CN106636796A - Conductive aluminum alloy material and preparation method thereof - Google Patents
Conductive aluminum alloy material and preparation method thereof Download PDFInfo
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- CN106636796A CN106636796A CN201611100600.0A CN201611100600A CN106636796A CN 106636796 A CN106636796 A CN 106636796A CN 201611100600 A CN201611100600 A CN 201611100600A CN 106636796 A CN106636796 A CN 106636796A
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- aluminum alloy
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- aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
- H01B1/023—Alloys based on aluminium
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- Materials Engineering (AREA)
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- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
The invention discloses a aluminum alloy material for conductive use and a preparation method thereof. The aluminum alloy material for conductive use is prepared by smelting the following alloy elements in percentage by mass: 2.57 to 2.63% of magnesium, 1.26 to 1.49% of stannum, 0.36 to 0.67% of molybdenum, 0.11 to 0.20% of germanium, 0.044 to 0.049% of magnesium, 0.026 to 0.037% of nickel, and the balance of aluminum. The preparation method comprises the following steps of (1) preparation and pretreatment: according to elements needed to be smelted in the aluminum alloy material, collecting and preparing the raw materials containing the elements, and performing purifying operation on the raw material containing aluminum by an electrolysis method; (2) smelting and forming: under the argon protection condition, putting the metal powder into a medium-frequency induction heating furnace, smelting, cooling, and casting into a die; stilling, demolding, and forming, so as to obtain the aluminum alloy material for conductive use. The aluminum alloy material for conductive use has the beneficial effects that the cost is low, the electric property is excellent, the large-scale production is realized, and the like.
Description
Technical field
The present invention relates to technical field of metal, specifically a kind of conduction aluminum alloy materials and preparation method thereof.
Background technology
At present most commonly used used in overhead transmission line is still steel-cored aluminium strand (ACSR), the big face of this kind of wire amount
Extensively, produce and application is more ripe.But with the needs that technological progress and power industry develop, the in the world transmission of electricity of many countries
All kinds of aluminium alloy conductors are widely used on circuit, mainly have all aluminium alloy twisted wire (AAAC), aluminum stranded wire of aluminum alloy core (ACAR),
Several classes such as steel core aluminum alloy stranded wire (AACSR).Divide from alloy wire performance, high-strength aluminum alloy line, middle intensity aluminium can be divided into again
Alloy wire and heat-resisting series alloys line.But at present the electric conductivity of domestic aluminium alloy conductor used for transmission line is weaker, anti-
The low present situation of tensile strength.
The content of the invention
It is an object of the invention to provide a kind of conduction aluminum alloy materials and preparation method thereof, to solve above-mentioned background skill
The problem proposed in art.
For achieving the above object, the present invention provides following technical scheme：
A kind of conduction aluminum alloy materials, are formed by the alloying element melting of following mass percent：Magnesium 2.57-
2.63%th, tin 1.26-1.49%, molybdenum 0.36-0.67%, germanium 0.11-0.20%, manganese 0.044-0.049%, nickel 0.026-
0.037%, balance of aluminium.
As further scheme of the invention：The conduction aluminum alloy materials, by the alloy unit of following mass percent
Plain melting is formed：Magnesium 2.60-2.61%, tin 1.33-1.40%, molybdenum 0.47-0.50%, germanium 0.16-0.17%, manganese 0.047-
0.048%th, nickel 0.029-0.032%, balance of aluminium.
As further scheme of the invention：The conduction aluminum alloy materials, by the alloy unit of following mass percent
Plain melting is formed：Magnesium 2.61%, tin 1.36%, molybdenum 0.49%, germanium 0.17%, manganese 0.048%, nickel 0.031%, balance of aluminium.
As further scheme of the invention：The raw material sources of aluminium are in electronic equipment in the conduction aluminum alloy materials
Reclaim.
