CN106638056A - Efficient environment-friendly acid color fixing agent and production method thereof - Google Patents
Efficient environment-friendly acid color fixing agent and production method thereof Download PDFInfo
- Publication number
- CN106638056A CN106638056A CN201611150479.2A CN201611150479A CN106638056A CN 106638056 A CN106638056 A CN 106638056A CN 201611150479 A CN201611150479 A CN 201611150479A CN 106638056 A CN106638056 A CN 106638056A
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- China
- Prior art keywords
- parts
- agent
- color fixing
- benzenediol
- chitin
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Abstract
The invention discloses an efficient environment-friendly acid color fixing agent and a production method thereof. The agent is formed by the following components in pars by weight: 6-8 parts of chitin, 10-20 parts of organic solvent, 1-2 parts of complexing agent, 10-12 parts of fatty alcohol-polyoxyethylene ether, 6-8 parts of benzenediol, 1-2 parts of catalyst, 40-60 parts of water, 5-7 parts of sodium hydroxide, 6-10 parts of epoxy chloropropane, 4-5 parts of dilute sulphuric acid, 1-2 parts of oxidizing agent, 4-8 parts of sodium hydroxide solution and 2-3 parts of penetrant. The agent provided by the invention has environment-friendly materials, without hazardous substances; components of the agent have mutual synergistic effects, so that better color fastness is achieved; fewer auxiliaries are added, so that a wastewater pollution degree is reduced, wastewater treatment costs can be reduced, and significant social and economic benefits can be generated.
Description
Technical field
The present invention relates to color fixing agent field, in particular to a kind of high-efficiency environment protection acidic color fixing agent and preparation method thereof.
Background technology
In recent years, with the raising of people's economic level, the demand of textile is increasing, the requirement to textile
More and more higher, such as requires that clothes are more bright-coloured colorful, it is desirable to which textile production reaches requirement of various standards etc..It is particularly Chinese
After accession to WTO, china textile Dyeing-finishing Industry is developed rapidly.In textile printing and dyeing product, a large amount of polyamide fibres, silk, hair and blended textile are adopted
Use acid dyeing.Polyamide fibre, silk, hair and blended textile are adopted and have after acid dyeing excellent homogenized diet, chromatogram
Complete, easy to use the advantages of, in recent years development is exceedingly fast, and usage amount is increasing.But polyamide fibre, silk, hair and blended textile
It is generally poor using color fastness after acid dyeing, it is difficult to meet the requirement of client and outlet, it is necessary to use acid fixation
Agent is improving color fastness, so factory uses in a large number acidic color fixing agent.But the acidic color fixing agent for the using mostly acidity containing formaldehyde
Color fixing agent, the acidic color fixing agent of most of imports also contains certain formaldehyde, and the country is without high-quality efficiently formaldehydeless environmental protection
Acidic color fixing agent.
The content of the invention
The invention provides a kind of high-efficiency environment protection acidic color fixing agent and preparation method thereof, raw material environmental protection of the present invention, without harmful
Material；Each component has mutually synergy, makes color fixation fastness effect more preferable；Promoter addition is few, can reduce contaminated wastewater degree,
And cost for wastewater treatment can be reduced, obvious Social benefit and economic benefit can be produced.
For achieving the above object, the present invention provides following technical scheme：
A kind of high-efficiency environment protection acidic color fixing agent and preparation method thereof, is made up of following mass fraction formula components：Chitin
6-8 parts, organic solvent 10-20 parts, complexing agent 1-2 parts, AEO 10-12 parts, benzenediol 6-8 parts, catalyst
1-2 parts, water 40-60 parts, NaOH 5-7 parts, epoxychloropropane 6-10 parts, dilute sulfuric acid 4-5 parts, oxidant 1-2 parts, hydroxide
Sodium solution 4-8 parts, bleeding agent 2-3 parts.
Further：It is made up of following mass fraction formula components：6 parts of chitin, 10 parts of organic solvent, 1 part of complexing agent, fat
10 parts of fat alcohol APEO, 6 parts of benzenediol, 1 part of catalyst, 40 parts of water, 5 parts of NaOH, 6 parts of epoxychloropropane, dilute sulphur
4 parts of acid, 1 part of oxidant, 4 parts of sodium hydroxide solution, 2 parts of bleeding agent.
Further：It is made up of following mass fraction formula components：7 parts of chitin, 15 parts of organic solvent, 1.5 parts of complexing agent,
11 parts of AEO, 7 parts of benzenediol, 1.5 parts of catalyst, 50 parts of water, 6 parts of NaOH, 8 parts of epoxychloropropane,
4.5 parts of dilute sulfuric acid, 1.5 parts of oxidant, 6 parts of sodium hydroxide solution, 2.5 parts of bleeding agent.
