CN106637991A - Durable waterproof breathable antistatic coating glue used for textiles and a preparing method thereof - Google Patents
Durable waterproof breathable antistatic coating glue used for textiles and a preparing method thereof Download PDFInfo
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- CN106637991A CN106637991A CN201610871870.5A CN201610871870A CN106637991A CN 106637991 A CN106637991 A CN 106637991A CN 201610871870 A CN201610871870 A CN 201610871870A CN 106637991 A CN106637991 A CN 106637991A
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- products
- textiles
- aluminum oxide
- antistatic coating
- coating glue
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Abstract
A preparing method of durable waterproof breathable antistatic coating glue used for textiles is disclosed. The method includes stirring 75-85 parts by weight of a polyurethane adhesive and 1.5-2.0 parts by weight of an associative type polyurethane rheological additive for 30-45 min, adding 5-10 parts by weight of a fluorine type waterproofing agent, stirring the mixture for 20-30 min, then adding 10-15 parts by weight of alumina, stirring the mixture for 20-30 min, filtering the mixture and discharging a product. The glue is particularly suitable for workwear fabrics for petrochemical and electronic product processing industries.
Description
Technical field
The present invention relates to after-finishing of textile products technology, be a kind of waterproof used for textiles, ventilative, antistatic coating glue and
Preparation method.Particularly prepare special industry tooling fabric special function type coating adhesive, the coating processed with this coating adhesive
Product has waterproof, ventilative, anti-static functional feature.
Background technology
Possesses the textile of anti-static function at present using the work for adding conductive filament when padding antistatic agent treatment or weaving
Skill is completing.Both of which has weak point, is wholly absent after the anti-static function washing that padding method is produced.And hatching is produced
Raw anti-static function with conductive filament wearing, wash, stack in fracture and lose most, and do not possess waterproof work(
Energy.
There is the coating product of waterproof and anti-static function on market but there is no airing function.
At present waterproof, ventilative, antistatic three kinds of functions all possess and the coating adhesive product technology with durability not
See there is disclosure.
The content of the invention
It is an object of the invention to provide a kind of durable waterproof used for textiles, ventilative, antistatic coating glue and preparation method.It is special
Yong Yu not petrochemical industry and electronic product machining industry the tooling fabric durable waterproof, ventilative, antistatic coating glue and the preparation side that use
Method.
Present invention durable waterproof used for textiles, ventilative, antistatic coating glue：
Raw material by weight ratio,
Fluorine system waterproofing agent 5-10
Polyurethane binder 75-85
Aluminum oxide 10-15
Association type polyurethane rheological agent 1.5-2.0
It is well mixed prepared：
Product chemical index is as follows：
Outward appearance：Faint yellow thick liquid
It is ionic：Sun
PH value：5±1
Solid content：≥25%
Viscosity：2000-2500mPa.s；
Described fluorine system waterproofing agent：For great Jin fluorination Gong Zhong Co., Ltd TG-581 products；
Described polyurethane binder：For Liaoning Sunichem Co., Ltd.'s FS-5131D products；
Described aluminum oxide：To win the products of wound Degussa Specialty Chemical Co., Ltd AEROXIDE Alu C 805；
Described association type polyurethane rheological agent：For the WT-204 products of De Qian Chemical Co., Ltd.s.
Present invention durable waterproof used for textiles, ventilative, antistatic coating glue preparation method：
Raw material by weight ratio,
Polyurethane binder 75-85, association type polyurethane auxiliary rheological agents 1.5-2.0 are added in stainless steel kettle, is stirred
Mix 30-45 minutes, add fluorine system waterproofing agent 5-10, stir 20-30 minutes, add aluminum oxide 10-15, stir 20-30
Minute, filtering and discharging obtains product.
Described fluorine system waterproofing agent：For great Jin fluorination Gong Zhong Co., Ltd TG-581 products；
Described polyurethane binder：For Liaoning Sunichem Co., Ltd.'s FS-5131D products；
Described aluminum oxide：To win the products of wound Degussa Specialty Chemical Co., Ltd AEROXIDE Alu C 805；
Described association type polyurethane rheological agent：For De Qian Chemical Co., Ltd.s WT-204 products.
Present invention durable waterproof used for textiles, ventilative, antistatic coating glue preparation method are simple.
Present invention durable waterproof used for textiles, ventilative, antistatic coating glue are applied to coating on terylene and nylon fabric.
Fluorine system waterproofing agent（TG-581）C8 structurally waterproof agent, the vinyl chloride segment contained in molecular structure 170 degree with
On bake can be with the congruent melting of chemical ＆ blended fabric strand and in embedded fiber, vinyl chloride segment can also be with polyurethane binder
（FS-5131D）There is addition reaction in the amino in molecule, in adhesive film formation surface washable waterproof layer, fluorine system waterproof are formed
Agent has respectively a binding strength with chemical ＆ blended fabric and polyurethane binder, and the water proofing property of such coating adhesive is provided with washable
Durability.
