CN104213415A - Production method of anti-pilling cashmere sweater - Google Patents

Production method of anti-pilling cashmere sweater Download PDF

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Publication number
CN104213415A
CN104213415A CN201410417581.9A CN201410417581A CN104213415A CN 104213415 A CN104213415 A CN 104213415A CN 201410417581 A CN201410417581 A CN 201410417581A CN 104213415 A CN104213415 A CN 104213415A
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Prior art keywords
cashmere
twisting
twist
fingers
fabric
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CN201410417581.9A
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CN104213415B (en
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陈冰梅
马丽芳
杨华英
李丽红
张秀玲
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Zhejiang Meimei Garment Technology Group Co., Ltd
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Whole America Zhejiang Industrial Co Ltd
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Abstract

The invention discloses a production method of an anti-pilling cashmere sweater. The production method comprises the following steps: (1) selecting cashmere fibers and milk protein fibers for spinning; (2) twisting; (3) weaving and tailoring; (4) carrying out anti-pilling treatment; and (5) inspecting finished products, packaging and warehousing.

Description

A kind of production method of balling resistant cashmere sweater
Technical field
The present invention relates to a kind of production method of goat fleecy sweatshirt, particularly a kind of processing technology of ANTIPILLING goat fleecy sweatshirt.
Background technology
Fabric is in the process of processing, dress and washing, effects such as constantly standing to rub, rub and be bending, in the time that the interfibrous frictional force of fabric is less than the extraneous resistance that fiber is subject to, its surperficial fibre end is exposed to fabric, present much tedious fine hair at fabric face, this fine hair is just called " fluffing "; If these fine hair can not come off in time in continuing dress and washing, just mutual tied up in knots, is kneaded into many spherical granules, is " balling-up ".
Cashmere sweater is the clothes that form as raw material is knitting taking goat cashmere.Be divided into slubbing according to yarn classification knitting and spinning knitting two kinds, can be divided into two kinds of pure cashmere and cashmere blending according to material rate.Feel jewelry, expensive clothing and other valuables, soft and smooth, glossy, warmth retention property is good, comfortable and easy to wear, but intensity is poor.Because cashmere fiber surface has scale and fiber is short thin, between fiber, cohesive force is poor, in dress and washing, has serious pilling effect, affects presentation quality and the service life of cashmere sweater.
Afterfinish method is the key factor that affects cashmere knit goods pilling.At present, cashmere knit goods mainly takes to reach by the mode that silicone oil auxiliary agent arranges the effect of ANTIPILLING.
Enzyme is a kind of pure biologic product, health environment-friendly noresidue, and also enzyme treatment temperature is low, less energy consumption, can not cause environmental pollution, belongs to green technology, and process after cashmere feel softness abundant, be difficult for the advantages such as yellowing, its application in textile industry will be more and more wider.Prior art discloses the cashmere through enzyme processing, not only has the performance of anti-fulling milling, and has reduced the rigidity of cashmere, make it to be easy to stretch and do not bounce back, increased the elasticity of cashmere simultaneously, its feel is also relatively soft, thereby make cashmere become sliding and thin, be rich in cashmere sense.Reducing under the prerequisite of cashmere cortical layer damage as far as possible, enzyme processing section or divest fully cashmere scale, has brought gratifying variation to cashmere wearability, processing characteristics, as spinning high-count yarn, knit cloister fabric processed, improve gloss, feel, wettability power.And had people by papain the anti-shrinking for cashmere, and the function of limited reduction fleece fabrics balling-up.
But although the disclosed enzyme processing mode of prior art has a comparatively desirable effect to shrinkproof, very general to the effect of ANTIPILLING.
The production technology that the present invention aims to provide a kind of process and do not add the ANTIPILLING goat fleecy sweatshirt of chemical reagent as far as possible, this process takes full advantage of biology enzyme and native protein, by lot of experiment validation the most optimized parameter of production technology, made cashmere sweater has good ANTIPILLING effect.
