantageously improved while making wallpaper that there is clear pattern,
Make its difficult for drop-off and fade, and the performances such as the water resistant of wallpaper, scrubbing resistance, anti-mildew can be improved, extend wallpaper service life, and
Wallpaper is more environmentally friendly；In addition it is possible to the amber decorative effect of uniqueness is presented, market flexible and diverse demand is met.
In the present invention, the transparent outer layer 502 of amber decorative layer 5 is formed by the resin slurry including following components：
The heat stabilizer is the one kind or many in calcium stearate, zinc stearate, pentaerythrite and calcium-zinc composite stabilizing agent
Kind with the compound stabilizer of compound rare-earth stabilizer, or for environmentally friendly organic tin stabilizer；
The lubricant is one or more in fatty acid ester type emollients and compounded lubricant.
According to the present invention, forming the resin slurry of transparent outer layer 502 includes polyvinyl chloride, the consumption of the polyvinyl chloride
Preferably 100 parts.In certain embodiments, the polyvinyl chloride can be purchased from German Vinnolit companies model E75SK
PVC paste resin.
According to the present invention, formed and also include in the resin slurry of transparent outer layer 502 heat stabilizer, the heat stabilizer is hard
One or more and the compounding of compound rare-earth stabilizer in resin acid calcium, zinc stearate, pentaerythrite and calcium-zinc composite stabilizing agent
Stabilizer, or for environmentally friendly organic tin stabilizer；Preferably calcium stearate, zinc stearate, pentaerythrite and calcium-zinc composite stabilizing agent
In one or more with the compound stabilizer of compound rare-earth stabilizer；More preferably pentaerythrite stablizes dosage form with compound rare-earth
Into the compound stabilizer that formed of compound stabilizer or calcium stearate and zinc stearate and compound rare-earth stabilizer；The environmental protection has
Machine tin stabilizer is preferably Methyl stannum mercaptide stabilizer.In the present invention, the compound rare-earth stabilizer is preferably fatty acid rare earth
Stabilizer, salicylic acid rare-earth stabilizer, citric acid rare-earth stabilizer, tartaric acid rare earth stabilizer, malic acid rare-earth stabilizer and
One or more in Carboxylic Ester Rare Earth Salt stabilizer.The present invention is not special to the source of each component material in the heat stabilizer
Limit, be general commercially available product.In the present invention, the consumption of the heat stabilizer is preferably 1～5 part.
In the present invention, in the compound stabilizer, the calcium stearate, zinc stearate, pentaerythrite and Ca Zn composite are steady
One or more determined in agent is preferably (0.5～3) with the mass ratio of compound rare-earth stabilizer:(1～5)；The pentaerythrite
In the compound stabilizer formed with compound rare-earth stabilizer, compound rare-earth stabilizer：The mass ratio of pentaerythrite be preferably (1～
3):(1～2)；In the compound stabilizer that the calcium stearate is formed with zinc stearate and compound rare-earth stabilizer, compound rare-earth is steady
Determine agent：Calcium stearate：The mass ratio of zinc stearate is preferably (1～2):(1～3):1.In the present invention, the Ca Zn composite is stablized
Calcium zinc mass ratio in agent is preferably (5～3):9.
According to the present invention, formed and also include in the resin slurry of transparent outer layer 502 lubricant, the lubricant is aliphatic acid
One or more in ester lubricant and compounded lubricant.In the present invention, the fatty acid ester type emollients are that aliphatic acid is sweet
One or more in grease, fatty acid pentaerythritol ester and aliphatic acid sorbitol ester；The compounded lubricant is preferably poly-
Ethylene waxes are with stearic acid with mass ratio (1～5):(0.5～3) compounded lubricant of compounding.The present invention is to each component in lubricant
The source of material is not particularly limited, and is general commercially available product.In the present invention, the consumption of the lubricant is preferably 0.2～
1.0 part.
