CN102358809B - Phenolic aldehyde and VOC (volatile organic compounds) free printing ink and its preparation method - Google Patents
Phenolic aldehyde and VOC (volatile organic compounds) free printing ink and its preparation method Download PDFInfo
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- CN102358809B CN102358809B CN201110272517.2A CN201110272517A CN102358809B CN 102358809 B CN102358809 B CN 102358809B CN 201110272517 A CN201110272517 A CN 201110272517A CN 102358809 B CN102358809 B CN 102358809B
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- oil
- phenolic aldehyde
- modified rosin
- ester resin
- rosin ester
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Abstract
The invention relates to phenolic aldehyde and VOC free printing ink, which comprises the following components by weight: 30%-40% of modified rosin ester resin, 35%-44% of linoleic, 3%-5% of tung oil, 12%-18% of a pigment, 3%-4% of colloidal calcium carbonate, 3%-5% of rapeseed oil methyl ester, 0.5%-1% of a drier, 1%-2.5% of micronized wax, 0.5%-1% of an anti-oxidant, and 0.5%-1% of vanilla oil. The formula of the invention adopts modified rosin ester resin, linoleic and tung oil as main raw materials for producing printing ink, which can has the characteristics of bright and pure color, biodegradability, and excellent mechanical stability as well as good post-press finishing property, good deinking effects of printed matters, and low comprehensive printing cost, etc.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of pot galvanize base material anticorrosive coating with good chemical protection against corrosion and splendid adhesion strength.
Background technology
In the manufacture of ink at present and printing use procedure, in product, remain phenolic aldehyde, in phenolic aldehyde, contain a large amount of harmful formaldehyde, phenolic aldehyde is due to the reason of its molecular structure, can not well link together each other, there is a large amount of meals, as chalk, with cutter all, a large amount of dust releasings.So a lot of producers is just bonded together it with a large amount of glue.At present ink also has the emission problem of volatile organic compounds (VOC), and barren rock oil-based ink after printing is difficult to biological degradation and the problem that pollutes.These problems have all produced detrimentally affect to environment in Printing ink producing use procedure, do not meet the requirement of modern society pair and environmental protection.
Summary of the invention
Goal of the invention of the present invention is in order to overcome the defect in above-mentioned background technology, and a kind of environmentally friendly ink without phenolic aldehyde VOC free is provided.
Another goal of the invention of the present invention is for providing a kind of rational practicable preparation method without phenolic aldehyde VOC free ink described in first goal of the invention.
First goal of the invention of the present invention is achieved by the following technical solution.A kind of without phenolic aldehyde VOC free ink, its each moiety taking and the per-cent of weight as modified rosin ester resin 30%～40%, sub-oil 35%～44%, tung oil 3%～5%, pigment 12%～18%, calcene 3%～4%, rapeseed methylester 3%～5%, siccative 0.5%～1%, micro mist wax 1%～2.5%, oxidation inhibitor 0.5%～1%, Rhizoma et radix valerianae oil 0.5%～1%.
Preparation method without phenolic aldehyde VOC free ink of the present invention is as follows:
Drop in stainless steel binder refining still or stainless steel resin kettle with modified rosin ester resin, add successively the tung oil measuring, sub-oil, heat up after melting, start stirring, continue to be warming up to after 220～250 DEG C of insulation for some time, cooling adds the rapeseed methylester adjustment index that measures to qualified rear filtration to turn to expect to binder storage tanks.On homogenizer, pigment will be added in the modified rosin ester resin binder of above-mentioned refining more successively, calcene, micro mist wax, oxidation inhibitor, siccative and Rhizoma et radix valerianae oil, utilize stirrer to disperse to stir after 0.5h, add the 10mm granulated glass sphere weighing with raw material total amount etc., utilize the abundant ground pigment of friction on its surface, it is uniformly dispersed in binder, stir 3～4h afterwards always, granulated glass sphere is separated, obtain finished product ink.
Beneficial effect of the present invention is as follows:
With modified rosin ester resin and sub-tung oil tree oil be that main raw material carrys out manufacture of ink, not only meet the policy of the development of national resource industries, also can advance the adjustment of domestic Vegetable oil lipoprotein industry simultaneously, expand the range of application of Vegetable oil lipoprotein, alleviate consumption and the import of non-renewable oil, also meet rural industries policy, drive the adjustment of agricultural planting structure, significant.Novel bright-coloured pure without phenolic aldehyde, VOC free ink color, there is biological degradability and excellent mechanical stability and good post-press finishing, printed matter deinking efficiency is good, the lower various features that waits of integrated printing cost.
Monologue story-telling with gestures accompanying drawing
Embodiment
Illustrate as follows to of the present invention further describing:
Example 1:
A kind of without phenolic aldehyde VOC free ink, its ink colors is Ruby red, and its its weight proportion of each moiety is: modified rosin ester resin 36%, sub-oil 34%, tung oil 3%, red pigment 16%, calcene 4%, rapeseed methylester 4%, siccative 0.5%, micro mist wax 1%, oxidation inhibitor 1%, Rhizoma et radix valerianae oil 0.5%.
Example 2:
A kind of without phenolic aldehyde VOC free ink, its ink colors is blue, and its its weight proportion of each moiety is: modified rosin ester resin 32%, sub-oil 39%, tung oil 3%, blue pigments 14%, calcene 4%, rapeseed methylester 5%, siccative 1%, micro mist wax 1%, oxidation inhibitor 0.5%, Rhizoma et radix valerianae oil 0.5%.
