CN106634348A - Magnesium seal solitary crystal air flue anion spray as well as preparation method and application thereof - Google Patents

Magnesium seal solitary crystal air flue anion spray as well as preparation method and application thereof Download PDF

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Publication number
CN106634348A
CN106634348A CN201611169787.XA CN201611169787A CN106634348A CN 106634348 A CN106634348 A CN 106634348A CN 201611169787 A CN201611169787 A CN 201611169787A CN 106634348 A CN106634348 A CN 106634348A
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parts
magnesium
anion
imperial
air channel
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罗小洪
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Chongqing Hao Shen Industrial Co Ltd
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Chongqing Hao Shen Industrial Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
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    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/16Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by purification, e.g. by filtering; by sterilisation; by ozonisation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/20Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
    • F24F8/24Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation using sterilising media
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24FAIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F8/00Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
    • F24F8/30Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ionisation
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08K2201/00Specific properties of additives
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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Abstract

The invention discloses magnesium seal solitary crystal air flue anion spray, which is prepared from the following components in parts by weight: 0.2 to 35 parts of pigment filler, 0.2 to 35 parts of anion powder, 0.5 to 15 parts of paraffin, 8 to 85 parts of synthetic resin emulsion, 0.2 to 3.5 parts of thickener, 0.1 to 1.5 parts of preservative and 0.01 to 3.5 parts of silver ion. The invention further discloses a preparation method of the magnesium seal solitary crystal air flue anion spray. According to the magnesium seal solitary crystal air flue anion spray provided by the invention, the properties of releasing anions, shielding neutrons and reflecting electromagnetic waves of the anion spray are realized through adding the pigment filler, the synthetic resin emulsion, tourmaline powder, the paraffin, the silver ion and the like; when the anion spray is applied to an air flue of an air conditioner and an air purifier, circulating ventilation of air is realized through the air flue of the air conditioner or the air purifier, so that the anion concentration of a whole space is higher and higher, the function of releasing negative ionic weight of the anion powder is greatly played, the neutrons are favorably shielded, the electromagnetic waves are favorably reflected, and the influences of the neutrons and the electromagnetic waves on human health are reduced.

Description

Magnesium imperial or royal seal prismatic crystal air channel anion spray and its preparation method and application
Technical field
The invention belongs to air cleaning facility technical field, and in particular to bear in a kind of magnesium imperial or royal seal prismatic crystal air channel of energy purify air Ion spray and preparation method thereof.
Background technology
In air purification field, because anion has splendid purifying and dedusting, reduces second-hand-cigarette harm, improves prevention breathing Tract disease, improve the health care of sleep, it is anti-oxidant, anti-aging, remove interior free yl and reduce blood viscosity effect, in medical circle Enjoy laudatory titles such as " tie up his oxygen ", " air vitamin ", " long-lived element " and " air vitamin ".
In physics, it is known that material is molecular, molecule be it is molecular by original, atom be by The electronics composition that atomic nucleus and enclosing is rotated about, obtains aobvious elecrtonegativity during electronics, loses aobvious electropositive during electronics, and we are positive and negative The motion artifacts of electronics are referred to as ionic phenomenon.In its natural state, the polarity of air molecule is in neutrality, i.e. neutral.But Under the effects such as cosmic ray, ultraviolet, micro- radiation, Lightning strike, air molecule can lose a part around atomic nucleus The outermost electron of rotation, ionizes air.The electronics of escape atomic nucleus constraint is referred to as free electron, negatively charged.When After free electron is combined with other neutral gas molecules, negatively charged negative aeroion is just formed, be more than in natural phenomena The anion of generation.
With the generation and development of artificial anion generation technique.At present the technology of artificially generated anion predominantly passes through The process of electric discharge manufacture negative oxygen ion is possible to produce ozone etc. in interior byproduct, and excessive ozone can accelerate cell old Change, health is had a negative impact.Current state-of-the-art anion generation technique both at home and abroad, including Japan and the United States, English, method, moral It is essentially all, using negative high voltage source, carbon fiber to be made into sparking electrode (also having referred to as " discharging antenna ") Deng state, connects high Carbon fiber electrode one pole is inserted into space after pressure, the peripherad space of electrode injection electronics at a high speed is made.Electronics is fast by air ion Speed capture, forms negative aeroion, while being sensed using the potential of negative electric field, in cation and will reduce, to obtain a phase To the anion field for purifying.The negative high voltage of the technology must be in more than 8000V, and voltage is higher, electrode and air contact area Bigger (electric discharge is extreme more), anion generation dosage is bigger, and the negative ion concentration of generation reaches 104/cm3~9 × 107/cm3, But regrettably increasing with anion dosage, the growing amount of ozone also accordingly increases.This is to restrict artificial anion at present Generation equipment urgent problem.