According to the present invention, formed and also include in the resin slurry of transparent outer layer 502 plasticizer, the plasticizer is preferably two
The fourth of glycol dibenzoate and/or tributyl 2-acetylcitrate, more preferably diethylene glycol dibenzoate and acetyl tributyl citrate three
The mixture of ester.In the present invention, the diethylene glycol dibenzoate：The mass ratio of tributyl 2-acetylcitrate is preferably 1：(1～
2), be conducive to improving the flexibility and resistance to low temperature of the paste resin bed of material.The present invention is to each component material in the plasticizer
Source is not particularly limited, and is general commercially available product.In the present invention, the consumption of the plasticizer is preferably 3～8 parts.
According to the present invention, formed and also include in the resin slurry of transparent outer layer 502 antioxidant, the antioxidant is preferably season
Penta tetrol (2,4- di-tert-butyl-phenyls-phosphorous acid) ester, double (3,5- di-tert-butyl-4-hydroxyl benzyl monoethyl phosphate) calcium and 1,
One or more in 6- hexylene glycols double [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic ester].The present invention is to the antioxygen
The source of each component material is not particularly limited in agent, is general commercially available product.In the present invention, the consumption of the antioxidant is excellent
Elect 0～0.5 part as, more preferably higher than 0 is less than or equal to 0.5 part.
According to the present invention, the viscosity for forming the resin slurry of transparent outer layer 502 is preferably 3000～10000cps.
According to the present invention, the resin slurry of the formation transparent outer layer 502 is preferably prepared as follows：By heat
Stabilizer, lubricant, plasticizer and antioxidant ratio by weight is invested in mixing and blending machine, first with 200～500r/min
Speed stir 10～15min, then lift stir speed (S.S.) to 800～1000r/min, Corvic is added while stirring,
20～30min is persistently stirred after adding, resin slurry is obtained.
Conventional amber of the prior art is the resin drippage of coniferale plant and is imbedded in underground for a long time, through certainization
The rosin fossil that after changing form, is insect or animals and plants etc. inside amber, outside for rosin resin integument, outside rosin
Integument transparency is often poor, even nontransparent, and, its often more coarse or many hollow, smoothness is poor.And this
Invention selects above-mentioned specific components to form resin slurry, and its is transparent higher, as the integument of amber core, can make amber
Core is high-visible；And, the resin slurry of the present invention can significantly improve free mobility and non-stick, with good wire mark
Transfer performance, to the easy feeding of amber core and the outer layer smoothness that formed is higher, and its not glue pollution resistance good, make amber core
Outer layer easy cleaning.
The invention provides a kind of amber decorative wall paper, including the substrate layer, priming coat, figure lamina for contacting successively, transparent
Resinous coat and amber decorative layer, and the outer layer of amber decorative layer made using specific resin slurry.The wall that the present invention is provided
Paper waterproof, mould proof, pollution resistance are good, scrubbing resistance, not fugitive color, and service life is longer, with good integrated quality, and more ring
Protect；In addition, the wallpaper that the application is provided also has unique amber decorative effect, market flexible and diverse demand is disclosure satisfy that；
And, in the amber decorative wall paper that the present invention is provided, the outer layer transparency for being wrapped in amber core is good, makes clear patterns, and it is not
Viscosity is good, makes wallpaper surface easy to clean, meanwhile, its outer layer pulp flow metastatic is good, to the easy feeding of amber core and makes transparent
Outer layer smoothness is high.
Present invention also offers a kind of preparation method of wallpaper described in above-mentioned technical proposal, comprises the following steps：
A) primer, drying are coated with or are printed in base material layer surface, form priming coat；
B) in the base coating surface composite diagram line film layer, figure lamina is formed；
C) transparent resin coating, drying are coated with or are printed on the figure lamina surface, form transparent resin coating；
D) amber decorative layer is made on the transparent resin coating surface, obtains amber decorative wall paper.
In the present invention, the substrate layer, priming coat, figure lamina, transparent resin layer and amber decorative layer and above-mentioned technical side
Case is consistent, and this is no longer going to repeat them.