Further：It is made up of following mass fraction formula components：8 parts of chitin, 20 parts of organic solvent, 2 parts of complexing agent, fat
12 parts of fat alcohol APEO, 8 parts of benzenediol, 2 parts of catalyst, 60 parts of water, 7 parts of NaOH, 10 parts of epoxychloropropane, dilute sulphur
5 parts of acid, 2 parts of oxidant, 8 parts of sodium hydroxide solution, 3 parts of bleeding agent.
Further：Preparation method of the present invention has following steps：
Step one, add in four-hole boiling flask chitin and water, the lower heated material to 80 DEG C of stirring；
Step 2, insulation, by containing AEO, benzenediol, NaOH, epoxychloropropane solution,
Contain the solution of dilute sulfuric acid with another, be slowly dropped within reactor within two hours；
Step 3, reactor are heated to 80～90 DEG C, are incubated 1-2 hours, and the copolymer solution for obtaining is cooled down, then
In being transferred to a cucurbit with thermometer and agitator, still head is guided in the middle of a recover；
Step 4, by reactor with 500 grams of deionized water rinsings, washings are merged in copolymer solution, to same
Mix with surplus stock in cucurbit；
Step 5, cucurbit is slowly warmed up at ambient pressure boiling, collects distillate, the temperature in cucurbit reaches
To 99～120 DEG C, extraction raffinate is finished product.
The invention has the beneficial effects as follows：
1st, raw material environmental protection of the present invention, unharmful substance；
2nd, each component has mutually synergy, makes color fixation fastness effect more preferable；
3rd, promoter addition is few, can reduce contaminated wastewater degree, and can reduce cost for wastewater treatment, can produce obvious society
Can benefit and economic benefit.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of high-efficiency environment protection acidic color fixing agent is made up of following mass fraction formula components：Chitin 6-8 parts, organic solvent
10-20 parts, complexing agent 1-2 parts, AEO 10-12 parts, benzenediol 6-8 parts, catalyst 1-2 parts, water 40-60
Part, NaOH 5-7 parts, epoxychloropropane 6-10 parts, dilute sulfuric acid 4-5 parts, oxidant 1-2 parts, sodium hydroxide solution 4-8 parts,
Bleeding agent 2-3 parts.
Embodiment two：
A kind of high-efficiency environment protection acidic color fixing agent is made up of following mass fraction formula components：6 parts of chitin, organic solvent 10
Part, 1 part of complexing agent, 10 parts of AEO, 6 parts of benzenediol, 1 part of catalyst, 40 parts of water, 5 parts of NaOH, epoxy
6 parts of chloropropane, 4 parts of dilute sulfuric acid, 1 part of oxidant, 4 parts of sodium hydroxide solution, 2 parts of bleeding agent.
Embodiment three：
A kind of high-efficiency environment protection acidic color fixing agent is made up of following mass fraction formula components：7 parts of chitin, organic solvent 15
Part, 1.5 parts of complexing agent, 11 parts of AEO, 7 parts of benzenediol, 1.5 parts of catalyst, 50 parts of water, 6 parts of NaOH,
8 parts of epoxychloropropane, 4.5 parts of dilute sulfuric acid, 1.5 parts of oxidant, 6 parts of sodium hydroxide solution, 2.5 parts of bleeding agent.
Example IV：
A kind of high-efficiency environment protection acidic color fixing agent is made up of following mass fraction formula components：8 parts of chitin, organic solvent 20
Part, 2 parts of complexing agent, 12 parts of AEO, 8 parts of benzenediol, 2 parts of catalyst, 60 parts of water, 7 parts of NaOH, epoxy
10 parts of chloropropane, 5 parts of dilute sulfuric acid, 2 parts of oxidant, 8 parts of sodium hydroxide solution, 3 parts of bleeding agent.
Embodiment five：
A kind of preparation method preparation method of high-efficiency environment protection acidic color fixing agent comprises the steps：
Step one, add in four-hole boiling flask chitin and water, the lower heated material to 80 DEG C of stirring；
Step 2, insulation, by containing AEO, benzenediol, NaOH, epoxychloropropane solution,
Contain the solution of dilute sulfuric acid with another, be slowly dropped within reactor within two hours；
Step 3, reactor are heated to 80～90 DEG C, are incubated 1-2 hours, and the copolymer solution for obtaining is cooled down, then
In being transferred to a cucurbit with thermometer and agitator, still head is guided in the middle of a recover；
Step 4, by reactor with 500 grams of deionized water rinsings, washings are merged in copolymer solution, to same
Mix with surplus stock in cucurbit；
Step 5, cucurbit is slowly warmed up at ambient pressure boiling, collects distillate, the temperature in cucurbit reaches
To 99～120 DEG C, extraction raffinate is finished product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of high-efficiency environment protection acidic color fixing agent, it is characterised in that：It is made up of following mass fraction formula components：
Chitin 6-8 parts, organic solvent 10-20 parts, complexing agent 1-2 parts, AEO 10-12 parts, benzenediol 6-8
Part, catalyst 1-2 parts, water 40-60 parts, NaOH 5-7 parts, epoxychloropropane 6-10 parts, dilute sulfuric acid 4-5 parts, oxidant 1-2
Part, sodium hydroxide solution 4-8 parts, bleeding agent 2-3 parts.
