CN106634487A - Wood lacquer and preparation method thereof - Google Patents
Wood lacquer and preparation method thereof Download PDFInfo
- Publication number
- CN106634487A CN106634487A CN201611134883.0A CN201611134883A CN106634487A CN 106634487 A CN106634487 A CN 106634487A CN 201611134883 A CN201611134883 A CN 201611134883A CN 106634487 A CN106634487 A CN 106634487A
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- Prior art keywords
- parts
- acid
- phthalic
- antioxidant
- benzoic acid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a wood lacquer and a preparation method thereof. The wood lacquer is prepared from the following formula components in parts by mass: 4 to 6 parts of soy acid, 12 to 14 parts of a mixed solvent, 2 to 4 parts of a wetting dispersing agent, 10 to 12 parts of glycerinum, 15 to 17 parts of phenolic resin, 5 to 7 parts of benzoic acid, 7 to 9 parts of antimonous oxide, 5 to 7 parts of a phthalic acid reclaimed material, 5 to 15 parts of lithium base bentonite, 5 to 7 parts of phthalic anhydride, 1 to 3 p arts of an antioxidant and 1 to 2 parts of an adjuvant. The wood lacquer is relatively high in dryness and weather resistance; the production cost is lower than that of conventionally produced glycerol-phthalic resin; moreover, waste of a petrochemical enterprise is reduced, and the environment can be protected from being polluted, so as to realize the purposes of using wastes, saving energy and reducing discharge.
Description
Technical field
The present invention relates to paint technology field, in particular to a kind of woodcare paint and preparation method thereof.
Background technology
Phthalic resin coating have paint film adhesion it is good, bright, it is plentiful the features such as, usually by grease (or oleic acid), many
Organic polymer resin obtained in Organic Chemicals Jing such as first alcohol, polyacid condensation chemical reaction.Used by synthetic alkyd resin
The conventional mostly phthalic anhydride (PA, abbreviation phthalic anhydride) of polyacid.
, used as the main film forming substance of traditional mixed paint, woodcare paint and enamel paint, its cost height is directly for phthalic resin coating
The production cost of paint is affected, therefore it is imperative to reduce alkyd resin production cost.
The method for reducing alkyd resin production cost is a lot, vegetable oil is such as replaced with vegetable oil acid, is modified with rosin production
Alkyd resin, replace the methods such as phthalic anhydride with terylene waste material, the cost of these products is more lower than traditional alkyd resin, but its
The space that performance is relatively low and price continues to decline is little, it is impossible to meet the requirement of present situation.
The content of the invention
The invention provides a kind of woodcare paint and preparation method thereof, the present invention preferably dryness, weatherability；Production cost compared with
The alkyd resin of conventional production is low, while also reduce waste environmental protection for petroleum chemical enterprise not being contaminated, accomplishes twice laid
Energy-saving and emission-reduction.
For achieving the above object, the present invention provides following technical scheme：
A kind of woodcare paint and preparation method thereof, is made up of following mass fraction formula components：Soybean oleic acid 4-6 parts, mixing
Solvent 12-14 parts, wetting dispersing agent 2-4 parts, glycerine 10-12 parts, phenolic resin 15-17 parts, benzoic acid 5-7 parts, three oxidations two
Antimony 7-9 parts, phthalic acid reclaimed materials 5-7 parts, lithium bentonite 5-15 parts, phthalic anhydride 5-7 parts, antioxidant 1-3 parts, auxiliary agent 1-2 parts.
Further：It is made up of following mass fraction formula components：4 parts of soybean oleic acid, 12 parts of mixed solvent, wetting dispersing agent
2 parts, 10 parts of glycerine, 15 parts of phenolic resin, 5 parts of benzoic acid, 7 parts of antimony oxide, 5 parts of phthalic acid reclaimed materials, lithium base swelling
5 parts of soil, 5 parts of phthalic anhydride, 1 part of antioxidant, 1 part of auxiliary agent.
Further：It is made up of following mass fraction formula components：5 parts of soybean oleic acid, 13 parts of mixed solvent, wetting dispersing agent
3 parts, 11 parts of glycerine, 16 parts of phenolic resin, 6 parts of benzoic acid, 8 parts of antimony oxide, 6 parts of phthalic acid reclaimed materials, lithium base swelling
10 parts of soil, 6 parts of phthalic anhydride, 2 parts of antioxidant, 1.5 parts of auxiliary agent.