In the present invention, first primer, drying are coated with or are printed in base material layer surface, form priming coat.The drying
Temperature is preferably 80～150 DEG C, makes primer film-forming, forms priming coat.It is compound in base coating surface after forming priming coat
Figure line film layer, forms figure lamina；The compound side is not particularly limited, such as can be using conventional mode of printing such as cylinder, recessed
The mode such as print or convex print is in base coating surface composite diagram line film layer and drying forms figure lamina, it would however also be possible to employ inkjet printing or hand
Mode is painted in base coating surface composite diagram lamina；The temperature of the drying is preferably 60～120 DEG C.After forming figure lamina, in figure
Lamina surface is coated with or prints transparent resin coating, drying, forms transparent resin coating；The temperature of the drying is 80～110
℃.After forming transparent resin layer, amber decorative layer is made on the transparent resin coating surface, obtain amber decorative wall paper；Tool
Body, amber core can be pasted in transparent resin coating Dispersion on surface, then transparent outer layer, drying are coated in amber wicking surface wire mark,
Amber decorative layer is formed, the speed of the wire mark can be 30～120m/min, and the temperature of the drying is preferably 120～160
℃；First amber core can also be pasted in transparent resin coating dispersion, then in amber wicking surface and transparent resin coating surface printing
Or coating transparent outer layer, it is dried, amber decorative layer is formed, so as to obtain amber decorative wall paper, the temperature of the drying is preferably
120～160 DEG C.
For a further understanding of the present invention, the preferred embodiment of the invention is described with reference to embodiment, but
It should be appreciated that these descriptions are simply to further illustrate the features and advantages of the present invention, rather than to the claims in the present invention
Limit.
Embodiment 1
By 1 part of pentaerythrite, 2 parts of bigcatkin willow acid rare earths, 0.3 part of Tissuemat E, 0.2 part of stearic acid, 2.5 parts of diethylene glycol (DEG) hexichol
Formic acid esters, 2.5 parts of tributyl 2-acetylcitrates and 0.3 part of pentaerythrite (2,4- di-tert-butyl-phenyls-phosphorous acid) ester input are stirred
Mix the mixing that speed is 300r/min several, stir 13min, improve stir speed (S.S.) to 900r/min, and be slowly added to 100
Part Corvic, continues to stir 25min after adding, and obtains the resin slurry that viscosity is 3000cps, stand-by.
Ester-polyurethane resin emulsion B-612 is coated with non-woven paper substrate surface, film forming is dried at 100 DEG C, form priming coat；
Figure line slurry is printed in base coating surface, film forming is dried at 80 DEG C, form figure lamina；In the coating of figure lamina surface678 clear acrylic emulsions, dry at 100 DEG C, form transparent resin coating；In transparent resin coating table
Amber core is pasted in face dispersion, and the printing of above-mentioned resin slurry is wrapped in into amber wicking surface using screen printing process, and at 140 DEG C
Drying, obtains the amber decorative wall paper of structure as shown in Figure 2.
With 6 months as the time limit is investigated, wallpaper is cleaned with the weekly frequency, investigate water resistant, the anti-scratch of wallpaper
Wash, as a result anti-colour fading and fungicidal properties show, investigating in the time limit, wallpaper surface is without bubbling, edge without playing a side, wallpaper surface
Without fading, it is mould without rising, it has an excellent water resistant scrub performance, good colour retention and pattern tack, and good
Anti-mold effect.
The average transmittance of the transparent outer layer in the amber decorative layer of gained wallpaper is 90%, and the outer layer is without coarse lines
Or hollow, it is seen then that its transparent outer layer has excellent transparency and smoothness.
Embodiment 2
By 0.5 part of pentaerythrite, 0.5 portion of citric acid rare earth, 0.1 portion of Tissuemat E, 0.1 portion of stearic acid, 1 portion of diethylene glycol (DEG)
Double (the 3,5- di-tert-butyl-4-hydroxyl benzyl monoethyl phosphates) calcium of dibenzoate, 2 parts of tributyl 2-acetylcitrates and 0.1 part
Input stir speed (S.S.) is several for the mixing of 200r/min, stirs 15min, improves stir speed (S.S.) to 800r/min, and slowly
100 parts of Corvics are added, continues to stir 30min after adding, obtain the resin slurry that viscosity is 6500cps, it is stand-by.
