CN106634506A - Coating for protecting aerostat capsule material and preparation method and application thereof - Google Patents
Coating for protecting aerostat capsule material and preparation method and application thereof Download PDFInfo
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- CN106634506A CN106634506A CN201610928351.8A CN201610928351A CN106634506A CN 106634506 A CN106634506 A CN 106634506A CN 201610928351 A CN201610928351 A CN 201610928351A CN 106634506 A CN106634506 A CN 106634506A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a coating for protecting an aerostat capsule material and a preparation method and application thereof. The coating is prepared by mixing a component A and a component B. The mass ratio of the component A to the component B is 100:(10-15). By weight parts, the component A comprises 45-55 parts of polyurethane resin, 10-15 parts of titanium dioxide, 0-1 part of defoamer, 0-1 part of dispersing agent and 25-35 parts of diluent. The component B is polyamide curing agent. NY-35 type polyurethane resin is taken as a base body, an appropriate amount of titanium dioxide is added to improve covering power of the coating, the prepared aerostat capsule material protecting coating can be matched with the flexibility of the aerostat capsule base material, and the helium barrier property of the aerostat capsule base material is greatly improved. After undergoing kneading testing, the base material coated with the protecting coating can still conform to technical requirements though the helium barrier property is reduced to some extent.
Description
Technical field
The present invention relates to a kind of coating of protection aerostatics envelop materialses and its preparation method and application.
Background technology
Aerostatics utricule protective coating is referred to for the coating with protective effect on aerostatics envelop materialses, is broadly divided into
Aerostatics utricule hinders helium coating and aerostatics utricule protective coating.Aerostatics generally refer to proportion be lighter than air, rely on air
The aircraft of buoyancy lift-off.In electronics and military civil area, typically not by fire balloon stroke in the range of aerostatics.Additionally, empty
Between dirigible not necessarily rely on buoyancy.In addition to military, large-scale civilian aerostatics can be also used for traffic, transport, entertain, relieving the people in stricken areas,
Movies-making, scientific experiment etc..The particularity such as helium rejection rate, wearability, the resistance to ag(e)ing of aerostatics utricule protective coating
Can ensure that aerostatics is capable of the working life of smooth working, the safety of aerostatics staff and aerostatics, to floating
Device completes for a long time task and plays an important role.
The aerostatics envelop materialses of China's independent research are mainly made up of aramid fiber, its have helium barrier it is relatively low,
The shortcomings of ageing-resistant performance is poor, is unable to reach the technical requirements of heaven work on the premise of protective coating is not coated by.By in
The aerostatics envelop materialses of Aerospace Science and Industry Corporation of state independent research, its helium rejection rate is relatively low, it is impossible to when ensureing that dirigible is in long
Between normal operating conditions;Ultraviolet aging resistance is poor, causes aerostatics service life shorter, current domestic existing common resistance to old
Changing coating its wearability cannot match with flexible aramid fiber base material, in addition external blockade on new techniques and dependence in the field
The enormous expenditure that import is caused, be badly in need of it is a kind of can Long-Time Service, possess higher helium barrier, wearability, resistance to ag(e)ing
New aerostatics utricule protective coating, to reduce the R&D costs and maintenance cost of aerostatics as far as possible, and it is stable to lift its
Property.For improving domestic aerostatics job stability and increasing the service life, tool is of great significance.
The content of the invention
The technical problem to be solved is to provide one kind and is mainly coated on aerostatics envelop materialses surface to be lifted
The polyurethane series aerostatics utricule that its helium barrier, resistance to ag(e)ing and anti-wear performance and aerostatics envelop materialses match is protected
Shield coating.
The technical scheme is that, there is provided a kind of coating of protection aerostatics envelop materialses, the coating is by component A and B
Component is mixed with and forms, and component A is 100 with the mass ratio of B component:10~15;
Wherein, by weight, component A includes consisting of:
Polyurethane resin:45~55 parts
Titanium dioxide:10~15 parts
Defoamer:0~1 part
Dispersant:0~1 part
Diluent:25~35 parts
B component is:Polyamide curing agent.
Preferably, the polyurethane resin in component A is NY-35 type polyurethane resins.
Preferably, the titanium dioxide in component A is rutile-type 2377# titanium dioxides.