Further：It is made up of following mass fraction formula components：6 parts of soybean oleic acid, 14 parts of mixed solvent, wetting dispersing agent
4 parts, 12 parts of glycerine, 17 parts of phenolic resin, 7 parts of benzoic acid, 9 parts of antimony oxide, 7 parts of phthalic acid reclaimed materials, lithium base swelling
15 parts of soil, 7 parts of phthalic anhydride, 3 parts of antioxidant, 2 parts of auxiliary agent.
Further：Preparation method of the present invention has following steps：
Step one, by soybean oleic acid, glycerine, phenolic resin, terephthalic acid (TPA) reclaimed materials, benzoic acid input reactor after,
Lead to nitrogen in reactor, and be warming up to 40～80 DEG C, start to stir and continue to be warmed up to 230～240 DEG C, be incubated 1 hour, so
After continue to be rapidly heated to 200～240 DEG C, insulation sampling observation resin whether turn clear, later per 15min sampling once until tree
Lower the temperature at once after fat is as clear as crystal；
Step 2, be cooled to less than 200 DEG C when step one, put into in reactor phthalic anhydride, benzoic acid, lithium bentonite and
Antimony oxide, is warming up to 190～210 DEG C of refuxing esterification insulations；
Step 3, insulation start sampling after 1 hour, qualified to sample viscosity, acid number, are cooled to less than 180 DEG C, add and mix
Bonding solvent, antioxidant, auxiliary agent and wetting dispersing agent, obtain finished product.
The invention has the beneficial effects as follows：The simple and cheap woodcare paint alcohol of excellent performance of the present invention, preparation method
The composition of raw materials of acid resin.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of woodcare paint is made up of following mass fraction formula components：Soybean oleic acid 4-6 parts, mixed solvent 12-14 parts, profit
Hygroscopic water powder 2-4 parts, glycerine 10-12 parts, phenolic resin 15-17 parts, benzoic acid 5-7 parts, antimony oxide 7-9 parts, benzene diformazan
Acid recovery material 5-7 parts, lithium bentonite 5-15 parts, phthalic anhydride 5-7 parts, antioxidant 1-3 parts, auxiliary agent 1-2 parts.
Embodiment two：
A kind of woodcare paint is made up of following mass fraction formula components：4 parts of soybean oleic acid, 12 parts of mixed solvent, wetting point
2 parts of powder, 10 parts of glycerine, 15 parts of phenolic resin, 5 parts of benzoic acid, 7 parts of antimony oxide, 5 parts of phthalic acid reclaimed materials, lithium base
5 parts of bentonite, 5 parts of phthalic anhydride, 1 part of antioxidant, 1 part of auxiliary agent.
Embodiment three：
A kind of woodcare paint is made up of following mass fraction formula components：5 parts of soybean oleic acid, 13 parts of mixed solvent, wetting point
3 parts of powder, 11 parts of glycerine, 16 parts of phenolic resin, 6 parts of benzoic acid, 8 parts of antimony oxide, 6 parts of phthalic acid reclaimed materials, lithium base
10 parts of bentonite, 6 parts of phthalic anhydride, 2 parts of antioxidant, 1.5 parts of auxiliary agent.
Example IV：
A kind of woodcare paint is made up of following mass fraction formula components：6 parts of soybean oleic acid, 14 parts of mixed solvent, wetting point
4 parts of powder, 12 parts of glycerine, 17 parts of phenolic resin, 7 parts of benzoic acid, 9 parts of antimony oxide, 7 parts of phthalic acid reclaimed materials, lithium base
15 parts of bentonite, 7 parts of phthalic anhydride, 3 parts of antioxidant, 2 parts of auxiliary agent.
Embodiment five：
A kind of preparation method preparation method of woodcare paint comprises the steps：
Step one, by soybean oleic acid, glycerine, phenolic resin, terephthalic acid (TPA) reclaimed materials, benzoic acid input reactor after,
Lead to nitrogen in reactor, and be warming up to 40～80 DEG C, start to stir and continue to be warmed up to 230～240 DEG C, be incubated 1 hour, so
After continue to be rapidly heated to 200～240 DEG C, insulation sampling observation resin whether turn clear, later per 15min sampling once until tree
Lower the temperature at once after fat is as clear as crystal；
Step 2, be cooled to less than 200 DEG C when step one, put into in reactor phthalic anhydride, benzoic acid, lithium bentonite and
Antimony oxide, is warming up to 190～210 DEG C of refuxing esterification insulations；
Step 3, insulation start sampling after 1 hour, qualified to sample viscosity, acid number, are cooled to less than 180 DEG C, add and mix
Bonding solvent, antioxidant, auxiliary agent and wetting dispersing agent, obtain finished product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of woodcare paint, it is characterised in that：It is made up of following mass fraction formula components：
Soybean oleic acid 4-6 parts, mixed solvent 12-14 parts, wetting dispersing agent 2-4 parts, glycerine 10-12 parts, phenolic resin 15-17
Part, benzoic acid 5-7 parts, antimony oxide 7-9 parts, phthalic acid reclaimed materials 5-7 parts, lithium bentonite 5-15 parts, phthalic anhydride 5-7
Part, antioxidant 1-3 parts, auxiliary agent 1-2 parts.
