CN106637972A - Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof - Google Patents

Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof Download PDF

Info

Publication number
CN106637972A
CN106637972A CN201611144308.9A CN201611144308A CN106637972A CN 106637972 A CN106637972 A CN 106637972A CN 201611144308 A CN201611144308 A CN 201611144308A CN 106637972 A CN106637972 A CN 106637972A
Authority
CN
China
Prior art keywords
parts
cashmere
collagen
adds
skin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611144308.9A
Other languages
Chinese (zh)
Inventor
张永超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Martial Prowess Cashmere Product Co Ltd
Original Assignee
Anhui Martial Prowess Cashmere Product Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Martial Prowess Cashmere Product Co Ltd filed Critical Anhui Martial Prowess Cashmere Product Co Ltd
Priority to CN201611144308.9A priority Critical patent/CN106637972A/en
Publication of CN106637972A publication Critical patent/CN106637972A/en
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/15—Proteins or derivatives thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D01F1/103—Agents inhibiting growth of microorganisms
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11—Compounds containing epoxy groups or precursors thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40—Fibres of carbon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Abstract

The invention discloses antioxidant skin-friendly collagen and cashmere composite fabric and a production method thereof. The fabric is formed by the following materials in parts by weight: 42-45 parts of cashmere fibers, 13-15 parts of ES binding fibers, 18-20 parts of white bamboo carbon fibers, 8.5-9.1 parts of pure collagen powder, 2.5-3.1 parts of ethylene glycol diglycidyl ether, 3-4 parts of wheat protein powder, 1-2 parts of nanometer kieselguhr, 2.1-2.4 parts of grape seed extract, 1-2 parts of vinyl acetate-acrylic emulsion, 0.4-0.7 part of linseed oil, 0.9-1.2 parts of isobutyltriethoxysilane, 190-195 parts of 1-allyl-3-methimidazole chloride, and a proper amount of water. According to a production method of the fabric provided by the invention, oxygen low-temperature plasma is used for pre-processing, and then the ethylene glycol diglycidyl ether is used as a cross-linking agent for grafting the modified collagen onto the surfaces of the cashmere composite fibers. The produced cashmere composite fabric has silky hand feeling, and is skin-friendly, antioxidant and long in service life.