Meanwhile, all objects in nature, as long as temperature in absolute temperature above zero, when all in the form of an electromagnetic wave Ceaselessly outside transfer of heat is carved, this energy-delivering mode is referred to as radiated.Object passes through the released energy of radiation, referred to as Radiation energy.Radiation is calculated by roentgen/hour (R).Radiation can be divided into particle radiation and electromagenetic wave radiation, wherein particle radiation bag Neutron irradiation, proton irradiation and electron radiation etc. are included, electromagenetic wave radiation is divided into X-ray, ultraviolet and microwave etc..These spokes Penetrate the harm to human body larger, wherein electromagenetic wave radiation and the more difficult protection of neutron irradiation.Radiate how far at us from us Living environment in, radiate ubiquitous, household electrical appliance:TV, refrigerator, air-conditioning, micro-wave oven, dust catcher, computer etc.;Office Equipment:Mobile phone, computer, duplicator, electronic instrument, Medical Devices etc..Jing is often in work in the environment that neutron or X-ray are concentrated Make, study, the people of life, easy insomnia and dreamful sleep, failure of memory, body void are weak, hypoimmunity etc., the growth of its cancer cell Speed is faster than normal person 24 times, for this purpose, how to minimize neutron and radiation ray in space etc. be also always me The direction made great efforts.
The content of the invention
For the defect that prior art is present, the invention provides a kind of environmental protection, energy sustained release anion, shielding neutron With the magnesium imperial or royal seal prismatic crystal air channel anion spray of the function of reflection electromagnetic wave.Present invention also offers the magnesium imperial or royal seal prismatic crystal air channel anion The preparation method and application field of spray.
The purpose of the present invention is achieved through the following technical solutions:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, in parts by weight containing following component:Color stuffing:0.2-35 parts, bear Ion powder:0.2-35 parts, paraffin:0.5-15 parts, synthetic resin emulsion:8-85 parts, thickener:0.2-3.5 parts, preservative: 0.1-1.5 parts, silver ion:0.01-3.5 parts.
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, more preferably, in parts by weight containing following component:Face is filled out Material:0.2-15 parts, negative ion powder:5-35 parts, paraffin:0.5-10 parts, synthetic resin emulsion:25-65 parts, thickener:0.5-3 Part, preservative:0.3-1.2 parts, silver ion:0.1-3 parts.
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, more preferably, color stuffing:0.5-5 parts, negative ion powder:10-35 Part, paraffin:1-5 parts, synthetic resin emulsion:25-55 parts, thickener:1-2.5 part, preservative:0.5-1 parts, silver ion:0.15- 2.5 part.
Preferably, wherein the negative ion powder is the tourmaline powder that mesh number is 500-10000, the color stuffing is kaolinite Soil, at least one in white carbon, diatomite, calcium carbonate, alumina silicate, mica, talcum powder, silica flour, silicon powder, aluminum oxide.
Preferably, wherein the synthetic resin emulsion is pure-acrylic emulsion, styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion, poly- ammonia One kind or its mixture in ester emulsion, epoxy resin latex and acrylic emulsion, and the viscosity of the synthetic resin emulsion is 300-1000cp, solid content is 20-40wt%, and pH value is 8-9, and acid number is 50-60.
Preferably, wherein the thickener is in hydroxyethyl cellulose, alkali soluble is swollen acrylic thickener, sodium bentonite It is at least one.
Preferably, wherein the silver ion is liquid nano silver ion, and the effective content of its silver ion is 3-8wt%.
Preferably, in parts by weight, the magnesium imperial or royal seal prismatic crystal air channel anion spray also contains 3-10 part nano bamboo powdered carbons.
A kind of preparation method of above-mentioned magnesium imperial or royal seal prismatic crystal air channel anion spray, it is characterised in that comprise the steps:
(1) by the synthetic resin emulsion of formula ratio 1/2-2/3, and the color stuffing of formula ratio, negative ion powder and paraffin (are received Rice bamboo charcoal powder) sequentially add high pressure and rush in mill apparatus, rush mill and be dispersed into suspension oar body;
(2) synthetic resin emulsion that be uniformly added into surplus is rushed in mill apparatus to high pressure, it is vibrated after high-speed stirred dispersion Filter;
(3) thickener, preservative and the silver ion of formula ratio are uniformly added into, after dispersed with stirring is uniform, packing.
Magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray has and the air for flowing through air-conditioning, air purifier Application in all parts of the contact surface of contact.
Compared with prior art, the present invention at least has advantages below:
Magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by being used as physique material using color stuffing so that The characteristics such as the resistance to ag(e)ing of anion spray, heat resistance, mechanical strength and chemical resistance;Using the glue of synthetic resin emulsion Knot agent is used as filmogen so that anion spray can be perfectly adhered on base material, and VOC free is discharged, safety and environmental protection;And Add the materials such as tourmaline powder, paraffin and silver ion in system so that anion spray has anion releasing, shielding The performance of neutron and reflection electromagnetic wave, meanwhile, the addition of paraffin, because the density ratio water of paraffin is low and surface tension of paraffin Low, during use, the paraffin for being enclosed with negative ion powder is migrated to air surface so that the negative ion powder with air contact Specific surface area increase, and then cause negative ion powder just anion can be gone out with sustained release;When it is used for air-conditioning, air purifier Air channel on when, the air channel circulating ventilation that air passes through air-conditioning or air purifier so that the anion in whole space is dense Degree more and more higher, the amount of anion adopts the static transmitting weight testing method of anion to test as 300/cm3When, using anion Dynamic emission weight testing method is determined up to 10000/cm3More than, the work(of negative ion powder anion releasing amount has been played significantly Can, and be conducive to shielding neutron and transmitting electromagnetic wave, reduce the impact of neutron and electromagnetic wave to health.
Description of the drawings
Fig. 1 is that anion spray provided by the present invention is used for air-conditioning, the layer structure schematic diagram of air purifier.
Wherein, 1, with flow through air-conditioning, air purifier in air contact part;1a, contact surface;2nd, bear from Sub- coating.
Specific embodiment
Below in conjunction with accompanying drawing and specific implementation, the present invention is described in detail.
When stated in the form of scope, preferred scope or preferred numerical upper limits and lower limit certain amount, concentration or its It is worth or when parameter, it should be understood that equivalent to specifically disclose by by any pair range limit or preferred value with appoint Any scope that meaning range lower limit or preferred value combine, and do not consider whether the scope specifically discloses.Unless referred in addition Go out, number range value listed herein is in the end points including scope, and all integers and fraction within the scope of being somebody's turn to do.
Unless otherwise indicated, herein all of percentage, number, ratio etc. are by weight.
The material of this paper, method and embodiment are exemplary, and unless stated otherwise, be should not be construed as restricted 's.
Details are as follows for the present invention:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, in parts by weight containing following component:Color stuffing:0.2-35 parts, bear Ion powder:0.2-35 parts, paraffin:0.5-15 parts, synthetic resin emulsion:8-85 parts, thickener:0.2-3.5 parts, preservative: 0.1-1.5 parts, silver ion:0.01-3.5 parts.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including the face of 0.2-35 parts Filler, more preferably 0.2-15 parts, more preferably 0.5-5 parts, the color stuffing that adopts of the present invention for kaolin, white carbon, At least one in diatomite, calcium carbonate, alumina silicate, mica, talcum powder, silica flour, silicon powder, aluminum oxide, the color stuffing It is incorporated as improving resistance to ag(e)ing, mechanical strength and chemical resistance of the cured layer that anion spray is formed etc. there is provided technology Support.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including 0.2-35 parts is negative Ion powder, more preferably 5-35 parts, more preferably 10-35 parts, the negative ion powder that the present invention is adopted is human use's nature Boundary produce anion principle, a kind of artificial synthesized or proportioning complex mineral, typically all tourmaline powder+lanthanide series or Person's rare earth element, its main composition is as shown in the table:
Composition Al2O3 SiO2 B2O3 MgO Fe2O3 Na2O
Content (%) 35.10 34.81 11.02 4.70 10.18 0.91
Composition K2O CaO P2O5 TiO2 FeO Other
Content (%) 0.04 It is micro 0.22 0.26 1.35 It is micro