Preferably, the diluent in component A is that mass ratio is 4:1 dimethylbenzene and the mixed liquor of n-butanol.
Preferably, the dispersant in component A is the solution with acid base co-polymer.
Preferably, the defoamer in component A is the diisobutyl ketone solution of polysiloxanes.
Preferably, the defoamer in component A is BYK-066N type defoamers.
The technical problem further to be solved of the invention is to provide one kind and can strictly control coating layer thickness, and then limits
The unit area of aerostatics envelop materialses increases weight and coating structure is uniform, performance is higher, easy construction coating processes.For this purpose,
The present invention provides the preparation method of above-mentioned coating and its specific application.
The present invention further provides the preparation method of described coating, comprises the following steps:
(1) 45~55 parts of polyurethane resins, 10~15 parts of titanium dioxides are added in material-compound tank, 0~1 part of dispersant, 0~1
Part defoamer, stirring, then bead is added thereto to, and 2~4h is disperseed under 2500~3500r/min, obtained with filter-cloth filtering
White colorant, is designated as component A;
(2) component A and B component are pressed into 100:10~15 mass ratio is mixed, and is stirred, and obtains final product protection aerostatics
The coating of envelop materialses.
Above-mentioned preparation method is more specifically comprised the following steps:(1) 45~55 parts of polyurethane resins are added in material-compound tank,
And add 10~15 parts of titanium dioxides, 0~1 part of dispersant, 0~1 part of defoamer, with the rotating speed stirring 25 of 450~550r/min~
35min, then be added thereto to the 80~120g of bead of a diameter of 2~3mm, disperse 2 at a high speed under 2500~3500r/min~
4h, with filter-cloth filtering white colorant is obtained, and is designated as component A;
(2) component A and B component are pressed into 100:10~15 mass ratio is mixed, and is stirred with the rotating speed of 100~200r/min
15~30min is mixed, the coating of protection aerostatics envelop materialses is obtained final product.
Further, the coating for above-mentioned preparation method being obtained is using 6 μm of coating line bar coatings to aerostatics utricule base material
On, treat that paint solidification is dried, obtain final product aerostatics envelop materialses protective coating.
Especially, it is emphasized that the coating line bar gauge lattice that the present invention is used are 6 μm, if coating thickness is higher than 6 μm, can cause to apply
Film thickness is excessive, causes the weightening of base material unit area overweight.
Coating of protection aerostatics envelop materialses of the present invention and preparation method thereof has the advantages that:
(1) aerostatics envelop materialses protective coating of the present invention can film-forming at room temperature, reality is completed in 24h
Dry, its drying mode needs the drying mode of heating, drying due to conventional urethane elastomer, is adapted to different shape, chi
Very little base material;
(2) aerostatics envelop materialses protective coating of the present invention is at room temperature after film-forming, paint film appearance is homogeneous,
Stable, almost free of surface defects, preferably, paint film can realize normal temperature rapid curing to glossiness, and adhesive force is preferably, wear-resisting after solidification
Property is excellent;
(3) present invention is based on special polyurethane (NY-35 type polyurethane resins), and in addition appropriate titanium dioxide is carrying
The covering power of coating is risen, the aerostatics envelop materialses protective coating of preparation can match with aerostatics utricule base material pliability, greatly
Amplitude lifts its helium barrier, coats the base material of the protective coating after rubbing test is undergone, though its helium barrier is
Decline, but still conform to technical requirements.
Therefore, the aerostatics envelop materialses protective coating that prepared by this method rapid curing can be dried at normal temperatures, film
With excellent helium barrier and good wearability, resistance to ag(e)ing, the protection requirement of aerostatics envelop materialses is met.
Specific embodiment
With reference to embodiment, the invention will be further described.
Various chemical reagent manufacturers used in the embodiment of the present invention and comparative example are as follows, if no special instructions,
Obtained by routine business approach.
NY-35 type polyurethane resins are purchased from Yantai Huada Chemical Group Co., Ltd.;Titanium dioxide covers beautification work purchased from Shanghai
Co., Ltd;Defoamer (BYK-066N) is purchased from BYK companies of Germany;Dispersant (TEGO-628) is purchased from Ying Chuan companies of Germany;Gu
Agent is purchased from Yantai Huada Chemical Group Co., Ltd.;It is dimethylbenzene that diluent is solvent:N-butanol=4:1 (mass ratio) it is mixed
Close liquid;Dimethylbenzene is purchased from company of Kai Xin chemical reagent Co., Ltd, and n-butanol is purchased from Chemical Reagent Co., Ltd., Sinopharm Group.