Summary of the invention
Based on the technical problem of background technology existence, the present invention is directed to the shortcoming of the processing method of current cashmere sweater, a kind of processing technology of ANTIPILLING goat fleecy sweatshirt of new environmental protection is provided.
The present invention's biology enzyme used is papain.
Papain is to utilize the milk in immature papaya fruit to refine the neutral protease forming, belong to peptide protease in sulfydryl, there is wider substrate specificity, act on L-arginine in protein, 1B, glycine and Cit residue carboxyl and participate in the peptide bond forming, the polypeptide class that can cut holoprotein intramolecule peptide chain-CO-NH-generation molecular weight, has been applied to the process such as medicine, food, feed, leather and weaving.As a kind of fabric protease, in the time that it is shrinkproof for cashmere, the hydrolysis rate of epicuticula albumen is equated with globular preteins hydrolysis rate or close, reach the hydrolysis pattern effect of uniform treatment, and the effect that makes protease is concentrated on cashmere surface by this hydrolysis pattern, do not have " rotten core " phenomenon, thereby the damage of the mechanical property of cashmere is less.
On shitosan macromolecular chain, contain amino and two kinds of active reactive groups of hydroxyl simultaneously.Utilize the reactivity of amino or hydroxyl, on its macromolecular chain, can carry out carboxylation reaction, conventionally have the product of three types: a.O-using carboxyl chitosan: under alkali condition, by controlling reaction condition, can synthesize CARB OXYMETHYL-CHITOSAN; B.N-using carboxyl chitosan: a kind of method is the radical reaction that shitosan first contains carbonyl with glyoxalic acid and levulic acid etc., obtains schiff bases, and then with sodium borohydride reduction and get final product; Another kind method is direct with shitosan and anhydride reaction obtains corresponding carboxylation product; C.N, O-using carboxyl chitosan: in alcohol or alkali systems, react with shitosan with carboxylic alkyl halide, can obtain the derivative that N, O-replace.
Carboxylated shitosan, not only has good water-soluble and certain bacteriostasis, and its moisture-absorbing moisture-keeping performance is close to hyaluronic acid.
Collagen has special structure and function, and tool has been widely used.And protein content in pigskin is up to 33%, wherein collagen content is 87.8%, and pigskin collagen is a kind of economical and practical, is applicable to the collagen of suitability for industrialized production.
Technical scheme of the present invention is as follows:
(1) choose cashmere fiber and milk protein fiber blending, the fineness of described cashmere is 25 μ m, and length is 26mm.Described milk protein fiber fineness is 32 μ m, length 40mm, and described cashmere and milk protein fiber are according to mass ratio 5:1 blending;
(2) twisting: make cashmere blended yarn single twist: 560 sth. made by twisting/m, twist with the fingers to twisting with the fingers for Z; In double twisting step, make the cashmere blended yarn plying twist: 350 sth. made by twisting/m, twist with the fingers to twisting with the fingers for S; Its plying is 0.51 with single twist ratio;
(3) then through braiding, ready-made clothes;
(4) ANTIPILLING processing:
A. add the olive oil of 2g/ (kg fabric), and water-wet fleece fabrics, then by 90 DEG C of hot water treatment 10min for fleece fabrics, then with 1.1~1.6% (owf) papain at 55 DEG C, pH=7.0 processes 90min afterwash;
B. carboxylated shitosan is equipped to the aqueous solution of 0.2~0.3% mass percent, the fabric that step 1 is obtained soaks wherein, dipping 3hr, natural air drying;
C. again with 3% (owf) papain at 59 DEG C, pH=7.0 processes 30min afterwash, the enzyme that then goes out in 90 DEG C of hot water is processed 5min, natural air drying;
D. after air-dry, to the pigskin collagen solution of fabric spray mass percent 0.1%, wetting;
E. fully vexed fleece fabrics putting left standstill to 1 day, 60 DEG C of low temperature dryings, flatiron;
(5) finished product inspection, packaging warehouse-in: ANTIPILLING cashmere sweater finished product after treatment is tested, pack warehouse-in through after the assay was approved.