Its mesh number is 500-10000, more preferably 2000-8000, and negative ion powder is that chemical general formula is XY3Z6[Si6018] (BO3)3(OH)4, the wherein position of X mainly occupies by Na, Ca, K, and the position of Y is mainly occupied by Mg, Fe, A1, Li, the position of Z Mainly occupied by A1, due to the difference of X, Y, the displacement of Z location and soil boy structure, define numerous species, when Y is with Mg Magnesium imperial or royal seal prismatic crystal powder when main.Negative ion powder provides technology for the cured layer anion releasing for being aided with the formation of anion spray Hold.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including the stone of 0.5-15 parts Wax, more preferably 0.5-10 parts, more preferably 1-5 parts, the paraffin that the present invention is adopted also known as crystalline wax, typically white, Tasteless waxy solid, in 47-64 DEG C of fusing, density about 0.9g/cm3, be dissolved in gasoline, carbon disulfide, dimethylbenzene, ether, benzene, The class non-polar solven of chloroform, carbon tetrachloride, naphtha etc. one, water insoluble and methyl alcohol polar solvent.Paraffin refined wax is good Insulator, its resistivity is 1013-1017Ohm meter, than the most of materials in addition to some plastics (especially Teflon) all Will height.Paraffin is also good heat accumulating, and its specific heat capacity is 2.14-2.9JgK, and heat of fusion is 200-220Jg.Stone Wax, to the neutron source (such as radium-beryllium neutron source) with strong γ backgrounds, is further fitted as hydrogenous material with good absorption seed The effect of degree shielding neutron, more preferably, paraffin is had than paraffin more using modified polyvinyl paraffin wax, polyvinyl paraffin wax High fusion temperature and lower surface energy, are more beneficial for being migrated to air surface, transport efficiency in anion spray system 30% is up to than paraffin.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including the synthesis of 8-85 parts Resin emulsion, more preferably 25-65 parts, more preferably 25-55 parts, as long as the synthetic resin emulsion that adopts of the present invention can be with The various synthetic resin emulsions of cementation are played, is made in order to it is preferably supporting with the air channel of air-conditioning, air purifier With preferred pure-acrylic emulsion, styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion, polyaminoester emulsion, epoxy resin latex and propylene yogurt One kind or its mixture in liquid, the viscosity of the synthetic resin emulsion is 300-1000cp, and solid content is 20-40wt%, PH value is 8-9, and acid number is 40-60, and the synthetic resin emulsion acts primarily as cementation, and the other materials in anion spray are glued Altogether, to produce firm adhesion with base material.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including 0.2-3.5 parts Thickener, more preferably 0.5-3 parts, more preferably 1-2.5 parts, the thickener that the present invention is adopted is good to have with the system The characteristics such as thickening well, suspension, dispersion, emulsification, bonding, film forming, protection moisture and offer protection adhesive tape, can specifically select hydroxyl At least one in ethyl cellulose type thickener, alkali soluble is swollen acrylic thickener, sodium bentonite.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including 0.1-1.5 parts Preservative, more preferably 0.3-1.2 parts, more preferably 0.5-1.0 parts, the present invention adopt preservative act as postpone Growth of microorganism causes anion spray corrupt, can for hydroxybenzoate class, imidazolidinyl urea, KF88, bronopol, One kind or its mixture in 1- phenoxy group propan-2-ols etc., as long as addition specifies content less than products standards.
Wherein, magnesium imperial or royal seal prismatic crystal air channel provided by the present invention anion spray, by weight, including 0.01-3.5 parts Silver ion, more preferably 0.1-3 parts, more preferably 0.15-2.5 parts, the silver ion that adopts of the present invention be lose one with The silver ion of upper electronics, with ionic condition presence, generally in positive charge, such as Ag1+、Ag2+、Ag3+Deng.There is silver ion oxidation to make With being usually used in sterilizing in daily life.It not only has antisepsis and sterilization in the anion spray system of the present invention Effect, when also causing the cured film that anion spray is formed on air-conditioning, the air channel of air purifier, using in cured film Silver ion constitute loop produce induced current, reverse electromagnetic field is produced by induced current and is shielded.Metal good conductor energy Reflection electromagnetic wave, i.e., when wire netting aperture is less than electromagnetic wavelength (wavelength=light velocity/speed) 1/4, then electromagnetic wave can not be saturating Cross, so as to substantially increase the function such as antistatic, X-ray-preventing and ultraviolet of product.
Wherein, anion spray provided by the present invention, in parts by weight, also containing 3-10 part nano bamboo powdered carbons, nanometer Bamboo charcoal powder has loose porous structure, and the fine and closely woven porous of its molecule, quality is hard, there is a very strong adsorption capacity, can purify air, Eliminate peculiar smell, antibacterial expelling parasite;And it also has exceptional function that is releasing far infrared and isolating negative ion, further increases The anion releasing of anion spray and releasing far infrared function.