Polyurethane binder（FS-5131D）It is watersoluble closed property cationic polyurethane resin, at ambient temperature
It is stable, when more than 170 DEG C of heating, discharge NCO（-NCO）, meet water reaction and generate carbon dioxide, carbon dioxide
Gas can form microcellular structure in adhesive film forming, and microcellular structure ensures that coated fabric has good gas permeability, body when wearing
Sense is comfortable.
Aluminum oxide（AEROXIDE®Alu C 805）It is hydrophobic structure and positively charged, polyurethane binder
（FS-5131D）Cationic structural also it is positively charged with aluminum oxide it is positively charged be superimposed the ability with higher neutralization negative electrical charge,
Moment eliminates the electrostatic that fabric is produced, with excellent anti-static function.
Aluminum oxide（AEROXIDE®Alu C 805）It is that hydrophobic structure surface carries water-proof function and fluorine system waterproofing agent（TG-
581）Water-proof function is consistent, all with durable waterproof.
Aluminum oxide（AEROXIDE®Alu C 805）It is powder structure, poly- amino first is dispersed in by high-speed stirred
Acid esters adhesive（FS-5131D）In system, polyurethane binder film forming wherein, realizes alumina-coated and chemical fibre
Fabric has the bonding of fastness, and the anti-static function for making aluminum oxide is provided with washable and durability.
Fluorine system waterproofing agent（TG-581）, polyurethane binder（FS-5131D）, aluminum oxide（AEROXIDE®Alu
C 805）Three function materials compatibilities are good, function can be overlapped mutually raising, baking temperature and play optimal work(for more than 170 DEG C
Energy.
Specific embodiment
Embodiment 1
Polyurethane binder 85, association type polyurethane auxiliary rheological agents 2.0,45 points of stirring at normal temperature are added in stainless steel kettle
Clock, addition fluorine system waterproofing agent 10, stirring at normal temperature 30 minutes, addition aluminum oxide 13, stirring at normal temperature 30 minutes, filtering and discharging must be produced
Product.
Embodiment 2
Polyurethane binder 83, association type polyurethane auxiliary rheological agents 1.8,45 points of stirring at normal temperature are added in stainless steel kettle
Clock, addition fluorine system waterproofing agent 7, stirring at normal temperature 30 minutes, addition aluminum oxide 15, stirring at normal temperature 30 minutes, filtering and discharging obtains product.
Embodiment 3
Polyurethane binder 80, association type polyurethane auxiliary rheological agents 1.6,45 points of stirring at normal temperature are added in stainless steel kettle
Clock, addition fluorine system waterproofing agent 6, stirring at normal temperature 30 minutes, addition aluminum oxide 12, stirring at normal temperature 30 minutes, filtering and discharging obtains product.
Embodiment 4
Polyurethane binder 75, association type polyurethane auxiliary rheological agents 1.5,45 points of stirring at normal temperature are added in stainless steel kettle
Clock, addition fluorine system waterproofing agent 5, stirring at normal temperature 30 minutes, addition aluminum oxide 10, stirring at normal temperature 30 minutes, filtering and discharging obtains product.
Described in above-described embodiment：
Fluorine system waterproofing agent：For great Jin fluorination Gong Zhong Co., Ltd TG-581 products；
Polyurethane binder：For Liaoning Sunichem Co., Ltd.'s FS-5131D products；
Aluminum oxide：To win the products of wound Degussa Specialty Chemical Co., Ltd AEROXIDE Alu C 805；
Association type polyurethane rheological agent：For De Qian Chemical Co., Ltd.s WT-204 products.
Testing inspection
1st, base fabric fabric：Polyamide fibre 20D/380T, base fabric uses in advance nylon roller calendering（90 DEG C of pressure 10MPa, temperature）, then rolling
Optical surface carries out a coating（Coating knife thickness 1.5mm）, enter baking oven and bake (170 DEG C of temperature, 60 seconds time), do weightening 8-10g/
m2, obtain coating product.
Performance test results such as following table.
2nd, base fabric fabric：Terylene 50D/260T, base fabric uses in advance nylon roller calendering（90 DEG C of pressure 10MPa, temperature）, Ran Hou
Calendering surface carries out a coating（Coating knife thickness 1.5mm）, enter baking oven and bake (170 DEG C of temperature, 60 seconds time), do weightening 8-
10g/m2, obtain coating product.
Performance test results such as following table.
Testing standard：
1st, moisture resistance is adopted：The detection and evaluation of GB/T4745-2012 textile water proof performances gets wet method.5 grades is the superlative degree,
The higher cloth cover of the rank less water proofing property of area that gets wet is also better.
2nd, half-life employing：The evaluation Part I electrostatic pressure of GB/T12703.1-2008 textile antistatic properties partly declines
Phase.It is within 0 second best, it is faster that time shorter explanation eliminates electrostatic speed.
3rd, air penetrability is adopted：The measure of GB/T5453-1997 textile fabric gas permeabilities.Air penetrability is more than 0 cm3/cm2/
Behalf has gas permeability
4th, washability is adopted：GB/T8629-2001 Textile Tests home washings and drying program.