A kind of preparation method of conduction aluminum alloy materials, concretely comprises the following steps：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is entered
Row is collected and prepared, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and containing
The raw material of tin element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element are respectively directly using pure
Metal material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, gold after mixing
Particle mean size d of category powder is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with, in being subsequently placed at Medium Frequency Induction Heating Furnace
Melting is carried out, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, be incubated 42min, subsequently cooled down, be cooled to
632.7 DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
As further scheme of the invention：The raw material containing aluminium element is carried by electrolytic method in concrete steps (1)
Pure operation, the electrolytic method carry out purification operations be specially by containing aluminium element raw material be added in electrolytic cell obtain aluminium melt
Body, is subsequently added ice crystal and titanium dioxide heating obtains electrolyte fused salt, controls temperature for 823 DEG C, and voltage is 6.2V, and be powered electricity
Solution, obtains solid-state aluminium block after condensation.
Compared with prior art, the invention has the beneficial effects as follows：
Conduction aluminum alloy materials prepared by the present invention, with low cost, electric property is excellent, can be mass-produced etc. has
Beneficial feature, and can at -20 DEG C to 60 DEG C Long-Time Service, intensity, electric conductivity and heat resistance index are all up super heat-resisting
The international standard of alloy.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of conduction aluminum alloy materials, are formed by the alloying element melting of following mass percent：Magnesium 2.57%, tin
1.26%th, molybdenum 0.36%, germanium 0.11%, manganese 0.044%, nickel 0.026%, balance of aluminium；In the conduction aluminum alloy materials
The raw material sources of aluminium are in the recovery of electronic equipment.
A kind of preparation method of conduction aluminum alloy materials, concretely comprises the following steps：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is entered
Row is collected and prepared, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and containing
The raw material of tin element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element are respectively directly using pure
Metal material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, gold after mixing
Particle mean size d of category powder is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with, in being subsequently placed at Medium Frequency Induction Heating Furnace
Melting is carried out, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, be incubated 42min, subsequently cooled down, be cooled to
632.7 DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
Wherein：The raw material containing aluminium element carries out purification operations, the electrolytic method by electrolytic method in concrete steps (1)
Carry out purification operations and be specially to be added in electrolytic cell and obtaining aluminum melt the raw material containing aluminium element, be subsequently added ice crystal and titanium
White powder heating obtains electrolyte fused salt, controls temperature for 823 DEG C, and voltage is 6.2V, and be powered electrolysis, and solid aluminum is obtained after condensation
Block.
Embodiment 2
A kind of conduction aluminum alloy materials, are formed by the alloying element melting of following mass percent：Magnesium 2.60%, tin
1.33%th, molybdenum 0.47%, germanium 0.16%, manganese 0.047%, nickel 0.029%, balance of aluminium；In the conduction aluminum alloy materials
The raw material sources of aluminium are in the recovery of electronic equipment.
A kind of preparation method of conduction aluminum alloy materials, concretely comprises the following steps：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is entered
Row is collected and prepared, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and containing
The raw material of tin element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element are respectively directly using pure
Metal material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, gold after mixing
Particle mean size d of category powder is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with, in being subsequently placed at Medium Frequency Induction Heating Furnace
Melting is carried out, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, be incubated 42min, subsequently cooled down, be cooled to
632.7 DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
Wherein：The raw material containing aluminium element carries out purification operations, the electrolytic method by electrolytic method in concrete steps (1)
Carry out purification operations and be specially to be added in electrolytic cell and obtaining aluminum melt the raw material containing aluminium element, be subsequently added ice crystal and titanium
White powder heating obtains electrolyte fused salt, controls temperature for 823 DEG C, and voltage is 6.2V, and be powered electrolysis, and solid aluminum is obtained after condensation
Block.
Embodiment 3
A kind of conduction aluminum alloy materials, are formed by the alloying element melting of following mass percent：Magnesium 2.61%, tin
1.36%th, molybdenum 0.49%, germanium 0.17%, manganese 0.048%, nickel 0.031%, balance of aluminium；In the conduction aluminum alloy materials
The raw material sources of aluminium are in the recovery of electronic equipment.