A kind of preparation method of magnesium imperial or royal seal prismatic crystal air channel anion spray, comprises the steps:
(1) at normal temperatures and pressures, by the synthetic resin emulsion of formula ratio 1/2-2/3, and formula ratio color stuffing, bear from Sub- powder and paraffin (nano bamboo powdered carbon) sequentially add high pressure and rush in mill apparatus, with the rotating speed stirring punching mill point of 1000-3000r/min Dissipate into suspension oar body;
(2) synthetic resin emulsion that be uniformly added into surplus is rushed in mill apparatus to high pressure, with the rotating speed of 1000-3000r/min After dispersed with stirring, vibration filtering;
(3) thickener, preservative and the silver ion of formula ratio are uniformly added into, are stirred with the rotating speed of 1000-3000r/min After being uniformly dispersed, packing.
Wherein, high pressure rushes the patented product that mill apparatus are our company, and its Patent No. " CN203842640U ", the equipment exists Allow mixed slurry to circulate under the drive of high-pressure pump, and mixed slurry is fully contacted with wear-resistant ball, and in stainless steel ball High-speed rotation, so that mixed slurry is sufficiently mixed uniformly.
Unless otherwise defined, all technologies used herein and scientific terminology have and those skilled in the art of the invention The identical meanings being generally understood that.If there is contradiction, it is defined by the definition that the application is provided, wherein:
Magnesium imperial or royal seal prismatic crystal is referred to chemical general formula as XY3Z6[Si6018](BO3)3(OH)4, wherein the position of X mainly by Na, Ca, K is occupied, and the position of Y is mainly occupied by Mg, Fe, A1, Li, and the position of Z is mainly occupied by A1, due to X, Y, Z location displacement with And the difference of soil boy structure, numerous species are defined, the tourmaline powder when Y is based on Mg.
Embodiment 1:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, it contains by weight following component:Color stuffing:0.2kg, anion Powder:35kg, paraffin:5kg, synthetic resin emulsion:57kg, thickener:0.5kg, preservative:0.2kg, silver ion:2.1kg;
The preparation method of magnesium imperial or royal seal prismatic crystal air channel anion spray, comprises the steps:
(1) at normal temperatures and pressures, by 38kg synthetic resin emulsions, and 0.2kg color stuffings, 35kg negative ion powders and 5kg Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 1000r/min and is dispersed into suspension oar body;
(2) synthetic resin emulsion that be uniformly added into 19kg is rushed in mill apparatus to high pressure, with the rotating speed stirring point of 1200r/min After dissipating, vibration filtering;
(3) 0.5kg thickeners, 0.2kg preservatives and 2.1kg silver ions are uniformly added into, are stirred with the rotating speed of 3000r/min Mix after being uniformly dispersed, dispense.
Wherein, it is 3 that negative ion powder is the negative ion powder of 1800 mesh and the negative ion powder of 6000 mesh according to mass ratio:1 mixing Uniformly;Color stuffing is kaolin:White carbon:Diatomite:Silica flour:Silicon powder:Aluminum oxide is 1 according to mass ratio:2:1:1:1:1 Mix;Wherein synthetic resin emulsion is pure-acrylic emulsion, and the viscosity of pure-acrylic emulsion is 500cp, and solid content is 25wt%, pH It is worth for 8, acid number is 50;Thickener is hydroxyethyl cellulose;Silver ion is liquid nano silver ion, and its silver ion effectively contains Measure as 3wt%.
Embodiment 2:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, it contains by weight following component:Color stuffing:18kg, anion Powder:16kg, paraffin:10kg, synthetic resin emulsion:51kg, thickener:1.2kg, preservative:0.8kg, silver ion:3kg;
The preparation method of magnesium imperial or royal seal prismatic crystal air channel anion spray, comprises the steps:
(1) at normal temperatures and pressures, by 34kg synthetic resin emulsions, and 18kg color stuffings, 16kg negative ion powders and 10kg Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 1500r/min and is dispersed into suspension oar body;
(2) synthetic resin emulsion that be uniformly added into 17kg is rushed in mill apparatus to high pressure, with the rotating speed stirring point of 1000r/min After dissipating, vibration filtering;
(3) 1.2kg thickeners, 0.8kg preservatives and 3kg silver ions are uniformly added into, are stirred with the rotating speed of 2000r/min After being uniformly dispersed, packing.
Wherein, negative ion powder is 3000 tourmaline powder for mesh number;The color stuffing calcium carbonate:Alumina silicate:Mica:Talcum Powder:Silica flour:Silicon powder is 1 according to mass ratio:3:1:2:1:1 is well mixed;Synthetic resin emulsion is epoxy resin latex, and The viscosity of the synthetic resin emulsion is 800cp, and solid content is 30wt%, and pH value is 8, and acid number is 51;Thickener alkali soluble is swollen third Olefin(e) acid thickener;Silver ion is liquid nano silver ion, and the effective content of its silver ion is 3.5wt%.