2. a kind of woodcare paint according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
4 parts of soybean oleic acid, 12 parts of mixed solvent, 2 parts of wetting dispersing agent, 10 parts of glycerine, 15 parts of phenolic resin, 5 parts of benzoic acid, three
Aoxidize 7 parts of two antimony, 5 parts of phthalic acid reclaimed materials, 5 parts of lithium bentonite, 5 parts of phthalic anhydride, 1 part of antioxidant, 1 part of auxiliary agent.
3. a kind of woodcare paint according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
5 parts of soybean oleic acid, 13 parts of mixed solvent, 3 parts of wetting dispersing agent, 11 parts of glycerine, 16 parts of phenolic resin, 6 parts of benzoic acid, three
Aoxidize 8 parts of two antimony, 6 parts of phthalic acid reclaimed materials, 10 parts of lithium bentonite, 6 parts of phthalic anhydride, 2 parts of antioxidant, 1.5 parts of auxiliary agent.
4. a kind of woodcare paint according to claim 1, it is characterised in that：It is made up of following mass fraction formula components：
6 parts of soybean oleic acid, 14 parts of mixed solvent, 4 parts of wetting dispersing agent, 12 parts of glycerine, 17 parts of phenolic resin, 7 parts of benzoic acid, three
Aoxidize 9 parts of two antimony, 7 parts of phthalic acid reclaimed materials, 15 parts of lithium bentonite, 7 parts of phthalic anhydride, 3 parts of antioxidant, 2 parts of auxiliary agent.
5. a kind of a kind of preparation method of woodcare paint according to claim 1, it is characterised in that：Comprise the steps：
Step one, by soybean oleic acid, glycerine, phenolic resin, terephthalic acid (TPA) reclaimed materials, benzoic acid input reactor after, to anti-
Answer and lead in kettle nitrogen, and be warming up to 40～80 DEG C, start to stir and continue to be warmed up to 230～240 DEG C, be incubated 1 hour, Ran Houji
Continuous to be rapidly heated to 200～240 DEG C, whether insulation sampling observation resin turns clear, and later per 15min, sampling is once clear up to resin
Clear transparent rear cooling at once；
Step 2, less than 200 DEG C are cooled to when step one, phthalic anhydride, benzoic acid, lithium bentonite and three oxygen are put into in reactor
Change two antimony, be warming up to 190～210 DEG C of refuxing esterification insulations；
Step 3, insulation start sampling after 1 hour, qualified to sample viscosity, acid number, are cooled to less than 180 DEG C, add and mix molten
Agent, antioxidant, auxiliary agent and wetting dispersing agent, obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611134883.0A CN106634487A (en) | 2016-12-11 | 2016-12-11 | Wood lacquer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611134883.0A CN106634487A (en) | 2016-12-11 | 2016-12-11 | Wood lacquer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634487A true CN106634487A (en) | 2017-05-10 |
Family
ID=58824482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611134883.0A Pending CN106634487A (en) | 2016-12-11 | 2016-12-11 | Wood lacquer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106634487A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115042498A (en) * | 2021-03-08 | 2022-09-13 | 吉祥新材料股份有限公司 | Corrosion-resistant stone-like aluminum honeycomb plate and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
| CN103131291A (en) * | 2012-12-22 | 2013-06-05 | 桑达化工（南通）有限公司 | Water wood paint |
| CN103254416A (en) * | 2013-05-02 | 2013-08-21 | 广东银洋树脂有限公司 | Phenolic resin-modified water-based alkyd resin, preparation method thereof and coating |
-
2016
- 2016-12-11 CN CN201611134883.0A patent/CN106634487A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
| CN103131291A (en) * | 2012-12-22 | 2013-06-05 | 桑达化工（南通）有限公司 | Water wood paint |
| CN103254416A (en) * | 2013-05-02 | 2013-08-21 | 广东银洋树脂有限公司 | Phenolic resin-modified water-based alkyd resin, preparation method thereof and coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115042498A (en) * | 2021-03-08 | 2022-09-13 | 吉祥新材料股份有限公司 | Corrosion-resistant stone-like aluminum honeycomb plate and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20170510 |