Usefulness of the present invention is:
1, cashmere sweater of the present invention can make yarn entirety keep soft, and the suffered binding force of fiber in yarn is strengthened, and more difficultly while being subject to rubbing from yarn, skids off;
2, ANTIPILLING is processed and is not added chemical industry preparation, has added biology enzyme and the biomolecule of natural environmental-protective noresidue, and has optimized reaction condition, obtains the high-grade cashmere product of indices excellence;
3, treatment temperature is low, and less energy consumption can not cause environmental pollution, belongs to green technology.
Detailed description of the invention
Embodiment 1:
(1) choose cashmere fiber and milk protein fiber blending, the fineness of described cashmere is 25 μ m, and length is 26mm.Described milk protein fiber fineness is 32 μ m, length 40mm, and described cashmere and milk protein fiber are according to mass ratio 5:1 blending;
(2) twisting: make cashmere blended yarn single twist: 560 sth. made by twisting/m, twist with the fingers to twisting with the fingers for Z; In double twisting step, make the cashmere blended yarn plying twist: 350 sth. made by twisting/m, twist with the fingers to twisting with the fingers for S; Its plying is 0.51 with single twist ratio;
(3) then through braiding, ready-made clothes;
(4) ANTIPILLING processing:
A. add the olive oil of 2g/kg fabric, and water-wet fleece fabrics, then by 90 DEG C of hot water treatment 10min for fleece fabrics, then with 1.1% (owf) papain at 55 DEG C, pH=7.0 processes 90min afterwash;
B. carboxylated shitosan is equipped to the aqueous solution of mass percent 0.2%, the fabric that step 1 is obtained soaks wherein, dipping 3hr, natural air drying;
C. again with 3% (owf) papain at 59 DEG C, pH=7.0 processes 30min afterwash, the enzyme that then goes out in 90 DEG C of hot water is processed 5min, natural air drying;
D. after air-dry, to fabric spray mass percent 0.1% pigskin collagen solution, wetting;
E. fully vexed fleece fabrics putting left standstill to 1 day, 60 DEG C of low temperature dryings, flatiron;
(5) finished product inspection, packaging warehouse-in: ANTIPILLING cashmere sweater finished product after treatment is tested, pack warehouse-in through after the assay was approved.
Embodiment 2:
(1) choose cashmere fiber and milk protein fiber blending, the fineness of described cashmere is 25 μ m, and length is 26mm.Described milk protein fiber fineness is 32 μ m, length 40mm, and described cashmere and milk protein fiber are according to mass ratio 5:1 blending;
(2) twisting: make cashmere blended yarn single twist: 560 sth. made by twisting/m, twist with the fingers to twisting with the fingers for Z; In double twisting step, make the cashmere blended yarn plying twist: 350 sth. made by twisting/m, twist with the fingers to twisting with the fingers for S; Its plying is 0.51 with single twist ratio;
(3) then through braiding, ready-made clothes;
(4) ANTIPILLING processing:
A. add the olive oil of 2g/kg fabric, and water-wet fleece fabrics, then by 90 DEG C of hot water treatment 10min for fleece fabrics, then with 1.3% (owf) papain at 55 DEG C, pH=7.0 processes 90min afterwash;
B. carboxylated shitosan is equipped to the aqueous solution of mass percent 0.3%, the fabric that step 1 is obtained soaks wherein, dipping 3hr, natural air drying;
C. again with 3% (owf) papain at 59 DEG C, pH=7.0 processes 30min afterwash, the enzyme that then goes out in 90 DEG C of hot water is processed 5min, natural air drying;
D., after air-dry, spray 0.1% mass percent pigskin collagen solution to fabric, wetting;
E. fully vexed fleece fabrics putting left standstill to 1 day, 60 DEG C of low temperature dryings, flatiron;
(5) finished product inspection, packaging warehouse-in: ANTIPILLING cashmere sweater finished product after treatment is tested, pack warehouse-in through after the assay was approved.