Embodiment 3:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, it contains by weight following component:Color stuffing:25kg, anion Powder:20kg, paraffin:8kg, synthetic resin emulsion:44.8kg, thickener:0.7kg, preservative:1kg, silver ion:0.5kg;
The preparation method of magnesium imperial or royal seal prismatic crystal air channel anion spray, comprises the steps:
(1) at normal temperatures and pressures, by 22.4kg synthetic resin emulsions, and 25kg color stuffings, 20kg negative ion powders and 8kg Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 2000r/min and is dispersed into suspension oar body;
(2) synthetic resin emulsion for being uniformly added into 22.4kg is rushed in mill apparatus to high pressure, is stirred with the rotating speed of 1000r/min After dispersion, vibration filtering;
(3) 0.7kg thickeners, 1kg preservatives and 0.5kg silver ions are uniformly added into, are stirred with the rotating speed of 1500r/min After being uniformly dispersed, packing.
Wherein, the negative ion powder is 8000 tourmaline powder for mesh number;Color stuffing silica flour;Wherein described synthetic resin Emulsion is silicone acrylic emulsion, and the viscosity of silicone acrylic emulsion is 600cp, and solid content is 32wt%, and pH value is 8.4, and acid number is 55;It is described Thickener is the swollen acrylic thickener of alkali soluble;The silver ion is liquid nano silver ion, and the effective content of its silver ion is 7wt%.
Embodiment 4:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, it contains by weight following component:Color stuffing:30kg, anion Powder:25kg, paraffin:0.8kg, synthetic resin emulsion:40kg, thickener:2.2kg, preservative:0.6kg, silver ion:1.4kg;
The preparation method of magnesium imperial or royal seal prismatic crystal air channel anion spray, comprises the steps:
(1) at normal temperatures and pressures, by 25kg synthetic resin emulsions, and 30kg color stuffings, 25kg negative ion powders and 0.8kg Paraffin sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 1800r/min and is dispersed into suspension oar body;
(2) synthetic resin emulsion that be uniformly added into 15kg is rushed in mill apparatus to high pressure, with the rotating speed stirring point of 2000r/min After dissipating, vibration filtering;
(3) 2.2kg thickeners, 0.6kg preservatives and 1.4kg silver ions are uniformly added into, are stirred with the rotating speed of 3000r/min Mix after being uniformly dispersed, dispense.
Wherein, the negative ion powder is 10000 tourmaline powder for mesh number;The color stuffing is pressed for white carbon with talcum powder It is 2 according to mass ratio:1 is well mixed;Wherein synthetic resin emulsion is epoxy resin latex and ester-polyurethane resin emulsion according to quality Than for 1:1 is well mixed, and it is 350cp to mix the viscosity of synthetic resin emulsion, and solid content is 28wt%, and pH value is 9, and acid number is 60;Thickener is sodium hydroxyethyl cellulose base bentonite;Silver ion is liquid nano silver ion, and the effective content of its silver ion For 4.8wt%.
Embodiment 5:
A kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, it contains by weight following component:Color stuffing:30kg, anion Powder:0.5kg, paraffin:12kg, synthetic resin emulsion:43kg, thickener:3kg, preservative:1kg, silver ion:2.5kg, nanometer Bamboo charcoal powder:8kg;
The preparation method of magnesium imperial or royal seal prismatic crystal air channel anion spray, comprises the steps:
(1) at normal temperatures and pressures, by 28kg synthetic resin emulsions, and 30kg color stuffings, 0.5kg negative ion powders, 12kg The nano bamboo powdered carbon of paraffin and 8kg sequentially adds high pressure and rushes in mill apparatus, rushes mill with the rotating speed stirring of 2000r/min and is dispersed into Suspension oar body;
(2) synthetic resin emulsion that be uniformly added into 15kg is rushed in mill apparatus to high pressure, with the rotating speed stirring point of 3000r/min After dissipating, vibration filtering;
(3) 3kg thickeners, 1kg preservatives and 2.5kg silver ions are uniformly added into, with the rotating speed stirring point of 1000r/min After dissipating uniformly, packing.
Wherein, the negative ion powder is 6000 tourmaline powder for mesh number;Color stuffing silica flour;Wherein synthesized resin breast Liquid is polyaminoester emulsion, and the viscosity of the synthetic resin emulsion is 900cp, and solid content is 36wt%, and pH value is 8, and acid number is 55;The thickener is hydroxyethyl cellulose;The silver ion is liquid nano silver ion, and the effective content of its silver ion is 6wt%.