In coated paper substrate surface acrylic resins of painting latex A cronalDS 3502, film forming, shape are dried at 80 DEG C
Into priming coat；Figure line slurry is printed in base coating surface, film forming is dried at 60 DEG C, form figure lamina；Apply on figure lamina surface
Cloth678 clear acrylic emulsions, dry at 80 DEG C, form transparent resin coating；In transparent resin coating
Dispersion on surface pastes amber core, and the printing of above-mentioned resin slurry is wrapped in into amber wicking surface and transparent resin using screen printing process
Coating surface, and dry at 120 DEG C, obtain the amber decorative wall paper of structure as shown in Figure 3.
Method according to embodiment 1 investigates water resistant, the scrubbing resistance of wallpaper, anti-colour fading and fungicidal properties, as a result shows, is examining
Examine in the time limit, without rising, side, wallpaper surface are mould without colour fading, nothing without bubbling, edge for wallpaper surface, and it has excellent water resistant anti-scratch
Wash performance, good colour retention and pattern tack, and good anti-mold effect.
Meanwhile, the average transmittance of the transparent outer layer in the amber decorative layer of gained wallpaper is 93%, and the outer layer is without thick
Rough lines or hollow, it is seen then that its transparent outer layer has excellent transparency and smoothness.
Embodiment 3
By 2 parts of calcium stearates, 1 part of zinc stearate, 2 parts of tartaric acid rare earths, 0.6 part of Tissuemat E, 0.4 part of stearic acid, 3.2
Part diethylene glycol dibenzoate, 4.8 parts of tributyl 2-acetylcitrates and 0.5 part of 1,6- hexylene glycol it is double [β-(3,5- di-t-butyls-
4- hydroxy phenyls) propionic ester] input stir speed (S.S.) for 500r/min mixing it is several, stir 10min, improve stir speed (S.S.)
To 1000r/min, and 100 parts of Corvics are slowly added to, continue to stir 20min after adding, obtain viscosity for 8000cps
Resin slurry, it is stand-by.
Fluorocarbon resin emulsion is coated with linen-cotton chemical ＆ blended fabric base material layer surface, film forming is dried at 150 DEG C, form primary coat
Layer；Figure line slurry is printed in base coating surface, film forming is dried at 120 DEG C, form figure lamina；In the coating of figure lamina surface678 clear acrylic emulsions, dry at 110 DEG C, form transparent resin coating；In transparent resin coating table
Amber core is pasted in face dispersion, and the printing of above-mentioned resin slurry is wrapped in into amber wicking surface and transparent resin painting using screen printing process
Layer surface, and dry at 160 DEG C, obtain the amber decorative wall paper of structure as shown in Figure 4.
Method according to embodiment 1 investigates water resistant, the scrubbing resistance of wallpaper, anti-colour fading and fungicidal properties, as a result shows, is examining
Examine in the time limit, without rising, side, wallpaper surface are mould without colour fading, nothing without bubbling, edge for wallpaper surface, and it has excellent water resistant anti-scratch
Wash performance, good colour retention and pattern tack, and good anti-mold effect.
Meanwhile, the average transmittance of the transparent outer layer in the amber decorative layer of gained wallpaper is 92%, and the outer layer is without thick
Rough lines or hollow, it is seen then that its transparent outer layer has excellent transparency and smoothness.
Embodiment 4
By 3 parts of calcium stearates, 1 part of zinc stearate, 1 part of apple acid rare earth, 0.5 part of Tissuemat E, 0.5 part of stearic acid, 4 parts
Diethylene glycol dibenzoate, 4 parts of tributyl 2-acetylcitrates, 0.25 part of 1,6- hexylene glycols pair [β-(3,5- di-t-butyl -4- hydroxyls
Base phenyl) propionic ester] and 0.25 part of pentaerythrite (2,4- di-tert-butyl-phenyls-phosphorous acid) ester input stir speed (S.S.) be 300r/
The mixing of min is several, stirs 13min, improves stir speed (S.S.) to 900r/min, and is slowly added to 100 parts of polyvinyl chloride trees
Fat, continues to stir 25min after adding, and obtains the resin slurry that viscosity is 9500cps, stand-by.