Embodiment 1
The protection of aerostatics envelop materialses is carried out with the NY-35 type polyurethane resins of Yantai Huada Chemical Group Co., Ltd. to apply
The preparation of material, is coated to the utricule base material of 20 × 20mm with 6 μm of coating bars, carries out performance test.
Aerostatics envelop materialses protective coating:
It is mixed with by component A, B component and is formed, wherein, the mass content of B component is the 12.5% of component A, each component
It is specific as follows:
Component A:Polyurethane resin:50 parts;
Titanium dioxide:12 parts;
Defoamer:1 part;
Dispersant:1 part;
Solvent:30 parts;
B component:Curing agent.
The preparation method of aerostatics envelop materialses protective coating:
(1) 50 parts of polyurethane resins are added in material-compound tank, and to its 12 parts of titanium dioxide of addition, 1 part of dispersant, 1 part disappears
Infusion, 30 parts of solvents stir 30min with the rotating speed of 500r/min;
(2) the bead 100g of a diameter of 3mm is added thereto to again, disperses 3h at a high speed under 2500~3500r/min, use
Filter-cloth filtering obtains white colorant and is designated as component A;
(3) component A and B component are pressed into 100:12 mass ratio is mixed, and with the rotating speed of 200r/min 20min is stirred,
Obtain final product aerostatics envelop materialses protective coating;
By aerostatics envelop materialses protective coating with 6 μm of coating line bar coating to 20 × 20 aramid fiber base materials, room
The lower film-forming of temperature, while determining the drying varniss time, a series of performances that paint film is carried out after film curing is dried completely are surveyed
Examination and research, concrete outcome is as shown in table 1.
The gained aerostatics envelop materialses protective coating all-round property testing result of 1 embodiment of table 1
As shown in Table 1, solidify after being dried, paint film appearance is homogeneous, stable, almost free of surface defects;Paint film can be realized often
Warm rapid curing, surface drying time≤2h does solid work the time≤24h;Adhesive force is 1 grade, close 0 grade;Film thickness be 0.33~
0.38mm, unit area weightening 13.5g/m2, far below given requirements;Helium rate is leaked to it to test, and is without when crumpling
584ml/m2, rubbing is afterwards for 100 times 729ml/m2, leakage helium rate is far below set technical requirements.
Why the helium rejection rate of envelop materialses is improved, and is because being coated with after this protective coating, envelop materialses
On hole filled up, and then material leakage helium rate decline;After being subjected to 100 rubbings, the leakage helium rate of envelop materialses rises,
It is because during rubbing, envelop materialses protective coating structure is destroyed, envelop materialses surface folding increases, interlayer hole
Gap increases, and then fault in material increases, and the barrier of helium is declined, but because the coating flexibility for coating is preferable, is undergoing
After 100 rubbings, the pliability for keeping matching with base material is remained to, therefore the destroyed degree of coating structure is less, still to helium
Keep good barrier.It is reported that, the base material of the protective coating is not coated after 100 rubbings are undergone, its leakage helium rate will
By the 1000ml/m of normality2Rise to 2000~3000ml/m2。
Embodiment 2
Similarly, aerostatics utricule material is carried out with the NY-35 type polyurethane resins of Yantai Huada Chemical Group Co., Ltd.
The preparation of material protective coating, is coated to the utricule base material of 20 × 20mm with 6 μm of coating bars, carries out performance test.