Performance test:
(1) each performance indications of the magnesium imperial or royal seal prismatic crystal air channel anion spray prepared by embodiment of the present invention 1-5 are examined Survey, concrete numerical value is as shown in table 1:
Table 1:Property indices
Project Standard is required Examination criteria
Condition in container It is in uniform state after stirring without lump HG/T2458-1993
Application property Spraying -----
Drying time (surface drying) h ≤2h GB/T1728-1989
Bin stability (1 year) Never degenerate HG/T2458-1993
Radioactive material radionuclides limitation Meet the index request of A class finishing materials GB6566-2010
Remarks:Wherein radiological safety detection method is:50cm × 50cm × 1.2cm common white glass is taken, is entered with 5g products Row even application, normal temperature 24h is pressed after being dried《GB6566-2010 radioactive material radionuclides limitations》Detected.
(2) in order to test the effect of the air channel anion spray anion releasing that embodiment of the present invention 1-5 is provided, and draw Enter 4 groups of contrast groups, contrast groups 1 not spray anion spray, contrast groups 2 with when preparation method with embodiment 2, difference Place is will to be added without paraffinic components;With embodiment 2, difference is to be added without to the proportioning and preparation method of contrast groups 3 Silver ion;With embodiment 2, difference is to be added without paraffin and silver ion component to the proportioning and preparation method of contrast groups 4, And we are measured using the method for anion static state emission measure and anion dynamic two kinds of test anions of generating capacity, wherein Anion static state emission measure method of testing be:1L products are taken, is contained with 1L measuring cups, with static anionic textiles instrument measuring cup is stretched into Middle test;The method of testing of anion dynamic emission amount is:Take 5 50cm × 50cm × 1.2cm common white glass, every common white Glass 5g products carry out even application, and spraying is inward-facing to make cloche, is placed on simple glass table top, and 1L burettes are fallen Cloche central authorities are placed in, after 15 minutes, are continued the anion in 15 minutes test burettes with dynamic anionic textiles instrument and is released High-volume.The technical indicator of gained is as shown in table 2:
The anion emission amount situation test of the anion spray of table 2
Project name Anion static state emission measure Anion dynamic emission amount (15 minutes)
Contrast groups 1 0 0
Contrast groups 2 300/cm3 3000/cm3More than
Contrast groups 3 300/cm3 7600/cm3More than
Contrast groups 4 300/cm3 2100/cm3More than
Embodiment 1 1000/cm3 35000/cm3More than
Embodiment 2 300/cm3 10000/cm3More than
Embodiment 3 517/cm3 17000/cm3More than
Embodiment 4 715/cm3 25000/cm3More than
Embodiment 5 250/cm3 8620/cm3More than
As shown in Table 2, by comparing contrast groups 1 and embodiment 1, there is the air-conditioning of coating anion spray or net Changing device air channel will greatly improve the anion concentration in space;By comparing contrast groups 2 and embodiment 1, have and add paraffinic components The anion dynamic emission amount of anion spray will be greatly improved, and the density that this is primarily due to paraffin itself is relatively low, and surface Tension force is little, easily migrates to air surface, and during anion spray use, paraffin drives negative ion powder to air surface Migration, increases the contact area of negative ion powder and air in system, so as to substantially increase the dynamic emission amount of negative ion powder; By comparing contrast groups 3 and embodiment 1, silver ion is added to also contribute to the raising of anion dynamic emission amount, this is main Pyroelectricity and the piezoelectricity having in negative ion powder is because, when silver ion is added in components system, air is even similar to The small changes such as flowing, it is easier to cause the electrical potential difference between composition crystal, so that air is ionized, the electricity for being hit The son water that closes on of attachment and oxonium ion simultaneously make it be converted into negative aeroion;By comparing embodiment 1-4, with anion Powder occupies the increase of ratio, and anion static state emission measure and dynamic generating capacity are substantially improved, and this has widened anion spray significantly The use range of agent, to provide technical support rich in anion in large space;In addition, in embodiment 5, introducing bamboo charcoal nano Powder, nano bamboo powdered carbon and anion form cooperative effect, not only can allow in space rich in anion, at the same nano bamboo powdered carbon from Body has strong adsorptivity, can also effectively remove humidity of peculiar smell in space and adjustment space etc..
