CN106637165A - Filming agent used for treatment of wires processed by cold plastic deformation and preparing method thereof - Google Patents
Filming agent used for treatment of wires processed by cold plastic deformation and preparing method thereof Download PDFInfo
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- CN106637165A CN106637165A CN201610876729.4A CN201610876729A CN106637165A CN 106637165 A CN106637165 A CN 106637165A CN 201610876729 A CN201610876729 A CN 201610876729A CN 106637165 A CN106637165 A CN 106637165A
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- Prior art keywords
- plastic deformation
- wire rod
- cold plastic
- film agent
- reactor
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/13—Orthophosphates containing zinc cations containing also nitrate or nitrite anions
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Metal Extraction Processes (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to a metal surface treatment technology, in particular to a filming agent used for the treatment of wires processed by cold plastic deformation and a preparing method thereof. The preparing method comprises the following steps: weighing or measuring the following raw materials in parts by weight: 10-20% of zinc oxide, 5-10% of ferric nitrate, 5-10% of zinc nitrate, 1-5% of nickel nitrate, 25-30% of phosphoric acid, 20-25% of nitric acid and 10-15% of water; adding the zinc oxide into a reactor, then filling the water, and stirring; respectively filling the phosphoric acid and the nitric acid into the reactor, and stirring; after reaction is over, filling the ferric nitrate, the nickel nitrate and the zinc nitrate into the reactor, and stirring; and after a temperature is cooled to a normal temperature, preparing the filming agent used for the treatment of the wires processed by cold plastic deformation.
Description
Technical field
The present invention relates to be related to metal surface treatment technology, and in particular to one kind is processed for cold plastic deformation processing wire rod
In film agent and preparation method thereof.
Background technology
Plastic working is to make metal in external force, typically under pressure effect, produces plastic deformation, obtains required form, chi
Very little, tissue, a kind of basic metalworking technology of the product of performance, to claim pressure processing habitually in the past.The kind of Metal Forming
Class is a lot, and according to the stress and mode of texturing that add man-hour workpiece, basic plastic processing method has forging, rolling, extruding, drawing
Several classes such as pull out, stretch, bending, shearing.
Metal is without the plastic deformation for heating, referred to as cold plastic deformation.For example, punching press, clod wash, cold-drawn, cold-heading etc. adds
Work method, belongs to cold plastic deformation.
At present, lubricant both at home and abroad used in metal cold plasticity process generally with oil, animal and plant fat,
The organic compounds such as various soaps are constituted, using methods such as dipping, sprinkle, brushings so as to be attached to metal surface and played lubrication
Effect.Because the physics of conventional lubricant, chemical property are not ideal enough, in blank Cold Drawing Process, need to do metal surface
Necessary pretreatment, just can guarantee that the attachment quantity and firmness of lubricant.So, according to traditional processing mode, it is necessary to according to
Traditional processing mode, it is necessary to pickling, washing, phosphatization, washing, neutralization and saponification process, operation are carried out to blank before cold-drawn
It is various, low production efficiency, and after each cold-drawn, or return to phosphorus wash, wash, neutralizing, saponification, cold-drawn again；Or Jing
Annealing returns to the pretreatment process that from the beginning pickling repeats again before above-mentioned cold-drawn.From blank to finished product, the several roads of cold-drawn are typically needed
Secondary to more than ten passage, causes the repetitive cycling again and again of said process.Because lubricant effect is bad, pulling capacity is big, power mould
Consume high, it is difficult to which company pulls out, high processing costs；The surface smoothness of finished product is low, and workman's working condition is poor, seriously polluted.
Friction in cold plastic deformation processing wire rod process between wire rod and mould causes loss ratio larger, by reducing friction
Power reduces mould loss and improve production efficiency, and in wire surface epithelium process is carried out, and generates the film layer of one layer of densification, and deformation adds
Good lubrication is played during work, thus develops this skin being exclusively used in during cold plastic deformation processing wire rod is processed
Film.
The content of the invention
In order to solve the above problems, the present invention matches somebody with somebody to a kind of film agent processed during wire rod is processed for cold plastic deformation
Method processed is improved.The film agent that the present invention is prepared used in cold plastic deformation processing wire rod is processed can be reduced and rubbed
Power is wiped, power consumption is reduced, drawing speed is improved；The abrasion of reduction instrument, reduces production cost；Reduce material surface
Roughness, reduces the waste product caused due to seam and scratch；Particularly with the follow-up cold-heading molding technique of alloy steel product, by
In its good lubrication ductility, production efficiency is improve.