Description

A kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric and preparation method thereof
Technical field
The present invention relates to textile material technical field, more particularly to a kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric And preparation method thereof.
Background technology
Cashmere fiber is a kind of natural precious textile material, and in recent years, cashmere apparel product is competing in fierce garment market In striving with its comfortable feel, color and luster is unique, quality is frivolous, heat-insulation breathable is good the features such as be increasingly subject to consumers.But As ecological environment opposite applies flexibly the friendly requirement of light green color, health, comfortable, environmental protection, the safe consumption master for having become people Topic.Therefore, using environmental pollution is little or free of contamination process technology, exploitation with skin-friendly and the features such as emollient, can The high-grade cashmere fabric for lifting its added value of product is the direction for being worth research.
Collagen has low antigenicity, superior biocompatibility and biological degradability, in biomedical material, medicine Many fields such as delivery vehicles, organizational project, cosmetics, food have critically important status.Especially in recent years, with collagen egg White bioaffinity is at the aspect such as textile material is modified, compound gradually into focus.Collagen can be given necessary to skin layer Nutrient, strengthens the collagen activity in skin, keeps the integrality of cuticula moisture and fibre structure, improves skin thin The physiology circulation of born of the same parents' living environment and enhancing skin histology.Once collagen is securable to cashmere fiber, then may produce The various health care functions such as skin care, anti-aging and whitening,《Using plasma-crosslinking agent complex technique in cashmere fiber Collagen is fixed on surface》One literary grace pre-processes cashmere fiber with oxygen low temperature plasma, using ethylene glycol diglycidyl Collagen is grafted onto cashmere surface by ether as crosslinking agent, as a result shows absorb-discharge humid and the dyeing of collagen modification cashmere fiber Property is superior to untreatment fiber.In addition, the fixation of collagen has certain changing to the ultimate strength and extension at break of fiber Kind effect.
The absorb-discharge humid and dyeability of cashmere are only improved in text, but cashmere yield is few expensive, pure cashmere is such as Fruit stores the improper even raw mite that goes mouldy that can make moist because of the humidity of environment, due to the intensity of cashmere itself it is poor, it is washed how easy Crushing, conglomeration, balling-up, the especially cold north are dried, and cashmere product is also also easy to produce electrostatic etc..So that develop having Multifunctional novel collagen Cashmere composite shell fabric.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of anti-oxidant pro-skin collagen cashmere is answered Close fabric and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric, is prepared by the raw materials in：Cashmere fiber 42-45, ES binder fibre 13-15, white bamboo-carbon fibre 18-20, pure collagen protein powder 8.5-9.1, ethylene glycol diglycidylether 2.5- 3.1st, gluten powder 3-4, nano diatomite 1-2, grape seed extract 2.1-2.4, acrylate and vinyl acetate emulsion 1-2, linseed oil 0.4- 0.7th, isobutyl triethoxy silane 0.9-1.2,1- pi-allyls -3- methylimidazole villaumites 190-195, suitable quantity of water.
The preparation method of described a kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric, comprises the following steps：
（1）By nano diatomite in 455-480 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds isobutyl group Triethoxysilane stirs 10-15 minutes, is vacuum dried to obtain modified Nano diatomite；
（2）Gluten powder is dried into ground 100 mesh sieve, sprinkling acrylate and vinyl acetate emulsion is stirred and evenly mixed, in 60-80 DEG C of water bath with thermostatic control Magnetic agitation 2-3 hour, washs to neutral vacuum drying, adds linseed oil ultrasonic grinding 1-3 hours, dries to obtain modified wheat egg White superfine powder；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, ES binder fibres, white bamboo charcoal fibre Dimension grinding 20-40 minutes, 100-120 DEG C is heated to, adds step（2）Material, grape seed extract stirring reaction 50-70 point Clock, spinning, drying is put into reaction chamber, using oxygen low temperature plasma, in electric discharge pressure 150Pa, power 120W 1 point is processed Clock, obtains plasma pretreatment cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control toward pure collagen protein powder to be stirred continuously to whole dissolvings, add Step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two 10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air It is dry, discharging.
It is an advantage of the invention that：Optimization of C/C composites of the present invention improves production technology, by ES binder fibres, white bamboo-carbon fibre and sheep Down Fiber is combined, and cashmere composite fibre is obtained by binding agent Jing wet spinnings of modified wheat albumen superfines, not only alleviates Easily go mouldy life because the problem that the cashmere fiber that environmental degradation brings is reduced year by year also overcomes pure cashmere product balling-up, low intensity The defects such as mite, are finally pre-processed obtained cashmere composite fibre using oxygen low temperature plasma, to fibrous inside Less environmentally safe is damaged, plasma can etch the scale on cashmere surface, make scale layer thinning, weaken surface scale " barrier " effect, so as to strengthen its humidity absorption and release, improve hydrophily of the cashmere during follow-up dyeing and finishing etc., be then used by Modified collagen is grafted onto cashmere surface by ethylene glycol diglycidylether as crosslinking agent, because collagen is also belonged to The good protein of performance of keeping humidity, improves the skin-friendly and beauty and health care performance of fabric, obtained cashmere composite surface after crosslinking Material feel cunning is glutinous, and pro-skin is anti-oxidant, long service life.
Specific embodiment
A kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric, is prepared by the raw materials in：Cashmere fiber 42, ES binder fibres 13, white bamboo-carbon fibre 18, pure collagen protein powder 8.5, ethylene glycol diglycidylether 2.5, gluten powder 3, Nano diatomite 1, grape seed extract 2.1, acrylate and vinyl acetate emulsion 1, linseed oil 0.4, isobutyl triethoxy silane 0.9,1- allyls Base -3- methylimidazole villaumites 190, suitable quantity of water.
The preparation method of described a kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric, comprises the following steps：
（1）By nano diatomite in 455-480 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds isobutyl group Triethoxysilane stirs 10-15 minutes, is vacuum dried to obtain modified Nano diatomite；
（2）Gluten powder is dried into ground 100 mesh sieve, sprinkling acrylate and vinyl acetate emulsion is stirred and evenly mixed, in 60-80 DEG C of water bath with thermostatic control Magnetic agitation 2-3 hour, washs to neutral vacuum drying, adds linseed oil ultrasonic grinding 1-3 hours, dries to obtain modified wheat egg White superfine powder；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, ES binder fibres, white bamboo charcoal fibre Dimension grinding 20-40 minutes, 100-120 DEG C is heated to, adds step（2）Material, grape seed extract stirring reaction 50-70 point Clock, spinning, drying is put into reaction chamber, using oxygen low temperature plasma, in electric discharge pressure 150Pa, power 120W 1 point is processed Clock, obtains plasma pretreatment cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control toward pure collagen protein powder to be stirred continuously to whole dissolvings, add Step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two 10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air It is dry, discharging.
The bacteriostasis rate of staphylococcus aureus can reach using collagen Cashmere composite shell fabric obtained in the present invention 96.748%；Average ultimate strength is 8.88cN；Dyeing dye uptake can reach 98%.