Aerostatics envelop materialses protective coating:
It is mixed with by component A, B component and is formed, wherein, the mass content of B component is the 12.5% of component A, each component
It is specific as follows:
Component A:Polyurethane resin:50 parts;
Titanium dioxide:20 parts;
Defoamer:1 part;
Dispersant:1 part;
Solvent:30 parts;
B component:Curing agent;
The preparation method of aerostatics envelop materialses protective coating:
(1) 50 parts of polyurethane resins are added in material-compound tank, and to its 20 parts of titanium dioxide of addition, 1 part of dispersant, 1 part disappears
Infusion, 30 parts of solvents stir 30min with the rotating speed of 500r/min;
(2) the bead 100g of a diameter of 3mm is added thereto to again, disperses 3h at a high speed under 3000r/min, use filter cloth mistake
Filter obtains white colorant and is designated as component A;
(3) component A and B component are pressed into 100:12 mass ratio is mixed, and with the rotating speed of 200r/min 20min is stirred,
Obtain final product aerostatics envelop materialses protective coating;
By aerostatics envelop materialses protective coating with 6 μm of coating line bar coating to 20 × 20 aramid fiber base materials, room
The lower film-forming of temperature, while determining the drying varniss time, a series of performances that paint film is carried out after film curing is dried completely are surveyed
Examination and research, concrete outcome is as shown in table 2.
The gained aerostatics envelop materialses protective coating all-round property testing result of 2 embodiment of table 2
As shown in Table 2, solidify after being dried, paint film appearance is homogeneous, stable, almost free of surface defects;Paint film can be realized often
Warm rapid curing, surface drying time≤2h does solid work the time≤24h;Adhesive force is 1 grade, close 0 grade;Film thickness be 0.35~
0.38mm, unit area weightening 21.6g/m2, meet set technical requirements;Helium rate is leaked to it to test, and is without when crumpling
575ml/m2, rubbing is afterwards for 100 times 784ml/m2, leakage helium rate is far below set technical requirements.
Comparative example 1
Aerostatics utricule material is carried out with the JF-A-WV1008B type polyurethane resins that Zhejiang Huafeng Group Corp., Ltd. develops
The preparation of material protective coating, is coated to the utricule base material of 20 × 20mm with 6 μm of coating bars, carries out performance test.
Aerostatics envelop materialses protective coating:
It is mixed with by component A, B component and is formed, wherein, the mass content of B component is the 12.5% of component A, each component
It is specific as follows:
Component A:Polyurethane resin:50 parts;
Titanium dioxide:12 parts;
Defoamer:1 part;
Dispersant:1 part;
Solvent:30 parts;
B component:Curing agent;
The preparation method of aerostatics envelop materialses protective coating:
(1) the JF-A-WV1008B type polyurethane resins that 50 parts of Zhejiang Huafeng Group Corp., Ltd. develop are added to into material-compound tank
In, and add 12 parts of titanium dioxides, 1 part of dispersant, 1 part of defoamer to stir 30min with the rotating speed of 500r/min to it;
(2) the bead 100g of a diameter of 3mm is added thereto to again, disperses 3h at a high speed under 3000r/min, use filter cloth mistake
Filter obtains white colorant and is designated as component A;
(3) component A and B component are pressed into 100:12 mass ratio is mixed, and with the rotating speed of 200r/min 20min is stirred,
Obtain final product aerostatics envelop materialses protective coating;
By aerostatics envelop materialses protective coating with 6 μm of coating line bar coating to 20 × 20 aramid fiber base materials, room
The lower film-forming of temperature, while determining the drying varniss time, a series of performances that paint film is carried out after film curing is dried completely are surveyed
Examination and research, concrete outcome is as shown in table 2.
The gained aerostatics envelop materialses protective coating all-round property testing result of 3 comparative example of table 1
As shown in Table 3, solidify after being dried, paint film appearance is homogeneous, stable, almost free of surface defects;Paint film can be realized often
Warm rapid curing, surface drying time≤2h does solid work the time≤24h;Adhesive force is 1 grade;Film thickness be 0.35~0.38mm, unit
Area weightening 20.8g/m2, meet set technical requirements;Leak helium rate to it to test, without rubbing when be 712ml/m2, leak helium
Rate disclosure satisfy that given requirements;Rubbing is afterwards for 100 times 1160ml/m2, leaking helium rate can not meet set technical requirements.
Comparative example 2
Being full of the DU-3060 type polyurethane resins of chemical industry greatly with Guangzhou carries out the preparation of aerostatics envelop materialses protective coating,
Coated to the utricule base material of 20 × 20mm with 6 μm of coating bars, carried out performance test.