The technical solution used in the present invention is：A kind of preparation of the film agent processed during wire rod is processed for cold plastic deformation
Method, it is characterized by completing according to the following steps：
(1) following raw materials according is weighed or measured according to following parts by weight：
(2) zinc oxide weighed in step (1) is added into reactor, then by the water measured in step (1) injection, is entered
Row stirring；
(3) phosphoric acid measured in step (1) and nitric acid are injected separately into reactor and are stirred, material is in reactor
Middle reaction；
(4) after above-mentioned reaction terminates, by the ferric nitrate weighed in step (1), nickel nitrate, zinc nitrate injection reactor
In, it is stirred；
(5) treat that temperature is cooled to normal temperature, prepare a kind of epithelium processed during wire rod is processed for cold plastic deformation
Agent.
The optimization of the present invention, according to a kind of film agent processed during wire rod is processed for cold plastic deformation described above
Compound method, it is characterized by the raw material weight percentage composition described in step (1) is：
The further optimization of the present invention, in a kind of processing wire rod process for cold plastic deformation according to the top
The compound method of film agent, it is characterized by the reactor inner surface acid corrosion-resistant.
The further optimization of the present invention, according to a kind of skin processed during wire rod is processed for cold plastic deformation described above
The compound method of film, it is characterized by the reactor material is stainless steel, the reactor inner surface brushing acid-proof coating.
Arbitrary one recited above a kind of film agent processed during wire rod is processed for cold plastic deformation, it is characterized by institute
It is liquid to state for the film agent in cold plastic deformation processing wire rod process, described to process for cold plastic deformation processing wire rod
In film agent main component be by following reactants react generate product：Zinc oxide, ferric nitrate, zinc nitrate, nickel nitrate, phosphorus
Acid, nitric acid, water；It is described for cold plastic deformation process wire rod process in film agent weight percentage be：
The further optimization of the present invention, according to a kind of skin processed during wire rod is processed for cold plastic deformation recited above
Film, it is characterized by the weight percentage of the film agent reactant processed during wire rod is processed for cold plastic deformation is：
Compared with prior art, its effect is the present invention：Institute of the present invention is adopted in cold plastic deformation processing wire rod is processed
The film agent of preparation.
(1) rate of film build is fast, and phosphorization treatment time is short, energy saving；
(2) phosphatization crystallization is especially fine and smooth, and film layer is fine and close, firm, and anti-corrosive properties are higher；
(3) membranous layer ingredient simple structure, processing follow-up dephosphorization becomes very convenient；
(4) sediment growing amount is few and is difficult to be adsorbed on heating tube, more environmental protection；
(5) saponification layer --- lubricating layer even compact, excellent adsorption, wire surface lubricity is splendid；
(6) operational stability is good, simpler using managing.
Specific embodiment
In order that the technological means of the present invention, creation characteristic, reached purpose and effect are easy to understand, in conjunction with concrete
Embodiment, is further elaborated to the present invention.
Embodiment one：A kind of compound method of the film agent processed during wire rod is processed for cold plastic deformation, it is characterized by
Complete according to the following steps：
(1) following raw materials according is weighed or measured according to parts by weight：
Wherein, 100 grams of zinc oxide, 100 grams of ferric nitrate, 100 grams of zinc nitrate, 10 grams of nickel nitrate, 63% phosphoric acid 260ml,
98% nitric acid 170ml, water 100ml.
(2) zinc oxide weighed in step (1) is added into reactor, then by the water measured in step (1) injection, is entered
Row stirring；
(3) phosphoric acid measured in step (1) and nitric acid are injected separately into reactor and are stirred, material is in reactor
Middle reaction；
(4) after above-mentioned reaction terminates, by the ferric nitrate weighed in step (1), nickel nitrate, zinc nitrate injection reactor
In, it is stirred；
(5) treat that temperature is cooled to normal temperature, prepare a kind of film agent processed during wire rod is processed for cold plastic deformation.
A kind of reactor material used in the process for preparation of the film agent processed during wire rod is processed for cold plastic deformation
Matter is stainless steel, the reactor inner surface brushing vinyl lacquer of the resistance to peroxotungstic acid coating.
Embodiment two：A kind of compound method of the film agent processed during wire rod is processed for cold plastic deformation, it is characterized by
Complete according to the following steps：
(1) following raw materials according is weighed or measured according to parts by weight：
Wherein, 200 grams of zinc oxide, 50 grams of ferric nitrate, 50 grams of zinc nitrate, 50 grams of nickel nitrate, 63% phosphoric acid 328ml, 98%
Nitric acid 136ml, water 150ml.