Claims (2)

1. a kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric, it is characterised in that be prepared by the raw materials in：Sheep Down Fiber 42-45, ES binder fibre 13-15, white bamboo-carbon fibre 18-20, pure collagen protein powder 8.5-9.1, ethylene glycol two shrink Glycerin ether 2.5-3.1, gluten powder 3-4, nano diatomite 1-2, grape seed extract 2.1-2.4, acrylate and vinyl acetate emulsion 1-2, Asia Sesame oil 0.4-0.7, isobutyl triethoxy silane 0.9-1.2,1- pi-allyl -3- methylimidazole villaumites 190-195, suitable quantity of water.
2. the preparation method of a kind of anti-oxidant pro-skin collagen Cashmere composite shell fabric according to claim 1, its feature It is to comprise the following steps：
（1）By nano diatomite in 455-480 DEG C of high-temperature calcination 20-30 minute, it is cooled to 100-120 DEG C of constant temperature and adds isobutyl group Triethoxysilane stirs 10-15 minutes, is vacuum dried to obtain modified Nano diatomite；
（2）Gluten powder is dried into ground 100 mesh sieve, sprinkling acrylate and vinyl acetate emulsion is stirred and evenly mixed, in 60-80 DEG C of water bath with thermostatic control Magnetic agitation 2-3 hour, washs to neutral vacuum drying, adds linseed oil ultrasonic grinding 1-3 hours, dries to obtain modified wheat egg White superfine powder；
（3）1- pi-allyl -3- methylimidazole villaumites is put into and add in reactor cashmere fiber, ES binder fibres, white bamboo charcoal fibre Dimension grinding 20-40 minutes, 100-120 DEG C is heated to, adds step（2）Material, grape seed extract stirring reaction 50-70 point Clock, spinning, drying is put into reaction chamber, using oxygen low temperature plasma, in electric discharge pressure 150Pa, power 120W 1 point is processed Clock, obtains plasma pretreatment cashmere composite fibre；
（4）Add suitable quantity of water to be put in 85-95 DEG C of water bath with thermostatic control toward pure collagen protein powder to be stirred continuously to whole dissolvings, add Step（1）Material ultrasonic disperse 30-40 minutes obtain modified collagen albumen dressing liquid；
（5）By step（3）Material puts into step（4）In dressing liquid, keeping temperature adds water and adjusts bath raio 1: 50, adds ethylene glycol two 10-15 minutes are placed in glycidol ether stirring, are cooled to 25 DEG C and react 24 hours, take out, and clean with distilled water flushing, room temperature is dried in the air It is dry, discharging.
CN201611144308.9A 2016-12-13 2016-12-13 Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof Pending CN106637972A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611144308.9A CN106637972A (en) 2016-12-13 2016-12-13 Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611144308.9A CN106637972A (en) 2016-12-13 2016-12-13 Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof

Publications (1)

Publication Number Publication Date
CN106637972A true CN106637972A (en) 2017-05-10

Family

ID=58824928

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611144308.9A Pending CN106637972A (en) 2016-12-13 2016-12-13 Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof

Country Status (1)