Aerostatics envelop materialses protective coating:
It is mixed with by component A, B component and is formed, wherein, the mass content of B component is the 12.5% of component A, each component
It is specific as follows:
Component A:Polyurethane resin:50 parts;
Titanium dioxide:12 parts;
Defoamer:1 part;
Dispersant:1 part;
Solvent:30 parts;
B component:Curing agent;
The preparation method of aerostatics envelop materialses protective coating:
(1) 50 parts of Guangzhou are full of greatly into the DU-3060 type polyurethanes of chemical industry to add in material-compound tank, and 12 parts of titanium whites is added to it
Powder, 1 part of dispersant, 1 part of defoamer, 30 parts of solvents stir 30min with the rotating speed of 500r/min;
(2) the bead 100g of a diameter of 3mm is added thereto to again, disperses 3h at a high speed under 3000r/min, use filter cloth mistake
Filter obtains white colorant and is designated as component A;
(3) component A and B component are pressed into 100:12 mass ratio is mixed, and with the rotating speed of 200r/min 20min is stirred,
Obtain final product aerostatics envelop materialses protective coating;
By aerostatics envelop materialses protective coating with 6 μm of coating line bar coating to 20 × 20 aramid fiber base materials, room
The lower film-forming of temperature, while determining the drying varniss time, a series of performances that paint film is carried out after film curing is dried completely are surveyed
Examination and research, concrete outcome is as shown in table 4.
The gained aerostatics envelop materialses protective coating all-round property testing result of 4 comparative example of table 2
As shown in Table 4, solidify after being dried, paint film appearance is homogeneous, stable, almost free of surface defects;Paint film can be realized often
Warm rapid curing, surface drying time≤2h does solid work the time≤24h;Adhesive force is 1 grade;Film thickness be 0.39~0.42mm, unit
Area weightening 20.8g/m2, meet set technical requirements;Leak helium rate to it to test, without rubbing when be 712ml/m2, leak helium
Rate disclosure satisfy that given requirements;Rubbing is afterwards for 100 times 1160ml/m2, leaking helium rate can not meet set technical requirements.
Comparative example 3
With the preparation that the JF-B-60 type polyurethane resins of Zhejiang China peaking work carry out aerostatics envelop materialses protective coating,
Coated to the utricule base material of 20 × 20mm with 6 μm of coating bars, carried out performance test.
Aerostatics envelop materialses protective coating:
It is mixed with by component A, B component and is formed, wherein, the mass content of B component is the 12.5% of component A, each component
It is specific as follows:
Component A:Polyurethane resin:50 parts;
Titanium dioxide:12 parts;
Defoamer:1 part;
Dispersant:1 part;
Solvent:30 parts;
B component:Curing agent;
The preparation method of aerostatics envelop materialses protective coating:
(1) the JF-B-60 type polyurethanes of 50 parts of Zhejiang China peaking works are added in material-compound tank, and 12 parts of titanium whites is added to it
Powder, 1 part of dispersant, 1 part of defoamer, 30 parts of solvents stir 30min with the rotating speed of 500r/min;
(2) the bead 100g of a diameter of 3mm is added thereto to again, disperses 3h at a high speed under 3000r/min, use filter cloth mistake
Filter obtains white colorant and is designated as component A;
(3) component A and B component are pressed into 100:12 mass ratio is mixed, and with the rotating speed of 200r/min 20min is stirred,
Obtain final product aerostatics envelop materialses protective coating;
By aerostatics envelop materialses protective coating with 6 μm of coating line bar coating to 20 × 20 aramid fiber base materials, room
The lower film-forming of temperature, while determining the drying varniss time, a series of performances that paint film is carried out after film curing is dried completely are surveyed
Examination and research, concrete outcome is as shown in table 5.
The gained aerostatics envelop materialses protective coating all-round property testing result of 5 comparative example of table 3
As shown in Table 5, solidify after being dried, paint film appearance is homogeneous, stable, almost free of surface defects;Paint film can be realized often
Warm rapid curing, surface drying time≤2h does solid work the time≤24h;Adhesive force is 1 grade;Film thickness be 0.35~0.38mm, unit
Area weightening 23.2g/m2, meet set technical requirements;Leak helium rate to it to test, without rubbing when be 840ml/m2, leak helium
Rate disclosure satisfy that given requirements;Rubbing is afterwards for 100 times 1226ml/m2, leaking helium rate can not meet set technical requirements.