By prepared by embodiments of the invention 1-5 into air channel anion spray be used to having with to flow through air-conditioning, air net In all parts 1 of contact surface 1a for changing the air contact of device, the part 1 includes heat exchanger, purifier housing, ventilation At least one in road and water receiving disk component, it can be used on the air channels such as baking oven, smoke exhaust ventilator, as shown in figure 1, i.e. in tool There are setting anion coating 2, the anion at least one contact surface 1a with the air contact in air-conditioning, air purifier Anion spray spraying of the coating 2 by described in embodiment of the present invention 1-5 is formed;Air with air-conditioning, air purifier by connecing Tactile surface 1a circulating ventilations so that the negative ion concentration more and more higher in whole space, have played negative ion powder release negative significantly The function of ionic weight, and be conducive to shielding neutron and transmitting electromagnetic wave, reduce the impact of neutron and electromagnetic wave to health.
More than, the only present invention preferably specific embodiment, but the protection domain invented is not limited thereto, any ripe Know those skilled in the art the invention discloses technical scope in, the change or replacement that can be readily occurred in all should be contained Cover within protection scope of the present invention.Therefore, protection scope of the present invention should be defined by the protection domain of claims.

Claims (10)

1. a kind of magnesium imperial or royal seal prismatic crystal air channel anion spray, it is characterised in that in parts by weight containing following component:Color stuffing: 0.2-35 parts, negative ion powder:0.2-35 parts, paraffin:0.5-15 parts, synthetic resin emulsion:8-85 parts, thickener:0.2-3.5 Part, preservative:0.1-1.5 parts, silver ion:0.01-3.5 parts.
2. magnesium imperial or royal seal prismatic crystal air channel according to claim 1 anion spray, it is characterised in that in parts by weight containing as follows Component:Color stuffing:0.2-15 parts, negative ion powder:5-35 parts, paraffin:0.5-10 parts, synthetic resin emulsion:25-65 parts, thickening Agent:0.5-3 parts, preservative:0.3-1.2 parts, silver ion:0.1-3 parts.
3. magnesium imperial or royal seal prismatic crystal air channel according to claim 1 and 2 anion spray, it is characterised in that contain in parts by weight Following component:Color stuffing:0.5-5 parts, negative ion powder:10-35 parts, paraffin:1-5 parts, synthetic resin emulsion:25-55 parts, thickening Agent:1-2.5 part, preservative:0.5-1 parts, silver ion:0.15-2.5 parts.
4. the magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of claims 1 to 3, it is characterised in that described negative Ion powder is the tourmaline powder that mesh number is 500-10000, and the color stuffing is kaolin, white carbon, diatomite, calcium carbonate, silicon At least one in sour aluminium, mica, talcum powder, silica flour, silicon powder, aluminum oxide.
5. the magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of Claims 1 to 4, it is characterised in that the conjunction Resin emulsion is pure-acrylic emulsion, styrene-acrylic emulsion, vinyl acetate emulsion, silicone acrylic emulsion, polyaminoester emulsion, epoxy resin latex and propylene One kind or its mixture in yogurt liquid, and the viscosity of the synthetic resin emulsion is 300-1000cp, solid content is 20- 40wt%, pH value is 8-9, and acid number is 50-60.
6. the magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of Claims 1 to 5, it is characterised in that the increasing Thick dose is at least one in hydroxyethyl cellulose, alkali soluble is swollen acrylic thickener, sodium bentonite.
7. the magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of claim 1~6, it is characterised in that the silver Ion is liquid nano silver ion, and the effective content of its silver ion is 3-8wt%.
8. the magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of claim 1~7, it is characterised in that with weight Part meter, the magnesium imperial or royal seal prismatic crystal air channel anion spray also contains 3-10 part nano bamboo powdered carbons.
9. a kind of preparation method of the magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of claim 1~8, it is special Levy and be, comprise the steps:
(1) by the synthetic resin emulsion of formula ratio 1/2-2/3, and the color stuffing of formula ratio, negative ion powder and paraffin (nano bamboo Powdered carbon) sequentially add high pressure and rush in mill apparatus, rush mill and be dispersed into suspension oar body;
(2) synthetic resin emulsion that be uniformly added into surplus is rushed in mill apparatus to high pressure, after high-speed stirred dispersion, vibration filtering;
(3) thickener, preservative and the silver ion of formula ratio are uniformly added into, after dispersed with stirring is uniform, packing.
10. a kind of magnesium imperial or royal seal prismatic crystal air channel anion spray according to any one of claim 1~8 has and is flowing through sky Application in tune, all parts of the contact surface of the air contact of air purifier.
CN201611169787.XA 2016-12-16 2016-12-16 Magnesium seal solitary crystal air flue anion spray as well as preparation method and application thereof Pending CN106634348A (en)

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CN108673679A (en) * 2018-04-24 2018-10-19 阜南县宇翔工艺品有限公司 A kind of preparation method of deodorizing antibiotic wicker plaiting article shoe rack
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