In non-woven paper substrate surface coating PVC systems resin slurry, film forming is dried at 100 DEG C, form priming coat；In primary coat
Layer surface prints figure line slurry, and film forming is dried at 80 DEG C, forms figure lamina；In the coating of figure lamina surface
678 clear acrylic emulsions, dry at 100 DEG C, form transparent resin coating；Amber is pasted in transparent resin coating Dispersion on surface
Amber core, and the printing of above-mentioned resin slurry is wrapped in by amber wicking surface and transparent resin coating surface using screen printing process, and in
Dry at 140 DEG C, obtain the amber decorative wall paper of structure as shown in Figure 5.
Method according to embodiment 1 investigates water resistant, the scrubbing resistance of wallpaper, anti-colour fading and fungicidal properties, as a result shows, is examining
Examine in the time limit, without rising, side, wallpaper surface are mould without colour fading, nothing without bubbling, edge for wallpaper surface, and it has excellent water resistant anti-scratch
Wash performance, good colour retention and pattern tack, and good anti-mold effect.
Meanwhile, the average transmittance of the transparent outer layer in the amber decorative layer of gained wallpaper is 95%, and the outer layer is without thick
Rough lines or hollow, it is seen then that its transparent outer layer has excellent transparency and smoothness.
Comparative example 1
Figure line slurry is printed in non-woven paper substrate surface, film forming is dried at 80 DEG C, form figure lamina, obtain wallpaper.
Method according to embodiment 1 investigates water resistant, the scrubbing resistance of wallpaper, anti-colour fading and fungicidal properties, as a result shows, is examining
Examine in the time limit, wallpaper surface foaming phenomena is serious, edge plays side, meanwhile, wallpaper surface fades serious, and many places are risen mould, it is seen then that wall
The water resistant scrub performance of paper is poor, and colour retention and pattern tack and anti-mold effect are poor.
Comparative example 2
Ester-polyurethane resin emulsion B-612 is coated with non-woven paper substrate surface, film forming is dried at 100 DEG C, form priming coat；
Figure line slurry is printed in base coating surface, film forming is dried at 80 DEG C, form figure lamina, obtain wallpaper.
Method according to embodiment 1 investigates water resistant, the scrubbing resistance of wallpaper, anti-colour fading and fungicidal properties, as a result shows, is examining
Examine in the time limit, wallpaper surface foaming phenomena is serious, edge plays side, meanwhile, wallpaper surface has a certain degree of colour fading, and many places are risen
It is mould, it is seen then that the water resistant scrub performance of wallpaper is poor, colour retention and pattern tack and anti-mold effect it is also poor.
As seen from the above embodiment, the amber decorative wall paper water resistant abrasive proof of present invention offer, mildew resistance are good, are difficult to take off
Color, service life is longer, with good integrated quality；In addition, the wallpaper that the application is provided also has unique amber decoration
Effect, disclosure satisfy that market flexible and diverse demand；And, in the amber decorative wall paper that the present invention is provided, it is wrapped in amber core
Outer layer transparency it is good, make clear patterns, meanwhile, its outer layer pulp flow metastatic is good, and transparent outer layer smoothness is high.
The explanation of above example is only intended to help and understands the method for the present invention and its core concept.To these embodiments
Various modifications will be apparent for those skilled in the art, generic principles defined herein can be with
Without departing from the spirit or scope of the present invention, realize in other embodiments.Therefore, the present invention will not be limited
In the embodiments shown herein, and it is to fit to the most wide model consistent with principles disclosed herein and features of novelty
Enclose.
Claims (10)
1. a kind of amber decorative wall paper, it is characterised in that include：
Substrate layer；
It is compound in the priming coat of the base material layer surface；
It is compound in the figure lamina of the base coating surface；
It is compound in the transparent resin coating on the figure lamina surface；
It is compound in the amber decorative layer on the transparent resin coating surface；
The transparent outer layer of the amber decorative layer is formed by the resin slurry including following components：
The heat stabilizer be calcium stearate, zinc stearate, pentaerythrite and calcium-zinc composite stabilizing agent in one or more with
The compound stabilizer of compound rare-earth stabilizer, or for environmentally friendly organic tin stabilizer；
The lubricant is one or more in fatty acid ester type emollients and compounded lubricant.