Claims (10)
1. a kind of coating of protection aerostatics envelop materialses, it is characterised in that the coating be mixed with by component A and B component and
Into component A is 100 with the mass ratio of B component:10~15;
Wherein, by weight, component A includes consisting of:
Polyurethane resin:45 ~ 55 parts
Titanium dioxide:10 ~ 15 parts
Defoamer:0 ~ 1 part
Dispersant:0 ~ 1 part
Diluent:25 ~ 35 parts
B component is:Polyamide curing agent.
2. coating as claimed in claim 1, it is characterised in that the polyurethane resin in component A is NY-35 type polyurethane trees
Fat.
3. coating as claimed in claim 1 or 2, it is characterised in that the titanium dioxide in component A is rutile-type 2377# titanium whites
Powder.
4. coating as claimed in claim 1, it is characterised in that it is 4 that the diluent in component A is mass ratio:1 dimethylbenzene with
The mixed liquor of n-butanol.
5. coating as claimed in claim 1, it is characterised in that the dispersant in component A is the solution with acid base co-polymer.
6. coating as claimed in claim 1, it is characterised in that the defoamer in component A is molten for the diisobutyl ketone of polysiloxanes
Liquid.
7. coating as claimed in claim 1, it is characterised in that the defoamer in component A is BYK-066N type defoamers.
8. a kind of preparation method of the coating as described in any one of claim 1-7, it is characterised in that comprise the following steps:
(1)45 ~ 55 parts of polyurethane resins, 10 ~ 15 parts of titanium dioxides of addition in material-compound tank, 0 ~ 1 part of dispersant, 0 ~ 1 part of defoamer,
Stirring, then bead is added thereto to, 2 ~ 4h is disperseed under 2500 ~ 3500r/min, white colorant is obtained with filter-cloth filtering, remember
For component A;
(2)Component A and B component are pressed into 100:10 ~ 15 mass ratio is mixed, and is stirred, and obtains final product protection aerostatics utricule
The coating of material.
9. preparation method as claimed in claim 8, it is characterised in that comprise the following steps:(1)By 45 ~ 55 parts of polyurethane trees
Fat is added in material-compound tank, and adds 10 ~ 15 parts of titanium dioxides, 0 ~ 1 part of dispersant, 0 ~ 1 part of defoamer, turning with 450 ~ 550r/min
Speed 25 ~ 35min of stirring, then the 80 ~ 120g of bead of a diameter of 2 ~ 3mm is added thereto to, under 2500 ~ 3500r/min at a high speed
2 ~ 4h of dispersion, with filter-cloth filtering white colorant is obtained, and is designated as component A;
(2)Component A and B component are pressed into 100:10 ~ 15 mass ratio is mixed, with the rotating speed of 100 ~ 200r/min stirring 15 ~
30min, obtains final product the coating of protection aerostatics envelop materialses.
10. application of the coating described in any one of claim 1-7 in protection aerostatics envelop materialses, it is characterised in that by right
The coating for requiring 8 or 9 preparation method acquisition utilizes 6 μm of coating line bar coatings to aerostatics utricule base material, treats paint solidification
It is dried, obtains final product aerostatics envelop materialses protective coating.
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CN101260273A (en) * | 2008-04-23 | 2008-09-10 | 海洋化工研究院 | Flexile epoxy anticorrosion paint |
CN101735706A (en) * | 2010-01-07 | 2010-06-16 | 同济大学 | Waterborne polyurethane modified epoxy steel structure anti-corrosive paint and preparation method thereof |
CN103849296A (en) * | 2014-02-28 | 2014-06-11 | 北京东方雨虹防水技术股份有限公司 | Elastic epoxy resin waterproof coating and preparation method thereof |
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2016
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101260273A (en) * | 2008-04-23 | 2008-09-10 | 海洋化工研究院 | Flexile epoxy anticorrosion paint |
CN101735706A (en) * | 2010-01-07 | 2010-06-16 | 同济大学 | Waterborne polyurethane modified epoxy steel structure anti-corrosive paint and preparation method thereof |
CN103849296A (en) * | 2014-02-28 | 2014-06-11 | 北京东方雨虹防水技术股份有限公司 | Elastic epoxy resin waterproof coating and preparation method thereof |
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