Embodiment 3:
(1) choose cashmere fiber and milk protein fiber blending, the fineness of described cashmere is 25 μ m, and length is 26mm.Described milk protein fiber fineness is 32 μ m, length 40mm, and described cashmere and milk protein fiber are according to mass ratio 5:1 blending;
(2) twisting: make cashmere blended yarn single twist: 560 sth. made by twisting/m, twist with the fingers to twisting with the fingers for Z; In double twisting step, make the cashmere blended yarn plying twist: 350 sth. made by twisting/m, twist with the fingers to twisting with the fingers for S; Its plying is 0.51 with single twist ratio;
(3) then through braiding, ready-made clothes;
(4) ANTIPILLING processing:
A. add the olive oil of 2g/kg fabric, and water-wet fleece fabrics, then by 90 DEG C of hot water treatment 10min for fleece fabrics, then with 1.5% (owf) papain at 55 DEG C, pH=7.0 processes 90min afterwash;
B. carboxylated shitosan is equipped to the aqueous solution of mass percent 0.2%, the fabric that step 1 is obtained soaks wherein, dipping 3hr, natural air drying;
C. again with 3% (owf) papain at 59 DEG C, pH=7.0 processes 30min afterwash, the enzyme that then goes out in 90 DEG C of hot water is processed 5min, natural air drying;
D. after air-dry, to fabric spray mass percent 0.1% pigskin collagen solution, wetting;
E. fully vexed fleece fabrics putting left standstill to 1 day, 60 DEG C of low temperature dryings, flatiron;
(5) finished product inspection, packaging warehouse-in: ANTIPILLING cashmere sweater finished product after treatment is tested, pack warehouse-in through after the assay was approved.
Embodiment 4:
(1) choose cashmere fiber and milk protein fiber blending, the fineness of described cashmere is 25 μ m, and length is 26mm.Described milk protein fiber fineness is 32 μ m, length 40mm, and described cashmere and milk protein fiber are according to mass ratio 5:1 blending;
(2) twisting: make cashmere blended yarn single twist: 560 sth. made by twisting/m, twist with the fingers to twisting with the fingers for Z; In double twisting step, make the cashmere blended yarn plying twist: 350 sth. made by twisting/m, twist with the fingers to twisting with the fingers for S; Its plying is 0.51 with single twist ratio;
(3) then through braiding, ready-made clothes;
(4) ANTIPILLING processing:
A. add the olive oil of 2g/kg fabric, and water-wet fleece fabrics, then by 90 DEG C of hot water treatment 10min for fleece fabrics, then with 1.6% (owf) papain at 55 DEG C, pH=7.0 processes 90min afterwash;
B. carboxylated shitosan is equipped to the aqueous solution of mass percent 0.3%, the fabric that step 1 is obtained soaks wherein, dipping 3hr, natural air drying;
C. again with 3% (owf) papain at 59 DEG C, pH=7.0 processes 30min afterwash, the enzyme that then goes out in 90 DEG C of hot water is processed 5min, natural air drying;
D. after air-dry, to fabric spray mass percent 0.1% pigskin collagen solution, wetting;
E. fully vexed fleece fabrics putting left standstill to 1 day, 60 DEG C of low temperature dryings, flatiron;
(5) finished product inspection, packaging warehouse-in: ANTIPILLING cashmere sweater finished product after treatment is tested, pack warehouse-in through after the assay was approved.
Embodiment 5: index test and appraisal
The index of the cashmere sweater that embodiment 1-4 is obtained is tested, as follows:
Cashmere weight-loss ratio is measured:
According to fabric regain, calculate the treated front constant dry state quality w0 of sample; The accurate constant dry state quality w1 that processes rear fabric that weighs, is calculated as follows fabric enzyme and processes the weight-loss ratio of front and back:
Weight-loss ratio=(w0-w1)/w0 × 100%
The pilling resistance of cashmere knit goods detects the GB/T4802.3-2008 balling-up case method that adopts.