(2) zinc oxide weighed in step (1) is added into reactor, then by the water measured in step (1) injection, is entered
Row stirring；
(3) phosphoric acid measured in step (1) and nitric acid are injected separately into reactor and are stirred, material is in reactor
Middle reaction；
(4) after above-mentioned reaction terminates, by the ferric nitrate weighed in step (1), nickel nitrate, zinc nitrate injection reactor
In, it is stirred；
(5) treat that temperature is cooled to normal temperature, prepare a kind of film agent processed during wire rod is processed for cold plastic deformation.
A kind of reactor material used in the process for preparation of the film agent processed during wire rod is processed for cold plastic deformation
Matter is stainless steel, the acidproof phenolic acid resistance paint coating of the reactor inner surface brushing.
Embodiment three：According to a kind of preparation of film agent processed during wire rod is processed for cold plastic deformation described above
Method, it is characterized by the raw material weight percentage composition described in step (1) is：
Wherein, 150 grams of zinc oxide, 60 grams of ferric nitrate, 80 grams of zinc nitrate, 20 grams of nickel nitrate, 63% phosphoric acid 328ml, 98%
Nitric acid 170ml, water 140ml.
A kind of reactor material used in the process for preparation of the film agent processed during wire rod is processed for cold plastic deformation
Matter is stainless steel, the acidproof polyurethane paint coating of the reactor inner surface brushing.
The film agent processed during wire rod is processed for cold plastic deformation prepared in above-described embodiment one, two, three is used
In practical application, and Contrast on effect is carried out with traditional film agent.
It is applied to cold working industry：The operations such as adapter, wire drawing, extruding, deep-drawing, and carry out contrast with traditional film agent
Existing, processing the film agent that the present invention is prepared used in wire rod is processed in cold plastic deformation can reduce frictional force, reduce power
Consume, improve drawing speed；The abrasion of reduction instrument, reduces production cost；Particularly with the follow-up cold-heading of alloy steel product
Moulding process, due to its good lubrication ductility, improves production efficiency.
The film agent processed during wire rod is processed for cold plastic deformation prepared by embodiment one, two, three carries out actual answering
With contrast effect finds, the film agent prepared by embodiment three has better performance：
(1) rate of film build is fast, and phosphorization treatment time is short, energy saving；
(2) phosphatization crystallization is especially fine and smooth, and film layer is fine and close, firm, and anti-corrosive properties are higher；
(3) membranous layer ingredient simple structure, processing follow-up dephosphorization becomes very convenient；
(4) sediment growing amount is few and is difficult to be adsorbed on heating tube, more environmental protection；
(5) saponification layer --- lubricating layer even compact, excellent adsorption, wire surface lubricity is splendid；(6) operate steady
It is qualitative good, it is simpler using managing.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
It should be appreciated that the present invention is not restricted to the described embodiments, the description in above-described embodiment and specification is only the present invention to personnel
Preference, the present invention is not limited by above-mentioned preference, without departing from the spirit and scope of the present invention, of the invention
Can also there are various changes and modifications, these changes and improvements are both fallen within the scope of protection of present invention.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention
And modification, the scope of the present invention be defined by the appended.
Claims (6)
1. it is a kind of for cold plastic deformation process wire rod process in film agent compound method, it is characterized by according to the following steps
Complete：
(1) following raw materials according is weighed or measured according to following parts by weight：
(2) zinc oxide weighed in step (1) is added into reactor, then by the water measured in step (1) injection, is stirred
Mix；
(3) phosphoric acid measured in step (1) and nitric acid are injected separately into reactor and are stirred, material is anti-in a kettle.
Should；
(4) after above-mentioned reaction terminates, the ferric nitrate weighed in step (1), nickel nitrate, zinc nitrate are injected separately into reactor
In, it is stirred；
(5) treat that temperature is cooled to normal temperature, prepare a kind of film agent processed during wire rod is processed for cold plastic deformation.
2. it is according to claim 1 it is a kind of for cold plastic deformation process wire rod process in film agent compound method,
It is characterized by the raw material weight percentage composition described in step (1) is：
3. it is according to claim 1 it is a kind of for cold plastic deformation process wire rod process in film agent compound method,
It is characterized by the reactor inner surface acid corrosion-resistant.
4. it is according to claim 3 it is a kind of for cold plastic deformation process wire rod process in film agent compound method,
It is characterized by the reactor material is stainless steel, the reactor inner surface brushing acid-proof coating.