A kind of preparation method of conduction aluminum alloy materials, concretely comprises the following steps：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is entered
Row is collected and prepared, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and containing
The raw material of tin element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element are respectively directly using pure
Metal material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, gold after mixing
Particle mean size d of category powder is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with, in being subsequently placed at Medium Frequency Induction Heating Furnace
Melting is carried out, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, be incubated 42min, subsequently cooled down, be cooled to
632.7 DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
Wherein：The raw material containing aluminium element carries out purification operations, the electrolytic method by electrolytic method in concrete steps (1)
Carry out purification operations and be specially to be added in electrolytic cell and obtaining aluminum melt the raw material containing aluminium element, be subsequently added ice crystal and titanium
White powder heating obtains electrolyte fused salt, controls temperature for 823 DEG C, and voltage is 6.2V, and be powered electrolysis, and solid aluminum is obtained after condensation
Block.
Embodiment 4
A kind of conduction aluminum alloy materials, are formed by the alloying element melting of following mass percent：Magnesium 2.61%, tin
1.40%th, molybdenum 0.50%, germanium 0.17%, manganese 0.048%, nickel 0.032%, balance of aluminium；In the conduction aluminum alloy materials
The raw material sources of aluminium are in the recovery of electronic equipment.
A kind of preparation method of conduction aluminum alloy materials, concretely comprises the following steps：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is entered
Row is collected and prepared, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and containing
The raw material of tin element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element are respectively directly using pure
Metal material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, gold after mixing
Particle mean size d of category powder is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with, in being subsequently placed at Medium Frequency Induction Heating Furnace
Melting is carried out, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, be incubated 42min, subsequently cooled down, be cooled to
632.7 DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
Wherein：The raw material containing aluminium element carries out purification operations, the electrolytic method by electrolytic method in concrete steps (1)
Carry out purification operations and be specially to be added in electrolytic cell and obtaining aluminum melt the raw material containing aluminium element, be subsequently added ice crystal and titanium
White powder heating obtains electrolyte fused salt, controls temperature for 823 DEG C, and voltage is 6.2V, and be powered electrolysis, and solid aluminum is obtained after condensation
Block.
Embodiment 5
A kind of conduction aluminum alloy materials, are formed by the alloying element melting of following mass percent：Magnesium 2.63%, tin
1.49%th, molybdenum 0.67%, germanium 0.20%, manganese 0.049%, nickel 0.037%, balance of aluminium；In the conduction aluminum alloy materials
The raw material sources of aluminium are in the recovery of electronic equipment.
A kind of preparation method of conduction aluminum alloy materials, concretely comprises the following steps：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is entered
Row is collected and prepared, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and containing
The raw material of tin element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element are respectively directly using pure
Metal material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, gold after mixing
Particle mean size d of category powder is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with, in being subsequently placed at Medium Frequency Induction Heating Furnace
Melting is carried out, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, be incubated 42min, subsequently cooled down, be cooled to
632.7 DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
Wherein：The raw material containing aluminium element carries out purification operations, the electrolytic method by electrolytic method in concrete steps (1)
Carry out purification operations and be specially to be added in electrolytic cell and obtaining aluminum melt the raw material containing aluminium element, be subsequently added ice crystal and titanium
White powder heating obtains electrolyte fused salt, controls temperature for 823 DEG C, and voltage is 6.2V, and be powered electrolysis, and solid aluminum is obtained after condensation
Block.
In sum, conduction prepared by embodiment of the present invention 1-5 is tested with aluminum alloy materials, its electrical conductivity exists
53-56S/cm, and tensile strength is in the range of 134-149MPa；Inventor has been carried out under -20 DEG C to 60 DEG C environment temperatures again, is led
The conductivity of electricity aluminum alloy materials only declines 1.3%, when environment temperature is in -40 DEG C or 100 DEG C, conduction aluminium alloy material
The conductivity of material is reduced only by 4.8%.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can be with the premise of without departing from this patent objective
Make a variety of changes.