Table 1 detects for embodiment 1-4 is produced to the cashmere sweater obtaining the result obtaining.
Table 1 performance measurement
Test item Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Cashmere weight-loss ratio is measured 1.9 2.0 2.0 2.1
Anti-fluffing and anti-pilling grade/level 4 4 4 4.5
Feel Very soft Very soft Very soft Very soft
Glossiness Glossy Glossy Glossy Glossy
Skin-friendly Very good Very good Very good Very good
This detects data only for above-mentioned detection sample.
Can see from experimental data, the cashmere sweater that explained hereafter of the present invention obtains, although do not use industrial chemicals completely in Anti-Pilling Finishes, still has very outstanding anti-pilling property, and ANTIPILLING grade reaches more than 4 grades.
And the method and little, soft, plentiful to cashmere fiber infringement, good luster, wettability power is strong.A kind of environmental-friendly natural, the brand-new production technology of effect excellence.
The above; it is only preferably detailed description of the invention of the present invention; but protection scope of the present invention is not limited to this; any be familiar with those skilled in the art the present invention disclose technical scope in; be equal to replacement or changed according to technical scheme of the present invention and inventive concept thereof, within all should being encompassed in protection scope of the present invention.

Claims (2)

1. a production method for balling resistant cashmere sweater, is characterized in that its step is as follows:
(1) choose cashmere fiber and milk protein fiber blending, the fineness of described cashmere is 25 μ m, and length is 26mm, and described milk protein fiber fineness is 32 μ m, length 40mm, and described cashmere and milk protein fiber are according to mass ratio 5:1 blending;
(2) twisting: make cashmere blended yarn single twist: 560 sth. made by twisting/m, twist with the fingers to twisting with the fingers for Z; In double twisting step, make the cashmere blended yarn plying twist: 350 sth. made by twisting/m, twist with the fingers to twisting with the fingers for S; Its plying is 0.51 with single twist ratio;
(3) braiding, ready-made clothes;
(4) ANTIPILLING processing:
A. add 2g/(kg fabric) olive oil, with water-wet fleece fabrics, then by 90 DEG C of hot water treatment 10 min for fleece fabrics, then with 1.1~1.6% (owf) papain at 55 DEG C, pH=7. process 90 min afterwash under 0 environment;
B. carboxylated shitosan is equipped to mass percent and is 0.2~0.3% the aqueous solution, the fabric that step 1 is obtained soaks wherein, floods natural air drying 3 hours;
C. again with 3% (owf) papain at 59 DEG C, under the environment of pH=7.0, process 30 min afterwash, the enzyme that then goes out in 90 DEG C of hot water is processed 5 min, natural air drying;
D. spray 0.1% pigskin collagen solution to fabric, wetting;
E. fully vexed fleece fabrics putting left standstill to 1 day, 60 DEG C of low temperature dryings, flatiron;
(5) finished product inspection, packaging warehouse-in: ANTIPILLING cashmere sweater finished product after treatment is tested, pack warehouse-in through after the assay was approved.
2. production method claimed in claim 1 is produced the goat fleecy sweatshirt obtaining.