5. according to claim 1-4 is arbitrary one it is a kind of for cold plastic deformation process wire rod process in film agent,
It is characterized by the film agent in the processing wire rod process for cold plastic deformation is liquid, it is described to add for cold plastic deformation
Film agent main component in the process of work wire rod is that the product for generating is reacted by following reactants：Zinc oxide, ferric nitrate, nitric acid
Zinc, nickel nitrate, phosphoric acid, nitric acid, water；The weight hundred of the film agent reactant processed during wire rod is processed for cold plastic deformation
Point content is：
6. it is according to claim 5 it is a kind of for cold plastic deformation process wire rod process in film agent, it is characterized by institute
Stating a kind of weight percentage of the film agent processed during wire rod is processed for cold plastic deformation is：
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610876729.4A CN106637165A (en) | 2016-10-08 | 2016-10-08 | Filming agent used for treatment of wires processed by cold plastic deformation and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610876729.4A CN106637165A (en) | 2016-10-08 | 2016-10-08 | Filming agent used for treatment of wires processed by cold plastic deformation and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106637165A true CN106637165A (en) | 2017-05-10 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610876729.4A Pending CN106637165A (en) | 2016-10-08 | 2016-10-08 | Filming agent used for treatment of wires processed by cold plastic deformation and preparing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055382A (en) * | 2019-05-10 | 2019-07-26 | 安徽长江紧固件有限责任公司 | A kind of manufacturing method of torque-shear type stud |
| CN114054586A (en) * | 2021-10-25 | 2022-02-18 | 南京筑新技术集团有限公司 | Punch forming process for large-area hyperbolic mirror surface stainless steel plate |
| CN116970322A (en) * | 2023-07-20 | 2023-10-31 | 东莞市颖兴金属表面处理材料有限公司 | Environment-friendly cold plastic working surface treatment composition with good lubricating effect, and preparation method and application thereof |
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| US3939014A (en) * | 1974-11-20 | 1976-02-17 | Amchem Products, Inc. | Aqueous zinc phosphating solution and method of rapid coating of steel for deforming |
| KR100317680B1 (en) * | 1999-04-29 | 2001-12-22 | 이계안 | Surface treatment agent for treating aluminium alloy and steel plate simultaneously before painting |
| CN101864563A (en) * | 2010-07-14 | 2010-10-20 | 西安北方光电有限公司 | Phosphating liquid of high corrosion resistance black phosphating production process |
| CN102304708A (en) * | 2011-04-25 | 2012-01-04 | 大连三达奥克化学股份有限公司 | Signal detonator body deep-drawing phosphating agent and preparation method for signal detonator body deep-drawing phosphating agent |
| CN103320777A (en) * | 2013-05-31 | 2013-09-25 | 南京洁雅新材料有限公司 | Normal temperature non-slag coating agent and production technology therefor |
| CN103695881A (en) * | 2013-12-19 | 2014-04-02 | 湖南金裕化工有限公司 | Normal-temperature sludgeless fast phosphating liquid and preparation method thereof |
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2016
- 2016-10-08 CN CN201610876729.4A patent/CN106637165A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3939014A (en) * | 1974-11-20 | 1976-02-17 | Amchem Products, Inc. | Aqueous zinc phosphating solution and method of rapid coating of steel for deforming |
| KR100317680B1 (en) * | 1999-04-29 | 2001-12-22 | 이계안 | Surface treatment agent for treating aluminium alloy and steel plate simultaneously before painting |
| CN101864563A (en) * | 2010-07-14 | 2010-10-20 | 西安北方光电有限公司 | Phosphating liquid of high corrosion resistance black phosphating production process |
| CN102304708A (en) * | 2011-04-25 | 2012-01-04 | 大连三达奥克化学股份有限公司 | Signal detonator body deep-drawing phosphating agent and preparation method for signal detonator body deep-drawing phosphating agent |
| CN103320777A (en) * | 2013-05-31 | 2013-09-25 | 南京洁雅新材料有限公司 | Normal temperature non-slag coating agent and production technology therefor |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055382A (en) * | 2019-05-10 | 2019-07-26 | 安徽长江紧固件有限责任公司 | A kind of manufacturing method of torque-shear type stud |
| CN114054586A (en) * | 2021-10-25 | 2022-02-18 | 南京筑新技术集团有限公司 | Punch forming process for large-area hyperbolic mirror surface stainless steel plate |
| CN116970322A (en) * | 2023-07-20 | 2023-10-31 | 东莞市颖兴金属表面处理材料有限公司 | Environment-friendly cold plastic working surface treatment composition with good lubricating effect, and preparation method and application thereof |
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