Can be seen that from test result after the coating of polyamide fibre 20D/380T and terylene 50D/260T：
Moisture resistance（Level）Reach after washing before washing more than 4 grades, water proofing property it is outstanding；
Half-life（s）Within reaching after washing before washing 1 second, antistatic behaviour it is outstanding；
Air penetrability（cm3/cm2/s）1 cm is reached after washing before washing3/cm2/ more than s, gas permeability makes body-sensing comfortable.
Claims (3)
1. durable waterproof used for textiles, ventilative, antistatic coating glue, is characterized in that：
Raw material is by weight ratio
Fluorine system waterproofing agent 5-10
Polyurethane binder 75-85
Aluminum oxide 10-15
Association type polyurethane rheological agent 1.5-2.0
It is well mixed prepared：
Product chemical index is as follows：
Outward appearance：Faint yellow thick liquid
It is ionic：Sun
PH value：5±1
Solid content：≥25%
Viscosity：2000-2500mPa.s；
Described fluorine system waterproofing agent：For great Jin fluorination Gong Zhong Co., Ltd TG-581 products；
Described polyurethane binder：For Liaoning Sunichem Co., Ltd.'s FS-5131D products；
Described aluminum oxide：To win the products of wound Degussa Specialty Chemical Co., Ltd AEROXIDE Alu C 805；
Described association type polyurethane rheological agent：For the WT-204 products of De Qian Chemical Co., Ltd.s.
2. durable waterproof used for textiles, ventilative, antistatic coating glue preparation method, its thing is levied and is：
Raw material by weight ratio,
Polyurethane binder 75-85, association type polyurethane auxiliary rheological agents 1.5-2.0 are added in stainless steel kettle, is stirred
Mix 30-45 minutes, add fluorine system waterproofing agent 5-10, stir 20-30 minutes, add aluminum oxide 10-15, stir 20-30
Minute, filtering and discharging obtains product；
Described fluorine system waterproofing agent：For great Jin fluorination Gong Zhong Co., Ltd TG-581 products；
Described polyurethane binder：For Liaoning Sunichem Co., Ltd.'s FS-5131D products；
Described aluminum oxide：To win the products of wound Degussa Specialty Chemical Co., Ltd AEROXIDE Alu C 805；
Described association type polyurethane rheological agent：For De Qian Chemical Co., Ltd.s WT-204 products.
3. such as claim 1 preparation method is obtained durable waterproof used for textiles, ventilative, antistatic coating glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610871870.5A CN106637991A (en) | 2016-10-03 | 2016-10-03 | Durable waterproof breathable antistatic coating glue used for textiles and a preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610871870.5A CN106637991A (en) | 2016-10-03 | 2016-10-03 | Durable waterproof breathable antistatic coating glue used for textiles and a preparing method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106637991A true CN106637991A (en) | 2017-05-10 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610871870.5A Pending CN106637991A (en) | 2016-10-03 | 2016-10-03 | Durable waterproof breathable antistatic coating glue used for textiles and a preparing method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064905A (en) * | 1991-03-18 | 1992-09-30 | 胡伯康 | The dyeing and finishing method of many anti-(waterproof, fire-retardant, anticorrosion, antistatic etc.) fabric |
| CN1193639A (en) * | 1998-04-29 | 1998-09-23 | 王国真 | Anti-electrostatic powder coating material and spraying method |
| CN102108638A (en) * | 2010-12-08 | 2011-06-29 | 辽宁恒星精细化工有限公司 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
| CN102277721A (en) * | 2011-06-28 | 2011-12-14 | 东华大学 | Method for finishing nanometer aluminum oxide fluoride-free superhydrophobic textile fabric |
| CN102493200A (en) * | 2011-12-05 | 2012-06-13 | 辽宁恒星精细化工有限公司 | Waterproof ventilating anti-mosquito coating glue for textile and preparation method |
| CN104695251A (en) * | 2015-02-12 | 2015-06-10 | 南通奥斯特鞋业有限公司 | Anti-static radiation protection fabric and manufacturing method thereof |
-
2016
- 2016-10-03 CN CN201610871870.5A patent/CN106637991A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064905A (en) * | 1991-03-18 | 1992-09-30 | 胡伯康 | The dyeing and finishing method of many anti-(waterproof, fire-retardant, anticorrosion, antistatic etc.) fabric |
| CN1193639A (en) * | 1998-04-29 | 1998-09-23 | 王国真 | Anti-electrostatic powder coating material and spraying method |
| CN102108638A (en) * | 2010-12-08 | 2011-06-29 | 辽宁恒星精细化工有限公司 | Durable, waterproof, oil-proof, antistatic and antibacterial functional coating adhesive and preparation method |
| CN102277721A (en) * | 2011-06-28 | 2011-12-14 | 东华大学 | Method for finishing nanometer aluminum oxide fluoride-free superhydrophobic textile fabric |
| CN102493200A (en) * | 2011-12-05 | 2012-06-13 | 辽宁恒星精细化工有限公司 | Waterproof ventilating anti-mosquito coating glue for textile and preparation method |
| CN104695251A (en) * | 2015-02-12 | 2015-06-10 | 南通奥斯特鞋业有限公司 | Anti-static radiation protection fabric and manufacturing method thereof |
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Application publication date: 20170510 |