2. a kind of high-efficiency environment protection acidic color fixing agent according to claim 1, it is characterised in that：Filled a prescription by following mass fraction
Into being grouped into：
6 parts of chitin, 10 parts of organic solvent, 1 part of complexing agent, 10 parts of AEO, 6 parts of benzenediol, catalyst 1
Part, 40 parts of water, 5 parts of NaOH, 6 parts of epoxychloropropane, 4 parts of dilute sulfuric acid, 1 part of oxidant, 4 parts of sodium hydroxide solution, infiltration
2 parts of agent.
3. a kind of high-efficiency environment protection acidic color fixing agent according to claim 1, it is characterised in that：Filled a prescription by following mass fraction
Into being grouped into：
7 parts of chitin, 15 parts of organic solvent, 1.5 parts of complexing agent, 11 parts of AEO, 7 parts of benzenediol, catalyst
1.5 parts, 50 parts of water, 6 parts of NaOH, 8 parts of epoxychloropropane, 4.5 parts of dilute sulfuric acid, 1.5 parts of oxidant, sodium hydroxide solution 6
Part, 2.5 parts of bleeding agent.
4. a kind of high-efficiency environment protection acidic color fixing agent according to claim 1, it is characterised in that：Filled a prescription by following mass fraction
Into being grouped into：
8 parts of chitin, 20 parts of organic solvent, 2 parts of complexing agent, 12 parts of AEO, 8 parts of benzenediol, catalyst 2
Part, 60 parts of water, 7 parts of NaOH, 10 parts of epoxychloropropane, 5 parts of dilute sulfuric acid, 2 parts of oxidant, 8 parts of sodium hydroxide solution, infiltration
3 parts of agent.
5. a kind of a kind of preparation method of high-efficiency environment protection acidic color fixing agent according to claim 1, it is characterised in that：Including
Following steps：
Step one, add in four-hole boiling flask chitin and water, the lower heated material to 80 DEG C of stirring；
Step 2, insulation, by containing AEO, benzenediol, NaOH, epoxychloropropane solution, and separately
One solution containing dilute sulfuric acid, is slowly dropped within reactor within two hours；
Step 3, reactor are heated to 80～90 DEG C, are incubated 1-2 hours, and then the copolymer solution for obtaining, cooling proceed to
To in a cucurbit with thermometer and agitator, still head is guided in the middle of a recover；
Step 4, by reactor with 500 grams of deionized water rinsings, washings are merged in copolymer solution, to same distillation
Mix with surplus stock in bottle；
Step 5, cucurbit is slowly warmed up at ambient pressure boiling, collects distillate, the temperature in cucurbit reaches 99
～120 DEG C, extraction raffinate is finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611150479.2A CN106638056A (en) | 2016-12-14 | 2016-12-14 | Efficient environment-friendly acid color fixing agent and production method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611150479.2A CN106638056A (en) | 2016-12-14 | 2016-12-14 | Efficient environment-friendly acid color fixing agent and production method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106638056A true CN106638056A (en) | 2017-05-10 |
Family
ID=58825206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611150479.2A Pending CN106638056A (en) | 2016-12-14 | 2016-12-14 | Efficient environment-friendly acid color fixing agent and production method thereof |
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| Country | Link |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323851A (en) * | 2001-05-24 | 2001-11-28 | 邓卫生 | Environment protection type color fixing agent |
| CN101245563A (en) * | 2008-03-12 | 2008-08-20 | 徐辉 | High-efficiency environment protection acidic color fixing agent and manufacture method thereof |
| CN103334325A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Dye-fixing agent for wool fiber and preparation method thereof |
| CN103603217A (en) * | 2013-11-20 | 2014-02-26 | 上海德桑精细化工有限公司 | Color fixing agent and preparation method thereof |
| CN105735015A (en) * | 2016-03-15 | 2016-07-06 | 季华 | Clothing color fixing agent |
-
2016
- 2016-12-14 CN CN201611150479.2A patent/CN106638056A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323851A (en) * | 2001-05-24 | 2001-11-28 | 邓卫生 | Environment protection type color fixing agent |
| CN101245563A (en) * | 2008-03-12 | 2008-08-20 | 徐辉 | High-efficiency environment protection acidic color fixing agent and manufacture method thereof |
| CN103334325A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Dye-fixing agent for wool fiber and preparation method thereof |
| CN103603217A (en) * | 2013-11-20 | 2014-02-26 | 上海德桑精细化工有限公司 | Color fixing agent and preparation method thereof |
| CN105735015A (en) * | 2016-03-15 | 2016-07-06 | 季华 | Clothing color fixing agent |
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Application publication date: 20170510 |