2. wallpaper according to claim 1, it is characterised in that the compound rare-earth stabilizer is stable for fatty acid rare earth
Agent, salicylic acid rare-earth stabilizer, citric acid rare-earth stabilizer, tartaric acid rare earth stabilizer, malic acid rare-earth stabilizer and carboxylic acid
One or more in ester rare-earth stabilizer；
The fatty acid ester type emollients are in fatty glyceride, fatty acid pentaerythritol ester and aliphatic acid sorbitol ester
One or more；
The compounded lubricant is Tissuemat E and stearic acid with mass ratio (0.1～0.6):(0.1～2.0) the compound profit of compounding
Lubrication prescription.
3. wallpaper according to claim 1 and 2, it is characterised in that in the compound stabilizer is the calcium stearate, hard
One or more in resin acid zinc, pentaerythrite and calcium-zinc composite stabilizing agent is (0.5～3) with the mass ratio of rare-earth stabilizer:
(1～5).
4. wallpaper according to claim 1, it is characterised in that the plasticizer is diethylene glycol dibenzoate and/or second
Acyl ATBC；
The antioxidant is pentaerythrite (2,4- di-tert-butyl-phenyls-phosphorous acid) ester, double (3,5- di-t-butyl -4- hydroxyl benzyls
Base monoethyl phosphate) one kind or several in calcium and 1,6- hexylene glycol double [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic ester]
Kind.
5. wallpaper according to claim 1, it is characterised in that the viscosity of the resin slurry is 3000～10000cps.
6. wallpaper according to claim 1, it is characterised in that the amber decorative layer connects with the transparent resin coating
Area of the contacting surface product less than or equal to the side surface contacted with amber decorative layer in the transparent resin coating.
7. wallpaper according to claim 1, it is characterised in that the substrate layer is nonwoven paper layers, coating ply of paper or linen-cotton
Chemical ＆ blended fabric layer.
8. wallpaper according to claim 1, it is characterised in that the priming coat is PVC systems resin slurry coating, polyurethane
Resin emulsion coating, emulsion acrylic resin coating or fluorocarbon resin emulsion coating.
9. wallpaper according to claim 1, it is characterised in that the transparent resin coating is that acroleic acid polymerization emulsion is applied
Layer.
10. the preparation method of the wallpaper any one of a kind of claim 1～9, it is characterised in that comprise the following steps：
A) primer, drying are coated with or are printed in base material layer surface, form priming coat；
B) in the base coating surface composite diagram line film layer, figure lamina is formed；
C) transparent resin coating, drying are coated with or are printed on the figure lamina surface, form transparent resin coating；
D) amber decorative layer is made on the transparent resin coating surface, obtains amber decorative wall paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611250302.XA CN106638161B (en) | 2016-12-29 | 2016-12-29 | A kind of amber decorative wall paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611250302.XA CN106638161B (en) | 2016-12-29 | 2016-12-29 | A kind of amber decorative wall paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106638161A true CN106638161A (en) | 2017-05-10 |
| CN106638161B CN106638161B (en) | 2018-07-20 |
Family
ID=58836133
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611250302.XA Active CN106638161B (en) | 2016-12-29 | 2016-12-29 | A kind of amber decorative wall paper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106638161B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109208388A (en) * | 2017-07-03 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of oil-stain-preventing wallpaper |
| CN109505198A (en) * | 2018-12-20 | 2019-03-22 | 广东玉兰集团股份有限公司 | A kind of transparent slurry, wallpaper and preparation method thereof |
| CN112876715A (en) * | 2021-01-19 | 2021-06-01 | 科一(福建)超纤有限责任公司 | Environment-friendly TPU cartoon bright-surface antifouling wall leather |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2090388U (en) * | 1991-01-07 | 1991-12-11 | 国家建筑材料工业局南京玻璃纤维研究设计院 | Waterproof compound wall paper |