CN201410417581.9A 2014-08-22 2014-08-22 A kind of production method of balling resistant cashmere sweater Active CN104213415B (en)

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* Cited by examiner, † Cited by third party
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CN105220483A (en) * 2015-11-12 2016-01-06 长兴千尺度纺织品有限公司 A kind of antibacterial finish technique of cashmere sweater
CN105220491A (en) * 2015-11-13 2016-01-06 长兴新天龙印染有限公司 A kind of antibacterial finish technique of woollen sweater
CN105239412A (en) * 2015-11-12 2016-01-13 长兴永杰纺织有限公司 Deodorization finishing technology for washable wool blended fabric
CN105239391A (en) * 2015-11-13 2016-01-13 浙江森悦纺织科技有限公司 Anti-solarization antibacterial cashmere sweater
CN105256542A (en) * 2015-11-13 2016-01-20 长兴新天龙印染有限公司 Antibacterial finishing auxiliary of woolen sweater
CN105256579A (en) * 2015-11-12 2016-01-20 长兴千尺度纺织品有限公司 Bacteriostatic pilling-resistant finishing auxiliary of cashmere sweater
CN105256570A (en) * 2015-11-13 2016-01-20 长兴华海纺织有限公司 Finishing auxiliary of woolen sweater
CN105369635A (en) * 2015-11-19 2016-03-02 德清县伊得利丝绸有限公司 Anti-pilling cashmere sweater production method
CN105442318A (en) * 2015-11-13 2016-03-30 浙江森悦纺织科技有限公司 Sun-protecting and antibacterial finishing auxiliary agent for cashmere sweaters
CN106637974A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Collagen-cashmere composite fabric with good drapability and preparation method of collagen-cashmere composite fabric
CN106637972A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof
CN106637971A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Flame-retardant and anti-pilling collagen-cashmere composite fabric and making method thereof
CN106637970A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Anti-electromagnetic radiation collagen cashmere composite fabric and making method thereof
CN106637486A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Anti-fatigue collagen cashmere composite fabric and manufacturing method thereof
CN106637973A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Mothproof collagen/cashmere composite fabric and preparation method thereof
CN106637909A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Warm collagen and cashmere composite fabric with high thermal stability and production method thereof
CN106637910A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Antistatic collagen-cashmere composite fabric and production method thereof
CN107245799A (en) * 2017-04-28 2017-10-13 嵊州市瑞林羊绒纺织厂 A kind of production method of balling resistant cashmere sweater

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CN105256579A (en) * 2015-11-12 2016-01-20 长兴千尺度纺织品有限公司 Bacteriostatic pilling-resistant finishing auxiliary of cashmere sweater
CN105220483A (en) * 2015-11-12 2016-01-06 长兴千尺度纺织品有限公司 A kind of antibacterial finish technique of cashmere sweater
CN105239412A (en) * 2015-11-12 2016-01-13 长兴永杰纺织有限公司 Deodorization finishing technology for washable wool blended fabric
CN105442318A (en) * 2015-11-13 2016-03-30 浙江森悦纺织科技有限公司 Sun-protecting and antibacterial finishing auxiliary agent for cashmere sweaters
CN105256542A (en) * 2015-11-13 2016-01-20 长兴新天龙印染有限公司 Antibacterial finishing auxiliary of woolen sweater
CN105239391A (en) * 2015-11-13 2016-01-13 浙江森悦纺织科技有限公司 Anti-solarization antibacterial cashmere sweater
CN105256570A (en) * 2015-11-13 2016-01-20 长兴华海纺织有限公司 Finishing auxiliary of woolen sweater
CN105220491A (en) * 2015-11-13 2016-01-06 长兴新天龙印染有限公司 A kind of antibacterial finish technique of woollen sweater
CN105369635A (en) * 2015-11-19 2016-03-02 德清县伊得利丝绸有限公司 Anti-pilling cashmere sweater production method
CN106637972A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Antioxidant skin-friendly collagen and cashmere composite fabric and production method thereof
CN106637974A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Collagen-cashmere composite fabric with good drapability and preparation method of collagen-cashmere composite fabric
CN106637971A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Flame-retardant and anti-pilling collagen-cashmere composite fabric and making method thereof
CN106637970A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Anti-electromagnetic radiation collagen cashmere composite fabric and making method thereof
CN106637486A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Anti-fatigue collagen cashmere composite fabric and manufacturing method thereof
CN106637973A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Mothproof collagen/cashmere composite fabric and preparation method thereof
CN106637909A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Warm collagen and cashmere composite fabric with high thermal stability and production method thereof
CN106637910A (en) * 2016-12-13 2017-05-10 安徽天威羊绒制品有限公司 Antistatic collagen-cashmere composite fabric and production method thereof
CN107245799A (en) * 2017-04-28 2017-10-13 嵊州市瑞林羊绒纺织厂 A kind of production method of balling resistant cashmere sweater

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