Claims (6)
1. a kind of conduction aluminum alloy materials, it is characterised in that formed by the alloying element melting of following mass percent：Magnesium
2.57-2.63%, tin 1.26-1.49%, molybdenum 0.36-0.67%, germanium 0.11-0.20%, manganese 0.044-0.049%, nickel
0.026-0.037%, balance of aluminium.
2. conduction aluminum alloy materials according to claim 1, it is characterised in that the conduction aluminum alloy materials, by
The alloying element melting of following mass percent is formed：Magnesium 2.60-2.61%, tin 1.33-1.40%, molybdenum 0.47-0.50%, germanium
0.16-0.17%, manganese 0.047-0.048%, nickel 0.029-0.032%, balance of aluminium.
3. conduction aluminum alloy materials according to claim 1, it is characterised in that the conduction aluminum alloy materials, by
The alloying element melting of following mass percent is formed：Magnesium 2.61%, tin 1.36%, molybdenum 0.49%, germanium 0.17%, manganese
0.048%th, nickel 0.031%, balance of aluminium.
4. conduction aluminum alloy materials according to claim 1, it is characterised in that aluminium in the conduction aluminum alloy materials
Raw material sources in the recovery of electronic equipment.
5. a kind of preparation method of the conduction aluminum alloy materials as described in claim 1-4 is arbitrary, it is characterised in that concrete step
Suddenly it is：
(1) prepare and pre-process：According to the element of melting needed for aluminum alloy materials, subsequently the raw material containing each element is received
Collection prepares, wherein the raw material containing aluminium element carries out purification operations by electrolytic method, wherein the raw material containing magnesium elements and stanniferous unit
The raw material of element is milled respectively through calcining and carries out electrorefining, and remaining molybdenum, germanium, manganese, nickel element directly adopt respectively simple metal
Material, is then proportionally ground the pure powder of each element, places in batch mixer after grinding and mixes, metal powder after mixing
Particle mean size d at end is less than or equal to 100 μm；
(2) melting and shaping：Under the protection of argon gas, by metal dust with being subsequently placed in Medium Frequency Induction Heating Furnace is carried out
Melting, programming rate is 50 DEG C/min, until being warming up to 1300 DEG C, is incubated 42min, is subsequently cooled down, and is cooled to 632.7
DEG C, in being poured into mould, stripping forming is carried out after standing, obtain final product conduction aluminum alloy materials.
6. the preparation method of conduction aluminum alloy materials according to claim 4, it is characterised in that in concrete steps (1)
Raw material containing aluminium element carries out purification operations by electrolytic method, and the electrolytic method carries out purification operations will specially contain aluminium unit
The raw material of element is added in electrolytic cell and obtains aluminum melt, is subsequently added ice crystal and titanium dioxide heating obtains electrolyte fused salt, control
Temperature processed is 823 DEG C, and voltage is 6.2V, and be powered electrolysis, and solid-state aluminium block is obtained after condensation.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5053085A (en) * | 1988-04-28 | 1991-10-01 | Yoshida Kogyo K.K. | High strength, heat-resistant aluminum-based alloys |
| CN105039808A (en) * | 2015-08-04 | 2015-11-11 | 安徽科蓝特铝业有限公司 | Novel energy-saving aluminum alloy profile and manufacturing technique thereof |
| CN105039790A (en) * | 2015-06-29 | 2015-11-11 | 余姚市朗霞镇大众铸件精工厂 | Aluminum alloy |
-
2016
- 2016-12-05 CN CN201611100600.0A patent/CN106636796A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5053085A (en) * | 1988-04-28 | 1991-10-01 | Yoshida Kogyo K.K. | High strength, heat-resistant aluminum-based alloys |
| CN105039790A (en) * | 2015-06-29 | 2015-11-11 | 余姚市朗霞镇大众铸件精工厂 | Aluminum alloy |
| CN105039808A (en) * | 2015-08-04 | 2015-11-11 | 安徽科蓝特铝业有限公司 | Novel energy-saving aluminum alloy profile and manufacturing technique thereof |
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Application publication date: 20170510 |