Example 3:
A kind of without phenolic aldehyde VOC free ink, its ink colors is black, and its its weight proportion of each moiety is: modified rosin ester resin 30%, sub-oil 39%, tung oil 3%, black pigment 17%, calcene 4%, rapeseed methylester 4%, siccative 0.5%, micro mist wax 1.5%, oxidation inhibitor 0.5%, Rhizoma et radix valerianae oil 0.5%.
The preparation method of above-mentioned three embodiment is as follows: drop in stainless steel binder refining still or stainless steel resin kettle with modified rosin ester resin, add successively the tung oil measuring, sub-oil, heat up after melting, start stirring, continue to be warming up to after 220～250 DEG C of insulation for some time, cooling adds the rapeseed methylester adjustment index that measures to qualified rear filtration to turn to expect to binder storage tanks.On homogenizer, pigment will be added in the modified rosin ester resin binder of above-mentioned refining more successively, calcene, micro mist wax, oxidation inhibitor, siccative and Rhizoma et radix valerianae oil, utilize stirrer to disperse to stir after 0.5h, add the 10mm granulated glass sphere weighing with raw material total amount etc., utilize the abundant ground pigment of friction on its surface, it is uniformly dispersed in binder, stir 3～4h afterwards always, granulated glass sphere is separated, obtain finished product ink.
The ink and the traditional ink ratio that utilize the method to prepare, all technical is as shown in table 1 below:
Table 1
| Mo Xing | Without phenolic aldehyde VOC free ink | Tradition ink |
| Viscosity | 9.8 | 9.5～10 |
| Viscosity | 41.4Pa.s | Abt.40pa.s |
| Bent clothes value | 515Pa | ＞300Pa |
| Short degree | 10.8 | ＞7.5 |
| Mobility | 37mm | 35-38mm |
| Set | 5’ | 6～9’ |
| Gloss | 67.6 | ＞65 |
| Colour density | 2.39 | 2.35 |
| Wear resistance | Outstanding | Well |
| VOC discharge | Nothing | 3％ |
| Phenolic aldehyde content | Nothing | 11％～15％ |
| Renewable substances content | 79％ | 45％ |
More than showing data can analyze, and VOC free, has kept the due China ink of traditional ink more outstanding aspect the feature of environmental protection without phenolic aldehyde ink.
Claims (2)
1. one kind without phenolic aldehyde VOC free ink, its each moiety taking and the per-cent of weight as modified rosin ester resin 30%～40%, sub-oil 35%～44%, tung oil 3%～5%, pigment 12%～18%, calcene 3%～4%, rapeseed methylester 3%～5%, siccative 0.5%～1%, micro mist wax 1%～2.5%, oxidation inhibitor 0.5%～1%, Rhizoma et radix valerianae oil 0.5%～1%.
2. claimed in claim 1 without phenolic aldehyde VOC free ink, it is characterized in that its preparation method is as follows: drop in stainless steel binder refining still or stainless steel resin kettle with modified rosin ester resin, add successively the tung oil measuring, sub-oil, heat up after melting, start stirring, continue to be warming up to after 220～250 DEG C of insulation for some time, cooling adds the rapeseed methylester adjustment index that measures to qualified rear filtration to turn to expect to binder storage tanks, on homogenizer, pigment will be added in the modified rosin ester resin binder of above-mentioned refining more successively, calcene, micro mist wax, oxidation inhibitor, siccative and Rhizoma et radix valerianae oil, utilize stirrer to disperse to stir after 0.5h, add the 10mm granulated glass sphere weighing with raw material total amount etc., utilize the abundant ground pigment of friction on its surface, it is uniformly dispersed in binder, after stirring 3～4h, granulated glass sphere is separated always, obtain finished product ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110272517.2A CN102358809B (en) | 2011-09-15 | 2011-09-15 | Phenolic aldehyde and VOC (volatile organic compounds) free printing ink and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110272517.2A CN102358809B (en) | 2011-09-15 | 2011-09-15 | Phenolic aldehyde and VOC (volatile organic compounds) free printing ink and its preparation method |
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| Publication Number | Publication Date |
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| CN102358809A CN102358809A (en) | 2012-02-22 |
| CN102358809B true CN102358809B (en) | 2014-07-23 |
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| CN201110272517.2A Active CN102358809B (en) | 2011-09-15 | 2011-09-15 | Phenolic aldehyde and VOC (volatile organic compounds) free printing ink and its preparation method |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105273490A (en) * | 2015-10-28 | 2016-01-27 | 苏州市博来特油墨有限公司 | Novel environmental-friendly printing ink without harmful additives |
| CN105315767A (en) * | 2015-10-28 | 2016-02-10 | 苏州市博来特油墨有限公司 | Environment-friendly highly renewable component printing ink |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102426A (en) * | 1993-11-04 | 1995-05-10 | 应永祯 | Specific printing ink oil |
| CN101265377A (en) * | 2008-05-13 | 2008-09-17 | 福建师范大学 | Method for preparing environment-friendly type ink preparing oil used for hectograph |
| CN101531869A (en) * | 2008-11-21 | 2009-09-16 | 董学明 | Wood wax oil and preparation technology thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3658298B2 (en) * | 2000-08-24 | 2005-06-08 | 大日本インキ化学工業株式会社 | Printing ink composition |
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- 2011-09-15 CN CN201110272517.2A patent/CN102358809B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102426A (en) * | 1993-11-04 | 1995-05-10 | 应永祯 | Specific printing ink oil |
| CN101265377A (en) * | 2008-05-13 | 2008-09-17 | 福建师范大学 | Method for preparing environment-friendly type ink preparing oil used for hectograph |
| CN101531869A (en) * | 2008-11-21 | 2009-09-16 | 董学明 | Wood wax oil and preparation technology thereof |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2002-69354A 2002.03.08 |
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| CN102358809A (en) | 2012-02-22 |
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