Country Link
CN (1) CN106637972A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101134852A (en) * 2007-10-15 2008-03-05 江苏河海纳米科技股份有限公司 Inorganic powder organic surface modifying method
CN104213415A (en) * 2014-08-22 2014-12-17 浙江全美实业有限公司 Production method of anti-pilling cashmere sweater
CN104862818A (en) * 2015-06-09 2015-08-26 江南大学 Preparation method of keratin complex fiber
CN104911737A (en) * 2015-05-20 2015-09-16 铜陵宏正网络科技有限公司 Nanometer antibacterial mothproof cashmere composite fiber and manufacturing method thereof
CN105239413A (en) * 2015-11-12 2016-01-13 长兴千尺度纺织品有限公司 Application of ecological auxiliary in finishing of cashmere sweater
CN105839409A (en) * 2016-03-25 2016-08-10 赤峰昭乌达羊绒制品有限责任公司 Ecotype anti-pilling finishing method for cashmere knitted fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101134852A (en) * 2007-10-15 2008-03-05 江苏河海纳米科技股份有限公司 Inorganic powder organic surface modifying method
CN104213415A (en) * 2014-08-22 2014-12-17 浙江全美实业有限公司 Production method of anti-pilling cashmere sweater
CN104911737A (en) * 2015-05-20 2015-09-16 铜陵宏正网络科技有限公司 Nanometer antibacterial mothproof cashmere composite fiber and manufacturing method thereof
CN104862818A (en) * 2015-06-09 2015-08-26 江南大学 Preparation method of keratin complex fiber
CN105239413A (en) * 2015-11-12 2016-01-13 长兴千尺度纺织品有限公司 Application of ecological auxiliary in finishing of cashmere sweater
CN105839409A (en) * 2016-03-25 2016-08-10 赤峰昭乌达羊绒制品有限责任公司 Ecotype anti-pilling finishing method for cashmere knitted fabric

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
康红波: "应用等离子体-交联剂复合技术在羊绒纤维表面固定胶原蛋白", 《毛纺科技》 *

Similar Documents

Publication Publication Date Title
CN104997206B (en) A kind of bamboo fiber garment fabric with bacteriostasis
CN104264321B (en) A kind of processing method of imitative peach face fabric
CN107974828A (en) A kind of preparation method of the special antibacterial wool fiber of wool cap
CN106637486A (en) Anti-fatigue collagen cashmere composite fabric and manufacturing method thereof
CN102268820A (en) Preparation method of anti-ultraviolet knitted coated fabric
CN107009712A (en) A kind of environment-friendly insulating fabric
CN102260933A (en) Milk protein blending regenerating cellulose fiber, and preparation process and application thereof
CN102215815A (en) Mask pack comprising cosmetic cotton-like material prepared from paper mulberry
CN106835703A (en) A kind of new anti pilling natural plants antibacterial Cashmere composite shell fabric and preparation method thereof
CN106637909A (en) Warm collagen and cashmere composite fabric with high thermal stability and production method thereof
CN106757766B (en) A kind of collagen fabric cellulose fiber spunlace non-woven cloth and its production method
CN108754778A (en) A kind for the treatment of process of silk, blend polyester fabric
CN106637972A (en) Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof
CN106757442A (en) A kind of oil-stain-preventing collagen Cashmere composite shell fabric and preparation method thereof
CN105755855A (en) Production technology of water-proof cloth
CN106637974A (en) Collagen-cashmere composite fabric with good drapability and preparation method of collagen-cashmere composite fabric
CN106637970A (en) Anti-electromagnetic radiation collagen cashmere composite fabric and making method thereof
CN106085300B (en) A kind of compound flocking adhesive of white fungus
CN106811971A (en) A kind of natural plants antibacterial Cashmere composite shell fabric with fatigue resistance and preparation method thereof
CN106811969A (en) A kind of antistatic natural plants antibacterial Cashmere composite shell fabric and preparation method thereof
CN109591390A (en) A kind of anti-ultraviolet fabric and preparation method thereof that sun-proof performance is good
CN106637971A (en) Flame-retardant and anti-pilling collagen-cashmere composite fabric and making method thereof
CN106637910A (en) Antistatic collagen-cashmere composite fabric and production method thereof
CN106637973A (en) Mothproof collagen/cashmere composite fabric and preparation method thereof
CN107502981A (en) A kind of processing technology of down jackets antibacterial protection against the tide eider down

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170510