| JPH0760931A (en) * | 1993-08-31 | 1995-03-07 | Sekisui Chem Co Ltd | Double-layer pattern surface and formation thereof |
| CN203284695U (en) * | 2013-05-10 | 2013-11-13 | 苏州工业园区方圆金属制品有限公司 | Novel PVC fireproof wallpaper for interior decoration |
| CN204401365U (en) * | 2014-12-12 | 2015-06-17 | 广东玉兰装饰材料有限公司 | A kind of Jinsha wallpaper |
| CN105835595A (en) * | 2016-04-19 | 2016-08-10 | 李贺 | Manufacturing process of coal amber decoration painting |
-
2016
- 2016-12-29 CN CN201611250302.XA patent/CN106638161B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2090388U (en) * | 1991-01-07 | 1991-12-11 | 国家建筑材料工业局南京玻璃纤维研究设计院 | Waterproof compound wall paper |
| JPH0760931A (en) * | 1993-08-31 | 1995-03-07 | Sekisui Chem Co Ltd | Double-layer pattern surface and formation thereof |
| CN203284695U (en) * | 2013-05-10 | 2013-11-13 | 苏州工业园区方圆金属制品有限公司 | Novel PVC fireproof wallpaper for interior decoration |
| CN204401365U (en) * | 2014-12-12 | 2015-06-17 | 广东玉兰装饰材料有限公司 | A kind of Jinsha wallpaper |
| CN105835595A (en) * | 2016-04-19 | 2016-08-10 | 李贺 | Manufacturing process of coal amber decoration painting |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109208388A (en) * | 2017-07-03 | 2019-01-15 | 镇江市睿泽文化传播有限公司 | A kind of oil-stain-preventing wallpaper |
| CN109505198A (en) * | 2018-12-20 | 2019-03-22 | 广东玉兰集团股份有限公司 | A kind of transparent slurry, wallpaper and preparation method thereof |
| CN109505198B (en) * | 2018-12-20 | 2022-04-01 | 广东玉兰集团股份有限公司 | Transparent slurry, wallpaper and preparation method thereof |
| CN112876715A (en) * | 2021-01-19 | 2021-06-01 | 科一(福建)超纤有限责任公司 | Environment-friendly TPU cartoon bright-surface antifouling wall leather |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106638161B (en) | 2018-07-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106638161B (en) | A kind of amber decorative wall paper and preparation method thereof | |
| CN201753515U (en) | Ultraviolet light curing direct-printing ink simulation wood grain floor | |
| CN101647654B (en) | Manufacturing process of novel acrylic splicing decorative panel | |
| CN104876469A (en) | Imitation stone paint for preparing imitation sandstone and construction technology of imitation stone paint | |
| CN204662828U (en) | A kind of Novel multilayer composite aluminium moulds plate ornament materials | |
| CN202318502U (en) | Composite wooden board for replacing natural veneers | |
| CN206186655U (en) | Building outer wall decorative board and preparation facilities are drawn to rock colored drawing | |
| CN104499286A (en) | Leatherware repair agent | |
| CN202380363U (en) | Waterproof wallpaper | |
| CN104890430A (en) | Method for producing propylene wall painting | |
| CN206503038U (en) | A kind of amber decorative wall paper | |
| CN201745361U (en) | Demirelief fresco | |
| CN101284976A (en) | Adhesive for adhesive joint between metal and natural wood and method of use thereof | |
| CN211335366U (en) | Holographic copying painting substrate | |
| CN109608993A (en) | 3d art floor coatings | |
| CN206581079U (en) | A kind of novel plastic particle wallpaper | |
| KR20110048199A (en) | A method making patterns for furniture | |
| CN109280442A (en) | Excellent color art coatings of a kind of shell coloured silk piece and preparation method thereof | |
| CN204605246U (en) | A kind of PVC high definition printing film | |
| CN1215668A (en) | Method for mfg. color ink lacquer painting | |
| CN103213452B (en) | A kind of oil painting painting canvas with crackle and preparation method thereof | |
| CN202493013U (en) | Bamboo printed floor board | |
| US20240271414A1 (en) | Apparatus and methods for panels and accessories for use in wet environments such as baths and showers | |
| CN206477519U (en) | One kind foaming wallpaper | |
| CN108047886A (en) | A kind of Water transparent primer for loose putty |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |